Surface ion-imprinted in combination with sol-gel process was applied to synthesis a new Pb（Ⅱ）-imprinted polymer for selective separation and enrichment of trace Pb（Ⅱ） from aqueous solution. The prepared materia...Surface ion-imprinted in combination with sol-gel process was applied to synthesis a new Pb（Ⅱ）-imprinted polymer for selective separation and enrichment of trace Pb（Ⅱ） from aqueous solution. The prepared material was characterized by using the infrared spectra, X-ray diffractometer, and scanning electron microscopy. The batch experiments were conducted to study the optimal adsorption condition of adsorption trace Pb（Ⅱ） from aqueous solutions on Pb（Ⅱ）-imprinted polymer. The equilibrium was achieved in approximately 4,0 h, and the experimental kinetic data were fitted the pseudo second-order model better. The maximum adsorption capacity was 22.7 mg/g, and the Langmuir equation fitted the adsorption isotherm data. The results of selectivity experiment showed that selectively adsorbed rate of Pb（Ⅱ） on Pb（Ⅱ）-imprinted polymer was higher than all other studied ions. Desorption conditions of the adsorbed Pb（Ⅱ） from the Pb（Ⅱ）-imprinted polymer were also studied in batch experiments. The prepared Pb（Ⅱ）-imprinted polymer was shown to be promising for the separation and enrichment of trace Pb（Ⅱ） from water samples. The adsorption and desorption mechanisms were proposed.展开更多
Chitosan and chitosan membranes with Pb(Ⅱ) ion as template were studied. The adsorption isotherms were correlated by dc/dt=-kcn at the temperature of 30 ℃, 35 ℃, 40 ℃, 45 ℃, 50 ℃. By means of linear correlation,...Chitosan and chitosan membranes with Pb(Ⅱ) ion as template were studied. The adsorption isotherms were correlated by dc/dt=-kcn at the temperature of 30 ℃, 35 ℃, 40 ℃, 45 ℃, 50 ℃. By means of linear correlation, the shapes of the isotherm curves were similar to the kinetic function of 2/C=-kt and the apparent activation energy for with chitosan(123.8 kJ·moL-1) was larger than that of membrane with Pb(Ⅱ) ion(92.3 kJ·moL-1). The chitosan membrane with Pb(Ⅱ) ion template was better "memory" function. The adsorption mechanism of chitosan with Pb(Ⅱ) was studied by IR and XPS. The results indicated that the nitrogen in-NH2 and the oxygen in C3-OH of chitosan were coordination atoms.展开更多
采用表面印迹技术,结合溶胶凝胶过程,合成了巯基功能化的Pb(Ⅱ)离子印迹吸附剂,利用傅立叶变换红外光谱和N2吸附-脱附对其进行了表征,并用平衡吸附实验研究了其固相萃取性能。结果表明,该印迹吸附剂对Pb(Ⅱ)的结合能力和选择性明显高于...采用表面印迹技术,结合溶胶凝胶过程,合成了巯基功能化的Pb(Ⅱ)离子印迹吸附剂,利用傅立叶变换红外光谱和N2吸附-脱附对其进行了表征,并用平衡吸附实验研究了其固相萃取性能。结果表明,该印迹吸附剂对Pb(Ⅱ)的结合能力和选择性明显高于非印迹吸附剂,并且具有较快的吸附速率,20 m in即达到吸附平衡,最大的平衡吸附量达221 mg/g,在Cd(Ⅱ)存在下,相对选择性系数达到121。该法的检出限为0.23μg/L,相对标准偏差为3.7%。将该印迹吸附剂用于实际水样的分离富集和测定,结果令人满意。展开更多
基金supported by the National Natural Science Foundation of China (No. 20877036)
文摘Surface ion-imprinted in combination with sol-gel process was applied to synthesis a new Pb（Ⅱ）-imprinted polymer for selective separation and enrichment of trace Pb（Ⅱ） from aqueous solution. The prepared material was characterized by using the infrared spectra, X-ray diffractometer, and scanning electron microscopy. The batch experiments were conducted to study the optimal adsorption condition of adsorption trace Pb（Ⅱ） from aqueous solutions on Pb（Ⅱ）-imprinted polymer. The equilibrium was achieved in approximately 4,0 h, and the experimental kinetic data were fitted the pseudo second-order model better. The maximum adsorption capacity was 22.7 mg/g, and the Langmuir equation fitted the adsorption isotherm data. The results of selectivity experiment showed that selectively adsorbed rate of Pb（Ⅱ） on Pb（Ⅱ）-imprinted polymer was higher than all other studied ions. Desorption conditions of the adsorbed Pb（Ⅱ） from the Pb（Ⅱ）-imprinted polymer were also studied in batch experiments. The prepared Pb（Ⅱ）-imprinted polymer was shown to be promising for the separation and enrichment of trace Pb（Ⅱ） from water samples. The adsorption and desorption mechanisms were proposed.
文摘Chitosan and chitosan membranes with Pb(Ⅱ) ion as template were studied. The adsorption isotherms were correlated by dc/dt=-kcn at the temperature of 30 ℃, 35 ℃, 40 ℃, 45 ℃, 50 ℃. By means of linear correlation, the shapes of the isotherm curves were similar to the kinetic function of 2/C=-kt and the apparent activation energy for with chitosan(123.8 kJ·moL-1) was larger than that of membrane with Pb(Ⅱ) ion(92.3 kJ·moL-1). The chitosan membrane with Pb(Ⅱ) ion template was better "memory" function. The adsorption mechanism of chitosan with Pb(Ⅱ) was studied by IR and XPS. The results indicated that the nitrogen in-NH2 and the oxygen in C3-OH of chitosan were coordination atoms.
文摘采用表面印迹技术,结合溶胶凝胶过程,合成了巯基功能化的Pb(Ⅱ)离子印迹吸附剂,利用傅立叶变换红外光谱和N2吸附-脱附对其进行了表征,并用平衡吸附实验研究了其固相萃取性能。结果表明,该印迹吸附剂对Pb(Ⅱ)的结合能力和选择性明显高于非印迹吸附剂,并且具有较快的吸附速率,20 m in即达到吸附平衡,最大的平衡吸附量达221 mg/g,在Cd(Ⅱ)存在下,相对选择性系数达到121。该法的检出限为0.23μg/L,相对标准偏差为3.7%。将该印迹吸附剂用于实际水样的分离富集和测定,结果令人满意。
