Polyacrylate-based conductive coatings were prepared from polyacrylate emulsion as matrix and carbon black (CB) whose surface was treated with titanate coupling agent as conducting particles.One kind of organic crysta...Polyacrylate-based conductive coatings were prepared from polyacrylate emulsion as matrix and carbon black (CB) whose surface was treated with titanate coupling agent as conducting particles.One kind of organic crystal was added to study its effects on the electrical conductivity and PTC(positive temperature coefficient)effect of the conductive coatings.Experimental results show that the coatings containing only polyacrylate emulsion and CB exhibit an excellent electrical conductivity but bad PTC effect,and when organic crystal is added,PTC effect is characterized and can increase by 2 orders of magtitude.The critical transformation temperature of polyacrylate emulsion/CB PTC composites is decided by melting point of organic crystals.展开更多
（Ca, Mn）-codoped Ba1-xSrxTiO3 （BST） solid solution, i.e. Ba0.4Sr0.5Ca0.08Mn0.02TiO3, was successfully synthesized via sol-gel process. The product was characterized by TG-DTA thermal analyses, XRD, TEM. The effect...（Ca, Mn）-codoped Ba1-xSrxTiO3 （BST） solid solution, i.e. Ba0.4Sr0.5Ca0.08Mn0.02TiO3, was successfully synthesized via sol-gel process. The product was characterized by TG-DTA thermal analyses, XRD, TEM. The effects of both curing temperature and applied voltage on the resistance, etc. were investigated. It showed that the structure of BST was unable to be changed even though it was codoped by Ca^2＋ and Mn^2＋. TEM photographs demonstrated the influence of curing temperature on the morphologies of the tested samples. The dependence of resistance on the curing temperature illustrated that （Ca, Mn）-codoped BST was capable of exhibiting the positive temperature coefficient （PTC） effect at low frequency; nevertheless, it might display the negative temperature coefficient （NTC） effect at other frequencies. The relationships between the resistance and applied voltage revealed that the resistance property of （Ca, Mn）-codoped BST appeared at low frequencies, but its property of capacitive reactance might present at high frequency. These findings mean that the electrical property of BST can be adjusted by codoping method. These phenomena can be explained by the grain boundary resistance effect, Heywang model and ion polarization theory.展开更多
文摘Polyacrylate-based conductive coatings were prepared from polyacrylate emulsion as matrix and carbon black (CB) whose surface was treated with titanate coupling agent as conducting particles.One kind of organic crystal was added to study its effects on the electrical conductivity and PTC(positive temperature coefficient)effect of the conductive coatings.Experimental results show that the coatings containing only polyacrylate emulsion and CB exhibit an excellent electrical conductivity but bad PTC effect,and when organic crystal is added,PTC effect is characterized and can increase by 2 orders of magtitude.The critical transformation temperature of polyacrylate emulsion/CB PTC composites is decided by melting point of organic crystals.
文摘（Ca, Mn）-codoped Ba1-xSrxTiO3 （BST） solid solution, i.e. Ba0.4Sr0.5Ca0.08Mn0.02TiO3, was successfully synthesized via sol-gel process. The product was characterized by TG-DTA thermal analyses, XRD, TEM. The effects of both curing temperature and applied voltage on the resistance, etc. were investigated. It showed that the structure of BST was unable to be changed even though it was codoped by Ca^2＋ and Mn^2＋. TEM photographs demonstrated the influence of curing temperature on the morphologies of the tested samples. The dependence of resistance on the curing temperature illustrated that （Ca, Mn）-codoped BST was capable of exhibiting the positive temperature coefficient （PTC） effect at low frequency; nevertheless, it might display the negative temperature coefficient （NTC） effect at other frequencies. The relationships between the resistance and applied voltage revealed that the resistance property of （Ca, Mn）-codoped BST appeared at low frequencies, but its property of capacitive reactance might present at high frequency. These findings mean that the electrical property of BST can be adjusted by codoping method. These phenomena can be explained by the grain boundary resistance effect, Heywang model and ion polarization theory.
