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Thermo-magnetic analysis of thick-walled spherical pressure vessels made of functionally graded materials 被引量:3
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作者 M. A. NEMATOLLAHI A. DINI M. HOSSEINI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2019年第6期751-766,共16页
This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressur... This study presents an analytical solution of thermal and mechanical displacements, strains, and stresses for a thick-walled rotating spherical pressure vessel made of functionally graded materials (FGMs). The pressure vessel is subject to axisymmetric mechanical and thermal loadings within a uniform magnetic field. The material properties of the FGM are considered as the power-law distribution along the thickness. Navier’s equation, which is a second-order ordinary differential equation, is derived from the mechanical equilibrium equation with the consideration of the thermal stresses and the Lorentz force resulting from the magnetic field. The distributions of the displacement, strains, and stresses are determined by the exact solution to Navier’s equation. Numerical results clarify the influence of the thermal loading, magnetic field, non-homogeneity constant, internal pressure, and angular velocity on the magneto-thermo-elastic response of the functionally graded spherical vessel. It is observed that these parameters have remarkable effects on the distributions of radial displacement, radial and circumferential strains, and radial and circumferential stresses. 展开更多
关键词 analytical solution magnetic field thermal loading ROTATING thick-walled SPHERICAL pressure VESSEL functionally GRADED material (FGM)
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Revisiting the elastic solution for an inner-pressured functionally graded thick-walled tube within a uniform magnetic field 被引量:1
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作者 Libiao XIN Yanbin LI +2 位作者 Dongmei PAN Guansuo DUI Chengjian JU 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2018年第10期1485-1498,共14页
In this paper, the mechanical responses of a thick-walled functionally graded hollow cylinder subject to a uniform magnetic field and inner-pressurized loads are studied. Rather than directly assume the material const... In this paper, the mechanical responses of a thick-walled functionally graded hollow cylinder subject to a uniform magnetic field and inner-pressurized loads are studied. Rather than directly assume the material constants as some specific function forms displayed in pre-studies, we firstly give the volume fractions of different constituents of the functionally graded material(FGM) cylinder and then determine the expressions of the material constants. With the use of the Voigt method, the corresponding analytical solutions of displacements in the radial direction, the strain and stress components, and the perturbation magnetic field vector are derived. In the numerical part, the effects of the volume fraction on the displacement, strain and stress components, and the magnetic perturbation field vector are investigated. Moreover, by some appropriate choices of the material constants, we find that the obtained results in this paper can reduce to some special cases given in the previous studies. 展开更多
关键词 functionally graded material(FGM) thick-walled tube elasticity solution magnetic field perturbation of magnetic field vector
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Bending analysis of five-layer curved functionally graded sandwich panel in magnetic field:closed-form solution 被引量:1
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作者 M.SHABAN H.MAZAHERI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2021年第2期251-274,共24页
In this paper,an exact closed-form solution for a curved sandwich panel with two piezoelectric layers as actuator and sensor that are inserted in the top and bottom facings is presented.The core is made from functiona... In this paper,an exact closed-form solution for a curved sandwich panel with two piezoelectric layers as actuator and sensor that are inserted in the top and bottom facings is presented.The core is made from functionally graded(FG)material that has heterogeneous power-law distribution through the radial coordinate.It is assumed that the core is subjected to a magnetic field whereas the core is covered by two insulated composite layers.To determine the exact solution,first characteristic equations are derived for different material types in a polar coordinate system,namely,magneto-elastic,elastic,and electro-elastic for the FG,orthotropic,and piezoelectric materials,respectively.The displacement-based method is used instead of the stress-based method to derive a set of closed-form real-valued solutions for both real and complex roots.Based on the elasticity theory,exact solutions for the governing equations are determined layer-by-layer that are considerably more accurate than typical simplified theories.The accuracy of the presented method is compared and validated with the available literature and the finite element simulation.The effects of geometrical and material parameters such as FG index,angular span along with external conditions such as magnetic field,mechanical pressure,and electrical difference are investigated in detail through numerical examples. 展开更多
