Tetrabromobisphenol A and hexabromocyclododecane in sediments from the Zhujiang(Pearl) River Estuary and South China Sea

Marine sediments collected from the Zhujiang(Pearl) River Estuary(ZRE) and South China Sea(SCS) were utilized to study the occurrence and spatial distribution of tetrabromobisphenol A(TBBPA) and hexabromocyclododecane(HBCDD).The levels of TBBPA and HBCDD in sediments ranged from not detected(nd) to 6.14 ng/g dry weight(dw) and nd to 0.42 ng/g dw.TBBPA concentrations in marine sediments were substantially higher than HBCDD.The concentrations of TBBPA and HBCDD in the ZRE sediments were significantly greater than those in the SCS.α-HBCDD(48.7%) and γ-HBCDD(46.2%) were the two main diastereoisomers of HBCDD in sediments from the ZRE,with minor contribution of β-HBCDD(5.1%).HBCDD were only found in one sample from the northern SCS.The enantiomeric fraction of α-HBCDD in sediments from the ZRE was obviously greater than 0.5,indicating an accumulation of(+)-α-HBCDD.The enantiomers of HBCDD were not measured in sediments from the SCS.This work highlighted the environmental behaviors of TBBPA and HBCDD in marine sediments.

Difference Analysis of Urban Landscape Pattern Change at Both Banks of Pearl River Estuary in China

By using remote sensing image data of Landsat-5 TM (1988, 1995 and 1998) and Landsat-7 ETM (2002), remote sensing image data, land-use map and DEM had been put in the same coordinate system and projection. In ArcView, all data had been rasterized as grid data of 30 m×30 m. By Fragstats, landscape pattern indexes had been calculated. Based on the average area, patch density, landscape isolation, boundary density, shape index, fractal dimension, aggregation degree, diversity and evenness index, landscape pattern at different periods and its evolution had been analyzed, revealing the differentiation of spatio-temporal change of landscape pattern at both banks of Pearl River Estuary.

Offshore Fault Geometrics in the Pearl River Estuary,Southeastern China:Evidence from Seismic Reflection Data

The Pearl River Estuary(PRE) is located at the onshore-offshore transition zone between South China and South China Sea Basin, and it is of great significant value in discussing tectonic relationships between South China block and South China Sea block and seismic activities along the offshore active faults in PRE. However, the researches on geometric characteristics of offshore faults in this area are extremely lacking. To investigate the offshore fault distribution and their geometric features in the PRE in greater detail, we acquired thirteen seismic reflection profiles in 2015. Combining the analysis of the seismic reflection and free-air gravity anomaly data, this paper revealed the location, continuity, and geometry of the littoral fault zone and other offshore faults in PRE. The littoral fault zone is composed of the major Dangan Islands fault and several parallel, high-angle, normal faults, which mainly trend northeast to northeast-to-east and dip to the southeast with large displacements. The fault zone is divided into three different segments by the northwest-trending faults. Moreover, the basement depth around Dangan Islands is very shallow, while it suddenly increases along the islands westward and southward. These has resulted in the islands and neighboring areas becoming the places where the stress accumulates easily. The seismogenic pattern of this area is closely related to the comprehensive effect of intersecting faults together with the low velocity layer.

Phytoplankton Assemblage Structure Shaped by Key Environmental Variables in the Pearl River Estuary, South China

Spatial distribution and temporal dynamics of phytoplankton community and their relationships with environmental factors were studied in the Pearl River Estuary(PRE), South China, in three seasons. Salinity was considered as the key environmental variable controlling horizontal distributions of phytoplankton community composition. A transition from dominance of freshwater diatoms(Aulacoseira granulata and A. granulata v. angustissima) to estuarine species(Skeletonema costatum and Pseudonitzschia delicatissima) was observed in the high flow season(summer) along the estuary gradient; in the low flow season(spring), the inner estuary was relatively homogeneous and some typical estuarine species could be found near the river mouth. In the normal flow season(autumn), a potentially toxic bluegreen species, Microcystis spp. was predominant in the middle reaches of the estuary, which should be seeded from upstream and transported downstream by river discharges. Phytoplankton abundance was negatively correlated with suspended solid content and nutrient concentration in the PRE, suggesting that turbidity and nutrient availability were the crucial factors regulating the algal biomass. Phytoplankton abundance in the outer estuary was enhanced by increasing irradiance and continued to be enhanced until phosphorus-limitation.

