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A low-noise X-band microwave source with digital automatic frequency control for electron paramagnetic resonance spectroscopy
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作者 贺羽 康润琪 +1 位作者 石致富 荣星 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第8期46-51,共6页
We report a new design of microwave source for X-band electron paramagnetic resonance spectrometer.The microwave source is equipped with a digital automatic frequency control circuit.The parameters of the digital auto... We report a new design of microwave source for X-band electron paramagnetic resonance spectrometer.The microwave source is equipped with a digital automatic frequency control circuit.The parameters of the digital automatic frequency control circuit can be flexibly configured for different experimental conditions,such as the input powers or the quality factors of the resonator.The configurability makes the microwave source universally compatible and greatly extends its application.To demonstrate the ability of adapting to various experimental conditions,the microwave source is tested by varying the input powers and the quality factors of the resonator.A satisfactory phase noise as low as-135 d Bc/Hz at 100-k Hz offset from the center frequency is achieved,due to the use of a phase-locked dielectric resonator oscillator and a direct digital synthesizer.Continuous-wave electron paramagnetic resonance experiments are conducted to examine the performance of the microwave source.The outstanding performance shows a prospect of wide applications of the microwave source in numerous fields of science. 展开更多
关键词 electron paramagnetic resonance X-BAND microwave source automatic frequency control
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Temperature-Dependent Formation of Redox Sites in Molybdenum Trioxide Studied by Electron Paramagnetic Resonance Spectroscopy
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作者 谭天 陈明 +1 位作者 苏吉虎 杜江峰 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2019年第6期657-660,I0002,共5页
The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature depend... The formation and qualification of redox sites in transition metal oxides are always the active fields related to electronics, catalysis, sensors, and energy-storage units. In the present study, the temperature dependence of thermal reduction of MoO3 was surveyed at the range of 350℃ to 750℃. Upon reduction, the formed redox species characterized by EPR spectroscopy are the MoVion and superoxide anion radical (O2-) when the reduction was induced at the optimal temperature of 300-350℃. When heating-up from 350℃, the EPR signals started to decline in amplitude. The signals in the range of 400-450℃ decreased to half of that at 350℃, and then to zero at ~600℃. Further treatment at even higher temperature or prolonged heating time at 500℃ caused more reduction and more free electrons were released to the MoO3 bulk, which results in a delocalized means similar to the antiferromagnetic coupling. These data herein are helpful to prepare and study the metal-oxide catalysts. 展开更多
关键词 MOO3 Thermal reduction Mo~Ⅴ Superoxide anion radical Electron paramagnetic resonance spectroscopy
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Identification of Superoxide O2^- during KNO3-NaNO2-NaNO3 Salt by Electron UV-Vis Absorption Spectroscopy Thermal Decomposition of Molten Paramagnetic Resonance and
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作者 刘舒婷 苏涛 +2 位作者 张鹏 费泽杰 刘洪涛 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2017年第4期372-378,I0001,共8页
On account of excellent thermal physical properties, molten nitrates/nitrites salt has been widely employed in heat transfer and thermal storage industry, especially in concentrated solar power system. The thermal sta... On account of excellent thermal physical properties, molten nitrates/nitrites salt has been widely employed in heat transfer and thermal storage industry, especially in concentrated solar power system. The thermal stability study of molten nitrate/nitrite salt is of great importance for this system, and the decomposition mechanism is the most complicated part of it. The oxide species O2^2- and O2^- were considered as intermediates in molten KNO3-NaNO3 while hard to been detected in high temperature molten salt due to their trace concentration and low stability. In this work, the homemade in situ high temperature UV- Vis instrument and a commercial electron paramagnetic resonance were utilized to supply evidence for the formation of superoxide during a slow decomposition process of heat transfer salt (HTS, 53 wt% KNO3/40 wt% NaNO2/7 wt% NaNO3). It is found that the superoxide is more easily generated from molten NaNO2 compared to NaNO3, and it has an absorption band at 420-440 nm in HTS which red shifts as temperature increases. The band is assigned to charge-transfer transition in NaO2 or KO2, responsible for the yellow color of the molten nitrate/nitrite salt. Furthermore, the UV absorption bands of molten NaNO2 and NANO3 are also obtained and compared with that of HTS. 展开更多
