期刊文献+
共找到652篇文章
< 1 2 33 >
每页显示 20 50 100
Coordination of distinctive pesticide adjuvants and atomization nozzles on droplet spectrum evolution for spatial drift reduction
1
作者 Shidong Xue Jingkun Han +3 位作者 Xi Xi Zhong Lan Rongfu Wen Xuehu Ma 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第2期250-262,共13页
Pesticide adjuvants,as crop protection products,have been widely used to reduce drift loss and improve utilization efficiency by regulating droplet spectrum.However,the coordinated regulation mechanisms of adjuvants a... Pesticide adjuvants,as crop protection products,have been widely used to reduce drift loss and improve utilization efficiency by regulating droplet spectrum.However,the coordinated regulation mechanisms of adjuvants and nozzles on droplet spectrum remain unclear.Here,we established the relationship between droplet spectrum evolution and liquid atomization by investigating the typical characteristics of droplet diameter distribution near the nozzle.Based on this,the regulation mechanisms of distinctive pesticide adjuvants on droplet spectrum were clarified,and the corresponding drift reduction performances were quantitively evaluated by wind tunnel experiments.It shows that the droplet diameter firstly shifts to the smaller due to the liquid sheet breakup and then prefers to increase caused by droplet interactions.Reducing the surface tension of sprayed liquid facilitates the uniform liquid breakup and increasing the viscosity inhibits the liquid deformation,which prolong the atomization process and effectively improve the droplet spectrum.As a result,the drift losses of flat-fan and hollow cone nozzles are reduced by about 50%after adding organosilicon and vegetable oil adjuvants.By contrast,the air induction nozzle shows a superior anti-drift ability,regardless of distinctive adjuvants.Our findings provide insights into rational adjuvant design and nozzle selection in the field application. 展开更多
关键词 pesticide drift Spray droplets Particle size distribution Spray atomization Transport processes ADJUVANTS
下载PDF
Research Progress of QuEChERS Pretreatment Technique in the Detection of Multiple Pesticide Residues
2
作者 Bo LIU Dawei WANG +3 位作者 Yuhang GUO Xuehua WANG Lei WANG Yajuan SONG 《Agricultural Biotechnology》 2024年第2期10-11,37,共3页
The QuEChERS extraction technique is a pretreatment technique that has been rapidly applied in recent years and is widely used in the field of pesticide residues with many advantages. This technique is based on solid ... The QuEChERS extraction technique is a pretreatment technique that has been rapidly applied in recent years and is widely used in the field of pesticide residues with many advantages. This technique is based on solid phase extraction (SPE), which uses the interaction between adsorbent and impurities in the matrix to achieve the purpose of purification. The method has easier operation and better purification effect than SPE. In this paper, the research progress of the QuEChERS technique in pesticide residue detection in different fields in recent years and its future development were reviewed, hoping to provide reference for further development and utilization of the QuEChERS technique in pesticide residue detection in the future. 展开更多
关键词 QUECHERS PRETREATMENT pesticide residues Research progress
下载PDF
Evaluation of Agricultural Contamination Level by Heavy Metals and Pesticides in Sediments of Rivers and Water Bodies for Shrimp Fishing in the Lower Ouémé: Case of the Aguigadji, Ahlan and Sele Stations in Benin
3
作者 Souradjou Orou Goura Fadéby Modeste Gouissi +3 位作者 Armelle Sabine Yélignan Hounkpatin Wakili Bolatito Yessoufou Tayéwo Sylvain Biaou Nonvignon Martial Fassinou 《Advances in Materials Physics and Chemistry》 CAS 2024年第2期25-46,共22页
This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochl... This study assessed sediment contamination by heavy metals and pesticide active ingredients linked to chemical inputs used in agricultural activities in the lower Ouémé. Pesticide residues from the organochlorine, pyrethroid and organophosphorus families were investigated by gas chromatography, and heavy metals (Cd, Pb, As, Ni, Zn, Fe, Mg, Cr and Hg) by atomic absorption spectrophotometry. The metallic pollution indices, the contamination factor (CF) and the ecological risk index were calculated. The results revealed 8 active ingredients in the rainy season and 9 in the dry season. Glyphosate was the active ingredient with the highest concentration at all stations, 9.65 ± 0.84 mg/kg recorded in the dry season at the Aguigadji station. All glyphosate values were above the EQS. DDT, Atrazine and Endosulfan also showed high concentrations in the dry and rainy seasons. Emamectin, Abamectin and Lambda Cyhalothrin also showed high concentrations in the dry season at Aguigadji, Ahlan and Sele. Only glyphosate was recorded at the control station (Toho), but in very low concentrations. Lead showed the highest concentrations at all the stations, 265.96 ± 21.02 mg/Kg in the rainy season and 255.38 ± 79.09 mg/Kg in the dry season, all detected at the Aguigadji station and above the EQS. Zn, Ni, Fe, Cu and Cr were all representative in both the dry and rainy seasons at the contaminated stations. Manganese showed high concentrations in the rainy season. Pb showed very high contamination (FC ≥ 6) at the Aguigadji and Ahlan stations and significant contamination (3 ≤ FC 6) at the Sele station in both the rainy and dry seasons. Ni, Hg and Cd, showed either moderate or significant contamination at the contaminated stations. The risk values showed a considerable ecological Ri (190 ≤ Ri < 380) in the rainy season and a moderate ecological Ri (95 ≤ Ri < 190) in the dry season at these contaminated stations. 展开更多