Geometry and 3D seismic characterisation of post-rift normal faults in the Pearl River Mouth Basin,northern South China Sea

Based on high-resolution 3D seismic data acquired in the Pearl(Zhujiang)River Mouth Basin of the northern South China Sea,this study investigated the geometry,spatial extension,and throw distribution of the post-rift normal fault through detailed seismic interpretation and fault modeling.A total of 289 post-rift normal faults were identified in the study area and can be classified into four types:(1)isolated normal faults above the carbonate platform;(2)isolated normal faults cutting through the carbonate platform;(3)conjugate normal faults,and(4)connecting normal faults.Throw distribution analysis on the fault planes show that the vertical throw profiles of most normal fault exhibit flat-topped profiles.Isolated normal faults above the carbonate platform exhibit roughly concentric ellipses with maximum throw zones in the central section whereas the normal faults cutting through the carbonate platform miss the lowermost section due to the chaotic seismic reflections in the interior of the carbonate platform.The vertical throws of conjugate normal faults anomalously decrease toward their intersection region on the fault plane whereas the connecting normal faults present two maximum throw zones in the central section of the fault plane.According to the symmetric elliptical distribution model of fault throw,an estimation was made indicating that normal faults cutting through the carbonate platform extended downward between-1308 s and-1780 s(two-way travel time)in depth and may not penetrate the entire Liuhua carbonate platform.Moreover,it is observed that the distribution of karst caves on the top of the carbonate platform disaccord with those of hydrocarbon reservoirs and the post-rift normal faults cutting through the carbonate platform in the study area.We propose that these karst caves formed most probably by corrosive fluids derived from magmatic activities during the Dongsha event,rather than pore waters or hydrocarbons.

Impact of Hinterland Manufacturing on the Development of Container Ports: Evidence from the Pearl River Delta, China

Container ports and hinterland manufacturing are two important forces of the local participation in economic globalization.This study,taking the Pearl River Delta(PRD),China with an export-oriented economy as an example,applies Huff and panel regres-sion models to evaluate the impact of hinterland manufacturing on the development of container ports during the period of 1993–2019.The results show that 1)the spatial patterns of hinterlands for hub ports help to determine the distribution range and scale of economic variables that affect port throughput;2)the hinterland’s gross manufacturing output has universally positive influence on port through-put,wherein export-oriented processing and the entire manufacturing industry have significantly positive impact on port throughput in 1993–2011 and 2001–2019,respectively;3)the two internal structural factors related to an export-oriented economy,labor-intensive sectors and foreign-funded terminals,have positively moderate the direct influence of hinterland manufacturing on port throughput.Our results highlight the importance of local context in understanding port-manufacturing relationship in developing economies.Based on our findings,policy implications are further proposed to enhance port network organization in PRD.

Tectonic-thermal history and hydrocarbon potential of the Pearl River Mouth Basin,northern South China Sea:Insights from borehole apatite fission-track thermochronology

The Pearl River Mouth Basin(PRMB)is one of the most petroliferous basins on the northern margin of the South China Sea.Knowledge of the thermal history of the PRMB is significant for understanding its tectonic evolution and for unraveling its poorly studied source-rock maturation history.Our investigations in this study are based on apatite fission-track(AFT)thermochronology analysis of 12 cutting samples from 4 boreholes.Both AFT ages and length data suggested that the PRMB has experienced quite complicated thermal evolution.Thermal history modeling results unraveled four successive events of heating separated by three stages of cooling since the early Middle Eocene.The cooling events occurred approximately in the Late Eocene,early Oligocene,and the Late Miocene,possibly attributed to the Zhuqiong II Event,Nanhai Event,and Dongsha Event,respectively.The erosion amount during the first cooling stage is roughly estimated to be about 455-712 m,with an erosion rate of 0.08-0.12 mm/a.The second erosion-driven cooling is stronger than the first one,with an erosion amount of about 747-814 m and an erosion rate between about 0.13-0.21 mm/a.The erosion amount calculated related to the third cooling event varies from 800 m to 3419 m,which is speculative due to the possible influence of the magmatic activity.

