Mass transfer enhancement and hydrodynamic performance with wire mesh coupling solid particles in bubble column reactor

It is of vital significance to investigate mass transfer enhancements for chemical engineering processes.This work focuses on investigating the coupling influence of embedding wire mesh and adding solid particles on bubble motion and gas-liquid mass transfer process in a bubble column.Particle image velocimetry(PIV)technology was employed to analyze the flow field and bubble motion behavior,and dynamic oxygen absorption technology was used to measure the gas-liquid volumetric mass transfer coefficient(kLa).The effect of embedding wire mesh,adding solid particles,and wire mesh coupling solid particles on the flow characteristic and kLa were analyzed and compared.The results show that the gas-liquid interface area increases by 33%-72%when using the wire mesh coupling solid particles strategy compared to the gas-liquid two-phase flow,which is superior to the other two strengthening methods.Compared with the system without reinforcement,kLa in the bubble column increased by 0.5-1.8 times with wire mesh coupling solid particles method,which is higher than the sum of kLa increases with inserting wire mesh and adding particles,and the coupling reinforcement mechanism for affecting gas-liquid mass transfer process was discussed to provide a new idea for enhancing gas-liquid mass transfer.

Unified Description of the Three Stable Particles in Self-Action Allows Determination of Their Relative Masses

The Dirac equation γμ(δμ-eAμ)Ψ=mc2Ψ describes the bound states of the electron under the action of external potentials, Aμ. We assumed that the fundamental form of the Dirac equation γμ(δμ-Sμ)Ψ=0 should describe the stable particles (the electron, the proton and the dark-matter-particle (dmp)) bound to themselves under the action of their own potentials Sμ. The new equation reveals that self energy is consequence of self action, it also reveals that the spin angular momentum is consequence of the dynamic structure of the stable particles. The quantitative results are the determination of their relative masses as well as the determination of the electromagnetic coupling constant.

Characterizations That Help Explain Particle and Cosmic Data

This paper suggests explanations for otherwise seemingly unexplained data about elementary particles and cosmology. The explanations have bases in coordinate-based modeling and in integer-based characterizations for some catalogs. One catalog features properties—including charge, mass, and angular momentum—of objects. Another catalog features all known and some possible elementary particles. Assumptions include that multipole-expansion mathematics has uses regarding long-range interactions, such as gravity, and that nature includes six isomers of all elementary particles other than long-range-interaction bosons. One isomer associates with ordinary matter. Five isomers are associated with dark matter. Multipole notions help explain large-scale aspects such as the rate of expansion of the universe.

Chemical composition and quantitative relationship between meteorological condition and fine particles in Beijing

The recent year's monitor results of Beijing indicated that the pollution level of fine particles PM 2.5 showed an increasing trend. To understand pollution characteristics of PM 2.5 and its relationship with the meteorological conditions in Beijing, a one-year monitoring of PM 2.5 mass concentration and correspondent meteorological parameters was performed in Beijing in 2001. The PM 2.5 levels in Beijing were very high, the annual average PM 2.5 concentration in 2001 was 7 times of the National Ambient Air Quality Standards proposed by US EPA. The major chemical compositions were organics, sulfate, crustals and nitrate. It was found that the mass concentrations of PM 2.5 were influenced by meteorological conditions. The correlation between the mass concentrations of PM 2.5 and the relative humidity was found. And the correlation became closer at higher relative humidity. And the mass concentrations of PM 2.5 were negtive-correlated to wind speeds, but the correlation between the mass concentration of PM 2.5 and wind speed was not good at stronger wind.

Seasonal Variations of Number Size Distributions and Mass Concentrations of Atmospheric Particles in Beijing

Particle number and mass concentrations were measured in Beijing during the winter and summer periods in 2003, together with some other parameters including black carbon (BC) and meteorological conditions. Particle mass concentrations exhibited low seasonality, and the ratio of PM2.5/PM10 in winter was higher than that in summer. Particle number size distribution (PSD) was characterized by four modes and exhibited low seasonality. BC was well correlated with the number and mass concentrations of accumulation and coarse particles, indicating these size particles are related to anthropogenic activities. Particle mass and number concentrations (except ultra-fine and nucleation particles) followed well the trends of BC concentration for the majority of the day, indicating that most particles were associated with primary emissions. The diurnal number distributions of accumulation and coarse mode particles were characterized by two peaks.