关键词 pesticideS Heavy Metals SEDIMENTS Shrimp Fishing Area Lower Ouémé
下载PDF
Agricultural Contamination of the Surface Waters of the Upper Ouémé in Benin: The Case of Heavy Metals and Pesticides
4
作者 Armelle Sabine Yélignan Hounkpatin Nonvignon Martial Fassinou +5 位作者 Fadéby Modeste Gouissi Zoulkanerou Orou Piami Dossou Armel Géraldo Houndeton Souradjou Orou Goura Wakili Bolatito Yessoufou Tayéwo Sylvain Biaou 《Journal of Agricultural Chemistry and Environment》 2024年第1期83-99,共17页
Objective: The main objective of this study was to assess the degree of contamination of surface waters by heavy metals and pesticides. Method: To this end, data were collected in December 2022 from four specific samp... Objective: The main objective of this study was to assess the degree of contamination of surface waters by heavy metals and pesticides. Method: To this end, data were collected in December 2022 from four specific sampling stations: Okpara, Térou, Affon and Adjiro. Levels of heavy metals, including cadmium, chromium, copper, iron, mercury, nickel and lead, were measured and subjected to in-depth statistical analysis using graphical summation models. In addition, the concentrations of pesticide active ingredients present in the samples were interpreted and evaluated. The statistical data collected during this study were processed using R software, version 3.5.0. Results: The values obtained at the different stations Okpara, Térou, Affon and Adjiro are respectively Arsenic (2 × 10<sup>-4</sup> mg/L;2.2 × 10<sup>-1</sup> mg/L;1.2 × 10<sup>-4</sup> mg/L;2 × 10<sup>-4</sup> mg/L), Cadmium (4.4 × 10<sup>-5</sup> mg/L;1.1 × 10<sup>-2</sup> mg/L;10<sup>-4</sup> mg/L;4 × 10<sup>-4</sup> mg/L). Then Copper (7 × 10<sup>-4</sup> mg/L;3 × 10<sup>-3</sup> mg/L;7 × 10<sup>-4</sup> mg/L;1 × 10<sup>-4</sup> mg/L), Iron (1.51 mg/L;6.4 × 10<sup>-1</sup> mg/L;2.0012 mg/L;2.9 × 10<sup>-1</sup> mg/L), Lead (0 mg/L;0 mg/L;1.5 × 10<sup>-3</sup> mg/L;1.5 × 10<sup>-3</sup> mg/L). Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (Cadmium, Chromium, Copper, Iron, Mercury, nickel and chromium were not detected in surface waters. It is important to note that the values obtained for trace metals (cadmium, chromium, copper, iron, mercury, nickel and lead) were all below the guideline standards set by the WHO in 2006 for uncontaminated surface waters. This indicates that the surface waters of the Upper Ouémé were below acceptable contamination thresholds in terms of heavy metals. However, the presence of pesticide active ingredients such as cyfluthrin, endosulfan-alpha, endosulfan-beta, profenosfos, tihan, atrazine, gala super and glycel clearly indicates that these surface waters are subject to agricultural contamination. 展开更多
关键词 Agricultural Contamination Heavy Metals pesticideS Surface Water North Benin
下载PDF
Efficacy of High-efficiency Formula Pesticides for Controlling Sesamia inferens Walker and Ceratovacuna lanigera Zehntner
5
作者 Yongde MA Xiaoyan WANG +3 位作者 Yinhu LI Hongli SHAN Rongyue ZHANG Yingkun HUANG 《Agricultural Biotechnology》 CAS 2023年第2期42-44,47,共4页
[Objectives]This study was conducted to screen high-efficiency formula pesticides and precise and efficient application techniques for the prevention and control of Sesamia inferens Walker and Ceratovacuna lanigera Ze... [Objectives]This study was conducted to screen high-efficiency formula pesticides and precise and efficient application techniques for the prevention and control of Sesamia inferens Walker and Ceratovacuna lanigera Zehntner.[Methods]Field efficacy trials were conducted using different combinations of 70%directed enhanced thiamethoxam seed treatment dispersible powder and 46%monosultap·Bacillus thuringiensis wettable powder.[Results]70%directed enhanced thiamethoxam ZF 450 g/hm^(2)+46%monosultap·B.thuringiensis WP 2250 g/hm^(2)had good control effects on both S.inferens and C.lanigera,so it was an ideal high-efficiency formula pesticide for controlling sugarcane S.inferens and C.lanigera.From January to May,combining with new plant or perennial root cultivation management,70%directed enhanced thiamethoxam ZF 450 g/hm^(2)can be evenly spread on sugarcane ditches and sugarcane stumps after being well mixed with fertilizers applied per hectare,and covered with soil in a timely manner,and during the peak incubation period of the first and second generation of S.inferens eggs from March to May,46%monosultap·B.thuringiensis WP 2250 g/hm^(2)was sprayed to the leaf surface in the mixture with water 675 kg with an electric backpack or a motorized sprayer.In such a way,the control efficacy on dead heart seedlings could reach over 89.8%,and that on C.lanigera could reach 100%.Meanwhile,it could effectively and concurrently control thrips,and the increases in yield and sugar content could reach 29310 kg/hm^(2)and 5.9 percentage points,respectively.