Path Integral Approach to the Interaction of Two-Electron Atoms with Elliptically Polarized Pulses

We study the dynamics of a two-electron atom interacting with a pulsed, elliptically polarized, ultrashort, excited coherent state. We use path integral methods and integrate on the photonic part. We angularly decompose the Coulomb interaction term of the two electrons and the interaction term of the two electrons with the photonic field and solve the sign problem. We give results on the survival probability of the ground state of Helium.

Feynman Path Integral Using Operator Integration in Banach Space

Feynman-Path Integral in Banach Space: In 1940, R.P. Feynman attempted to find a mathematical representation to express quantum dynamics of the general form for a double-slit experiment. His intuition on several slits with several walls in terms of Lagrangian instead of Hamiltonian resulted in a magnificent work. It was known as Feynman Path Integrals in quantum physics, and a large part of the scientific community still considers them a heuristic tool that lacks a sound mathematical definition. This paper aims to refute this prejudice, by providing an extensive and self-contained description of the mathematical theory of Feynman Path Integration, from the earlier attempts to the latest developments, as well as its applications to quantum mechanics. About a hundred years after the beginning of modern physics, it was realized that light could in fact show behavioral characteristics of both waves and particles. In 1927, Davisson and Germer demonstrated that electrons show the same dual behavior, which was later extended to atoms and molecules. We shall follow the method of integration with some modifications to construct a generalized Lebesgue-Bochner-Stieltjes (LBS) integral of the form , where u is a bilinear operator acting in the product of Banach spaces, f is a Bochner summable function, and μ is a vector-valued measure. We will demonstrate that the Feynman Path Integral is consistent and can be justified mathematically with LBS integration approach.

PATH INTEGRAL SOLUTION OF NONLINEAR DYNAMIC BEHAVIOR OF STRUCTURE UNDER WIND EXCITATION

A numerical scheme for the nonlinear behavior of structure under wind excitation is investigated. With the white noise filter of turbulent-wind fluctuations, the nonlinear motion equation of structures subjected to wind load was modeled as the Ito＇ s stochastic differential equation. The state vector associated with such a model is a diffusion process. A continuous linearization strategy in the time-domain was adopted. Based on the solution series of its stochastic linearization equations, the formal probabilistic density of the structure response was developed by the path integral technique. It is shown by the numerical example of a guyed mast that compared with the frequency-domain method and the time-domain nonlinear analysis, the proposed approach is highlighted by high accuracy and effectiveness. The influence of the structure non-linearity on the dynamic reliability assessment is also analyzed in the example.

Path integral solutions for n-dimensional stochastic differential equations underα-stable Lévy excitation

In this paper,the path integral solutions for a general n-dimensional stochastic differential equa-tions(SDEs)withα-stable Lévy noise are derived and verified.Firstly,the governing equations for the solutions of n-dimensional SDEs under the excitation ofα-stable Lévy noise are obtained through the characteristic function of stochastic processes.Then,the short-time transition probability density func-tion of the path integral solution is derived based on the Chapman-Kolmogorov-Smoluchowski(CKS)equation and the characteristic function,and its correctness is demonstrated by proving that it satis-fies the governing equation of the solution of the SDE,which is also called the Fokker-Planck-Kolmogorov equation.Besides,illustrative examples are numerically considered for highlighting the feasibility of the proposed path integral method,and the pertinent Monte Carlo solution is also calculated to show its correctness and effectiveness.

Unified treatment of the bound states of the Schioberg and the Eckart potentials using Feynman path integral approach

We obtain analytical expressions for the energy eigenvalues of both the Schioberg and Eckart potentials using an approximation of the centrifugal term. In order to determine the l-states solutions, we use the Feynman path integral approach to quantum mechanics. We show that by performing nonlinear space-time transformations in the radial path integral, we can derive a transformation formula that relates the original path integral to the Green function of a new quantum solvable system. The explicit expression of bound state energy is obtained and the associated eigenfunctions are given in terms of hypergeometric functions. We show that the Eckart potential can be derived from the Schioberg potential. The obtained results are compared to those produced by other methods and are found to be consistent.