关键词 Superoxide Decomposition of heat transfer salt High temperature UV-visible Electron paramagnetic resonance
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Electron paramagnetic resonance study of amphiphiles partitioning behavior in desiccation-tolerant moss during dehydration 被引量:3
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作者 Shu Jun Xu Wei Hong Chen +2 位作者 Ying Wen Chen Cui Fang Wang Yan Wang 《Chinese Chemical Letters》 SCIE CAS CSCD 2007年第7期865-868,共4页
Desiccation tolerance is a crucial characteristic for desert moss surviving in arid regions. Desiccation procedure always induces amphiphiles transferring from the polar cytoplasm into lipid bodies. The behavior of am... Desiccation tolerance is a crucial characteristic for desert moss surviving in arid regions. Desiccation procedure always induces amphiphiles transferring from the polar cytoplasm into lipid bodies. The behavior of amphiphiles transferring can contribute to the enhancement of desiccation tolerance and the reduction of plasma membrane integrity simultaneously. The effects of amphiphiles partitioning into the lipid phase during water loss has been studied for pollen and seeds using electron paramagnetic resonance (EPR) spectroscopy. However, desiccation-tolerant high plants occur among mosses, several angiosperms and higher plants seeds or pollens. They have different strategies for survival in dehydration and rehydration. A desiccation-tolerant moss Tortula desertorurn was used to investigate the behaviors of amphiphilic molecules during drying by spin label technology. There are small amount of amphiphilic probes partitioning into membrane during moss leaves dehydration, comparing with that in higher plants. Cytoplasm viscosity changed from 1.14 into glass state only dehydration less than 60 min. Moss leaves lost plasma membrane integrity slightly,from 0.115 to 0.237, occurred simultaneously with amphiphiles partition. The results showed the more advantages of mosses than higher plants in adapting fast dehydration. We propose that EPR spin label is feasible for studying the amphiphiles partitioning mechanisms in membrane protection and damage for desiccation-tolerant mosses. 展开更多
关键词 Plasma membrane permeability Amphiphiles partition Desiccation tolerance Electron paramagnetic resonance Tortula desertorum broth. MOSSES
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Electron paramagnetic resonance studies of the chelate-based ionic liquid in different solvents 被引量:3
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作者 Songna Zhang Xinyu Wang +1 位作者 Jia Yao Haoran Li 《Green Energy & Environment》 SCIE CSCD 2020年第3期341-346,共6页
The electron paramagnetic resonance spectra of the chelate-based ionic liquid[C_(10)mim][Cu(F_6-acac)_3]in different solvents have been obtained at 120 K.It was found that the values of the^(63)Cu hyperfine coupling c... The electron paramagnetic resonance spectra of the chelate-based ionic liquid[C_(10)mim][Cu(F_6-acac)_3]in different solvents have been obtained at 120 K.It was found that the values of the^(63)Cu hyperfine coupling constants(A_(IL))of[C_(10)mim][Cu(F_6-acac)_3]in molecular solvents were from 116 to 180 Gauss.Moreover,the A_(IL)values in general ionic liquids are more complicated,and two sets of peaks can often be observed in their electron paramagnetic resonance spectra.Based on the Kamlet-Taft parameters,relative permittivity,the experimental results were discussed in terms of solvation effect and coordination of the solvents. 展开更多
关键词 Chelate-based ionic liquid Probe Electron paramagnetic resonance spectra Solvents
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Electron paramagnetic resonance characterization of aluminum ion implantation-induced defects in 4H-SiC 被引量:1
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作者 Xiuhong Wang Zongwei Xua +4 位作者 Mathias Rommel Bing Dong Le Song Clarence Augustine TH Tee Fengzhou Fang 《Nanotechnology and Precision Engineering》 EI CAS CSCD 2019年第4期157-162,共6页
