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On Translation of Passiveness from English to Chinese
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作者 李锐 《海外英语》 2012年第1X期146-148,共3页
Translation is an art,a bilingual art.Like painting,translation enables us to reproduce the fine thought of somebody,not in colors,but in words,in words of a different language.It is no easy job,not so easy as it is s... Translation is an art,a bilingual art.Like painting,translation enables us to reproduce the fine thought of somebody,not in colors,but in words,in words of a different language.It is no easy job,not so easy as it is supposed.Many can speak and write it well,but they can not translate well.This paper is mainly discussing the method of translating English to Chinese.Also analyses and classifies the translation of the passive voice from English to Chinese,and also points several language points should be considered in translating. 展开更多
关键词 TRANSLATION PASSIVE VOICE active VOICE CHINESE ENG
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5G-A时代物联网应用及策略研究
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作者 蒋振伟 姚赛彬 潘婷 《邮电设计技术》 2024年第7期30-35,共6页
海量物联网通信是5G典型应用场景之一,为了实现蜂窝网的全场景物联能力,需要更多的场景化技术,5G-A引入了RedCap和Passive IoT。其中,RedCap降低了设备复杂性及成本,补充了5G中、高速率物联能力;Passive IoT实现了低成本无源物联。结合... 海量物联网通信是5G典型应用场景之一,为了实现蜂窝网的全场景物联能力,需要更多的场景化技术,5G-A引入了RedCap和Passive IoT。其中,RedCap降低了设备复杂性及成本,补充了5G中、高速率物联能力;Passive IoT实现了低成本无源物联。结合对物联产业的综合分析,重点论述基于RedCap和Pas-siveIoT的物联网构建方案、运营及优化。 展开更多
关键词 5G-A mMTC RedCap Passive IoT 物联网
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Low-energy-consumption temperature swing system for CO_(2) capture by combining passive radiative cooling and solar heating 被引量:1
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作者 Ying-Xi Dang Peng Tan +3 位作者 Bin Hu Chen Gu Xiao-Qin Liu Lin-Bing Sun 《Green Energy & Environment》 SCIE EI CAS CSCD 2024年第3期507-515,共9页
Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative coo... Temperature-swing adsorption(TSA)is an effective technique for CO_(2) capture,but the temperature swing procedure is energy-intensive.Herein,we report a low-energy-consumption system by combining passive radiative cooling and solar heating for the uptake of CO_(2) on commercial activated carbons(CACs).During adsorption,the adsorbents are coated with a layer of hierarchically porous poly(vinylidene fluoride-co-hexafluoropropene)[P(VdF-HFP)HP],which cools the adsorbents to a low temperature under sunlight through radiative cooling.For desorption,CACs with broad absorption of the solar spectrum are exposed to light irradiation for heating.The heating and cooling processes are completely driven by solar energy.Adsorption tests under mimicked sunlight using the CACs show that the performance of this system is comparable to that of the traditional ones.Furthermore,under real sunlight irradiation,the adsorption capacity of the CACs can be well maintained after multiple cycles.The present work may inspire the development of new temperature swing procedures with little energy consumption. 展开更多
关键词 CO_(2)capture Solar heating Passive radiative cooling Temperature swing adsorption
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Train post‑derailment behaviours and containment methods:a review 被引量:1
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作者 Zhao Tang Yuwei Hu +3 位作者 Shuangbu Wang Liang Ling Jianjun Zhang Kaiyun Wang 《Railway Engineering Science》 EI 2024年第1期59-80,共22页
Railway accidents,particularly serious derailments,can lead to catastrophic consequences.Therefore,it is essential to prevent derailment escalation to reduce the likelihood of severe derailments.Train post-derailment ... Railway accidents,particularly serious derailments,can lead to catastrophic consequences.Therefore,it is essential to prevent derailment escalation to reduce the likelihood of severe derailments.Train post-derailment behaviours and containment methods play a critical role in preventing derailment escalation and providing passive safety protection and accident prevention in the event of a derailment.However,despite the increasing attention on this field from academia and industry in recent years,there is a lack of systematic exploration and summarization of emerging applications and containment methods in train post-derailment research.For this reason,this paper presents a comprehensive review of existing studies on train post-derailment behaviours,encompassing various topics such as post-derailment contact-impact models,dynamic modelling and simulation techniques,and the primary factors influencing post-derailment behaviours.Significantly,this review introduces and elucidates substitute guidance mechanisms(SGMs),which serve as railway-specific passive safety protection and accident prevention measures.The various types of SGMs are depicted,and their ongoing developments and applications are explored in depth.The review additionally points out several unresolved challenges including the adverse effects of SGMs,and proposes future research directions to advance the theoretical understanding and practical application of train post-derailment behaviours and containment methods.This review seeks to be a valuable reference for railway industry professionals in preventing catastrophic derailment consequences through post-derailment containment methods. 展开更多