[Conclusions]The promotion and application of the formula pesticide could achieve precise application and control of sugarcane pests,and improvement of sugarcane quality and planting efficiency,and help promote green prevention and control of sugarcane diseases and pests and the sustained high-quality development of the sugar industry. 展开更多
关键词 SUGARCANE Efficient formula pesticide Accurate application of pesticides Sesamia inferens Walker Ceratovacuna lanigera Zehntner Control efficacy evaluation
下载PDF
Pesticide Residue Content in Vegetable Bases of Lhasa City
6
作者 Yaodi LIU Ruiyang CHEN 《Asian Agricultural Research》 2023年第11期31-34,共4页
[Objectives]To understand the quality safety of vegetables produced in vegetable planting bases around Lhasa City.[Methods]Four vegetable planting bases in the east,west,south,and north of Lhasa City were randomly sel... [Objectives]To understand the quality safety of vegetables produced in vegetable planting bases around Lhasa City.[Methods]Four vegetable planting bases in the east,west,south,and north of Lhasa City were randomly selected for testing using rapid measuring instrument for agricultural residues and solid-phase microextraction-gas chromatography-mass spectrometer,with 120 vegetable samples selected.The testing samples included seven categories:green leafy vegetables,eggplants,melons,onions and garlic,root vegetables,beans,and fungi,totaling 29 types of vegetables.The samples were tested for 8 common prohibited and restricted pesticides in organic phosphorus and carbamate esters,including methamidophos,parathion,methyl parathion,monocrotophos,isocarbophos,methamidophos,aldicarb,and carbofuran.[Results]The pesticide inhibition rate of 6 kinds of vegetables detected by the rapid measuring instrument for agricultural residues was relatively high,with green leafy vegetables being the majority,reaching over 25%.By further establishing a solid-phase microextraction-gas chromatography-tandem mass spectrometry method,the accuracy of the data was verified experimentally.The experimental results indicated that the inhibition rate of vegetable samples in this experiment did not exceed 15%,and it was determined as a pollution-free vegetable.[Conclusions]According to the restriction standard of national pesticide use,the inhibition rate of vegetable samples was less than or equal to 40%,indicating that the quality of vegetables was qualified. 展开更多
关键词 VEGETABLE Solid-phase microextraction pesticide residue Organophosphorus pesticide Lhasa of Tibet
下载PDF
Rapid screening of 420 pesticide residues in fruits and vegetables using ultra high performance liquid chromatography combined with quadrupole-time of flight mass spectrometry 被引量:2
7
作者 Junmei Ma Sufang Fan +5 位作者 Liqiong Yang Liangna He Hongwen Zhai Xiaowei Ren Qiang Li Yan Zhang 《Food Science and Human Wellness》 SCIE CSCD 2023年第4期1064-1070,共7页
A new method for screening and identification 420 pesticide residues in fruits and vegetables by ultra-performance liquid chromatography coupled with quadrupole-time of flight mass spectrometry(UPLC-Q-TOF/MS)were deve... A new method for screening and identification 420 pesticide residues in fruits and vegetables by ultra-performance liquid chromatography coupled with quadrupole-time of flight mass spectrometry(UPLC-Q-TOF/MS)were developed.The samples were extracted with acetonitrile/acetic acid(99:1,V/V),and clean-up by SinChERS-Nano(single-step,cheap,effective,rugged,safe,nano)column,determined by UPLC-Q-TOF/MS.The accurate mass database and MS/MS database which contains 420 pesticides were established,the automatic retrieval of detection results was carried on according to the accurate mass,retention time,isotope ratio,ion fragment information,and so on.Method verification was performed on leeks samples.The results showed that 420 pesticides had good linearity in the range of 0.1-100μg/L,and the correlation coeffificients(R2)was greater than 0.990.The limits of detections(LODs)and limits of quantifications(LOQs)of 420 pesticides were in range of 0.05-2.0 and 0.1-5.0μg/L,respectively.The average spike recoveries at 3 levels were 70.1%to 119.7%,and the relative standard deviations(RSD)were lower than 20%(n=6).With this method,a survey of pesticide residues was conducted for 110 samples of 10 different fruits and vegetables,which provided scientific data for ensuring pesticide residue safety of the fruits and vegetables consumed daily by the public.This method was simple,sensitive and accurate,and could be used for rapid screening of 420 pesticide residues in fruits and vegetables. 展开更多