Deep-level defects in silicon carbide(SiC)are critical to the control of the performance of SiC electron devices.In this paper,deep-level defects in aluminumion-implanted 4H-SiC after high-temperature annealingwere st... Deep-level defects in silicon carbide(SiC)are critical to the control of the performance of SiC electron devices.In this paper,deep-level defects in aluminumion-implanted 4H-SiC after high-temperature annealingwere studied using electron paramagnetic resonance(EPR)spectroscopy at temperatures of 77 K and 123 K under different illumination conditions.Results showed that the main defect in aluminum ion-implanted 4H-SiC was the positively charged carbon vacancy(VC+),and the higher the doping concentration was,the higher was the concentration of VC+.Itwas found that the type of material defectwas independent of the doping concentration,although more VC+defects were detected during photoexcitation and at lower temperatures.These results should be helpful in the fundamental research of p-type 4H-SiC fabrication in accordance with functional device development. 展开更多
关键词 Electron paramagnetic resonance Silicon carbide DEFECTS Carbon vacancy
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Theoretical Studies of Electron Paramagnetic Resonance Parameters for Cr^4+ Ions in Ca2GeO4 Crystals
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作者 WUXiao-Xuan ZHENGWen-Chen MEIYang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2005年第2期337-340,共4页
The electron paramagnetic resonance (EPR) parameters (zero-Geld splitting Dand g factors g_‖, g_⊥) of Cr~(4+) ions in Ca_2 GeO_4 crystals have been calculated from thecomplete high-order perturbation formulas of EPR... The electron paramagnetic resonance (EPR) parameters (zero-Geld splitting Dand g factors g_‖, g_⊥) of Cr~(4+) ions in Ca_2 GeO_4 crystals have been calculated from thecomplete high-order perturbation formulas of EPR parameters for a 3d~2 ion in trigonal MX_4clusters. In these formulas, in addition to the contributions to EPR parameters from the widely usedcrystal-field (CF) mechanism, the contributions from the charge-transfer (CT) mechanism (which areoften neglected) are included. From the calculations, it is found that for the high valence state3d~n ions in crystals, the reasonable explanation of EPR parameters (in particular, the g factors)should take both the CF and CT mechanisms into account. 展开更多
关键词 crystal- and ligand-field theory electron paramagnetic resonance charge-transfer mechanism optical spectroscopy tunable laser crystal
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Electron Paramagnetic Resonance and Optical Absorption Studies on Copper Ions in Mixed Alkali Cadmium Phosphate Glasses
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作者 G. Giridhar M. Rangacharyulu +1 位作者 R.V.S.S.N. Ravikumar P. Sambasiva Rao 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2009年第4期531-534,共4页
Electron paramagnetic resonance (EPR) and optical absorption studies were carried out at room temperature on copper doped mixed alkali cadmium phosphate (LiNaCdP) glasses to understand the nature and symmetry of d... Electron paramagnetic resonance (EPR) and optical absorption studies were carried out at room temperature on copper doped mixed alkali cadmium phosphate (LiNaCdP) glasses to understand the nature and symmetry of dopant. Three samples with varying concentrations of alkali ions have been prepared. The spin Harniltonian parameters obtained from room temperature EPR spectra are: gli=2.437, 9⊥=2.096, A‖=117×10-4 cm-1, A⊥=26×10-4 cm-1 for LiNaCdP1, g‖=2.441, g⊥=2.088, A‖=121×10-4 cm-1, A⊥=25×10-4 cm-1 for LiNaCdP2and g‖=2.433,g⊥=2.096, A‖=125×10 4cm-1, A⊥=32×10-4cm-1 for LiNaCdP3. TheseEPR results indicate that the dopant Cu2+ ion enters the glass matrix into a tetragonally elongated octahedral site. The bonding parameters evaluated by correlating optical and EPR data suggest that bonding between the central metal ion and ligands is partially covalent. The mixed alkali effect in cadmium phosphate glasses was reported. 展开更多
关键词 GLASSES Electron paramagnetic resonance (EPR) Optical properties
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Effect of local structure on electron paramagnetic resonance spectra for trigonal [Cr(H_2O)_6]^(3+) coordination complex in the sulfate alums series:a ligand field theory study
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作者 李艳芳 邝小渝 +2 位作者 高明亮 赵亚儒 王怀谦 《Chinese Physics B》 SCIE EI CAS CSCD 2009年第7期2967-2974,共8页