关键词 Railway passive safety Railway accident prevention Post-derailment behaviours Substitute guidance mechanisms(SGMs) Contact-impact model
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Enhancing the Performance of Perovskite Light-Emitting Diodes via Synergistic Effect of Defect Passivation and Dielectric Screening
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作者 Xuanchi Yu Jia Guo +11 位作者 Yulin Mao Chengwei Shan Fengshou Tian Bingheng Meng Zhaojin Wang Tianqi Zhang Aung Ko Ko Kyaw Shuming Chen Xiaowei Sun Kai Wang Rui Chen Guichuan Xing 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第10期244-256,共13页
Metal halide perovskites,particularly the quasi-two-dimensional perovskite subclass,have exhibited considerable potential for next-generation electroluminescent materials for lighting and display.Nevertheless,the pres... Metal halide perovskites,particularly the quasi-two-dimensional perovskite subclass,have exhibited considerable potential for next-generation electroluminescent materials for lighting and display.Nevertheless,the presence of defects within these perovskites has a substantial influence on the emission efficiency and durability of the devices.In this study,we revealed a synergistic passivation mechanism on perovskite films by using a dual-functional compound of potassium bromide.The dual functional potassium bromide on the one hand can passivate the defects of halide vacancies with bromine anions and,on the other hand,can screen the charged defects at the grain boundaries with potassium cations.This approach effectively reduces the probability of carriers quenching resulting from charged defects capture and consequently enhances the radiative recombination efficiency of perovskite thin films,leading to a significant enhancement of photoluminescence quantum yield to near-unity values(95%).Meanwhile,the potassium bromide treatment promoted the growth of homogeneous and smooth film,facilitating the charge carrier injection in the devices.Consequently,the perovskite light-emitting diodes based on this strategy achieve a maximum external quantum efficiency of~21%and maximum luminance of~60,000 cd m^(-2).This work provides a deeper insight into the passivation mechanism of ionic compound additives in perovskite with the solution method. 展开更多
关键词 Synergistic passivation strategy Defects passivation Dielectric screening Perovskite light-emitting diodes
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The effect of Laves phases and nano-precipitates on the electrochemical corrosion resistance of Mg-Al-Ca alloys under alkaline conditions
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作者 Markus Felten Veronika Chaineux +12 位作者 Siyuan Zhang Ali Tehranchi Tilmann Hickel Christina Scheu Joshua Spille Marta Lipińska-Chwałek Joachim Mayer Benjamin Berkels Marcus Hans Imke Greving Silja Flenner Sandra Sefa Daniela Zander 《Journal of Magnesium and Alloys》 SCIE EI CAS CSCD 2024年第6期2447-2461,共15页
The electrochemical corrosion mechanisms of Mg alloys were extensively studied in previous investigations of different chemical com-positions,modified surface states and various electrolyte conditions.However,recent r... The electrochemical corrosion mechanisms of Mg alloys were extensively studied in previous investigations of different chemical com-positions,modified surface states and various electrolyte conditions.However,recent research focused on the active state of Mg dissolution,leading to unresolved effects of secondary phases adjacent to a stableα-solid solution passive layer.The present study investigates the fundamental electrochemical corrosion mechanisms of three different Laves phases with varying phase morphologies and phase fractions in the passive state of Mg-Al-Ca alloys.The microstructure was characterized by(transmission-)electron microscopy and synchrotron-based transmission X-ray microscopy.The electrochemical corrosion resistance was determined with a standard three-electrode setup and advanced in-situ flow cell measurements.A new electrochemical activity sequence(C15>C36>α-Mg>C14)was obtained,as a result of a stable passive layer formation on theα-solid solution.Furthermore,nm-scale Mg-rich precipitates were identified within the Laves phases,which tend to inhibit the corrosion kinetics. 展开更多
关键词 Laves phase STEM MAGNESIUM Corrosion Passive layer