关键词 UPLC-Q-TOF/MS SinChERS-Nano column pesticide residues Fruits and vegetables
下载PDF
Regional selection of insecticides and fungal biopesticides to control aphids and thrips and improve the forage quality of alfalfa crops 被引量:1
8
作者 PAN Fan GAO Li-jie +6 位作者 ZHU Kai-hui DU Gui-lin ZHU Meng-meng ZHAO Li GAO Yu-lin TU Xiong-bing ZHANG Ze-hua 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第1期185-194,共10页
The efficacies of biological and conventional chemical insecticides against two major insect pests of alfalfa(aphids and thrips)were compared in three sites across China’s alfalfa belt.In addition,the persistence of ... The efficacies of biological and conventional chemical insecticides against two major insect pests of alfalfa(aphids and thrips)were compared in three sites across China’s alfalfa belt.In addition,the persistence of the residues of chemical insecticides in alfalfa and their influence on the quality of alfalfa hay were examined.Efficacy varied among the different biological and chemical insecticides.The chemical insecticides were significantly more effective than biopesticides in a short time-frame.The efficacy period of biopesticides was significantly longer than that of chemical insecticides,and the corrected mortality rate of aphids in all regions was above 50%at 14 days after application.The analysis of pesticide residues showed that the residual doses of all the pesticides were within the allowed ranges after the safe period.The acid detergent fiber and neutral detergent fiber contents in alfalfa hay were higher and the protein content was lower in chemical insecticide treatments than in biopesticide treatments in Hebei.The relative feeding value of alfalfa hay treated with Metarhizium anisopliae IPP330189 was the highest among the treatments.Compared with chemical insecticides,the yield of alfalfa hay was higher in the biopesticides treatments.Biopesticides show a stronger control effect on insect populations and also a better improvement in the quality of alfalfa hay than chemical insecticides.This study provides a basis for exploring and developing a comprehensive control regime for alfalfa insect pests in the different alfalfa-growing regions in China,and for reducing chemical insecticide usage and improving forage quality. 展开更多
关键词 insect pest control pollution free control pesticide residue APHIDS THRIPS
下载PDF
Farmers’precision pesticide technology adoption and its influencing factors:Evidence from apple production areas in China 被引量:1
9
作者 YUE Meng LI Wen-jing +7 位作者 JIN Shan CHEN Jing CHANG Qian Glyn JONES CAO Yi-ying YANG Gui-jun LI Zhen-hong Lynn JFREWER 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2023年第1期292-305,共14页
The research aimed to understand farmers’willingness to adopt(WTA)and willingness to pay(WTP)for precision pesticide technologies and analyzed the determinants of farmers’decision-making.We used a two-stage approach... The research aimed to understand farmers’willingness to adopt(WTA)and willingness to pay(WTP)for precision pesticide technologies and analyzed the determinants of farmers’decision-making.We used a two-stage approach to consider farmers’WTA and WTP for precision pesticide technologies.A survey of 545 apple farmers was administered in Bohai Bay and the Loess Plateau in China.The data were analyzed using the double-hurdle model.The results indicated that 78.72%of respondents were willing to apply precision pesticide technologies provided by service organizations such as cooperatives and dedicated enterprises,and 69.72%were willing to buy the equipment for using precision pesticide technologies.The results of the determinant analysis indicated that farmers’perceived perceptions,farm scale,cooperative membership,access to digital information,and availability of financial services had significant and positive impacts on farmers’WTA precision pesticide technologies.Cooperative membership,technical training,and adherence to environmental regulations increased farmers’WTP for precision pesticide technologies.Moreover,nonlinear relationships between age,agricultural experience,and farmers’WTA and WTP for precision pesticide technology services were found. 展开更多
关键词 precision technologies apple production precision pesticides willingness to adopt willingness to pay
下载PDF
Detection and Analysis of Pesticide Residues in Chinese Chives and Risk Assessment of Dietary Intake 被引量:1
10
作者 Lei WANG Huihui LIU +9 位作者 Shuo YANG Ying WANG Shuai WANG Haitao ZHAO Huifang YAO Yajing WANG Liang ZHANG Yancheng ZHOU Sining TANG Yanhua YAN 《Agricultural Biotechnology》 CAS 2023年第1期87-93,共7页
