Petrological and Geochemical Constraints on the Origin of Strongly Peraluminous Granitoids from the Triassic Guangtoushan Pluton in South Qinling

As an important part of the early Mesozoic granites in the South Qinling tectonic belt(SQTB),the Guangtoushan pluton provides a material basis for research on the composition of magma sources and the effects of peritectic assemblage entrainment(PAE)on the changes in the granite composition.As shown by the results of LA-ICP-MS zircon U-Pb dating,the Guangtoushan pluton was emplaced during the Late Triassic(214-212 Ma)and was formed in the post-collision stage between the SQTB and the Yangtze plate.The collected samples had high SiO_(2)content and low Cr and Ni contents,indicating that the magmas did not undergo significant crust-mantle mixing during their evolution.The Guangtoushan granitoids were distributed along the trend line of magmatic fractional crystallization in the F-An-Or diagram.This result,combined with the relatively homogeneous Sr-Nd isotopic composition,implies that the Guangtoushan pluton underwent slight assimilation and contamination.As can be inferred from the comparison between the compositions of the Guangtoushan granitoids and various fluid-absent experimental melts,the magma sources of the Guangtoushan granitoids contain a variety of materials,such as graywackes,pyroclastic graywackes,and pelites and are not derived from lower crustal mafic rocks.The correlation between the maficity and the major and trace elements further indicates that the strongly peraluminous granitoids from the Guangtoushan pluton was formed by the partial melting of biotite-bearing crustal rocks and its magmatic evolution was accompanied by the entrainment of clinopyroxenes and accessory minerals.

Petrochemistry ,Chronology and Tectonic Setting of Strong Peraluminous Anatectic Granitoids in Yunkai Orogenic Belt , Western Guangdong Province ,China

Arguments persist on the genesis and ages for the banded-augen （rapakivi） anatectic granitoids （charnockite） extensively outcropped in the Yunkai （云开） region, western Guangdong （广东） Province. Their petrochemistry, SHRIMP dating, deformational and metamorphic structure were studled. The results show that most granitoids are A/CNK〉1. 1, CaO/Na2O= 0. 62-1. 61 （average 0.94〉0.3）, Al2O3/TiO2 =16.6-60.6 （average 23.68）, depleted high field strong elements Ta, Nb, Zr, strong peraluminous high-K calcalkaline and calcalkaline granitoids in the post-collisional tectonic environment of a subduction-collision orogenic belt in an active-continental margin. The temperatures of charnockite and gneissic garnet-bearing biotite monzonitic granite are obviously higher than those of banded-augen （rapakivi） biotite monzonitic granite, and charnockite and gneissic garnet-bearing biotite monzonitic granite with the evolutional characteristics of A-type granites. The forming ages from banded-augen （rapakivi） biotite monzonitic granite to charnockite and gneissic garnet-bearing biotite monzonitic granite, whose crystallizing zircon SHRIMP ages are （465±10） Ma, （467±10 ） Ma, （435±11 ） Ma and （413±8） Ma, respectively, become younger. This shows that there was an oceaniccontinental subduction-collision and post-collisional extension-delamination-underplating between the Yangtze and Cathaysia plates during the Caledonian, and the granitoids experienced compressional uplift and extensional exhumation during the lndosinian. This provides important evidence of subduction collision of the Yangtze plate to the Cathaysia plate during the Caledonian in South China.

Carboniferous ridge subduction in the Xingmeng Orogenic Belt:Constraints from geochronological,geochemical,and Sr-Nd-Hf isotopic analysis of strongly peraluminous granites and gabbro-diorites in the Xilinhot micro-continent