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A-site assisted perovskite crystallization via ion-exchange MOFs for high efficient and stable perovskite solar cells
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作者 Xingrui Zhang Jian Zhang +5 位作者 Wei Wang Boyuan Hu Yayu Dong Debin Xia Kaifeng Lin Yulin Yang 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期436-442,I0011,共8页
Here,a novel strategy is proposed targeting the volatility of A-site cations and the disordered arrangement of perovskite grains through employing Cs~+contained metal-organic frameworks In-aip(Cs)obtained by ion-excha... Here,a novel strategy is proposed targeting the volatility of A-site cations and the disordered arrangement of perovskite grains through employing Cs~+contained metal-organic frameworks In-aip(Cs)obtained by ion-exchange and crystalline transform.Interatomic forces between Cs-O atoms split the pore channels of the pristine In-aip,endowing In-aip(Cs)with multidimensional charge transport channels,In addition,the partially freed Cs~+in the interlayer compensates for the vacancy of A-site cations during the perovskite preparation process.The In-aip(Cs)modified perovskite films have a flat morphology,large grains and excellent optoelectronic properties.Benefiting from the high-quality perovskite films and faster charge extraction,the In-aip(Cs)-modified PSCs achieved a champion PCE of 23.03%,superior to the In-aip-modified(22.29%)and control device(21.13%),More importantly,the unencapsulated PSCs modified with In-aip(Cs)exhibited outstanding humidity and thermal stability.Over a period of almost 1000 h,the unencapsulated In-aip(Cs)-modified device retained 85%of its initial PCE after storing in a glove box at 85℃,and retained 87%of the primary PCE upon storage in ambient condition at 25℃under a humidity of 40%. 展开更多
关键词 Metal-organic frameworks PSCs Stability Defect passivation
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Manipulating Crystal Growth and Secondary Phase PbI_(2)to Enable Efficient and Stable Perovskite Solar Cells with Natural Additives
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作者 Yirong Wang Yaohui Cheng +5 位作者 Chunchun Yin Jinming Zhang Jingxuan You Jizheng Wang Jinfeng Wang Jun Zhang 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第9期432-448,共17页
In perovskite solar cells(PSCs),the inherent defects of perovskite film and the random distribution of excess lead iodide(PbI_(2))prevent the improvement of efficiency and stability.Herein,natural cellulose is used as... In perovskite solar cells(PSCs),the inherent defects of perovskite film and the random distribution of excess lead iodide(PbI_(2))prevent the improvement of efficiency and stability.Herein,natural cellulose is used as the raw material to design a series of cellulose derivatives for perovskite crystallization engineering.The cationic cellulose derivative C-Im-CN with cyano-imidazolium(Im-CN)cation and chloride anion prominently promotes the crystallization process,grain growth,and directional orientation of perovskite.Meanwhile,excess PbI_(2)is transferred to the surface of perovskite grains or formed plate-like crystallites in local domains.These effects result in suppressing defect formation,decreasing grain boundaries,enhancing carrier extraction,inhibiting non-radiative recombination,and dramatically prolonging carrier lifetimes.Thus,the PSCs exhibit a high power conversion efficiency of 24.71%.Moreover,C-Im-CN has multiple interaction sites and polymer skeleton,so the unencapsulated PSCs maintain above 91.3%of their initial efficiencies after 3000 h of continuous operation in a conventional air atmosphere and have good stability under high humidity conditions.The utilization of biopolymers with excellent structure-designability to manage the perovskite opens a state-of-the-art avenue for manufacturing and improving PSCs. 展开更多
关键词 PEROVSKITE Solar cells Defect passivation Biomass additives Crystal orientation
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Constructing Al@C-Sn pellet anode without passivation layer for lithium-ion battery
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作者 Kangzhe Cao Sitian Wang +3 位作者 Yanan He Jiahui Ma Ziwei Yue Huiqiao Liu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2024年第3期552-561,共10页