关键词 five-layer sandwich panel piezoelectric material closed-form solution functionally graded(FG)material magnetic field
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Thermomagnetic viscoelastic responses in a functionally graded hollow structure 被引量:2
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作者 M.N.M.Allam R.Tantawy 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2011年第4期567-577,共11页
This paper presents an analytical solution for the interaction of electric potentials, electric displacements, elastic deformations, and thermoelasticity, and describes electromagnetoelastic responses and perturbation... This paper presents an analytical solution for the interaction of electric potentials, electric displacements, elastic deformations, and thermoelasticity, and describes electromagnetoelastic responses and perturbation of the magnetic field vector in hollow structures (cylinder or sphere), subjected to mechanical load and electric potential. The material properties, thermal expansion coefficient and magnetic permeability of the structure are assumed to be graded in the radial direction by a power law distribution. In the present model we consider the solution for the case of a hollow structure made of viscoelastic isotropic material, reinforced by elastic isotropic fibers, this material is considered as structurally anisotropic material. The exact solutions for stresses and perturbations of the magnetic field vector in FGM hollow structures are determined using the infinitesimal theory of magnetothermoelasticity, and then the hollow structure model with viscoelastic material is solved using the correspondence principle and Illyushin's approximation method. Finally, numerical results are carried out and discussed. 展开更多
关键词 functionally graded material Viscoelasticity Perturbation of magnetic field vector magnetoelasticity
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Electromagnetoelastic behaviors of functionally graded piezoelectric solid cylinder and sphere 被引量:10
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作者 H. L. Dai Y.M. Fu J.H. Yang 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2007年第1期55-63,共9页
Analytical studies on electromagnetoelastic behaviors are presented for the functionally graded piezoelectric material (FGPM) solid cylinder and sphere placed in a uniform magnetic field and subjected to the externa... Analytical studies on electromagnetoelastic behaviors are presented for the functionally graded piezoelectric material (FGPM) solid cylinder and sphere placed in a uniform magnetic field and subjected to the external pressure and electric loading. When the mechanical, electric and magnetic properties of the material obey an identical power law in the radial direction, the exact displacements, stresses, electric potentials and perturbations of magnetic field vector in the FGPM solid cylinder and sphere are obtained by using the infinitesimal theory of electromagnetoelasticity. Numerical examples also show the significant influence of material inhomogeneity. It is interesting to note that selecting a specific value of inhomogeneity parameter β can optimize the electromagnetoelastic responses, which will be of particular importance in modern engineering designs. 展开更多
关键词 functionally graded piezoelectric material (FGPM) Electromagnetoelastic Solid cylinder Solid sphere Perturbation of magnetic field vector
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Haptic Interface with Magnetic Field Sensitive Elastomer 被引量:1
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作者 Takehito Kikuchi Yasunobu Masuda Kento Amano Tetsu Mitsumata Suguru Ohori 《Journal of Mechanics Engineering and Automation》 2013年第3期146-151,共6页
Sense of touch is one of the important information from environment for human to live in daily life. Haptic interface is a hot topic in virtual reality but almost all of the devices focus on fingers and hands as targe... Sense of touch is one of the important information from environment for human to live in daily life. Haptic interface is a hot topic in virtual reality but almost all of the devices focus on fingers and hands as targets. In this paper, we focus on the foot haptic device with magnetic flied sensitive elastomer (MSE). We developed a haptic unit used as a magnetic field generator for MSE and contact point of foot haptic device. MSE samples mixed with 80 wt% carbonyl iron particles were prepared and evaluated with the developed magnet. Experimental results show that the mechanical property of the haptic unit can be modeled with the adjustable friction element. This property has a good advantage for the haptic unit. 展开更多
关键词 Human-machine interface haptic interface planter pressure magnetic field sensitive elastomer functional material.