A simple theoretical method is introduced for studying the interrelation between electronic and molecular structures.By diagonalizing the 120 × 120 complete energy matrices,the relationships between zero-field sp... A simple theoretical method is introduced for studying the interrelation between electronic and molecular structures.By diagonalizing the 120 × 120 complete energy matrices,the relationships between zero-field splitting (ZFS) parameter D and local distortion parameter △θ for Cr^3+ ions doped,separately,in α- and β- alums are investigated.Our results indicate that there exists an approximately linear relationship between D and △θ in a temperature range 4.2-297 K and the signs of D and △θ are opposite to each other.Moreover,in order to understand the contribution of spin-orbit coupling coefficient ζ to ZFS parameter D,the relation between D and ζ is also discussed. 展开更多
关键词 complete energy matrices electron paramagnetic resonance (EPR) spectra local structure
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Advancements and Prospects in Continuous Wave Time-resolved Electron Paramagnetic Resonance
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作者 ZHANG Shixue ZHOU Shengqi +1 位作者 WU Hao GUO Xingwei 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2024年第5期798-805,共8页
This brief review highlights the techniques and diverse applications of time-resolved electron paramagnetic resonance(TREPR)spectroscopy,underscoring its essential role in elucidating the structures,spin dynamics,and ... This brief review highlights the techniques and diverse applications of time-resolved electron paramagnetic resonance(TREPR)spectroscopy,underscoring its essential role in elucidating the structures,spin dynamics,and reactivities of open-shell systems.Furthermore,we discuss the limitations of traditional TREPR methodologies,particularly their challenges in directly observing reactive radical intermediates under real-world reaction conditions.Lastly,we present the latest advancements in TREPR technology developed in our laboratory,specifically ultrawide single-sideband phase-sensitive detection(U-PSD)TREPR,highlighting its significant impact and tremendous potential in advancing free radical chemistry research.We envision promising future applications of TREPR and its pivotal role in enhancing our understanding of mechanisms involved in complex radical processes and photocatalysis. 展开更多
关键词 Time-resolved electron paramagnetic resonance(TREPR) Ultrawide single-sideband phase-sensitive detection(U-PSD) Spin chemistry Radical chemistry PHOTOCHEMISTRY
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Elucidating solvent effects on the stability of phenoxyl radicals in monohydric alcohols via electron paramagnetic resonance
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作者 Xinyu Wang Wenjing Sun +1 位作者 Yongtao Wang Haoran Li 《Green Chemical Engineering》 EI CSCD 2024年第4期483-488,共6页
Research on solvent effects is an important and long-standing topic,but there still is some room,especially for the special solvent effect of fluoroalcohols.In this work,we investigated the stability of phenoxyl radic... Research on solvent effects is an important and long-standing topic,but there still is some room,especially for the special solvent effect of fluoroalcohols.In this work,we investigated the stability of phenoxyl radical in monohydric alcohol solvents through in-situ electron paramagnetic resonance detections.The decay behavior of phenoxyl radical showed a reasonable relationship with the mesoscopic structure of alcohols,characterized by smalland wide-angle X-ray scattering.Moreover,the distinct solvent effects of fluoroalcohols were emphasized,and the significant influence of van der Waals distance in the solvents was suggested.Overall,the stability of phenoxyl radical in alcohols was quantified and correlated with the solvent structures.We believe that the established method for stability study on radicals will encourage solvent effect studies on various organic reactions,and the proposed solvent effects in fluoroalcohols may inspire the development of green solvents in both industrial conversions and organic synthesis. 展开更多
关键词 Solvent effect FLUOROALCOHOL Phenoxyl radical STABILITY Electron paramagnetic resonance
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Developing in situ electron paramagnetic resonance characterization for understanding electron transfer of rechargeable batteries 被引量:1
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作者 Bin Wang Wanli Wang +5 位作者 Kang Sun Yujie Xu Yi Sun Qiang Li Han Hu Mingbo Wu 《Nano Research》 SCIE EI CSCD 2023年第10期11992-12012,共21页