The Xingmeng Orogenic Belt evolved through a long-lived orogeny involving multiple episodes of subduction and accretion.However,there is a debate on its tectonic evolution during the Late Paleozoic.Here,we report geochemical,geochronological,and isotopic data from strongly peraluminous granites and gabbro-diorites from the Sunidzuoqi-Xilinhot region.Zircon U-Pb ages suggest that the intrusive rocks were emplaced during the Early Carboniferous(333-322 Ma).The granites exhibit geochemical characteristics similar to S-type granites,with high SiO_(2)(72.34-76.53 wt.%),Al_(2)O_(3)(12.45-14.65 wt.%),and A/CNK(1.07-1.16),but depleted Sr,Nb,and Ta contents.They exhibit positiveε_(Nd)(t)andε_(Hf)(t)values(-0.3 to 2.8 and 2.7-5.7,respectively)and young Nd and Hf model ages(T_(DM2)(Nd)=853-1110 Ma and T_(DM2)(Hf)=975-1184 Ma),suggesting that they may be the partial melting products of heterogeneous sources with variable proportions of pelite,psammite,and metabasaltic rocks.The meta-gabbro-diorites from the Maihantaolegai pluton have low SiO_(2)(47.06-53.49 wt.%)and K_2O(0.04-0.99 wt.%)contents,and demonstrate slight light rare earth element(REE)depletion in the chondritenormalized REE diagrams.They have high zirconε_(Hf)(t)values(14.41-17.34)and young Hf model ages(T_(DM2)(Hf)=230-418 Ma),indicating a more depleted mantle source.The variations of the Sm/Yb and La/Sm ratios can thus be used to assess the melting degree of the mantle source from 5%to 20%,suggesting a quite shallow mantle melting zone.We propose that the petrogenesis and distribution of the strongly peraluminous granites and gabbro-diorites,as well as the tectonic architecture of the region,can be explained by a ridge subduction model.Based on these results,and previous studies,we suggest a southward ridge subduction model for the Sunidzuoqi-Xilinhot region.

Geochemistry and Geochronology of Peraluminous High-K Granitic Leucosomes of YaoundéSeries (Cameroon): Evidence for a Unique Pan-African Magmatism and Melting Event in North Equatorial Fold Belt

Geochemical and geochronological studies have been carry out on the leucosomes of Yaoundé series with the aims to identify the magma sources and to indicate their production periods and emplacement within the formations of the Pan-African North-Equatorial Fold Belt (PANEFB) in Cameroon. The Yaoundé series belongs to the Southern domain of the PANEFB and it is composed of migmatites in which two types of granitic leucosomes (in situ leucosomes and injected leucosomes) have been distinguished. These rocks display characteristic of calc-alkaline (in situ leucosomes) and high-K calc-alkaline to shoshonitic series (injected leucosomes). All the rocks are peraluminous with in situ leucosomes conform to S-type and injected leucosomes conform to I- and S-type granitoids. Major and trace elements composition reveal that in situ leucosomes derived from the partial melting of the host metapelite whereas injected leucosomes derived from the melting of metagreywacke. These sources are similar to those of granitoids from central and northern domains of the PANEFB. Th-U-Pb dating by electron microprobe (EMP) and LA-ICP-MS U-Pb dating on zircon have been used to constraints the melting event and emplacement of leucosomes in Yaoundé series. Th-U-Pb monazite dating, undertaken in two samples of leucosomes, gives two groups of monazite ages. The older group gives an age of 658 Ma whereas the age of younger group is 592 Ma. U-Pb dating of zircons from the leucosomes reveals a Pan-African age ranging from 626 to 654 Ma whereas zircons from metapelitic host rock reveal the overprinting of an early Pan-African event 911 - 1127 Ma on Palaeoproterozoic (2127 Ma) inheritance. These data clearly indicate that the host rocks of leucosomes of Yaoundé series have been firstly metamorphosed during Tonien-Stenien period (911 - 1127 Ma) and reveal the existence of extended unique melting event (592 and 658 Ma) in the Yaoundé series which is contemporaneous with the magmatism responsible for the emplacement of granitoids in the other domains of the PANEFB.

