The Morphology of Patterning with Pseudoplastic Metal Nanoparticle Fluids during Heat Treatment

A pseudoplastic metal nanoparticle fluid （PMNF） is used in nanoimprint to fabricate semiconductors and func- tional devices. The evaporation of the solvent and the sintering of the Au PMNF are investigated. The key parameters, which influence the morphology of patterning, such as the radius of metal particles, the concentra- tion of metal particles, the Hamaker constant of the solvent, viscosity of the fluids and the evaporation velocity, are analyzed. Based on a two-sphere sintering model, the equations are derived, which represent the relationships between the relative shrinkage and radius of the metal particles, sintering temperature and time. The optimal parameters for the heat treatment are provided in nanoimprint.

Fully Developed Convective Heat Transfer of Power Law Fluids in a Circular Tube

We present a theoretical analysis for fully developed convective beat transfer in a circular tube for power law fluids by assuming that the thermal diffusivity is a function of temperature gradient. The analytical eolution is obtained and the heat transfer behaviour is investigated under a constant heat flux boundary condition. It is shown that the Nusselt number strongly depends on the value of power law index n. The Nusselt number sharply decreases in the range of 0 〈 n 〈 0.1. However, for n 〉 0.5, the Nusselt number decreases monotonically with the increasing n, and for n 〉 20, the values of Nusselt number approach a constant.

Chaotic Characteristics of Bubbles Rising with Coalescences in Pseudoplastic Fluid

The chaotic characteristics of bubbles rising with accompanying coalescences in pseudoplastic aqueous carboxymethylcellulose sodium(CMC)solution were studied by means of smoothed pseudo Wigner-Ville distribution and Wigner-Hough distribution.The temporal signal of bubble passage was measured utilizing a photoconductive data acquisition system.As bubble coalescence occurred,the smoothed pseudo Wigner-Ville distribution of the signal revealed that the signal could be divided into low-frequency and high-frequency ranges and the transition range according to the distribution feature of frequency domain,which reflected eddy motion of fluid,high frequency fluctuations of fluid velocity and other random components measured in the signal,and bubbles rising accompanied with coalescences,respectively.However,bubble coalescence occurred in the lower position and the frequency range of bubbles motion became wide under higher gas flowrate,while the frequency range of bubbles motion became narrow when the CMC concentration increased.The typical dynamics of bubbles motion,such as periodicity,bifurcation and chaos,could be easily found in terms of the Wigner-Hough distribution.

Rheological properties of low consistency TMP from thinning wood of Chinese Fir

The rheological behavior of low consistency thermomechanical pulp of Chinese fir harvested by intermediate thinning was analyzed. The results show that the apparent viscosity of pulp changed along with the beating degree, pulp consistency and shearing velocity. With the increasing of pulp consistency, the apparent viscosity of pulp increased gradually. Beating degree of pulp had an effect on microstructure of pulp. The apparent viscosity of pulp declined as beating degree of pulp increased, and the apparent viscosity of pulp fell along with the shearing velocity increasing. Based on the results, the rheological models are set up. The models showed that the fluid types of the low consistency pulp could be described as pseudoplastics fluids （non-Newtonian fluids）.

Numerical Simulation and Analysis of Power Consumption and Metzner-Otto Constant for Impeller of 6PBT

Majority of non-Newtonian fluids are pseudoplastic with shear-thinning property, which means that the viscosity will be different in different parts of the stirred tank. In such mixing process, it is difficult to predict accurately the power consumption and mean shear rate for designing novel impeller. Metzner-Otto method is a widely accepted method to solve these questions in mixing non-Newtonian fluids. As a result, Metzner-Otto constant will become a key factor to achieve an optimum way of economical mixing. In this paper, taking glycerine and xanthan gum solutions as research system, the power consumption, stirred by the impeller composed of perturbed six-bent-bladed turbine （6PBT） with differently geometrical characteristics in a cylindrical vessel, is studied by means of computational fluid dynamics （CFD）. The flow is modeled as laminar and a multiple reference frame （MRF） approach is used to solve the discretized equations of motion. In order to determine the capability of CFD to forecast the flow process, the torque test experiment is used to measure the glycerine solution power consumption. The theological properties of the xanthan gum solutions are determined by a Brookfleld rheometer. It is observed that the power consumption predicted by numerical simulation agrees well with those measured using torque experiment method in stirring glycerine solution, which validate the numerical model. Metzner-Otto constant is almost not correlated with the flow behavior index of pseudoplastic fluids. This paper establishes the complete correlations of power constant and Metzner-Otto constant with impeller geometrical characteristics through linear regression analysis, which provides the valuable instructions and references for accurately predicting the power consumption and mean shear rate of pseudoplastic fluids in laminar flow, comparatively.

MORPHOLOGICAL MODEL FOR RHEOLOGICAL PROPERTIES OF PLANT CELL SUSPENSION CULTURE SYSTEM

This paper puts forward a physical and mathematical model for the rheological properties of a plant cell suspension culture system.The model can explain why the system is pseudoplastic satisfactorily,thus the rheological properties of the system as the effect of the flow behavior index on plant cell concentration are interpreted correctly and the mechanism of the rheological properties of the system is further understood.Therefore the model can be applied in the technological design and optimum conditions of the system and the reformation,evaluation and scale up of reactors.

Experimental Study of Pseudoplastic Fluid Flows in a Square Duct of Strong Curvature

In this paper, laminar and turbulent flows of pseudoplastic fluids(0.1% and 0.2% by weight aqueous solutions of carboxymethylcellulose) in a square duct of strong curvature were measured using an ultrasonic Doppler velocimetry and microphones. Streamwise velocity in cross-sections of the duct and the fluctuating pressure on walls were measured for different flow rates. The velocity contours and their development along the duct were presented and compared with benchmark experiments by Taylor, Whitelaw and Yianneskis(1982) which were for the laminar and turbulent flows of water. The spectra of fluctuating wall pressures were also presented and analyzed. The objective of this paper was to provide a basis for understanding the pseudoplastic fluid flows in curved ducts. The results were also intended for use in the further development of numerical methods and turbulence models for shear-thinning fluids.