Enhancement of CO2 Absorption under Taylor Flow in the Presence of Fine Particles

The physical absorption of CO2 in water containing different types of particles was studied in a micro-channel operated under Taylor flow. The maximum enhancement factors of 1.43-2.15 were measured for activated carbon （AcC） particles. The analysis shows that the enhancement effect can be attributed to the shuttle mechanism. Considering the separate contributions of mass transfer from bubble cap and liquid film, a heterogeneous enhance- ment model is developed. According to this model, the enhancement factors Ecap, EFilm and Eov are mainly determined by mass transfer coefficient gL （gL Cap and KL Film）, adsorptive capacity of particles m, and coverage fraction of particles at gas-liquid interface （. With both effects of particle-to-interface adhesion and apparent viscosity included, the model nredicts the enhancement effect of AcC varticles reasonably well.

The Enhancement of CO2 Chemical Absorption by K2CO3 Aqueous Solution in the Presence of Activated Carbon Particles

The enhancement of chemical absorption of CO2 by K2CO3/H2O absorbents in the presence of activated carbon （AC） particles was investigated. The results show that the gas absorption rates can be enhanced significantly in the presence of AC particles, and the maximum enhancement factor 3.7 was observed at low stirring intensities. The enhancement factor increased rapidly with the solid loading during the initial period of absorption and then be- came mild gradually to a maximum value. Both the liquid-solid contact area and the probability of solid particles residing at the gas-liquid interface decreased with the increase of the particle size, leading to a negative effect on the enhancement of mass transfer. The influence of the particles on gas absorption decreased with the reaction rate. The stirring speed changed the interfacial coverage and mass transfer rate on the liquid side and consequently affected the mass transfer between the gas and liquid phases; the enhancement factor decreased with the stirring intensity. A heterogeneous two-zone model was proposed for predicting the enhancement factor and the calculated results agreed well with the experimental data.

Particle flow code simulation of intact and fissured granitic rock samples

This study presents a calibration process of three-dimensional particle flow code(PFC3D)simulation of intact and fissured granite samples.First,laboratory stressestrain response from triaxial testing of intact and fissured granite samples is recalled.Then,PFC3D is introduced,with focus on the bonded particle models(BPM).After that,we present previous studies where intact rock is simulated by means of flatjoint approaches,and how improved accuracy was gained with the help of parametric studies.Then,models of the pre-fissured rock specimens were generated,including modeled fissures in the form of“smooth joint”type contacts.Finally,triaxial testing simulations of 1 t 2 and 2 t 3 jointed rock specimens were performed.Results show that both elastic behavior and the peak strength levels are closely matched,without any additional fine tuning of micro-mechanical parameters.Concerning the postfailure behavior,models reproduce the trends of decreasing dilation with increasing confinement and plasticity.However,the dilation values simulated are larger than those observed in practice.This is attributed to the difficulty in modeling some phenomena of fissured rock behaviors,such as rock piece corner crushing with dust production and interactions between newly formed shear bands or axial splitting cracks with pre-existing joints.

Investigation of the possible source for the solar energetic particle event on 2017 September 10

According to the solar proton data observed by Geostationary Operational Environmental Satellites （GOES）, ground-based neutron monitors on Earth and near-relativistic electron data measured by the ACE spacecraft, the onset times of protons with different energies and near-relativistic electrons have been estimated and compared with the time of solar soft and hard X-ray and radio burst data. The results show that first arriving relativistic and non-relativistic protons and electrons may have been accelerated by the concurrent flare. The results also suggest that release times of protons with different energies may be different, and the protons with lower energy may have been released earlier than those with higher energy. Some protons accelerated by concurrent flares may be further accelerated by the shock driven by the associated CME.

