The Growth of Latex Particles during the VAc/BA Copolymerization

The semi-continuous seeded emulsion eopolymerization of vinyl acetate and butyl acrylate was carried out with hydroxyethyl cellulose as a colloid stabilizer. The morphology of the latex particle and the relationship between the reaction time and the average particle diameter and/or the conversion ratio during the polymerization were invstiguted. The experimental results shaw that the morphology of the latex particle possesses the stable sterie construction. In the seeded polymerizution, the average particle diameter of latex decreased while the conversion ratio increased. At the second term of the emulsion copolymerization （the growth stage of particle size）, the latex particle average diameter increased with copolymerization continuously, but the instantaneous conversation ratio was not large, so it was very necessaO to properly prolong the time during the holding temperature stage.

Analysis of Correlation between Concentration of Atmospheric Particulates and Humidity Based on the Aerodynamic Particle Sizer

The TSI-3321 APS was used to measure concentration of atmospheric particulates in Ranjiaba region of Yubei District in Chongqing City during March 21- 29,2014,and the temporal variations in the hourly average mass and number concentration and median particle diameter of PM10 and PM2.5 as well as their correlation with relative humidity were analyzed. The results showed that the three indicators of PM10 and PM2.5 except for the mass concentration correlated with relative humidity,of which the correlation between the mass median particle diameter and relative humidity was the best. The correlation coefficient R^2 between the mass median particle diameter of PM10（ PM2.5） and relative humidity was up to 0. 943（ 0. 832）. Therefore,relative humidity and pressure are key impact factors of indicators of particles.

Correlation Between Yield Stress of Silty Mud Sediments and Continuous Oscillatory Shearing Properties

Analyzing the rheological properties of silty beds subjected to continuous oscillatory shear loading is crucial for understanding the morphological deformation of the seabed and ensuring safety in geological and marine engineering applications.In this study,the effects of oscillatory shearing properties on the yield stress(S_(u))of silty sediments were quantitatively investigated.The effects of oscillatory shear strength(0-3),water content(26.6%-70.84%),and particle diameter(8.79-50μm)were examined extensively through a series of laboratory tests.The results indicated that the three aforementioned parameters were the major factors that affected the rheological characteristics of silty sediments.Furthermore,their effects could be elucidated using the yield stress of cohesive sediments as the indicator parameter.The ratio of yield stress(S_(u)/S_(u0))varied as the oscillatory shear strength increased up to a critical value,Λ_(cr).S_(u)bsequently,the ratio remained at a constant value.It was deduced that the yield stress decreased with increasing oscillatory shear strength forΛ<Λ_(cr),when the sediments were in a non-equilibrium fluidization stage.WhenΛ>Λ_(cr),the sediments entered an equilibrium fluidization stage,and the yield stress remained almost constant,irrespective of the oscillatory shear strength.Furthermore,during the equilibrium fluidization stage,it was observed that the ratio S_(u)/S_(u0)did not vary with water content but decreased as the particle diameter increased.Finally,based on regression analysis of the experimental data for non-equilibrium and equilibrium fluidization stages,a correlation between yield stress of silty sediments and continuous oscillatory shearing properties was proposed.This correlation can aid in understanding the changes in solid resistance and assessing safety in piling engineering.Furthermore,it can provide a theoretical guidance for reducing soil resistance in marine structures using mechanical vibrations.