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A New Approach for Segregation Control in Alloys by High Magnetic Field Gradients and Its Application in Functional Materials
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作者 LIU Tie WANG Qiang +3 位作者 LIU Yin GAO Peng-fei LOU Chang-sheng HE Ji-cheng 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2012年第S1期291-296,共6页
In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discu... In this study,the effects of high magnetic field gradients on the segregation of alloying elements,crystallized phases,and particles in alloys during solidification process and corresponding microstructures were discussed.It was confirmed that applying an external high magnetic field gradient during solidification process is an effective processing route for controlling segregation in alloys and then fabricating functional materials which have special mierostruetures and properties.Such controlling and fabrication were realized by controlling the migration of the alloying elements, crystallized phases,and particles in the liquid matrix on the basis of the Lorentz and magnetic forces. 展开更多
关键词 high magnetic field gradient SEGREGATION functional material Lorentz force magnetic force
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Effect of High-Energy Ball Milling on the Magnetic Properties of NiZn Ferrite Ceramics Synthesized by Spark Plasma Sintering
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作者 Shang Gao Shenhua Song Qingguo Song 《Journal of Materials Science and Chemical Engineering》 2015年第8期50-55,共6页
High-density fine-grained Ni0.5Zn0.5Fe2O4 ferrite ceramics were synthesized by spark plasma sintering (SPS) in conjunction with high energy ball milling. The precursor powders were milled for 20 h, 40 h, and 60 h, res... High-density fine-grained Ni0.5Zn0.5Fe2O4 ferrite ceramics were synthesized by spark plasma sintering (SPS) in conjunction with high energy ball milling. The precursor powders were milled for 20 h, 40 h, and 60 h, respectively, and the milled powders were all sintered for 5 min at 900&degC. All the samples exhibit a single spinel phase. With increasing of the ball milling time, the relative density of the samples increases (up to 97.7%), however, the grain size decreases (down to ~200 nm). At room temperature, the sample from the 40 h-milled powder has the best combination of saturation magnetization and coercivity (83 emu/g and 15 Oe). These outstanding magnetic properties may be associated with high density and uniform microstructure created by SPS on the basis of fine precursor powders produced by high-energy ball milling. 展开更多
关键词 Ferrites functional materials magnetic materials
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An Improved Preisach Distribution Function Identification Method Considering the Reversible Magnetization
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作者 Long Chen Lvsheng Cui +1 位作者 Tong Ben Libing Jing 《CES Transactions on Electrical Machines and Systems》 CSCD 2023年第4期351-357,共7页
This paper presents an identification method of the scalar Preisach model to consider the effect of reversible magnetization in the process of distribution function identification.By reconsidering the identification p... This paper presents an identification method of the scalar Preisach model to consider the effect of reversible magnetization in the process of distribution function identification.By reconsidering the identification process by stripping the influence of reversible components from the measurement data,the Preisach distribution function is identified by the pure irreversible components.In this way,the simulation accuracy of both limiting hysteresis loops and the inner internal symmetrical small hysteresis loop is ensured.Furthermore,through a discrete Preisach plane with a hybrid discretization method,the irreversible magnetic flux density components are computed more efficiently through the improved Preisach model.Finally,the proposed method results are compared with the traditional method and the traditional method considering reversible magnetization and validated by the laboratory test for the B30P105 electrical steel by Epstein frame. 展开更多
关键词 magnetic material Preisach distribution function Reversible magnetization Hybrid discretization method
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Fabricating functionally graded Fe-Cr-Co permanent magnetic alloys via laser powder bed fusion