Pyrolysis of single large biomass particle: Simulation and experiments

Pyrolysis and heat transfer characteristics of single large biomass particle were investigated using threedimensional unsteady heat transfer model coupled with chemical reactions.The consumption of biomass and the production of products were simulated.Some experiments were designed to provide model parameters for simulation calculations.The simulation was verified by pyrolysis experiments of large biomass particle in a vertical tube furnace.The simulation results show the internal heat and mass transfer law during the pyrolysis of large biomass particle.When the biomass particle diameter is between 10 and 30 mm,for every 5 mm increase in particle diameter,the time required for complete pyrolysis will increase on average by about 50 s.When the pyrolysis temperature is between 673 K and 873 K,a slight decrease in the pyrolysis temperature will cause the time required for the biomass to fully pyrolyze to rise significantly.And the phenomenon is more obvious in the low temperature range.The results indicate that the numerical simulation agrees well with the experimental results.

Size Distribution of Particles Emitted from Liquefied Natural Gas Fueled Engine

The results of measurements conducted to determine the number and mass concentration of particles emitted from the liquefied natural gas （LNG） fueled spark ignition engines are presented. Particle size distributions were measured at different speeds, different loads and ESC cycles. The nanoparticles with diameter smaller than 39 nm, measured by the electrical low-pressure impactor （ELPI）, are dominant in number con- centration that is nearly 92.7 % of the total number of the emitted particles at the peak point. As for the mass of emission particle, it is shown that the mass of the particles greater than 1.2μm is more than 65 % that of the emitted particles.

Particle flux through the Huanghai Sea cold water mass

Settling particulate matter （SPM） was collected by using sediment traps at four stations in a survey section from Qingdao to Cheju-do, across the Huanghai Sea cold water mass （HSCWM）, in August 2002. The sediment traps were planted in three layers： the upper layer of the thermocline （ULT） above the HSCWM, the lower layer of the thermocline （LLT）, and the bottom layer of water column （BL）. To determine the particle flux, the contents of organic carbon （POC）, organic nitrogen （PON）, total carbon （PC）, and total phosphorous （PP） in SPM were analyzed, and two flux models （Ⅰ and Ⅱ） were improved to calculate the resuspension ratio, with an assumption in Model Ⅰ that the vertical flux of SPM in the LLT equals the net vertical flux of SPM in the whole water column. An X value, i.e., the fraction of the resuspension flux originating from the surficial sediments nearby the sampling station, was deduced from Model Ⅰ to estimate the contribution of lateral currents to the total resuspension flux. The results showed that inorganic particles, fecal pellets, and miscellaneous aggregates were the major types of SPM in the HSCWM, and the contents of POC, PON, PC, and PP all decreased with water depth. A great deal of fecal pellets found in the LLT indicates that the main space producing biogenic SPM is the thermocline, and especially the LLT, where the C/N ratio is lower than that in the ULT. The resuspension ratios, 90%-96% among stations, imply strong impact ofresuspension on particle flux in the BL. These values were not significantly different between the two flux models, suggesting that the hypothesis in Model Ⅰ that the flux in the LLT equaling the net flux to the bottom is acceptable for shallow waters with stratification like the HSCWM. The POC export ratio from the HSCWM ranges from 35% to 68%. It benefits from the short sinking distance in shallow water. The upwelling in the HSCWM enhanced the POC flux through the water mass, and the lateral currents provides up to being greater than 50% ofresuspension flux in the BL according to evaluation of the X value.

Black Carbon Instead of Particle Mass Concentration as an Indicator for the Traffic Related Particles in the Brussels Capital Region

The Brussels Capital Region has difficulties in meeting the stringent EU daily limit value for PM10 in all its measuring sites. Postponing the attainment of the deadline was not granted by the EU Commission, mainly due to insufficient judged measures to reduce road traffic emissions. However, a thorough analysis of the data makes clear that neither the particle mass concentration (PM10 and PM2.5) nor the particle number concentration are specific metrics for evaluating the particle pollution originated by traffic. In fact, increased formation of secondary aerosol, together with adverse meteorological conditions and the (re) suspension of the coarser fraction are by far the three main explanations for the numerous PM10 exceeding values. From our experience, amongst the particles measured, only the results for Black Carbon (BC), mainly present in the lower submicron range, are reflective of the direct influence of local traffic. Measured at two traffic sites along with PM mass and number concentrations, the data for Black Carbon show a striking correlation with nitrogen monoxide, a parameter strongly related with the proximity of the local traffic. The correlation factor between Black Carbon data and NO or NOX is much higher than between Black Carbon and the PM mass or number concentration. Therefore the assessment of traffic related particles should consider Black Carbon rather than PM10 or PM2.5.

