There were four doublets in the Mssbauer spectrum of cucumber (Cucumis sativus L.) photosystemⅡ (PSⅡ) particles. According to the value of isomer shift and quadrupole splitting, they represented oxidized cytochrome ...There were four doublets in the Mssbauer spectrum of cucumber (Cucumis sativus L.) photosystemⅡ (PSⅡ) particles. According to the value of isomer shift and quadrupole splitting, they represented oxidized cytochrome b559 (Cyt_b559), reduced Cyt_b559, Fe 3+ _quinone (Q) complex, and Fe 2+ _Q complex respectively. After water_stress, the electron transport rate between Q A (primary quinone electron acceptor of PSⅡ)/Q B(secondary quinone electron acceptor of PSⅡ) was affected and the absorption doublets of Fe 2+ disappeared, suggesting that the reduced Cyt_b559 and Fe 2+ _Q complex had been oxidized. The results indicated that water_stress had changed the redox status of iron in the iron_quinone complex. Iron took part in electron transport through the change from a state of reduction to oxidation.展开更多
Fe_3O_4/PS magnetic particles with core/shell structure has been prepared in the presence of Fe3O4 magnetic fluid in ethanol/water mixture.Magnetic particles with diameter size range from 5. 54 t0 187. 32 μm were obt...Fe_3O_4/PS magnetic particles with core/shell structure has been prepared in the presence of Fe3O4 magnetic fluid in ethanol/water mixture.Magnetic particles with diameter size range from 5. 54 t0 187. 32 μm were obtained by different reaction conditions.Some parameters such as ethanol, PEG and monomer which affect particle size diameter and size distribution are discussed briefly in this paper.展开更多
Mossbauer spectrum measured for the iron components of photosystem Ⅱ (PS Ⅱ ) particles of spinach is a superposition of 4 doublets. Quadrupole splitting and chemical shifting of doublets I -IV are characteris-tics o...Mossbauer spectrum measured for the iron components of photosystem Ⅱ (PS Ⅱ ) particles of spinach is a superposition of 4 doublets. Quadrupole splitting and chemical shifting of doublets I -IV are characteris-tics of proteins with oxidized cytochrome b-559, reduced cytochrome b-559, Fe3 + -Q complex and Fe2+ -Q complex re-spectively . After the PS II particles are treated with La3+ , two doublets of Fe2+ disappear and Fe2+ is converted into Fe3+ , indicating that the reduced cytochrome b-559 has been converted into the oxidized cytochrome b-559, and Fe2+-Q complex into Fe3+-Q complex. The Mossbauer spectrum of PS II particles treated with La3+ and Ca2+ shows that Ca2+ can weaken the inhibitory effect of La3+ in part, and a portion of the reduced cytochrome b-559 and Fe-Q complex still exist.展开更多
To effectively predict the permeability index of smelting process in the imperial smelting furnace, an intelligent prediction model is proposed. It integrates the case-based reasoning (CBR) with adaptive par- ticle ...To effectively predict the permeability index of smelting process in the imperial smelting furnace, an intelligent prediction model is proposed. It integrates the case-based reasoning (CBR) with adaptive par- ticle swarm optimization (PSO). The nmnber of nearest neighbors and the weighted features vector are optimized online using the adaptive PSO to improve the prediction accuracy of CBR. The adaptive inertia weight and mutation operation are used to overcome the premature convergence of the PSO. The proposed method is validated a compared with the basic weighted CBR. The results show that the proposed model has higher prediction accuracy and better performance than the basic CBR model.展开更多
文摘There were four doublets in the Mssbauer spectrum of cucumber (Cucumis sativus L.) photosystemⅡ (PSⅡ) particles. According to the value of isomer shift and quadrupole splitting, they represented oxidized cytochrome b559 (Cyt_b559), reduced Cyt_b559, Fe 3+ _quinone (Q) complex, and Fe 2+ _Q complex respectively. After water_stress, the electron transport rate between Q A (primary quinone electron acceptor of PSⅡ)/Q B(secondary quinone electron acceptor of PSⅡ) was affected and the absorption doublets of Fe 2+ disappeared, suggesting that the reduced Cyt_b559 and Fe 2+ _Q complex had been oxidized. The results indicated that water_stress had changed the redox status of iron in the iron_quinone complex. Iron took part in electron transport through the change from a state of reduction to oxidation.
文摘Fe_3O_4/PS magnetic particles with core/shell structure has been prepared in the presence of Fe3O4 magnetic fluid in ethanol/water mixture.Magnetic particles with diameter size range from 5. 54 t0 187. 32 μm were obtained by different reaction conditions.Some parameters such as ethanol, PEG and monomer which affect particle size diameter and size distribution are discussed briefly in this paper.
基金Project supported by the National Natural Science Foundation of China and the Natural Science Foundation of the Chinese Educational Commission.
文摘Mossbauer spectrum measured for the iron components of photosystem Ⅱ (PS Ⅱ ) particles of spinach is a superposition of 4 doublets. Quadrupole splitting and chemical shifting of doublets I -IV are characteris-tics of proteins with oxidized cytochrome b-559, reduced cytochrome b-559, Fe3 + -Q complex and Fe2+ -Q complex re-spectively . After the PS II particles are treated with La3+ , two doublets of Fe2+ disappear and Fe2+ is converted into Fe3+ , indicating that the reduced cytochrome b-559 has been converted into the oxidized cytochrome b-559, and Fe2+-Q complex into Fe3+-Q complex. The Mossbauer spectrum of PS II particles treated with La3+ and Ca2+ shows that Ca2+ can weaken the inhibitory effect of La3+ in part, and a portion of the reduced cytochrome b-559 and Fe-Q complex still exist.
基金supported by the by the National Natural Science Foundation(No.60874069,60634020)the National High Technology Research and Development Programme of China(No.2009AA04Z124)Hunan Provincial Natural Science Foundation of China(No.09JJ3122)
文摘To effectively predict the permeability index of smelting process in the imperial smelting furnace, an intelligent prediction model is proposed. It integrates the case-based reasoning (CBR) with adaptive par- ticle swarm optimization (PSO). The nmnber of nearest neighbors and the weighted features vector are optimized online using the adaptive PSO to improve the prediction accuracy of CBR. The adaptive inertia weight and mutation operation are used to overcome the premature convergence of the PSO. The proposed method is validated a compared with the basic weighted CBR. The results show that the proposed model has higher prediction accuracy and better performance than the basic CBR model.