Peraluminous granitoids within the Hangloa area,Adamawa-YadéDomain,Cameroon:Petrogenesis and tectonic implication

Hangloa granitoids form part of the wide range calc-alkaline Pan-African granitic suites within the Adamawa Yade Domain(AYD)in Cameroon.There are several reports on metaluminous granitoids within this domain.The peraluminous suite has been locally reported and their petrogenesis is not fully understood.Petrography and whole-rock geochemistry were used to study the petrogenesis/formation of granitic rocks within this area.The results show that the granitoids are composed of quartzo-feldspathic,made up of granites,monzonites and quartz monzonites which were intruded in the Paleoproterozoic orthogneissic basement.The major and trace element compositions show that they are high-K calc-alkaline to shoshonites,with S-type affinity.The molar ratio A/CNK is>1.1,while the ratio of CaO+Na_(2)O/Al_(2)O_(3) is generally<1 making them strongly peraluminous.The REE shows enrichment in the LREE over the HREE,with(La/Yb)N varying from 11.9 to 53.32,(Dy/Yb)N from 0.77 to 2.13 and moderately negative Eu anomaly((Eu/Eu^(*))N range from 0.42 to 0.93).Most granite samples show depletion in P,with CaO/Na_(2)O<0.3 and Rb/Sr≤1 indicative of clay-poor metapelitic source,while the others show clay-rich metagreywackes sources.The strong peraluminosity,S-type affinity,high Ba/Sr,Ba/Rb and low Rb/Sr indicate they are crustal-derived.The compositional variation might be induced by the partial melting of different source materials followed by fractional crystallization of the granitic magma.The source nature requires fragments of Paleoproterozoic metasedimentary and metaigneous rocks derived from the collision between the north-central Cameroon block and the Congo Craton during the Pan-African.

Petrogenesis of the Early Jurassic Longtang and Menglong Peraluminous Granites in Tengchong Terrane,and their Tectonic Implication

A comprehensive study of zircon U-Pb geochronology,in situ Hf isotopes,whole-rock major and trace element geochemistry,and Nd isotopes was carried out for two Early Jurassic two-mica granites(Longtang and Menglong)in the southern part of the Tengchong terrane,which is in the northern part of the larger Sibumasu terrane.We assess the origin of the granites and explore their possible genetic relationship to the Paleo-Tethyan regime.LA-ICP-MS zircon U-Pb dating shows that they were simultaneously emplaced in the Early Jurassic(ca.199 Ma).They have SiO2 contents of 69.7–75.1 wt%and are mainly strongly peraluminous with alumina saturation index(ASI)values ranging from 1.06 to 1.46.They show similar Mg#(0.29–0.42)to experimental partial melts of metasedimentary rocks under continental pressuretemperature(P-T)conditions.They are enriched in light rare earth elements(LREEs)relative to heavy rare earth elements(HREEs),with moderately negative Eu anomalies and flat HREEs patterns.They show negativeεNd(t)values(−9.0 to–12.4)andεHf(t)values(−8.0 to−9.1).Elemental and isotopic data suggest that they most likely to formed by muscovitedehydration melting of a metapelitic source at lower temperatures in the range of 700℃to 750℃.The granites might represent a post-collisional tectonic setting response to Paleo-Tethyan regime.

Strongly peraluminous granites of Mesozoic in Eastern Nanling Range, southern China: Petrogenesis and implications for tectonics

The strongly peraluminous granites (SPGs) of Eastern Nanling Range (ENR) are a characteristic of all bearing highly aluminous minerals, such as muscovite±Al-rich biotite±tourmaline±garnet, and lack of cordierite. In respect of petrography, geochemistry, Nd isotope, and single grain zircon U-Pb dating, the representative granite bodies of them are studied. The research shows that these granites were emplaced in two stages, namely 228－225 Ma BP and J2－3 159－156 Ma BP, belonging to Indosinian and early Yanshanian periods, respectively, and they have low εNd(t) values (-10.6－-11.1), high A/CNK, Rb/Sr ratios and tDM values (1887－1817 Ma), and REE's tetrad effect (TE1, 3=1.13－1.34). In comparison with related geology, petrology and chronology of granites in adjacent regions, it is suggested that Indosinian SPGs of ENR formed in the circumstance of post-collisional extension 20 Ma after the major collision of Indosinian Movement (258－243 Ma BP) in Indo-China Peninsula, and early Yanshanian SPGs formed in the background of back-arc extension setting controlled by paleo-Pacific tectonic domain, and J1, the interval of two stages, is the interim from Tethyan to Pacific tectonic domains in South China. These SPGs have similar geological and geochemical characteristics, because they all crystallized from the magma of partial melting of early Proterozoic metasedimentary rocks when the thickened crust (≤50 km) became thinning, decompression, and transmitting of water.