Al is considered as a promising lithium-ion battery(LIBs)anode materials owing to its high theoretical capacity and appropri-ate lithation/de-lithation potential.Unfortunately,its inevitable volume expansion causes th... Al is considered as a promising lithium-ion battery(LIBs)anode materials owing to its high theoretical capacity and appropri-ate lithation/de-lithation potential.Unfortunately,its inevitable volume expansion causes the electrode structure instability,leading to poor cyclic stability.What’s worse,the natural Al2O3 layer on commercial Al pellets is always existed as a robust insulating barrier for elec-trons,which brings the voltage dip and results in low reversible capacity.Herein,this work synthesized core-shell Al@C-Sn pellets for LIBs by a plus-minus strategy.In this proposal,the natural Al2O3 passivation layer is eliminated when annealing the pre-introduced SnCl2,meanwhile,polydopamine-derived carbon is introduced as dual functional shell to liberate the fresh Al core from re-oxidization and alle-viate the volume swellings.Benefiting from the addition of C-Sn shell and the elimination of the Al2O3 passivation layer,the as-prepared Al@C-Sn pellet electrode exhibits little voltage dip and delivers a reversible capacity of 1018.7 mAh·g^(-1) at 0.1 A·g^(-1) and 295.0 mAh·g^(-1) at 2.0 A·g^(-1)(after 1000 cycles),respectively.Moreover,its diffusion-controlled capacity is muchly improved compared to those of its counterparts,confirming the well-designed nanostructure contributes to the rapid Li-ion diffusion and further enhances the lithium storage activity. 展开更多
关键词 lithium-ion battery high-performance anode aluminum passivation layer plus-minus strategy
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Interfacial modification using the cross-linkable tannic acid for highly-efficient perovskite solar cells with excellent stability
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作者 Xing Gao Lirong Rong +6 位作者 Fei Wu Yen-Hung Lin Ye Zeng Junhong Tan Rongxing He Cheng Zhong Linna Zhu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第4期236-244,共9页
Although the performance of perovskite solar cells(PSCs)has been dramatically increased in recent years,stability is still the main obstacle preventing the PSCs from being commercial.PSC device instability can be caus... Although the performance of perovskite solar cells(PSCs)has been dramatically increased in recent years,stability is still the main obstacle preventing the PSCs from being commercial.PSC device instability can be caused by a variety of reasons,including ions diffusion,surface and grain boundary defects,etc.In this work,the cross-linkable tannic acid(TA)is introduced to modify perovskite film through post-treatment method.The numerous organic functional groups(–OH and C=O)in TA can interact with the uncoordinated Pb^(2+)and I^(-)ions in perovskite,thus passivating defects and inhibiting ions diffusion.In addition,the formed TA network can absorb a small amount of the residual moisture inside the device to protect the perovskite layer.Furthermore,TA modification regulates the energy level of perovskite,and reduces interfacial charge recombination.Ultimately,following TA treatment,the device efficiency is increased significantly from 21.31%to 23.11%,with a decreased hysteresis effect.Notably,the treated device shows excellent air,thermal,and operational stability.In light of this,the readily available,inexpensive TA has the potential to operate as a multipurpose interfacial modifier to increase device efficiency while also enhancing device stability. 展开更多
关键词 Tannic acid Defect passivation lons diffusion HYDROPHILIC STABILITY Perovskite solar cells
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Bifunctional passivation by lewis-base molecules for efficient printable mesoscopic perovskite solar cells
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作者 Hang Yang Jianhong Zhao +8 位作者 Xiaodong Ren Tong Zhou Henbing Zhang Weilong Zhang Jin Zhang Guangzhi Hu Yuming Zhang Wen-Hua Zhang Qingju Liu 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期177-184,共8页
Printable mesoscopic perovskite solar cells(PM-PSCs)possess notable merits in terms of cost-effectiveness,easy manufacturing,and large scale applications.Nevertheless,the absence of a hole transport layer contributes ... Printable mesoscopic perovskite solar cells(PM-PSCs)possess notable merits in terms of cost-effectiveness,easy manufacturing,and large scale applications.Nevertheless,the absence of a hole transport layer contributes to the exacerbation of carrier recombination,and the defects between the perovskite and electron transport layer(ETL)interfaces significantly decrease the efficiency of the devices.In this study,a bifunctional surface passivation approach is proposed by applying a thioacetamide(TAA)surfactant on the mesoporous TiO_(2)interface.The results demonstrate that TAA molecules could interact with TiO_(2),thereby diminishing the oxygen vacancy defects.Additionally,the amino group and sulfur atoms in TAA molecules act as Lewis base to effectively passivate the uncoordinated Pb^(2+)in perovskite and improve the morphology of perovskite,and decrease the trap-state density of perovskite.The TAA passivation mechanism improves the alignment of energy levels between TiO_(2)and perovskite,facilitating electron transport and reducing carrier recombination.Consequently,the TAA-passivated device achieved a champion power conversion efficiency(PCE)of 17.86%with a high fill factor(FF)of 79.16%and an open-circuit voltage(V_(OC))of 0.971 V.This investigation presents a feasible strategy for interfacial passivation of the ETL to further improve the efficiency of PM-PSCs. 展开更多