Electrochemical energy storage devices are pivotal in achieving“carbon neutrality”by enabling the storage of energy generated from renewable sources.To facilitate the development of these devices,it is important to ... Electrochemical energy storage devices are pivotal in achieving“carbon neutrality”by enabling the storage of energy generated from renewable sources.To facilitate the development of these devices,it is important to gain insight into the underlying the single-/multi-electron transfer process.This can be achieved through in-time detection under operational conditions,but there are limited tools available for monitoring electron transfer under operando conditions.Electron paramagnetic resonance(EPR)is a powerful technique that can meet these expectations,as it is highly sensitive to unpaired electrons and can detect changes of paramagnetic centres.Despite the long history of in situ electrochemical EPR research,its potential has been surprisingly underutilized due to the need for strict operando cell design under special testing conditions.This review comprehensively summarizes recent efforts to understand energy storage mechanisms using in situ/operando EPR,with the aim of drawing researchers’attention to this powerful technique.After introducing the fundamental principles of EPR,we describe the critical advances made in detecting batteries using operando EPR,along with the remaining challenges and opportunities for future development of this technology in batteries.We emphasize the need for strict operando cell design and the importance of designing experiments that closely mimic real-world conditions.We believe that this review will provide innovative solutions to solve tough problems that researchers may encounter during their battery research,and ultimately contribute to the development of more efficient and sustainable energy storage devices. 展开更多
关键词 electron paramagnetic resonance in situ energy storage BATTERY
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Electron paramagnetic resonance in monitoring of nitric oxide production after kidney transplantation in rats 被引量:4
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作者 徐涛 陈希 +6 位作者 王晓峰 黄晓波 曲星珂 叶海云 张小东 侯树坤 朱积川 《Chinese Medical Journal》 SCIE CAS CSCD 2004年第10期1552-1557,共6页
Background Much research has been focused on ischemia/reperfusion injury (IRI) to the transplanted organs. As a free radical, nitric oxide (NO) plays an important role in IRI. In this study, the production of NO and ... Background Much research has been focused on ischemia/reperfusion injury (IRI) to the transplanted organs. As a free radical, nitric oxide (NO) plays an important role in IRI. In this study, the production of NO and its functions during IRI were monitored in rat models after allotransplantation of kidney grafts.Methods Of 75 male LEW rats, 30 served as donors, and the remaining 45 rats were divided into three groups (15 rats in each group): controls (group 1), kidney allotransplantation followed by bilateral nephrectomy during reperfusion (group 2), 2 hours before operation, donors and recipients were treated with NG-nitro L-arginine methyl ester (L-NAME), a NO synthase inhibitor, at a dose of 30 mg/kg (group 3). Bilateral nephrectomies were performed while kidney grafts were reperfused. The kidney grafts were hypothemically stored for 24 hours. The production of NO before and after reperfusion was measured by electron paramagnetic resonance (EPR). The creatinine level, the glomerular filtration rate (GFR) and the protein carbonyl content in tissue samples were recorded on the first and the fifth day after operation. The data were evaluated by one-way analysis of variance. Differences were considered to be statistically significant when a P value was less than 0.05.Results After reperfusion for 15 minutes, the production of NO increased remarkably and kept increasing till 120 minutes, after which the level returned to normal. In group 3, which was pretreated with L-NAME, creatinine levels were higher than those in group 2 at the 24th hour (4.10±0.50 mg/dl vs. 3.77±0.42 mg/dl, P<0.05) and the 120th hour (3.19±0.79 mg/dl vs. 2.22±0.53 mg/dl, P<0.05). GFR levels in group 3 were lower than those in group 2 at the 24th hour (0.50±0.12 ml/min vs. 0.71±0.19 ml/min, P<0.05) and the 120th hour (0.59±0.38 ml/min vs. 1.27±0.23 ml/min, P<0.01). The content of protein carbonyl in tissue samples of group 3 was lower than that in group 2 at the 24th hour (29.01±7.02 nmol/mg protein vs. 49.39±13.13 nmol/mg protein, P<0.05), but was higher than that at the 120th hour (75.71±16.74 nmol/mg protein vs. 57.93±15.32 nmol/mg protein, P<0.05).Conclusions After transplantation of hypothemically stored kidney grafts, the increased NO production in the early stage has protective effects on the transplanted kidney. Application of L-NAME to inhibit NO production is harmful to the recovery of the renal functions of kidney grafts. 展开更多