Geochemical evidence for contribution of ore-forming materials from peraluminous granite basement —— Taking Fucheng pluton and No. 6722 uranium deposit in southern Jiangxi Province as examples

Using the induced fission-track method, mobile uranium leaching and lead isotope analysis, this work obtianed geochemical features of the peraluminous Fucheng granite basement and the host rock (shoshonite) of the No. 6722 uranium deposit in southern Jiangxi Province. (i) Uranium contents of the leucocratic rock-forming minerals (0.18 mg/g for quartz, 0.36 mg/g for feldspar) are lower than the uranium content of the whole rock (4.6 mg/g). Biotite and some ac-cessory mineral inclusions (zircon, monazite and uraninite) are the main uranium carriers of the Fucheng granite pluton. The fissure uranium in altered minerals (hydromica and chlorite) increased evidently. (ii) Leachable rate of mobile uranium in the biotite granite is 10.4%, while that in the al-tered granite increased to 31%. (iii) Caculation based on lead isotopes shows that during alteration the Fucheng granite lost uranium (DU = -37% — -65%), whereas the Caotaobei shoshonite gained uranium (DU = +37%— +58%). These features suggest that the ore-forming material of the No. 6722 uranium deposit was mainly derived from the altered peraluminous granite basement of Fucheng pluton.

Testing final closure time of the Paleo-Asian Ocean along the Solonker suture by a transition of compressional and extensional setting

The giant Central Asian Orogenic Belt is an extensive accretionary orogen,of which the Solonker suture,as a major regional suture,coincides closely with an early Permian paleobiogeographical boundary.This suture is considered to mark the location of the final closure of the Paleo-Asian Ocean between the North China Craton and the Mongolian Terrane.Although the closure time of the Paleo-Asian Ocean along the Solonker suture has generally been regarded as Late Permian-Early Triassic,uncertainty remains because of a lack of typical collisionrelated features(e.g.,high-grade regional metamorphism and well-developed fold-thrust structures)and a scarcity of outcrops.The present study reports Early Permian foliated gabbros and dikes(288-275 Ma)and Middle-Late Permian undeformed layered gabbros,strongly peraluminous granites,and I-type granites(265-254 Ma)in the Xinhure area along the northern margin of the North China Craton.The Early Permian foliated intrusions have a subduction-related geochemical signature and were derived from partial melting of lithospheric mantle modified by subduction-related melts or fluids at the active margin of the North China Craton.In contrast,the Late Permian undeformed layered gabbros and strongly peraluminous granites were derived from partial melting of lithospheric mantle and middle-upper crust,respectively,triggered by asthenospheric upwelling.Therefore,a transition from an end-compressional to an extensional environment according to a transition from collision termination to postcollision of the North China Craton and Mongolian Terrane may have occurred between 275 Ma and 262 Ma.This time span can be considered as the final closure time of the Paleo-Asian Ocean along the Solonker suture.