Leave or Stay?Antecedents of High-level Talent Migration in the Pearl River Delta Megalopolis of China:from a Perspective of Regional Differentials in Housing Prices

Rapid urbanization and population growth have triggered an increase in urban housing demand and rising housing prices,which can influence the migration intention of high-level talents.Much work within the literature has focused more on the migration of the general public.However,antecedents of migration intention and the impact of housing prices on the migration of high-level talents remain unclear.Therefore,based on the push-pull theory,this study investigates the influencing factors of talent migration intention and explores the role of housing prices.This study reveals a complex mechanism underlying migration decisions by using logistic regression models and survey data of high-level talents in the Pearl River Delta(PRD)megalopolis of China.The results indicate that:1)in high house-price regions,social integration is the primary push factor,and the main factors for retaining talents are the expectation of future work and intimate family relationships;2)in medium house-price regions,the main factors that attract talents are the current salary level and close family ties;3)in low house-price regions,living convenience is a determining factor in retaining talents.This study provides a new perspective for talent mobility research and offers valuable inputs for retaining and attracting talents in different economic development regions.Findings are of great significance for formulating talent introduction policies and forming a new pattern of rational spatial docking and effective allocation of human resources.

Spatially Heterogeneous Response of Carbon Storage to Land Use Changes in Pearl River Delta Urban Agglomeration, China

Carbon storage of terrestrial ecosystems plays a vital role in advancing carbon neutrality. Better understanding of how land use changes affect carbon storage in urban agglomeration will provide valuable guidance for policymakers in developing effective regional conservation policies. Taking the Pearl River Delta Urban Agglomeration(PRDUA) in China as an example, we examined the heterogeneous response of carbon storage to land use changes in 1990–2018 from a combined view of administrative units and physical entities. The results indicate that the primary change in land use was due to the expansion of construction land(5897.16 km2). The carbon storage in PRDUA decreased from 767.34 Tg C in 1990 to 725.42 Tg C in 2018 with a spatial pattern of high wings and the low middle. The carbon storage loss was largely attributed to construction land expansion(55.74%), followed by forest degradation(54.81%). Changes in carbon storage showed significant divergences in different sized cities and hierarchical boundaries. The coefficients of geographically weighted regression(GWR) reveal that the alteration in carbon storage in Guangzhou City was more responsive to changes in construction land(-0.11) compared to other cities, while that in Shenzhen was mainly affected by the dynamics of forest land(8.32). The change in carbon storage was primarily influenced by the conversion of farmland within urban extent(5.05) and the degradation of forest land in rural areas(5.82). Carbon storage changes were less sensitive to the expansion of construction land in the urban center, urban built-up area, and ex-urban built-up area, with the corresponding GWR coefficients of 0.19, 0.04, and 0.02. This study necessitates the differentiated protection strategies of carbon storage in urban agglomerations.

Distribution Characteristics of COD in the Waters of Pearl River Estuary

The surveys on the COD in the Lingdingyang waters of Pearl River estuary were carried out in May and August of 2002. The results showed that the concentrations of COD in the waters ranged from 0,41 to 2.72 mg·L^-1 with an average of 1.21 mg·L^-1.The spatial distributions showed that COD concentration decreased gradually from the north to south of Pearl River estuary, and the concentration near coastal waters was higher than that in offshore waters. The concentration of COD in summer was higher than in spring. Evaluated by the first class （COD ≤ 2 mg·L^-1） of sea water quality standard （Chinese standard）, there were about 15 % of COD concentrations over the standard. The concentration of COD showed a positive correlation with the concentration of suspend substances in spring and summer, but in summer it showed a negative correlation with the concentrations of inorganic nitrate and phosphate.