Hooke's Atom in an Arbitrary External Electric Field: Analytical Solutions of Two-Electron Problem by Path Integral Approach

By using the path integral approach, we investigate the problem of Hooke＇s atom （two electrons interacting with Coulomb potential in an external harmonic-oscillator potential） in an arbitrary time-dependent electric field. For a certain infinite set of discrete oscillator frequencies, we obtain the analytical solutions. The ground state polarization of the atom is then calculated. The same result is also obtained through linear response theory.

Generalized Fourth-Order Decompositions of Imaginary Time Path Integral:Implications of the Harmonic Oscillator

The imaginary time path integral formalism offers a powerful numerical tool for simulating thermodynamic properties of realistic systems.We show that,when second-order and fourth-order decompositions are employed,they share a remarkable unified analytic form for the partition function of the harmonic oscillator.We are then able to obtain the expression of the thermodynamic property and the leading error terms as well.In order to obtain reasonably optimal values of the free parameters in the generalized symmetric fourth-order decomposition scheme,we eliminate the leading error terms to achieve the accuracy of desired order for the thermodynamic property of the harmonic system.Such a strategy leads to an efficient fourth-order decomposition that produces thirdorder accurate thermodynamic properties for general systems.

Finite Size Effect in Path Integral Monte Carlo Simulations of ~4He Systems

Path integral Monte Carlo （PIMC） simulations are a powerful computational method to study interacting quantum systems at finite temperatures. In this work, PIMC has been applied to study the finite size effect of the simulated systems of ^4He. We determine the energy as a function of temperature at saturated-vapor-pressure （SVP） conditions in the temperature range of T ∈ [1.0 K,4.0 K], and the equation of state （EOS） in the grmmd state For systems consisted of 32, 64 and 128 ^4He atoms, respectively, We find that the energy at SVP is influenced significantly by the size of the simulated system in the temperature range of T ∈ [2.1 K, 3.0 K] and the larger the system is, the better results are obtained in comparison with the experimental values; while the EOS appeared to be unrelated to it.

Path integral Monte Carlo study of(H_2)_n@C_(70)(n = 1, 2, 3)

The path integral Monte Carlo(PIMC) method is employed to study the thermal properties of C70 with one, two,and three H2 molecules confined in the cage, respectively. The interaction energies and vibrationally averaged spatial distributions under different temperatures are calculated to evaluate the stabilities of(H2)n@C70(n = 1, 2, 3). The results show that(H2)2@C70is more stable than H2@C70. The interaction energy slowly changes in a large temperature range,so temperature has little effect on the stability of the system. For H2@C70and(H2)2@C70, the interaction energies keep negative; however, when three H2 molecules are in the cage, the interaction energy rapidly increases to a positive value.This implies that at most two H2 molecules can be trapped by C70. With an increase of temperature, the peak of the spatial distribution gradually shifts away from the center of the cage, but the maximum distance from the center of H2 molecule to the cage center is much smaller than the average radius of C70.

Effect of a force-free end on the mechanical property of a biopolymer--A path integral approach

We study the effect of a force-free end on the mechanical property of a stretched biopolymer.The system can be divided into two parts.The first part consists of the segment counted from the fixed point（i.e.,the origin） to the forced point in the biopolymer,with arclength L_f.The second part consists of the segment counted from the forced point to the force-free end with arclength △L.We apply the path integral technique to find the relationship between these two parts.At finite temperature and without any constraint at the end,we show exactly that if we focus on the quantities related to the first part,then we can ignore the second part completely.Monte Carlo simulation confirms this conclusion.In contrast,the effect for the quantities related to the second part is dependent on what we want to observe.A force-free end has little effect on the relative extension,but it affects seriously the value of the end-to-end distance if △L is comparable to L_f.

Coherent States and a Path Integral for the Relativistic Linear Singular Oscillator

The SU（1,1） coherent states for a relativistic model of the linear singular oscillator are considered. The corresponding partition function is evaluated. The path integral for the transition amplitude between SU（1,1） coherent states is given. Classical equations of the motion in the generalized curved phase space are obtained. It is shown that the use of quasiclassical Bohr Sommerfeld quantization rule yields the exact expression for the energy spectrum.

Establishing path integral in the entangled state representation for Hamiltonians in quantum optics

Based on two mutually conjugate entangled state representations, we establish the path integral formalism for some Hamiltonians of quantum optics in entangled state representations. The Wigner operator in the entangled state representation is presented. Its advantages are explained.