Large solar energetic particle event that occurred on 2012 March 7 and its VDA analysis

On 2012 March 7, the STEREO Ahead and Behind spacecraft, along with near-Earth spacecraft （e.g. SOHO, Wind） situated between the two STEREO spacecraft, observed an extremely large global solar energetic particle （SEP） event in Solar Cycle 24. Two successive coronal mass ejections （CMEs） have been detected close in time. From the multi-point in-situ observations, it can be found that this SEP event was caused by the first CME, but the second one was not involved. Using velocity dispersion analysis （VDA）, we find that for a well magnetically connected point, the energetic protons and electrons are released nearly at the same time. The path lengths to STEREO-B （STB） for protons and electrons have a distinct difference and deviate remarkably from the nominal Parker spiral path length, which is likely due to the presence of interplanetary magnetic structures situated between the source and STB. Also, the VDA method seems to only obtain reasonable results at well-connected locations and the inferred release times of energetic particles in different energy channels are similar. We suggest that good-connection is crucial for obtaining both an accurate release time and path length simultaneously, agreeing with the modeling result of Wang ＆ Qin （2015）.

Is the enhancement of type Ⅱ radio bursts during CME interactions related to the associated solar energetic particle event?

We investigated 64 pairs of interacting-CME events identified from simultaneous observations by the SOHO and STEREO spacecraft from January 2010 to August 2014, to examine the relationship between large SEP events in the energy range of ～25 to～60 MeV and properties of the interacting CMEs.We found that during CME interactions, the large SEP events in this study were all generated by CMEs with the presence of enhanced type Ⅱ radio bursts, which also have wider longitudinal distributions compared to events without a type Ⅱ radio burst or its enhancement(almost always associated with small SEP events).It seems that the signature of type Ⅱ radio burst enhancement is a good discriminator between large SEP and small or no SEP event producers during CME interactions. The type Ⅱ radio burst enhancement is more likely to be generated by CME interactions, with the main CME having a larger speed(v), angular width(WD), mass(m) and kinetic energy(Ek), and taking over the preceding CMEs. The preceding CMEs in these instances have higher v, WD, m and Ekthan those in CME pairs missing type Ⅱ radio bursts or enhancements. Generally, the values of these properties in the type-Ⅱ-enhanced events are typically higher than the corresponding non-type-Ⅱ or non-type-Ⅱ-enhanced cases for both the main and preceding CMEs. Our analysis also revealed that the intensities of associated SEP events correlate negatively with the intersection height of the two CMEs. Moreover, the overlap width of two CMEs is typically larger in type-Ⅱ-enhanced events than in non-type-Ⅱ or non-type-Ⅱ-enhanced events. Most type-Ⅱ-enhanced events and SEP events are coincident and are almost always made by the fast and wide main CMEs that sweep fully over relatively slower and narrower preceding CMEs. We suggest that a fast CME with enough energy completely overtaking a relatively narrower preceding CME, especially at low height, can drive a more energetic shock signified by the enhanced type Ⅱ radio bursts. The shock may accelerate ambient particles(likely provided by the preceding CME) and lead to large SEP events more easily.

Hypotheses on Vacuum and Elementary Particles: The Friedmann-Planck Micro-Universe, Friedmann and Schwarzschild Photon Spheres

This article presents the hypothesis that the vacuum is endowed with a quantum structure;the vacuum particles would be Friedmann-Planck micro-universes. For this, the article introduces a quantization of a closed Friedmann universe, then a quantization of the photon spheres filling this universe. This approach gives a numerical value consistent with cosmological measurements for the current dark energy density of our Universe. Next, the article takes the content of a model published in Physics Essays in 2013 [1], assuming that elementary particles are Schwarzschild photon spheres;these could be derived from the Friedmann photon spheres composing the vacuum particles. It is further recalled that the model presents a unified structure of elementary particles and allows us to calculate the value of the elementary electric charge as well as the mass of the elementary particles.