关键词 Perovskite solarcells Carbon electrode THIOACETAMIDE Interfacial passivation
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Multifunctional interfacial molecular bridge enabled by an aggregation-induced emission strategy for enhancing efficiency and UV stability of perovskite solar cells
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作者 Shuhang Bian Yuqi Wang +13 位作者 Fancong Zeng Zhongqi Liu Bin Liu Yanjie Wu Long Shao Yongzhi Shao Huan Zhang Shuainan Liu Jin Liang Xue Bai Lin Xu Donglei Zhou Biao Dong Hongwei Song 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第8期588-595,I0013,共9页
The interface defects between the electron transport layer(ETL)and the perovskite layer,as well as the low ultraviolet(UV)light utilization rate of the perovskite absorption layer,pose significant challenges for the c... The interface defects between the electron transport layer(ETL)and the perovskite layer,as well as the low ultraviolet(UV)light utilization rate of the perovskite absorption layer,pose significant challenges for the commercialization of perovskite solar cells(PSCs).To address this issue,this paper proposes an innovative multifunctional interface modulation strategy by introducing aggregation-induced emission(AIE)molecule 5-[4-[1,2,2-tri[4-(3,5-dicarboxyphenyl)phenyl]ethylene]phenyl]benzene-1,3-dicarboxylic acid(H_(8)ETTB)at the SnO_(2)ETL/perovskite interface.Firstly,the interaction of H_(8)ETTB with the SnO_(2)surface,facilitated by its carboxyl groups,is effective in passivating surface defects caused by noncoord inated Sn and O vacancies.This interaction enhances the conductivity of the SnO_(2)film and adjusts energy levels,leading to enhanced charge carrier transport.Simultaneously,H_(8)ETTB can passivate noncoord inated Pb^(2+)ions at the perovskite interface,promoting perovskite crystallization and reducing the interface energy barrier,resulting in a perovskite film with low defects and high crystalline quality.More importantly,the H_(8)ETTB molecule,can convert UV light into light absorbable by the perovskite,thereby reducing damage caused by UV light and improving the device's utilization of UV.Consequently,the champion PSC based on SnO_(2)-H_(8)ETTB achieves an impressing efficiency of 23.32%and significantly improved photostability compared with the control device after continuous exposure to intense UV radiation.In addition,the Cs_(0.05)(FA_(0.95)MA_(0.05))_(0.95)Pb(I_(0.95)Br_(0.05))_(3)based device can achieve maximum efficiency of 24.01%,demonstrating the effectiveness and universality of this strategy.Overall,this innovative interface bridging strategy effectively tackles interface defects and low UV light utilization in PSCs,presenting a promising approach for achieving highly efficient and stable PSCs. 展开更多
关键词 Perovskite solar cells Aggregation-induced emission Defect passivation EFFICIENCY UV stability
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面向工业化种植的光热管理农膜——机遇与挑战
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作者 Song Zhang Zhang Chen +2 位作者 Chuanxiang Cao Yuanyuan Cui Yanfeng Gao 《Engineering》 SCIE EI CAS CSCD 2024年第4期191-200,共10页
As indispensable parts of greenhouses and plant factories,agricultural covering films play a prominent role in regulating microclimate environments.Polyethylene covering films directly transmit the full solar spectrum... As indispensable parts of greenhouses and plant factories,agricultural covering films play a prominent role in regulating microclimate environments.Polyethylene covering films directly transmit the full solar spectrum.However,this high level of sunlight transmission may be inappropriate or even harmful for crops with specific photothermal requirements.Modern greenhouses are integrated with agricultural covering materials,heating,ventilation,and air conditioning(HVAC)systems,and smart irrigation and communication technologies to maximize planting efficiency.This review provides insight into the photothermal requirements of crops and ways to meet these requirements,including new materials based on passive radiative cooling and light scattering,simulations to evaluate the energy consumption and environmental conditions in a greenhouse,and data mining to identify key biological growth factors and thereby improve new covering films.Finally,future challenges and directions for photothermalmanagement agricultural films are elaborated on to bridge the gap between lab-scale research and large-scale practical applications. 展开更多
关键词 GREENHOUSE Photothermal management Passive radiative cooling Light scattering
