Performance characterization of rigid polyurethane foam with refined alkali lignin and modified alkali lignin

The two kinds of rigid polyurethane(PU) foams were prepared with respectively adding the refined alkali lignin and alkali lignin modified by 3-chloro-1,2-epoxypropane to be instead of 15% of the polyether glycol in weight.The indexes of mechanical performance, apparent density, thermal stability and aging resistance were separately tested for the prepared PU foams.The results show that the mechanical property, thermal insulation and thermal stability for PU foam with modified alkali lignin are excellent among two kinds of PU foams and control samples.The additions of the refined alkali lignin and modified alkali lignin to PU foam have little effect on the natural aging or heat aging resistance except for decreasing hot alkali resistance apparently.Additionally, the thermal conductivity of modified alkali lignin PU foam is lowest among two kinds of PU foams and control samples.The alkali lignin PU foam modified by 3-chloro-1,2-epoxypropane could be applied in the heat preservation field.

Alcoholysis of Waste Polyurethane Rigid Foam and Its Modification with Lignin for Recovery

A bi-component alcoholysis agent containing propylene glycol(PG)and ethanolamine(ETA)was used to catalyst the degradation of the waste polyurethane rigid foam.The oligomer polyols obtained through degradation were used as raw materials to produce recycled polyurethane rigid foam composites with lignin as reinforcing filler.The effect of alcoholysis mass ratio on degradation was investigated by analyzing the viscosity,hydroxyl content and chemical structure of the degradation products.The effect of lignin addition on the properties of regenerated polyurethane rigid foam were investigated by analyzing water absorption rate,compressive strength,porosity,thermal stability,thermal conductivity coefficient,morphology and thermal stability of the recycled polyurethane rigid foam.Results show that different mass ration of PG to ETA significantly affects the degradation of waste polyurethane rigid foam.Besides,only with the addition of appropriate amount of lignin,the regenerated polyurethane rigid foam composites can meet the Chinese national standard“rigid polyurethane foam for building thermal insulation”(GB/T21558-2008).At this point,the composite is with good mechanical and thermal prperties,including high compressive strength,excellent thermal insulation performance,complete cell morphology and good thermal stability.