关键词 nitric oxide · kidney transplantation · ischemia/reperfusion injury · electron paramagnetic resonance
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Management of electron paramagnetic resonance spectrometer in a university core laboratory
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作者 Yingli Xu Guangcan Bai Jingfen Lu 《Journal of Chinese Pharmaceutical Sciences》 CAS CSCD 2019年第7期519-526,共8页
Electron Paramagnetic Resonance(EPR)is the only spectral method for direct detection of paramagnetic substances.EPR technology can be used for the qualitative and quantitative analysis of free radicals and transition ... Electron Paramagnetic Resonance(EPR)is the only spectral method for direct detection of paramagnetic substances.EPR technology can be used for the qualitative and quantitative analysis of free radicals and transition metals in solid,liquid,gas,cell and living samples.It is widely used in chemistry,material science,life science,quantum physics and other researches.This report discusses the basic principle,instrument structure,common problem solving,daily maintenance,and management model of the electron paramagnetic resonance spectrometer(German Bruker A-200)in the State Key Laboratory of Natural and Biomimetic Drugs of Peking University Health Science Center,so that the instrument can be fully used for various scientific researches. 展开更多
关键词 Electron paramagnetic resonance spectrometer Operational attention problem Instrument maintenance
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Development of 3-actoxymethoxycarbonyl-2,2,5,5-tetramethyl-1-pyrrolidinyloxyl as an electron paramagnetic resonance imaging reagent for in vivo mapping brain oxygen distribution and infarction in ischemic brain
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作者 Gerald M.Rosen 《生物物理学报》 CAS CSCD 北大核心 2009年第S1期101-101,共1页
Measurement of oxygen concentration and distribution in brain is essential to understanding the pathophysiology of stroke. Although brain oxygen level is critical for brain tissue survival,
关键词 Development of 3-actoxymethoxycarbonyl-2 2 5 5-tetramethyl-1-pyrrolidinyloxyl as an electron paramagnetic resonance imaging reagent for in vivo mapping brain oxygen distribution and infarction in ischemic brain
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Analysis of the electron transfer pathway in small laccase by EPR and UV-vis spectroscopy coupled with redox titration
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作者 Lu Yu Aokun Liu +3 位作者 Jian Kuang Ruotong Wei Zhiwen Wang Changlin Tian 《Magnetic Resonance Letters》 2024年第3期52-59,共8页
Bacterial small laccases(SLAC) are promising industrial biocatalysts due to their ability to oxidize a broad range of substrates with exceptional thermostability and tolerance for alkaline p H. Electron transfer betwe... Bacterial small laccases(SLAC) are promising industrial biocatalysts due to their ability to oxidize a broad range of substrates with exceptional thermostability and tolerance for alkaline p H. Electron transfer between substrate, copper centers, and O2is one of the key steps in the catalytic turnover of SLAC. However, limited research has been conducted on the electron transfer pathway of SLAC and SLAC-catalyzed reactions, hindering further engineering of SLAC to produce tunable biocatalysts for novel applications. Herein, the combinational use of electron paramagnetic resonance(EPR) and ultraviolet-visible(UV-vis) spectroscopic methods coupled with redox titration were employed to monitor the electron transfer processes and obtain further insights into the electron transfer pathway in SLAC. The reduction potentials for type 1 copper(T1Cu), type 2 copper(T2Cu) and type 3copper(T3Cu) were determined to be 367 ± 2 mV, 378 ± 5 m V and 403 ± 2 mV,respectively. Moreover, the reduction potential of a selected substrate of SLAC, hydroquinone(HQ), was determined to be 288 mV using cyclic voltammetry(CV). In this way, an electron transfer pathway was identified based on the reduction potentials. Specifically,electrons are transferred from HQ to T1Cu, then to T2Cu and T3Cu, and finally to O2.Furthermore, superhyperfine splitting observed via EPR during redox titration indicated a modification in the covalency of T2Cu upon electron uptake, suggesting a conformational alteration in the protein environment surrounding the copper sites, which could potentially influence the reduction potential of the copper sites during catalytic processes. The results presented here not only provide a comprehensive method for analyzing the electron transfer pathway in metalloenzymes through reduction potential measurements, but also offer valuable insights for further engineering and directed evolution studies of SLAC in the aim for biotechnological and industrial applications. 展开更多