Variation Characteristics of Mass Concentration of Inhalable Particles in Qingdao, China

The geographical condition of Qingdao, China is relatively special;the transport of various inland pollutants, the emissions of marine aerosol and local pollutants will have an impact on the changes of atmospheric aerosol concentration. By using the stability classification method, trajectory clustering analysis and the NOAA HYSPLIT model, the seasonal distribution characteristics of atmospheric inhalable particulate matter concentration in Qingdao, China and its relationship with meteorological conditions, mixed layer height, and the seasonal characteristics of Qingdao pollutant transport were analyzed. The results show that the variation trends of PM2.5 and PM10 were about the same, and there are obvious seasonal differences, which are high in winter and spring, and low in summer and autumn. The concentration of inhalable particulate matter has a negative correlation with temperature, wind speed and relative humidity. The concentration of inhalable particulate matter is distinct in different relative humidity ranges. When the wind speed is less than 3 - 4 m/s, there are more inhalable particles, while the mass concentration shows obvious reduction with the wind speed more than 4 m/s. There is a significant negative correlation between the mass concentration of pollutants and the daily maximum mixed layer height. The larger the concentration of pollutants, the smaller the thickness of the daily largest mixed layer. Conversely, the smaller the mass concentration of pollutants, the larger the thickness of the daily largest mixed layer. The pollutant transport in Qingdao has obvious seasonal characteristics. The air mass in spring, autumn and winter is mainly medium-long distance transport from Mongolia and southern Russia, and medium-short distance transport from Inner Mongolia and northeast of China. The source of air masses in summer is mainly transported from the eastern and sea areas.

Effects of Particle Matters on Plant: A Review

The particle matter,particularly the suspended particle matter(PM≤2.5)in the air is not only a risk factor for human health,but also affects the survival and physiological features of plants.Plants show advantages in the adsorption of particle matter,while the factors,such as the leaf shape,leaf distribution density and leaf surface microstructure,such as grooves,folds,stomata,flocculent projections,micro-roughness,long fuzz,short pubescence,wax and secretory products,appeared to play an important role determing their absorption capacity.In this paper,the research progress on the capture or adsorption of atmospheric particles was summarized,and the forest vegetation and woody plants were discuessed.In addition,special attentions were paid to the effect of haze-fog weather on greenhouse plant,the different responses of plant leaves to dust particles and suspended particles,as well as the effect of suspended particles on morphological change of plants.In the future,research should focus on the mechanism of the influence of particulate matter on plants.More advanced effective and convenient research methods like spectral detection method also need to be developed.This paper may provide reference for future studies on plants’response to haze and particle matter.

Calculation of the Masses of All Fundamental Elementary Particles with an Accuracy of Approx. 1%

The masses of a l l fundamental elementary particles (those with a lifetime > 10-24 sec) can be calculated with an inaccuracy of approx. 1% using the equation m/melectron = N/2α where α is the coupling constant of quantum electrodynamics (also known as fine structure constant) (= 1/137.036), and N is an integer variable. This is the by far most accurate and most comprehensive approach to calculate the particle masses.

Numerical simulations of solar energetic particle event timescales associated with ICMEs

Recently, S. W. Kahler studied the timescales of solar energetic particle （SEP） events asso- ciated with coronal mass ejections （CMEs） from analysis of spacecraft data. They obtained different timescales for SEP events, such as TO, the onset time from CME launch to SEP onset, TR, the rise time from onset to half the peak intensity （0.5/p）, and TD, the duration of the SEP intensity above 0.5Ip. In this work, we solve the transport equation for SEPs considering interplanetary coronal mass ejection （ICME） shocks as energetic particle sources. With our modeling assumptions, our simulations show similar results to Kahler＇s analysis of spacecraft data, that the weighted average of TD increases with both CME speed and width. Moreover, from our simulation results, we suggest TD is directly dependent on CME speed, but not dependent on CME width, which were not found in the analysis of observational data.