An Optimal Algorithm for the Retrieval of Chlorophyll,Suspended Sediments and Gelbstoff of Case Ⅱ Waters in the Pearl River Estuary

An optimal algorithm for the retrieval of chlorophyll, suspended sediments and gelbstoff of case Ⅱ waters in the Pearl River estuary was established with the optical parameters derived from the in-situ data obtained in Jan. 2003 in the same area. And then, the chlorophyll, suspended sediments and gelbstoff of the SeaWiFS pixels on Jan. 29, 2003 corresponding to the in-situ sites of Jan. 25 and 26, 2003 were synchronously retrieved, with average relative errors of 14.9%, 12.1% and 13.6% for chlorophyll, suspended sediments and gelbstoff, respectively. The research results indicated that the optimal retrieval algorithm established here was relatively fit for the retrieval of the chlorophyll, suspended sediments and gelbstoff of case Ⅱ waters in the Pearl River estuary, and had quite good retrieval accuracy.

Turbidity maximum formation and its seasonal variations in the Zhujiang(Pearl River)Estuary,southern China

Real-time observations in the field and numerical simulations（with Delft3D） were combined to study the formation, distribution and the relevant influencing factors of turbidity maximum（TM） in the Zhujiang（Pearl River） Estuary（ZE）. The spatial distribution pattern of the TM varies with the longitudinal distributions of salinity and suspended sediment concentration（SSC）. The SSC is enhanced and the TM is intensified during dry seasons,whereas the center of the TM moves upstream by a distance of 10 km during wet seasons. The formation of the TM is influenced by a complex combination of numerous factors, including tides, river discharges and topography, wherein sediment resuspension and vertical circulation dominate the formations and variability of the TM.

Communities and Quantitative Analysis of Ammonia-oxidizing Organisms in Pearl River Estuary Sediments

[Objective] This study aimed to investigate the abundance and composition of ammonia-oxidizing bacteria and ammonia-oxidizing archaea in Pearl River Estuary sediment.[Method] Firstly,the amoA gene library was constructed;then based on that,the content and diversity of amoA genes of ammonia-oxidizing bacteria and ammonia-oxidizing archaea in Pearl River Estuary sediment were detected by using quantitative real-time polymerase chain reaction（Q-PCR）.[Result] The results of Q-PCR presented that ammonia-oxidizing archaea（AOA） were more abundant than ammonia-oxidizing bacteria（AOB） in the top of sediment cores,with ratios of AOA to AOB of 22 and 9 at the two sites.It suggested that ammonia-oxidizing archaea may play more important roles than ammonia-oxidizing bacteria in the process of ammonia oxidation in the Pearl River Estuary sediment.The phylogenetic tree based on amoA gene sequences revealed that the amoA sequences of both AOA and AOB shared high similarity with the clones from uncultured environment.In the top sediment layer at site Q7,AOB amoA-like gene sequences were dominated by Nitrosomonas-like sequence types,which could be classified into five groups（clusters A,B,C,D and E）.Cluster A accounted for 72.1% of the library.In the top sediment layer,the AOA amoA gene fell into two groups ＂water column/sediment＂ cluster（52.2%） and ＂soil/sediment＂ cluster（47.8%）.But in the bottom sediment layer of Q7,most of the AOA amoA sequences（93.3%） fell into ＂soil/sediment＂ cluster,and a little part（6.7%） fell into the ＂water/sediment＂ cluster.In addition,the total amount of amoA genes in the bottom sediment was higher than that in top sediment.[Conclusion] This study helps to realize the cycle of nitrogen in Pearl River Estuary Region,and thus to provide theoretical support for the treatment of nitrogen eutrophication.