Zircon saturation model in silicate melts:a review and update

Zircon stability in silicate melts-which can be quantitatively constrained by laboratory measurements of zircon saturation-is important for understanding the evolution of magma.Although the original zircon saturation model proposed by Watson and Harrison(Earth Planet Sci Lett 64(2):295-304,1983) is widely cited and has been updated recently,the three main models currently in use may generate large uncertainties due to extrapolation beyond their respective calibrated ranges.This paper reviews and updates zircon saturation models developed with temperature and compositional parameters.All available data on zircon saturation ranging in composition from mafic to silicic(and/or peralkaline to peraluminous)at temperatures from 750 to 1400℃ were collected to develop two refined models(1 and 2) that may be applied to the wider range of compositions.Model 1 is given by lnCZr(melt)=(14.297±0.308)+(0.964 ± 0.066).M-(11113±374)/r,and model 2 given by lnCZr(melt)=(18.99±0.423)-(1.069±0.102)·lnG-(12288±593)/T,where CZr(melt) is the Zr concentration of the melt in ppm and parameters M [=(Na+K+2 Ca)/(Al·Si)](cation ratios) and G [=(3·Al2 O3+SiO2)/(Na2-O+K2 O+CaO+MgO+FeO)](molar proportions)represent the melt composition.The errors are at one sigma,and T is the temperature in Kelvin.Before applying these models to natural rocks,it is necessary to ensure that the zircon used to date is crystallized from the host magmatic rock.Assessment of the application of both new and old models to natural rocks suggests that model 1 may be the best for magmatic temperature estimates of metaluminous to peraluminous rocks and that model 2 may be the best for estimating magmatic temperatures of alkaline to peralkaline rocks.

Early Cretaceous A-type Granites in the Dandong Area,NE China and its Geodynamical Implications

A-type granites,as an important petrologic sign to build up environmental recognition,were mainly formed in extensional tectonic settings.A biotite syenogranite from the Fenghuangshan pluton in Dandong,Liaoning Province gave SHRIMP zircon U-Pb ages of 122.5±1.6 Ma,124.9±1.7 Ma and 126.9±1.1 Ma.The monzogranites have SHRIMP zircon U-Pb ages of 118.2±1.6 Ma,128.1±1.7 Ma and 131.6±1.9 Ma,giving an emplacement age for the pluton in the Early Cretaceous.SiO_(2) is 65.48-74.49 wt%,whereas that of K_(2)O is 4.16-6.44 wt%,and that of Na_(2)O is 2.99-4.70 wt%.They also contain 13.24-15.76 wt% of Al_(2)O_(3),with an A/CNK ratio of 0.92-1.10,averaging 1.02.The alkalinity rate(AR)ranges from 2.68 to 5.12,and this range is within the AR of peraluminous type rocks.The granites of Fenghuangshan pluton are characterized by high contents of Na and K and low contents of Ca(thermophile element)and Mg,which are features of A-type granites.The(Na_(2)O+K_(2)O)-Fe_(2)O_(3)^(*)×5-(CaO+MgO)×5 discrimination diagram also shows that Fenghuangshan pluton is an A2-type granite.The above granite has zircon ε_(Hf)(t)values ranging from-17.06 to-9.09,with single-stage Hf model ages(T_(DM))of 1141 Ma to 1498 Ma and two-stage Hf crustal model ages(T_(DM)^(C))of 1762 Ma to 2263Ma.A comprehensive analysis suggests that the Fenghuangshan pluton might have been formed from the lithospheric-plate sliding during the late stages of evolution of hot rift structures and might have been closely associated with the tectonic settings of Mesozoic Eurasia and the ancient Pacific Plate.

Effect of Radioactive Minerals Potentiality and Primordial Nuclei Distribution on Radiation Exposure Levels within Muscovite Granite, Wadi Nugrus, Southeastern Desert, Egypt