关键词 Electron paramagnetic resonance Redox titration Electron transfer Reduction Potential Small laccase
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In Situ Electron Paramagnetic Resonance Reveals Fading Mechanism of Mn-Based Prussian Blue Analogue:Accelerated Mn Dissolution Due to Charge Delocalization
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作者 Xiaobing Lou Zonglin Li +4 位作者 Shinuo Kang Yufan Li Sen Ma Fushan Geng Bingwen Hu 《Renewables》 2024年第5期341-352,共12页
Contrasting with Fe-based Prussian blue analogues(PBAs),Mn-based PBAs with higher energy density are more promising cathode materials for Na-ion batteries.However,fast capacity fading has severely impeded its practica... Contrasting with Fe-based Prussian blue analogues(PBAs),Mn-based PBAs with higher energy density are more promising cathode materials for Na-ion batteries.However,fast capacity fading has severely impeded its practical use,which is still not well understood.To elucidate the fading mechanism,in situ and ex situ electron paramagnetic resonance are employed here.The results first demonstrate the charge delocalization of Mn2+and Mn dissolution during cycles,which are further proved to be highly related.Our work reveals the inherent shortcoming of Mn-based PBA cathodes in liquid electrolyte. 展开更多
关键词 electron paramagnetic resonance fading mechanism Prussian blue analogues sodium-ion batteries Mn dissolution
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Correlations between trace elements in pyrite and gold mineralization of gold deposits on the North China platform
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作者 Jianzhao Yin Ying Sun +4 位作者 Haoyu Yin Hongyun Shi James Sparling Yuhong Chao Shoupu Xiang 《Acta Geochimica》 EI CAS CSCD 2023年第6期1079-1103,共25页
By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform... By studying both the microscopic physical and chemical typomorphic characteristics of typical mineral pyrite samples associated with representative gold deposits on the north-central margin of the North China Platform,this paper seeks to identify macroscopic metallogenic mechanisms of gold deposits and to reveal the formation mechanism of lattice gold in pyrite.Typomorphic characteristics of pyrite reveal that pyrite grain size has a negative correlation with gold content.Cubic pyrite,as the dominant crystal form,contains more gold than pentagonal dodecahedral pyrite.Both pyrite crystal forms and chemical compositions indicate that the replacement style of gold deposit formed in a low saturability,low sulfur fugacity,and at temperatures either much higher or much lower than its best forming temperature;comparatively,that of the quartz vein style of gold deposit occurred under conditions with the best temperature,rich in sulfur,and with high sulfur fugacity.The Au/Ag ratios of the pyrites show that both the replacement and quartz vein styles of deposits are mesothermal and hypothermal,while the Co/Ni ratios of the pyrites indicate that the quartz vein style is of magmatic-hydrothermal origin.The X-ray diffraction intensity of pyrite rich in gold is lower than that of pyrite poor in gold at the quartz vein style.In general,with an increase in gold content in pyrite,the total sum intensityΣI decreases.The pyroelectricity coefficient has a negative correlation trend with the values of(Co+Ni+Se+Te)-As and(Co+Ni+Se+Te)/As.The pyrite pyroelectricity of the replacement style is N-type,indicating that it formed under low sulfur fugacity,while that of the quartz vein style is a mixture of P-N types,indicating that it formed under high sulfur fugacity.On the pyroelectricity-temperature diagram,pyrite of the replacement style is mainly distributed between 200 and 270°C,while that of the quartz vein style varies between 90–118 and274–386°C,demonstrating a multistage forming process.In contrast to previous researchers'conclusions,the authors confirm the existence of lattice gold in pyrites through the use of an electron paramagnetic resonance(EPR)test.Au in the form of Au~+,entering pyrite as an isomorph and producing electron–hole centers,makes the centers produce spin resonance absorption and results in EPR absorption peak II.The intensity of auriferous pyrite absorption peak II has certain direct positive correlations with pyrite gold content.The#I and#III absorption peaks of pyrites possibly result from the existence of Ni^(2+)and/or Cu^(2+).γ1,γ2,andγ3 are the strongest and most typical absorption peaks of the infrared spectra of the pyrites.Generally,with the increase in gold content in the pyrite samples,γ1,γ2,andγ3 tend to shift to higher wavenumbers,and the gold content in the pyrite samples has a positive correlation with their relative absorbance. 展开更多