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Foam rolling and stretching do not provide superior acute flexibility and stiffness improvements compared to any other warm-up intervention: A systematic review with meta-analysis
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作者 Konstantin Warneke Gerit Plöschberger +5 位作者 Lars H.Lohmann Eric Lichtenstein Daniel Jochum Stanislav D.Siegel Astrid Zech David G.Behm 《Journal of Sport and Health Science》 SCIE CAS CSCD 2024年第4期509-520,共12页
Background:Acute improvement in range of motion(ROM)is a widely reported effect of stretching and foam rolling,which is commonly explained by changes in pain threshold and/or musculotendinous stiffness.Interestingly,t... Background:Acute improvement in range of motion(ROM)is a widely reported effect of stretching and foam rolling,which is commonly explained by changes in pain threshold and/or musculotendinous stiffness.Interestingly,these effects were also reported in response to various other active and passive interventions that induce responses such as enhanced muscle temperature.Therefore,we hypothesized that acute ROM enhancements could be induced by a wide variety of interventions other than stretching or foam rolling that promote an increase in muscle temperature.Methods:After a systematic search in PubMed,Web of Science,and SPORTDiscus databases,38 studies comparing the effects of stretching and foam rolling with several other interventions on ROM and passive properties were included.These studies had 1134 participants in total,and the data analysis resulted in 140 effect sizes(ESs).ES calculations were performed using robust variance estimation model with R-package.Results:Study quality of the included studies was classified as fair(PEDro score=4.58)with low to moderate certainty of evidence.Results showed no significant differences in ROM(ES=0.01,p=0.88),stiffness(ES=0.09,p=0.67),or passive peak torque(ES=-0.30,p=0.14)between stretching or foam rolling and the other identified activities.Funnel plots revealed no publication bias.Conclusion:Based on current literature,our results challenge the established view on stretching and foam rolling as a recommended component of warm-up programs.The lack of significant difference between interventions suggests there is no need to emphasize stretching or foam rolling to induce acute ROM,passive peak torque increases,or stiffness reductions. 展开更多
关键词 Range of motion Passive properties Muscletendon unit Muscle tissue
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Interfacial engineering through lead binding using crown ethers in perovskite solar cells
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作者 Sun-Ju Kim YeonJu Kim +8 位作者 Ramesh Kumar Chitumalla Gayoung Ham Thanh-Danh Nguyen Joonkyung Jang Hyojung Cha Jovana Milić Jun-Ho Yum Kevin Sivula Ji-Youn Seo 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第5期263-270,共8页
In the domain of perovskite solar cells(PSCs),the imperative to reconcile impressive photovoltaic performance with lead-related issue and environmental stability has driven innovative solutions.This study pioneers an ... In the domain of perovskite solar cells(PSCs),the imperative to reconcile impressive photovoltaic performance with lead-related issue and environmental stability has driven innovative solutions.This study pioneers an approach that not only rectifies lead leakage but also places paramount importance on the attainment of rigorous interfacial passivation.Crown ethers,notably benzo-18-crown-6-ether(B18C6),were strategically integrated at the perovskite-hole transport material interface.Crown ethers exhibit a dual role:efficiently sequestering and immobilizing Pb^(2+)ions through host-guest complexation and simultaneously establishing a robust interfacial passivation layer.Selected crown ether candidates,guided by density functional theory(DFT)calculations,demonstrated proficiency in binding Pb2+ions and optimizing interfacial energetics.Photovoltaic devices incorporating these materials achieved exceptional power conversion efficiency(PCE),notably 21.7%for B18C6,underscoring their efficacy in lead binding and interfacial passivation.Analytical techniques,including time-of-flight secondary ion mass spectrometry(ToF-SIMS),ultraviolet photoelectron spectroscopy(UPS),time-resolved photoluminescence(TRPL),and transient absorption spectroscopy(TAS),unequivocally affirmed Pb^(2+)ion capture and suppression of non-radiative recombination.Notably,these PSCs maintained efficiency even after enduring 300 h of exposure to 85%relative humidity.This research underscores the transformative potential of crown ethers,simultaneously addressing lead binding and stringent interfacial passivation for sustainable PSCs poised to commercialize and advance renewable energy applications. 展开更多