The studied area at Wadi Nugrus, Southeastern Desert, Egypt, is located between lat. 24°41'00'' and 24°41'35''N and long. 34°36'47'' and 34°37'09''E. The rock types are represented by layered metagabbros, biotite schists, gneisses, granodiorites, and Muscovite granites. The muscovite granite of Wadi Nugrus, is small exposure in size (~5.0 km2), emplaced along NW-SE trend, with about 0.5 - 4.5 Km in length and 100 - 250 m in width and intruding the biotite schists. The studied muscovite granite is composed mainly of plagioclases, potash feldspars, quartz, biotite and muscovite. The recorded minerals assemblage can be classified into secondary U-minerals (uranophane and meta-autunite), U-bearing minerals (uranothorite and columbite) and accessory minerals (zircon, flourite, allanite, zinnwaldite and hematite). The U/eU is more unity where, the measured chemical uranium is higher than the measured equivalent uranium in the most analyzed samples especially in trenches, which reflect disequilibrium state. The activity concentrations range from 251.72 to 1096.2 Bq·kg-1 for 232Th, from 494 to 2593.5 Bq·kg-1 for 226Ra, and from 1314.6 to 1846.7 Bq·kg-1 for 40K. The obtained radiological data show that the average internal and external hazard indices are 9.11 and 5.78, respectively which are more than unity and highly exceeding the permissible limits (International Commission on Radiation Protection, ICRP). The internal and external hazards are mainly due to 226Ra nuclei while the absorbed dose rate (nGy/h) is related to 232Th nuclei. The contributions of the three nuclei in the total absorbed dose rates and internal and external hazardous, for 226Ra, it contributes by 72% in Hin, 57% in Hex and 55% of DR, for 232Th it contributes by 24% in Hin, 37% in Hex and 36.9% of DR, while for 40K it contributes by 4.1% in Hin, 6.4% in Hex and 8.1% of DR.

Petrogenesis,Geodynamics and Radioactivity of the Granitic Rocks of the Nugrus Weakness Zone,South Eastern Desert,Egypt

The studied granitic bodies belong to the south Eastern Desert of Egypt.They extend in a NNW–SSE trend along the same strike of the Nugrus weakness zone by which they are structurally controlled.These rocks are composed of biotite and biotite-muscovite monzogranites to syenogranites.Geochemically,a higher abundance of Ba and Rb in biotite granites with a relatively low abundance in biotite-muscovite granites as well as the diversity of Th,U,Nb,Ta,Zr,and REE reflects their origin from different sources and geodynamic settings.The biotite granites are predominantly metaluminous to low peraluminous whereas the biotite-muscovite granites have a peraluminous nature.Potassium enrichment at the expense of calcium in these rocks reflects a derivation from crustal sources by partial melting in the presence of a volatile system.Radiometric investigation showed high abundances of U(up to 38 ppm)and Th(up to 26 ppm)in biotite-muscovite granites relative to biotite granites(up to 5 ppm U and 18 ppm Th).Radioactive anomalies furthermore have been recorded in parts of biotite-muscovite granites that were affected by the faults(up to 116 ppm eU and 97 ppm eTh).Consequently,biotite-muscovite granites form a potentially fertile source for uranium mineralization.

Geochemistry of Micas from Issia Granite Complexe: A Marker of Geodynamic Evolution

The granites and pegmatites located in the southern part of the Issia region, near the columbo-tantaliferous placers, are characterized by the presence of rare metals such as beryl, lithium and Nb-Ta oxides. They mainly consist of micas, quartz, plagioclase and potassium feldspar. The work carried out on the micas of these granites and pegmatites (EPMA analyses) has provided new geochemical data contributing to the understanding of the magmatic evolution of the Issia granite complex. Mineralogically, the most evolved G3 granites are characterized by their abundance of muscovite compared to biotite and the presence of pegmatite veins. Geochemically, the muscovites of the G1 and G2 granites are more ferriferous than those of the G3 granites, however, the latter display higher Na contents than the G2 and G3. The muscovites of the granites show an evolution from the pure muscovite series to the zinnwaldite series (micas of the pegmatites) which are lithium-bearing micas. The mineralogical and chemical data of the micas show that they are S-type peraluminous granites and demonstrate the formation of granites and pegmatites through fractional crystallization of the same parental magma.