[Objectives]This study was conducted to understand the status of pesticide residues and dietary intake risk of Chinese chives in Tangshan area. [Methods] Sixty eight kinds of pesticide residues in 415 Chinese chive sa... [Objectives]This study was conducted to understand the status of pesticide residues and dietary intake risk of Chinese chives in Tangshan area. [Methods] Sixty eight kinds of pesticide residues in 415 Chinese chive samples collected from Tangshan area were qualitatively and quantitatively determined by high-performance liquid chromatography-tandem mass spectrometry(HPLC-MS/MS) and gas chromatography(GC) in 2020. [Results] The results showed that 41 kinds of pesticide residues were detected in the 415 Chinese chive samples, and the detection rate was 69.4%(288/415), and there was a combination of pesticides in many samples. According to the National Food Safety Standard―Maximum Residue Limits of Pesticides in Food(GB 2763-2019), the residues of 12 pesticides exceeded the maximum residue limits(MRLs), and the unqualified rate was 38.07%(158/415). The highest detection rate of clothianidin was 41.20%(171/415), but there was no MRL in GB 2763-2019. The next was procymidone, the detection rate of which was 35.42%(147/415), and the over-standard rate was 30.12%(125/415). Forbidden and restricted pesticides were detected in some samples. According to the dietary exposure risk assessment, the NEDI/ADI values were all less than 1 and the intake risk was within acceptable range. In Tangshan area, the types of pesticides used in Chinese chive production are complex, and there are risks of multi-residue pollution and use of banned and restricted pesticides and unregistered pesticides. It is suggested that routine monitoring of pesticide residues and management of pesticide use should be strengthened to ensure the quality and safety of agricultural products. [Conclusions] This study provides a theoretical basis for the safe production of Chinese chive and the standardized and rational use of pesticides. 展开更多
关键词 Chinese chive pesticide residues DETECTION Risk assessment
下载PDF
Water-Based Environmentally Friendly Pesticide Formulations Based on Cyclodextrin/Pesticide Loading System
11
作者 Xinyu Guo Zhe Sun +5 位作者 Rui Zhao Hongyi Shang Jiangyu Liu Yong Xu Laihua Liu Xuemin Wu 《Journal of Renewable Materials》 SCIE EI 2023年第2期777-789,共13页
Difenoconazole(DIF)is a representative variety of broad-spectrum triazole fungicides and liposoluble pesticides.However,the water solubility of DIF is so poor that its application is limited in plant protection.In add... Difenoconazole(DIF)is a representative variety of broad-spectrum triazole fungicides and liposoluble pesticides.However,the water solubility of DIF is so poor that its application is limited in plant protection.In addition,the conventional formulations of DIF always contain abundant organic solvents,which may cause pollution of the environment.In this study,two DIF/cyclodextrins(CDs)inclusion complexes(ICs)were successfully prepared,which were DIF/β-CD IC and DIF/hydroxypropyl-β-CD IC(DIF/HP-β-CD IC).The effect of cyclodextrins on the water solubility and the antifungal effect of liposoluble DIF pesticide were investigated.According to the phase solubility test,the molar ratio and apparent stability constant of ICs were obtained.Fourier transform infrared spectroscopy,thermal gravity analysis,X-ray diffraction and scanning electron microscopy were used systematically to characterize the formation and characteristics of ICs.The results noted that DIF successfully entered the cavities of two CDs.In addition,the antifungal effect test proved the better performance of DIF/HP-β-CD IC,which exceeded that of DIF emulsifiable concentrate.Therefore,our study provides informative direction for the intelligent use of liposoluble pesticides with cyclodextrins to develop water-based environmentally friendly formulations. 展开更多
关键词 Water-based environmentally friendly pesticide formulations DIFENOCONAZOLE Β-CYCLODEXTRIN HYDROXYPROPYL-Β-CYCLODEXTRIN inclusion complex preparation characterization
下载PDF
Recognition mechanism and sequence optimization of organophosphorus pesticides aptamers for better monitoring contaminations in food
12
作者 Pengfei Chen Chaoqiong Hu +6 位作者 Xuan Tao Zheng Zhou Lijun Wang Xiao Yang Zhenming Che Xianggui Chen Yukun Huang 《Food Science and Human Wellness》 SCIE CSCD 2023年第5期1708-1715,共8页
Aptamers as a kind of biological recognition element have shown great potential in monitoring and the rapid quantification of organophosphorus pesticides(OPPs). However, molecules of OPPs are structurally similar and ... Aptamers as a kind of biological recognition element have shown great potential in monitoring and the rapid quantification of organophosphorus pesticides(OPPs). However, molecules of OPPs are structurally similar and original aptamers selected by systematic evolution of ligands by exponential enrichment are usually long-chain bases, which hamper the further application under OPPs-aptamer recognition. The aim of the research was to develop a new strategy to design oligonucleotide sequences for binding OPPs by combination of experimental and molecular modeling methods. 3D models of aptamers binding OPPs were constructed, and binding energy and the most probable binding site for the OPPs were then determined by molecular docking, and the binding sites were further confirmed by the results of 2-AP replaced experiments. Based on the docking results, a new aptamer for detection 4 representative OPPs with only 29 bases was designed by reasonable truncation and mutation of the reported aptamer(named S4-29). The interaction between this new aptamer and OPPs were analyzed by molecular docking, microscale thermophoresis, circular dichroism and fluorometric analysis. The results revealed that the new aptamer exhibit more superior recognition performance to OPPs, which can be promote the monitoring ability of OPPs contaminations in food. 展开更多