关键词 Perovskite solar cells Interfacial passivation Crown ether materials Stability
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Provenance and depositional setting of the Late MiocenePleistocene clastic sediments in the eastern Arabian Peninsula and western Iraq using rare earth elements geochemistry
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作者 Salih M.Awadh Zinah S.Al-Ankaz +1 位作者 Mohanad R.A.Al-Owaidi John S.Armstrong-Altrin 《Acta Geochimica》 EI CAS CSCD 2024年第2期399-410,共12页
The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements(REE) and trace elements(Sc, Co,... The sandstones of the Late miocene–Pliocene Dibdibba Formation in the Najaf–Karbala Plateau and Basra were examined to determine their source rocks and origin. The rare earth elements(REE) and trace elements(Sc, Co, V, and Th) concentrations in these sandstones revealed that they likely derived from a single source. The steep light rare earth elements(LREE) and flat, heavy rare earth element(HREE) patterns, negative Eu anomaly, and high ΣREE contents in sandstones suggest its derivation from a suggests that a passive continental margin environment and originated from felsic source rocks. The average concentration of ΣREE is 93.5 ppm, which is lower than that of the average crustal compositions like Upper Continental Crust and Post Archean Australian Shale. The higher proportion of LREE compared to HREE implies that these sandstones were recycled and derived from a distal source. The Th/Co, Th/Sc, La/Sc, La/Co, Eu/Eu*and(La/Lu)cn elemental ratios indicated that these Late Miocene–Pliocene sandstones were derived from felsic rocks located in the marginal region of the Arabian Shield. 展开更多
关键词 REE Dibdibba formation Clastic sediments Passive continental margin
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Modulation on electrostatic potential to build a firm bridge at NiO_(x)/perovskite interface for efficient and stable perovskite solar cells
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作者 Xiangbao Yuan Xufeng Ling +4 位作者 Hongyu Wang Chengxia Shen Ru Li Yehao Deng Shijian Chen 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第9期249-258,共10页
The NiO_(x)/perovskite interface in NiO_(x)-based inverted perovskite solar cells(PSCs)is one of the main issues that restrict device performance and long-term stability,as the unwanted interfacial defects and undesir... The NiO_(x)/perovskite interface in NiO_(x)-based inverted perovskite solar cells(PSCs)is one of the main issues that restrict device performance and long-term stability,as the unwanted interfacial defects and undesirable redox reactions cause severe interfacial non-radiative recombination and open-circuit voltage(Voc)loss.Herein,a series of self-assembled molecules(SAMs)are employed to bind,bridge,and stabilize the NiO_(x)/perovskite interface by regulating the electrostatic potential.Based on systematically theoretical and experimental studies,4-pyrazolecarboxylic acid(4-PCA)is proven as an efficient molecule to simultaneously passivate the NiO_(x)and perovskite surface traps,release the interfacial tensile stress as well as quench the detrimental interface redox reactions,thus effectively suppressing the interfacial non-radiative recombination and enhancing the quality of perovskite crystals.Consequently,the PSCs with 4-PCA treatment exhibited an eminently increased Voc,leading to a significant increase in power conversion efficiency from 21.28%to 23.77%.Furthermore,the unencapsulated devices maintain 92.6%and 81.3%of their initial PCEs after storing in air with a relative humidity of 20%–30%for 1000 h and heating at 65℃for 500 h in a N_(2)-filled glovebox,respectively. 展开更多
关键词 Perovskite solar cells Nickel oxide Interface defects passivation Redox reaction Nonradiative recombination
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Ballistic design and testing of a composite armour reinforced by CNTs suitable for armoured vehicles
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作者 Evangelos Ch.Tsirogiannis Evangelos Daskalakis +2 位作者 Mohamed H.Hassan Abdalla M.Omar Paulo Bartolo 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期173-195,共23页