Zircon and Monazite Ages Constraints on Devonian Magmatism and Granulite-Facies Metamorphism in the Southern Qaidam Block:Implications for Evolution of Proto-and Paleo-Tethys in East Asia

High-temperature magma generation process and granulite-facies metamorphism can provide important information about mantle-crustal interaction and tectonic evolution. The strongly peralu- minous monzonite pluton, the Jinshuikou cordierite granite on the southern margin of the Qaidam Block, can provide important information about the mantle-crustal interaction and constraints on tectonic tran- sition from Proto-Tethys to Paleo-Tethys. This pluton develops enclaves of mafic granulite, amphibolite and quartzofeldspathic rocks, and is cut by massive monzonitic leuco-granite veins. Zircon and monazite U-Pb dating for the cordierite granite, the granulite enclaves and a massive monzonitic leuco-granite vein reveal that the cordierite granitic magma was generated from Mesoproterozoic continental crust with protolith derived from a provenanee that was composed of 〉2.8 Ga old recycled crustal materials and re- corded a -1.7 Ga magmatic event. The continental crust underwent low-pressure granulite-facies metamorphism at -380 Ma ago, whereas the cordierite granite magmas was generated and emplaced during 380 Ma, followed by intrusion of the massive monzonitic leuco-granite vein at circa 370-330 Ma. These data suggest that after the final closure of Proto-Tethys Ocean spreading along the southern Qaidam Block at -420 Ma, break-off of the subducted slab or delamination of the lower crustal base and upwelling of the asthenospheric mantle beneath the southern Qaidam Block occurred before the Mid-Devonian, and that the initiation of the Paleo-Tethys tectonics might initiate near the end of Early-Carboniferous in the East Kunlun-Qaidam region, East Asia.

Post-Orogenic Granites in Pingwu Region, Northwest Sichuan: Evidence for North China Block and Yangtze Block Collision during Triassic

The Nanyili （南一里）, Laohegou （老河沟）, and Shaiziyan （筛子岩） granitic intrusions are located in the southern margin of the Bikou （碧口） block in Pingwu （平武） area, Northwest Sichuan （四川）. The petrography and geochemical characteristics of the granitic intrusions as well as their source and tectonic settings are reported and discussed in this article. The Laohegou and Shaiziyan granites are with high SiO2 （69.89 wt.%-73.05 wt.%） and Al2O3 contents, and A/CNK=1.04-1.12. They are typical strongly peraluminous granites, with supersaturation in AI and Si. The abundance of ∑REE varies in the range of （33.13-89.12）×10^-6. The rocks show an LREE enrichment pattern and obvious Eu negative anomaly. The trace element geochemistry is characterized evidently by a negative anomaly of Ta, Nb, Ti, etc. and a positive anomaly of Rb, Ba, Sr, etc.. Zircons of the Nanyili granite have higher Th/U ratios, and their CL images have internal oscillatory zoning, suggesting that the zircons of the samples are igneous in origin. The LA ICP-MS zircon U-Pb isotopic concordia diagram yields an age of 223.1±2.6 Ma （MSWD=1.4）, which indicates that the granodiorite intrusions formed in the early Late Triassic. The Nanyili, Laohegou, and Shaiziyan granites have the characteristics of post-collisional granites and are regarded as post-orogenic granites. Thus, the granite intrusions are interpreted as syn-collisional granites that resulted from the crustal thickening caused by the collisions between the North China plate and the Yangtze plate during the Indosinian. The granitic intrusions formed in a transitional environment from syn- （compressional environment） to post-collision （extensional environment）.

Ga-(Nb+Ta)-(Nb/Ta)(Zr/Hf) Ternary Diagram: An Excellent Tool for Discriminating Barren and Ta-Hosting Granite-Pegmatite Systems

Discriminating barren and fertile intrusions is one of the main challenges in the search for rare-element pegmatites.Diagrams comprising more than one element can make discrimination of productive and barren samples more valid.These diagrams distinguish samples by simultaneous means of positive and/or negative correlations between variables.A ternary diagram for S-type peraluminous granites has been obtained in this study.Firstly,a database composed of Ta-bearing and barren granitic systems was created,then geochemical behavior of trace elements was studied,and statistical investigations were done using GCDkit software,which resulted in the Ga-(Nb+Ta)-(Nb/Ta)(Zr/Hf)ternary diagram which can distinguish the non-mineralized granites from productive ones.The Ta-bearing samples,which are situated in the fertile field in the diagram,are those which have high Nb and Ta contents,elevated Ga content and the lowest Nb/Ta and Zr/Hf values.