关键词 Organophosphorus pesticides APTAMER Recognition mechanism Sequence optimization
下载PDF
Q-Learning-Based Pesticide Contamination Prediction in Vegetables and Fruits
13
作者 Kandasamy Sellamuthu Vishnu Kumar Kaliappan 《Computer Systems Science & Engineering》 SCIE EI 2023年第4期715-736,共22页
Pesticides have become more necessary in modern agricultural production.However,these pesticides have an unforeseeable long-term impact on people's wellbeing as well as the ecosystem.Due to a shortage of basic pes... Pesticides have become more necessary in modern agricultural production.However,these pesticides have an unforeseeable long-term impact on people's wellbeing as well as the ecosystem.Due to a shortage of basic pesticide exposure awareness,farmers typically utilize pesticides extremely close to harvesting.Pesticide residues within foods,particularly fruits as well as veggies,are a significant issue among farmers,merchants,and particularly consumers.The residual concentrations were far lower than these maximal allowable limits,with only a few surpassing the restrictions for such pesticides in food.There is an obligation to provide a warning about this amount of pesticide use in farming.Previous technologies failed to forecast the large number of pesticides that were dangerous to people,necessitating the development of improved detection and early warning systems.A novel methodology for verifying the status and evaluating the level of pesticides in regularly consumed veggies as well as fruits has been identified,named as the Hybrid Chronic Multi-Residual Framework(HCMF),in which the harmful level of used pesticide residues has been predicted for contamination in agro products using Q-Learning based Recurrent Neural Network and the predicted contamination levels have been analyzed using Complex Event Processing(CEP)by processing given spatial and sequential data.The analysis results are used to minimize and effectively use pesticides in the agricultural field and also ensure the safety of farmers and consumers.Overall,the technique is carried out in a Python environment,with the results showing that the proposed model has a 98.57%accuracy and a training loss of 0.30. 展开更多
关键词 pesticide contamination complex event processing recurrent neural network Q learning multi residual level and contamination level
下载PDF
A Rapid Determination of 30 Prohibited Pesticide Residues in Lycii Fructus by UPLC-MS/MS
14
作者 Kesheng Lin Zhengqi Wang +6 位作者 Li Wang Jiawen Zhou Lijuan Han Jingjing Wen Tingxia Dong Ran Duan Ning Li 《Phyton-International Journal of Experimental Botany》 SCIE 2023年第2期423-437,共15页
Prohibited pesticide residues have become one of the main factors affecting the quality and safety of Lycii Fructus,However,rarely studies focus on the rapid determination of these residues.Here,a total of 30 kinds of... Prohibited pesticide residues have become one of the main factors affecting the quality and safety of Lycii Fructus,However,rarely studies focus on the rapid determination of these residues.Here,a total of 30 kinds of prohibited pesticide residues were determined by ultra-performance liquid chromatography tandem triple quadrupole mass spectrometry(UPLC-MS/MS)in five different process ways.Pretreatment methods,chromatographic separation and detection conditions in mass spectrometry were all optimized accordingly.Among the five different pretreatment methods,the first and third solid phase extraction failed to provide high recoveries of sulfosulfuron compounds(both lower than 60%).Recovery of chlorphenamidine by the Quick Easy Cheap Effective Rugged and Safe multiresidue method(QuEChERS)was lower than 60%,which did not meet the requirements of trace determination.The concentrations of 30 prohibited pesticides residues treated by straightforward and solid phase extraction showed good linearity in their corresponding ranges,with correlation coefficients over 0.99.The average recoveries of straightforward ranged from 78.13%to 110.9%,while RSD ranged from 1.3%to 16.9%,albeit poor purification was observed.The recovery yield from solid phase extraction was between 67.75%and 103.08%with RSD value from 0.8%to 14.0%,which met the requirements of trace determination,this method has good precision and stability.These results could be employed to other Traditional Chinese Medicines(TCMs)in detecting prohibited pesticide residues. 展开更多