A Note on Calculation of Phase Space Path Integral by Means of Invariants

In this note we use the method of invariant to calculate the phase space path integral appearing in our previous article.

Phase Space Path Integral Method for Problem of Obtaining Propagator of a Particle with a Force Quadratic in Velocity

This article uses the phase space path integral method to find the propagator for a particle with a force quadratic in velocity. Two specific canonical transformations has been used for this purpose.

Path Integral Formalism for Nondegenerate Parametric Amplifiers in Entangled State Representation

We establish the path integral formalism for nondegenerate parametric amplifiers in the entangled state representations. Its advantage in obtaining the energy level gap of this system is analyzed.

Path integral approach to electron scattering in classical electromagnetic potential

As is known to all, the electron scattering in classical electromagnetic potential is one of the most widespread applications of quantum theory. Nevertheless, many discussions about electron scattering are based upon single-particle Schrodinger equation or Dirac equation in quantum mechanics rather than the method of quantum field theory. In this paper, by using the path integral approach of quantum field theory, we perturbatively evaluate the scattering amplitude up to the second order for the electron scattering by the classical electromagnetic potential. The results we derive are convenient to apply to all sorts of potential forms. Furthermore, by means of the obtained results, we give explicit calculations for the one-dimensional electric potential.

Accurate Calculation of Equilibrium Reduced Density Matrix for the System-Bath Model:a Multilayer Multiconfiguration Time-Dependent Hartree Approach and its Comparison to a Multi-Electronic-State Path Integral Molecular Dynamics Approach

An efficient and accurate method for computing the equilibriurn reduced density matrix is presented for treating open quantum systems characterized by the systern-bath model. The method employs the rnultilayer nmlticonfiguration tirne-dependent Hartree theory for imag- inary time propagation and an importance sampling procedure for calculating the quantum mechanical trace. The method is applied to the spin-boson Harniltonian, which leads to ac- curate results in agreement with those produced by the rnulti-electronic-state path integral molecular dynamics method.

Path Integral Liouville Dynamics Simulations of Vibrational Spectra of Formaldehyde and Hydrogen Peroxide

Formaldehyde and hydrogen peroxide are two important realistic molecules in atmospheric chemistry.We implement path integral Liouville dynamics(PILD)to calculate the dipolederivative autocorrelation function for obtaining the infrared spectrum.In comparison to exact vibrational frequencies,PILD faithfully captures most nuclear quantum effects in vibrational dynamics as temperature changes and as the isotopic substitution occurs.

Thermodynamic Parameters of Central Spin Coupled to an Antiferromagnetic Bath: Path Integral Formalism

A path-integral representation of central spin system immersed in an antiferromagnetic environment was investigated. To carry out this study, we made use of the discrete-time propagator method associated with a basic set involving coherent states of Grassmann variables which made it possible to obtain the analytical propagator which is the centerpiece of the study. In this study, we considered that the environment was in the low-temperature and low-excitation limit and was split into 2 subnets that do not interact with each other. The evaluation of our system was made by considering the first neighbor approximation. From the formalism of the path integrals, it is easy to evaluate the partition function and thermodynamic properties followed from an appropriate tracing over Grassmann variables in the imaginary time domain. We show that the energy of the system depends on the number of sites n when β → 0.

Path Integral Molecular Dynamics Simulation on Atomic Distribution in Amorphized Ice Ic

We have investigated the effects of compression and quantization on atomic distribution in ice Ic and in its compressed states at 77 K and 10 K, using the path integral molecular dynamics (PIMD) simulations over wide range of volume. It has been found that the high density amorphous ice (HDA) is attained by compression but volume range to retain ice structure is wider at 10 K than 77 K. We have discovered that quantum dispersion of atoms in ice Ic at 10 K induces non-zero probability that hydrogen-bonded H2O molecular molecules are oriented nonlinearly in the crystal structure, which was believed to contain exclusively linear orientation of hydrogen-bonded molecular pairs in this ice. It has been found that for HDA there is each non-zero probability of orientational disorder of hydrogen-bonded H2O pairs, of such uniform distribution of H atoms as observed in supercritical fluids in general, and of H atoms located at the O-O midpoint. The present PIMD simulations have revealed that these observed anomalous characteristics of atomic distribution in HDA are caused by both quantization of atoms and compression of the system.