The dynamic observation of dissolved organic matter in the Zhujiang(Pearl River)Estuary in China from space

The distributions of estuarine colored dissolved organic matter（CDOM）are the combined results of physicalbiogeochemical processes.Remote sensing is needed to monitor highly dynamically estuarine CDOM.Using in situ data from four seasonal cruises,an algorithm is developed to estimate CDOM absorption coefficient at 400nm（aCDOM（400））in the Zhujiang（Pearl River）Estuary（ZJE）.The algorithm uses band ratios of Rrs（667）/Rrs（443）and Rrs（748）/Rrs（412）.By applying it to moderate resolution imaging spectroradiometer onboard Aqua satellite（MODIS/Aqua）data from 2002 to 2014,seasonal climatology aCDOM（400）in the ZJE is calculated.CDOM distributions are majorly influenced by water discharge from the Zhujiang River and underwater topography.Along the section vertical to a water depth gradient,the seasonal aCDOM（400）exponentially decreased（y=aebx,b〈0）,but with great differences among seasons.Riverine fresh water is the primary source of CDOM in the ZJE.Fulvic acid fraction decreases with increasing salinity.Using developed algorithms,conservative CDOM mixing equation,and river discharge,effective riverine end-member concentration and flux of dissolved organic carbon（DOC）in summer and winter from 2002 to 2014 are first estimated from the MODIS/Aqua data.Both effective riverine end-member DOC concentration and flux are positively related to the river discharge,significantly in summer with R-2 of 0.698 for concentration and 0.965 7 for flux.

Study on Dynamic Changes of Land Utilization and Landscape Layout in Pearl River Estuary

Taking advantage of remote sensing(RS) technology and geographic information system(GIS) technology to interpret the four periods' data of remote sensing images of Pearl River Estuary in the years of 1990,1995,2000,and 2005,the changes in land utilization and landscape layout of Pearl River Estuary have been analyzed with reference to land utilization dynamic model and quantitative method in landscape ecology.Results indicate several points as followings.①Located in the region typical of high-speed economic development,Pearl River Estuary shows noticeable changes in land types and evident spatial temporal difference.During these 15 years,the areas of cultivated land and forests have experienced dramatic decline while the land for construction purposes shows the trend of powerful increase.②On the prospect of variation,landscape metrics have indicated great differences among other landscape pattern indices except for Area-Weighted Mean Patch Fractal Dimension(AWMPFD) especially during the period from 1990 to 1995 which experiences the most obvious changes.③On the prospect of landscape,landscape pattern indices also indicate great changes in the landscape layout of Pearl River Estuary from 1990 to 2005 as well as noticeable increase in the number of patches,and various landscape pattern indices show the increase in the degree of regional landscape fragmentation and increase in diversity.

Astronomical Dating of the Middle Miocene Hanjiang Formation in the Pearl River Mouth Basin,South China Sea

The Hanjiang Formation of Langhian age （middle Miocene） in the Pearl River Mouth Basin （PRMB）, South China Sea consists of deltaic siliciclastic and neritic shelf carbonate rhythmic alternations, which form one of the potential reservoirs of the basin. To improve stratigraphic resolutions for hydrocarbon prospecting and exploration in the basin, the present study undertakes spectral analysis of high-resolution natural gamma-ray （NGR） well-logging record to determine the dominant frequency components and test whether Milankovitch orbital signals are recorded in rhythmic successions. Analytical results indicate the orbital cycles of precession （~19 ka and ~23 ka）, obliquity （-41 ka）, and eccentricity （~100 ka and --405 ka）, which provide the strong evidence for astronomically driven climate changes in the rhythmic alternation successions. Within biochronological constraint, a high-resolution astronomical timescale was constructed through the astronomical tuning of the NGR record to recent astronomically calculated variation of Earth＇s orbit. The astronomically tuned timescale can be applied to calculate astronomical ages for the geological events and bioevents recognized throughout the period. The first downhole occurrences of foraminifers Globorotalia peripheroronda and Globigerinoides sicanus are dated at 14.546 Ma and 14.919 Ma, respectively, which are slightly different from earlier estimates in the South China Sea. When compared with the global sea-level change chart, the astronomical estimate for the sequences recognized based on microfossil distributions have the same end time but the different initiation time. This is probably due to the local or regional tectonic activities superimposed on eustatic rise which postponed the effect of global sea-level rising. Astronomical timescale also resolves the depositional evolution history for the Langhian Stage （middle Miocene） with a variation that strongly resembles that of Earth＇s orbital eccentricity predicted from 13.65 Ma to 15.97 Ma. We infer that the main factor controlling the variability of the sedimentation rate in the Hanjiang Formation is related to the ^-405-ka-period eccentricity.