关键词 Lycii fructus prohibited pesticide residues UPLC-MS/MS
下载PDF
Rapid Screening of Pesticide Residues in Strawberry Based on HPLC-QTOF/MS SWATH Acquisition Mode
15
作者 Fang LI Yu ZOU +3 位作者 Xiangang LI Xuemei LI Sining LIU Ying WANG 《Plant Diseases and Pests》 CAS 2023年第3期10-13,共4页
[Objectives]The paper was to establish a rapid screening method of pesticide residues in strawberry based on HPLC-QTOF/MS SWATH acquisition mode.[Methods]The strawberry sample was extracted with acetonitrile,purified ... [Objectives]The paper was to establish a rapid screening method of pesticide residues in strawberry based on HPLC-QTOF/MS SWATH acquisition mode.[Methods]The strawberry sample was extracted with acetonitrile,purified with anhydrous magnesium sulfate,sodium chloride and primary secondary amine(PSA)powder,and then loaded on the machine.The full information spectrum was collected by positive ion mode and screened by comparing with the spectrum library,and 20 kinds of pesticide residues were quantitatively analyzed.[Results]The detection limits of 20 pesticide residues were 0.0002-0.0100 mg/kg,and they showed good linearity in the range of 0.0005-0.1000μg/mL(R 2≥0.995).The recoveries ranged from 62.8%to 106.3%.[Conclusions]This method is rapid,simple,sensitive and non-targeted,and can be used for rapid screening of multiple pesticide residues in strawberry. 展开更多
关键词 STRAWBERRY HPLC-QTOF/MS Non-targeted screening SWATH pesticide residue
下载PDF
Application of Mass Spectrometry (MS)-coupled Techniques in Pesticide Residue Detection
16
作者 Lei WANG Rundong Qiang +5 位作者 Aili XIANG Liang ZHANG Mingyuan YUN Huihui LIU Shuo YANG Jinlu LI 《Agricultural Biotechnology》 CAS 2023年第5期59-61,共3页
Pesticide residue detection is an important work to ensure the quality safety of agricultural products.In the process of agricultural production,in order to prevent and control agricultural diseases and pests,a certai... Pesticide residue detection is an important work to ensure the quality safety of agricultural products.In the process of agricultural production,in order to prevent and control agricultural diseases and pests,a certain amount of pesticides need to be used.However,if pesticides are used excessively,there will be certain pesticide residues in crops and related products.Therefore,it is necessary to do a good job in pesticide residue detection.The gas chromatography-mass spectrometry(GC-MS)and liquid chromatography-mass spectrometry(LC-MS)detection methods have good results and can effectively detect pesticide residues in related products.This paper reviewed and analyzed the application of GC-MS and LC-MS in pesticide residue detection,and proposed optimization measures based on practical experience,hoping to provide reference for relevant scholars. 展开更多
关键词 Gas chromatography-mass spectrometry Liquid chromatography-mass spectrometry pesticide residues Detection analysis APPLICATION
下载PDF
Problems in the Use of Pesticides by Farmers and Countermeasures
17
作者 Xiaofei BAI 《Plant Diseases and Pests》 CAS 2023年第5期1-4,共4页
Pesticide safety is an important guarantee for food security.At present,there are many problems in the process of choosing pesticides by farmers,such as low discernment ability and difficulty in retroactive blame,slow... Pesticide safety is an important guarantee for food security.At present,there are many problems in the process of choosing pesticides by farmers,such as low discernment ability and difficulty in retroactive blame,slow replacement of medical equipment,slow promotion of technology assistance,lack of professional knowledge,difficult to grasp the key points of application,improper use of pesticides,large resistance to reducing quantity and increasing efficiency,etc.In order to use pesticides rationally and realize safe production,countermeasures and suggestions on pesticide application are put forward from the aspects of drug development and application,promotion of biopesticides,change of farmers concept and cultivation of new farmers. 展开更多
关键词 FARMER pesticide safety Agricultural technology Medical equipment
下载PDF
Potential Risks to the Environment as a Result of Pesticide Handling in the Nanumba-North Municipality, Ghana
18
作者 Fusheini Yakubu Kenneth B. Pelig-Ba +1 位作者 Samson A. Abagale Lateef Adebayo Oseni 《Journal of Agricultural Chemistry and Environment》 CAS 2023年第2期65-83,共19页
