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重要传感材料荧光共轭聚合物PPESO_3的一种新的简便合成路线 被引量:8
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作者 张涛 范宏亮 +2 位作者 周建光 刘国良 金钦汉 《高等学校化学学报》 SCIE EI CAS CSCD 北大核心 2006年第5期853-855,共3页
A facile synthetic route for conjugated polymer PPESO3 was proposed,through which not only the procedure was simplified,but also the dealkylation by BBr3 was avoided,and therefore,the preparing difficulty and danger w... A facile synthetic route for conjugated polymer PPESO3 was proposed,through which not only the procedure was simplified,but also the dealkylation by BBr3 was avoided,and therefore,the preparing difficulty and danger were greatly reduced,which was obviously beneficial to the preparation and application of(PPESO3).At the same time,the interactions between(PPESO3) and nonionic surfactant(PVP) were investigated.The results indicate that the aggregation of polymer backbone was effectively broken up and the steady complexes consisted of PPESO3 and PVP were formed which would contribute to the preparation of highly sensitive bio-sensors due to the affinity of PVP to biological macromolecules. 展开更多
关键词 共轭聚合物 ppeso3 传感器 非离子表面活性剂 聚乙烯吡咯烷酮
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表面活性剂对水溶性荧光聚合物PPESO_3荧光性质的影响 被引量:1
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作者 李东 窦文超 +1 位作者 邹申 苏星光 《吉林大学学报(理学版)》 CAS CSCD 北大核心 2008年第5期978-982,共5页
研究几种不同类型的表面活性剂对所合成的新型水溶性荧光聚合物PPESO3(聚[5,3-二(3-磺酰化丙氧基)-1,4-苯撑乙烯])的作用.结果表明,阴离子表面活性剂SDS可使PPESO3荧光发生猝灭;中性表面活性剂使得聚合物的荧光显著增强;阳离子表面活性... 研究几种不同类型的表面活性剂对所合成的新型水溶性荧光聚合物PPESO3(聚[5,3-二(3-磺酰化丙氧基)-1,4-苯撑乙烯])的作用.结果表明,阴离子表面活性剂SDS可使PPESO3荧光发生猝灭;中性表面活性剂使得聚合物的荧光显著增强;阳离子表面活性剂一般情况下也会使聚合物荧光增强.利用表面活性剂对荧光聚合物的荧光增强作用可使这类聚合物成为一种新型的具有高灵敏性的荧光化学传感器. 展开更多
关键词 荧光聚合物 表面活性剂 聚[5 3-二(3-磺酰化丙氧基)-1 4-苯撑乙烯]
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