Long-term changes in sedimentary diatom assemblages and their environmental implications in the Changjiang(Yangtze) River estuary, China

Long-term data on diatom assemblages in a sediment core （60 cm） obtained from the Changjiang （Yangtze） River estuary were analyzed in order to assess the environmental changes that took place in the approximately 38 years （as determined by 210pb measurements）, i.e., between 1974 and 2012, of sediment accumulation. From the sediment core, 62 diatom taxa and genera were identified. The diatom biomass in the core generally increased beginning in the mid-1990s （core depth： 35 cm）, accompanied by a shift in the dominant species from Podosira stelliger and two species of Cyclotella （C. stylorum and C. striata） to Paralia sulcata, three species of Thalassiosira （ T. eccentria, I＂. oestrupii, and T. excentrica）, Actinoptychus undulates, and Thalassionema nitzschioides. The changes in both species diversity and abundance suggested that since the 1980s the estuary has undergone extensive eutrophication. This conclusion was supported by the increased proportion of planktonic species, another indicator of high nutrients inputs, in the Changjiang River estuary.

Frequency, Duration and Intensity of Dengue Fever Epidemic Risk in Townships in Pearl River Delta and Yunnan in China, 2013

Dengue fever （DF）, one of the neglected tropical diseases also known as breakbone fever, is a mosquito-borne disease common in the tropics and subtropics. Dengue fever is transmitted primarily by A.aegypti, resulting in infection with any of four distinct but closely related virus serotypes. The majority of infected people experience a self-limiting clinical course. A small proportion of cases develop into life-threatening Dengue Hemorrhagic Fever or Dengue Shock Syndrome.

Estimation of Bed Shear Stresses in the Pearl River Estuary

Mean and fluctuating velocities were measured by use of a pulse coherent acoustic Doppler profiler （PC-ADP） and an acoustic Doppler velocimeter in the tidal bottom boundary layer of the Pearl River Estuary. The bed shear stresses were estimated by four different methods： log profile （LP）, eddy correlation （EC）, turbulent kinetic energy （TKE）, and inertial dissipation （ID）. The results show that （a） all four methods for estimating bed stresses have advantages and disadvantages, and they should be applied simultaneously to obtain reliable frictional velocity and to identify potential sources of errors; （b） the LP method was found to be the most suitable to estimate the bed stresses in non-stratified, quasi-steady, and homogeneous flows; and （c） in the estuary where the semi-diurnal tidal current is dominant, bed shear stresses exhibit a strong quarter-diurnal variation.

Statistical Modeling and Trend Detection of Extreme Sea Level Records in the Pearl River Estuary

Sea level rise has become an important issue in global climate change studies. This study investigates trends in sea level records, particularly extreme records, in the Pearl River Estuary, using measurements from two tide gauge stations in Macao and Hong Kong. Extremes in the original sea level records （daily higher high water heights） and in tidal residuals with and without the 18.6-year nodal modulation are investigated separately. Thresholds for defining extreme sea levels are calibrated based on extreme value theory. Extreme events are then modeled by peaks-over-threshold models. The model applied to extremes in original sea level records does not include modeling of their durations, while a geometric distribution is added to model the duration of extremes in tidal residuals. Realistic modeling results are recommended in all stationary models. Parametric trends of extreme sea level records are then introduced to nonstationary models through a generalized linear model framework. The result shows that, in recent decades, since the 1960s, no significant trends can be found in any type of extreme at any station, which may be related to a reduction in the influence of tropical cyclones in the region. For the longer-term record since the 1920s at Macao, a regime shift of tidal amplitudes around the 1970s may partially explain the diverse trend of extremes in original sea level records and tidal residuals.