The present study deduced the potential risks to the environment as a result of pesticide handling in the Nanumba-North Municipality of the Northern Region of Ghana. Cluster sampling was used to select 30 communities ... The present study deduced the potential risks to the environment as a result of pesticide handling in the Nanumba-North Municipality of the Northern Region of Ghana. Cluster sampling was used to select 30 communities from Nanumba-North Municipality. Simple random sampling and purposive sampling were used respectively to select 7 households from each community and one farmer from each household, giving a sample size of 210 farmers. The instrument used for the study was a questionnaire of respondents. The quantitative data obtained were analyzed using frequencies and percentages. The study concluded that 11 types of pesticides are commonly used by the farmers on their fields, with atrazine (22%) being the most commonly used pesticide which is an herbicide, and deltamethrin (1%) was the least used pesticide which is an insecticide. The study, therefore, recommends that appropriate authorities in the area should inculcate means to enlighten farmers on the best way of pesticide utilization that can beef up the ambition of sustainable agricultural production and desirable environmental conditions. 展开更多
关键词 pesticide Risk Nanumba-North Municipality Environment
下载PDF
Multiple Pesticide Residues in Bananas Sold in Tangshan City and Dietary Risk Assessment
19
作者 Lin LI Huihui LIU +8 位作者 Hefeng ZHANG Yancheng ZHOU Yuping LIU Zhenguo ZHANG Qianqian CONG Liang ZHANG Yajing WANG Ling ZHENG Baiqin ZHENG 《Agricultural Biotechnology》 2023年第6期52-57,共6页
[Objectives]This study was conducted to investigate the pesticide residue status of bananas in Tangshan area and the dietary intake risk of consumers.[Methods]High-performance liquid chromatography-tandem mass spectro... [Objectives]This study was conducted to investigate the pesticide residue status of bananas in Tangshan area and the dietary intake risk of consumers.[Methods]High-performance liquid chromatography-tandem mass spectrometry(HPLC-MS/MS)was applied to detect 70 pesticide residues in 191 batches of banana samples extracted from Tangshan area,and chronic and acute risk assessments were conducted.[Results]Among the 191 batches of bananas,172 batches of samples were detected to contain agrochemicals,with a detection rate of 90.05%.Seventeen agrochemicals were detected,accounting for 24.29%of the total agrochemicals tested.There was a phenomenon of multiple pesticide residues in a single sample,and high detection rates were found in carbendazim(49.21%),prochloraz(41.88%),pyraclostrobin(34.03%)and imidacloprid(30.37%).According to GB 2763-2021 National Food Safety Standards—Maximum Residue Limits for Pesticides in Food,the over-standard rate of imidacloprid was 17.8%;and the chronic and acute dietary risks of the 17 pesticide residues were all less than 100%.[Conclusions]The pesticide residues in bananas consumed by consumers on a daily basis do not pose unacceptable dietary risks. 展开更多
关键词 Bananas pesticide residues Dietary intake Risk assessment
下载PDF
Phytosanitary Practices and Pesticide Levels in Fresh and Dried Mangoes Produced in Burkina Faso
20
作者 Alain Gustave Yaguibou Souleymane Zio +4 位作者 Bakary Tarnagda François Tapsoba Soumaila Konaté Fulbert Nikiema Aly Savadogo 《Food and Nutrition Sciences》 2023年第6期509-525,共17页
Pesticides are used to control fruit flies and other potential crop pests, particularly mango in Burkina Faso. Pesticides are a potential health hazard for users and consumers and are a major constraint to the export ... Pesticides are used to control fruit flies and other potential crop pests, particularly mango in Burkina Faso. Pesticides are a potential health hazard for users and consumers and are a major constraint to the export and commercialization of mangoes. The objective of this study was to evaluate phytosanitary practices in orchards and pesticide residue levels in four varieties of fresh and dried mangoes (Amelie, Brooks, Kents and Lippens) produced in four localities in Burkina Faso in order to determine their health impact on consumers. Surveys on pesticide use and monitoring of phytosanitary practices were carried out among 16 orchard owners in the localities of Bobo-Dioulasso, Orodara, Toussiana and Banfora, a high mango production area. Also, a total of 120 samples, including 60 samples of fresh mangoes and dried 60 samples of dried mango were collected. A multi-residue method was developed to detect pesticide levels in the collected samples by gas chromatography with a micro-electron capture detector. The study revealed the use of unauthorized pesticides, often specifically for other crops, and a monitoring trapping network in the orchards against insects. 34 chemical pesticides were detected in 120 samples of all mango varieties collected. Pesticide residues were detected in 72% of the samples, and of the positive samples, 48.52% contained concentrations above the maximum residue limit permissibility. Organochlorine pesticide residues were present in fresh mangoes (60.5%) and a total of fifteen active compounds were detected in dried mangoes. The very poor management and use of pesticides found in these orchards could pose a threat to the productivity of natural ecosystems and the health of producers, processors and consumers. Awareness raising and training of producers on the knowledge of the risks linked to the use of pesticides and good practices are necessary to preserve the health of all. 展开更多
关键词 Phytosanitary Problems ORCHARDS MANGOES pesticideS Burkina Faso
下载PDF
上一页 1 2 33 下一页 到第
使用帮助 返回顶部