This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite mate... This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite materials and high-performance ballistic projectiles. Four armour materials, consisted of front hybrid fibre reinforced polymer cover layer, ceramic strike-face, fibre reinforced polymer intermediate layer and the metal matrix composite reinforced backplate, were manufactured and assembled by adhesive technology. The proposed laminated protection system is suitable for armoured ground vehicles;however, it could be used as armour on ground, air and naval platforms. The design of the protection system, including material selection and thickness, was elaborated depending on the performance requirements of Level 4 + STANAG 4569 military standard(projectile 14.5 mm × 114 mm API B32) and especially on a design philosophy which is analysed with the specifications. The backplate of this new composite is a hybrid material of Metal Matrix Composite(MMC) reinforced with carbon nanotubes(CNTs), manufactured with the use of powder metallurgy technique. The composite backplate material was morphologically, mechanically and chemically analysed. Results show that all plates are presenting high mechanical properties and ballistic characteristics, compared to commonly used armour plates. Real military ballistic tests according to AEP-STANAG 4569 were carried out for the total composite armour systems. After the ballistic tests, AA2024-CNT3 showed the best protection results, compared with the other plates(AA2024-CNT1 and AA2024-CNT2), with the projectile being unable to fully penetrate the composite plate. 展开更多
关键词 Passive armour protection Protective armour Ballistic performance Hybrid composites Vehicle protection
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Reinforced SnO2 tensile-strength and“buffer-spring”interfaces for efficient inorganic perovskite solar cells
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作者 Yuanyuan Zhao Lei Gao +6 位作者 Qiurui Wang Qiang Zhang Xiya Yang Jingwei Zhu Hao Huang Jialong Duan Qunwei Tang 《Carbon Energy》 SCIE EI CAS CSCD 2024年第6期282-291,共10页
Suppressing nonradiative recombination and releasing residual strain areprerequisites to improving the efficiency and stability of perovskite solar cells(PSCs).Here,long-chain polyacrylic acid(PAA)is used to reinforce... Suppressing nonradiative recombination and releasing residual strain areprerequisites to improving the efficiency and stability of perovskite solar cells(PSCs).Here,long-chain polyacrylic acid(PAA)is used to reinforce SnO_(2)film and passivate SnO_(2)defects,forming a structure similar to“reinforcedconcrete”with high tensile strength and fewer microcracks.Simultaneously,PAA is also introduced to the SnO_(2)/perovskite interface as a“buffer spring”torelease residual strain,which also acts as a“dual-side passivation interlayer”to passivate the oxygen vacancies of SnO_(2)and Pb dangling bonds in halideperovskites.As a result,the best inorganic CsPbBr_(3)PSC achieves a championpower conversion efficiency of 10.83%with an ultrahigh open-circuit voltageof 1.674 V.The unencapsulated PSC shows excellent stability under 80%relative humidity and 80℃over 120 days. 展开更多
关键词 charge recombination defect passivation inorganic perovskite solar cells interfacial modification strain relaxation
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Highly Porous Yet Transparent Mechanically Flexible Aerogels Realizing Solar-Thermal Regulatory Cooling
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作者 Meng Lian Wei Ding +5 位作者 Song Liu Yufeng Wang Tianyi Zhu Yue-EMiao Chao Zhang Tianxi Liu 《Nano-Micro Letters》 SCIE EI CAS CSCD 2024年第7期231-243,共13页
The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but challenging.Herein,a delaminated aerogel film(DAF)is fab... The demand for highly porous yet transparent aerogels with mechanical flexibility and solar-thermal dual-regulation for energy-saving windows is significant but challenging.Herein,a delaminated aerogel film(DAF)is fabricated through filtration-induced delaminated gelation and ambient drying.The delaminated gelation process involves the assembly of fluorinated cellulose nanofiber(FCNF)at the solid-liquid interface between the filter and the filtrate during filtration,resulting in the formation of lamellar FCNF hydrogels with strong intra-plane and weak interlayer hydrogen bonding.By exchanging the solvents from water to hexane,the hydrogen bonding in the FCNF hydrogel is further enhanced,enabling the formation of the DAF with intra-layer mesopores upon ambient drying.The resulting aerogel film is lightweight and ultra-flexible,which pos-sesses desirable properties of high visible-light transmittance(91.0%),low thermal conductivity(33 mW m^(-1) K^(-1)),and high atmospheric-window emissivity(90.1%).Furthermore,the DAF exhibits reduced surface energy and exceptional hydrophobicity due to the presence of fluorine-containing groups,enhancing its durability and UV resistance.Consequently,the DAF has demonstrated its potential as solar-thermal regulatory cooling window materials capable of simultaneously providing indoor lighting,thermal insulation,and daytime radiative cooling under direct sunlight.Significantly,the enclosed space protected by the DAF exhibits a temperature reduction of 2.6℃ compared to that shielded by conventional architectural glass. 展开更多
关键词 Transparent aerogel Cellulose nanofiber aerogel Delaminated gelation Thermal insulation Passive daytime radiative cooling
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