关键词 Unit cell parameter PYROELECTRICITY Electron paramagnetic resonance Infrared spectrum PYRITE Gold deposit
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Thermoluminescent response of gamma irradiated Na^(+)–Cu^(+) ionexchanged silicate glass in large dose range
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作者 Safa Toumi Khaled Farah 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2023年第5期22-32,共11页
The introduction of metals into vitreous matrices is the origin of various interesting phenomena;in particular,the presence of copper ions in glass has been the subject of considerable research because of its numerous... The introduction of metals into vitreous matrices is the origin of various interesting phenomena;in particular,the presence of copper ions in glass has been the subject of considerable research because of its numerous applications.The ion-exchange process is primarily used to introduce copper ions into glass matrices.The thermoluminescence(TL)of silicate glass was studied to evaluate its potential as gamma-sensitive material for dosimetric applications;the effect of copper doping on the thermoluminescent sensitivity was investigated using the Cu-Na ion-exchange technique for different concentrations and doping conditions,over a wide dose range of 10 mGy to 100 kGy.The results showed that Cu doping significantly improved the sensitivity of the glasses to gamma radiation.After the ion-exchange,two peaks appeared in the glow curves at approximately 175 and 230°C,respectively,which possibly originated from the Cu^(+) centers,along with a weak TL peak at around 320℃.We also attempted to explain the origin of the observed thermoluminescence by exploiting the Electron paramagnetic resonance(EPR)spectra.The results clearly show quenching of the TL emission with increasing copper concentrations.The present work indicates that the thermoluminescence response of these glasses to gamma rays can be reasonably measured in the range of 0.001-100 kGy.This study also facilitates the understanding of the basic TL mechanism in this glass system. 展开更多
关键词 Cu-Na ion-exchange Silicate glass THERMOLUMINESCENCE Gamma irradiation Electron paramagnetic resonance
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Effects of Fe_(2)O_(3) content on microstructure and mechanical properties of CaO-Al_(2)O_(3)-SiO_(2) system 被引量:4
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作者 任祥忠 张卫 +2 位作者 章勇 张培新 刘剑洪 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第1期137-145,共9页
The effects of Fe2O3 content on the microstructure and mechanical properties of the CaO-Al2O3-SiO2 system were investigated by differential thermal analysis(DTA), X-ray diffraction(XRD), scanning electron microsc... The effects of Fe2O3 content on the microstructure and mechanical properties of the CaO-Al2O3-SiO2 system were investigated by differential thermal analysis(DTA), X-ray diffraction(XRD), scanning electron microscopy(SEM), electron spin resonance(ESR), and Mssbauer spectroscopy. The results show that the addition of Fe2O3 does not affect the main crystalline phase in the prepared glasses, but it reduces the crystallisation peak temperature, increases the crystallisation activation energy, and reduces the crystal granularity. The ESR results indicate that Fe2O3 can promote crystallization, as it leads to the phase separation of the CaO-Al2O3-SiO2 system due to axial distortion. Moreover, Fe2O3 alters the network structure of the CaO-Al2O3-SiO2 system, allowing Fe3+ to enter octahedral sites that exhibit higher symmetry than tetrahedral sites. All of these factors are favourable to increasing the bending strength. The Mssbauer results reveal that there are two types of coordination for both Fe3+ and Fe2+ and the bending strength of the CaO-Al2O3-SiO2 system increases with the amount of six-coordinate Fe3+. The increasing interaction between Fe3+ and Fe2+ can also enhance the bending strength of the CaO-Al2O3-SiO2 system. The microhardness of the CaO-Al2O3-SiO2 system was determined to be HV 896.9 and the bending strength to be 217 MPa under the heat treatment conditions of nucleation temperature of 700 °C and nucleation time of 2 h, crystallization temperature of 910 °C and crystallization time of 3 h. 展开更多
关键词 glass-ceramics CaO-Al_(2)O_(3)-SiO_(2) system Fe_(2)O_(3) electron paramagnetic resonance Mossbauer spectroscopy mechanical properties
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