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作者 Ya-zhou He Ya-qing Hou +3 位作者 Peng Shen Hao Zhang Dong Zhou Hang Su 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2024年第3期729-737,共9页
Laser powder bed fusion(LPBF)in-situ alloying technology offers the possibility to construct gradient materials with varied structures and properties.Functionally graded Fe-Cr-Co permanent magnetic alloys were fabrica... Laser powder bed fusion(LPBF)in-situ alloying technology offers the possibility to construct gradient materials with varied structures and properties.Functionally graded Fe-Cr-Co permanent magnetic alloys were fabricated by LPBF and in-situ alloying mixed powders of Fe,Cr,and Co elements.The effects of different Fe,Cr and Co contents on the microstructure,magnetic properties and hardness of Fe-Cr-Co alloys prepared by LPBF were studied.The as-built Fe-Cr-Co alloys present a single body-centered-cubic phase and have a homogeneous distribution of elements.The mechanical properties and magnetic properties of the compositionally graded sample show a gradient variation.With the increase in Cr content,the Vickers hardness of the sample increases,and the saturation magnetization of the sample decreases.The optimal magnetic properties in an isotropic state are given as coercivity HcB=21.65 kA/m,remanence Br=0.70 T and energy product(BH)_(max)=5.35 kJ/m^(3),which are comparable to or higher than the reported magnetic properties in an isotropic state prepared by traditional powder metallurgy.LPBF in-situ alloying technology has the potential to further explore Fe-Cr-Co magnetic materials,such as those consisting of multiple or more constituent elements,and to maximize the compositional flexibility of magnetic materials. 展开更多
关键词 Fe-Cr-Co alloy Laser powder bed fusion In-situ alloying functional material magnetic property
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Properties of Durable Magnetorheological Elastomers 被引量:1
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作者 Wang Jing Wei Yintao 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS CSCD 2023年第3期22-28,共7页
Magnetorheological elastomers(MREs)are a type of intelligent material that can be actively controlled.However,the ferromagnetic particles in MREs are large,meaning that MREs contain many holes,which degrade the mechan... Magnetorheological elastomers(MREs)are a type of intelligent material that can be actively controlled.However,the ferromagnetic particles in MREs are large,meaning that MREs contain many holes,which degrade the mechanical properties and fatigue resistance of MREs.In this work,liquid nitrile butadiene rubber-phenolic resin microcapsules were added as a self-healing agent to an MRE.The microcapsules reduced the number of holes caused by ferromagnetic particles and improved the mechanical properties and fatigue resistance of MREs.The magnetorheological effect of the MRE was not affected and was similar to that of the MRE without the self-healing agent.Under 100%strain and with the same number of cycles,the crack growth rate of the MRE without the self-healing agent was approximately 236%faster than that of the corresponding MRE with the self-healing agent and the crack length was approximately 136%longer. 展开更多
关键词 functional mechanical properties magnetic materials FATIGUE
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一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料
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作者 付华 陈慧媛 +1 位作者 宋维君 赵云 《材料导报》 EI CAS CSCD 北大核心 2024年第17期278-283,共6页
本研究成功制备了一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料(CFE)。通过溶剂热法合成了Fe_(3)O_(4)纳米颗粒磁核,利用3-氨丙基三乙氧基硅烷在碱性环境下的酯水解反应,在磁核表面包覆SiO_(2)并修饰氨基,制备了Fe_(3)O_(4)@SiO_(... 本研究成功制备了一种新型的用于萃取铷的冠醚功能化磁性固相纳米材料(CFE)。通过溶剂热法合成了Fe_(3)O_(4)纳米颗粒磁核,利用3-氨丙基三乙氧基硅烷在碱性环境下的酯水解反应,在磁核表面包覆SiO_(2)并修饰氨基,制备了Fe_(3)O_(4)@SiO_(2)-NH_(2)中间产物,再利用4′-羧基苯并-18-冠6-醚上的羧基与修饰在Fe_(3)O_(4)@SiO_(2)-NH_(2)表面的氨基在1-乙基-(3-二甲基氨基丙基)碳二亚胺盐酸盐的催化下发生酰胺化反应,将该冠醚修饰在中间产物的表面,制备了CFE新型材料。分析了Fe_(3)O_(4)、Fe_(3)O_(4)@SiO_(2)-NH_(2)、CFE的微观形貌、磁化性质、X射线衍射性质、红外吸收性质、元素组成,佐证了材料被成功制备,验证了CFE对Rb^(+)的萃取能力,研究了溶液pH对Rb^(+)萃取效果的影响。结果表明,室温下萃取30 min,在pH为13时CFE对Rb^(+)具有最佳的萃取效果,萃取率为90.0%。 展开更多
关键词 磁性固相萃取 冠醚 功能材料 纳米材料
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二维MXene材料CrVCF_(2)的电子性质和磁性的第一性原理研究
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作者 刘晓莹 黄海深 +2 位作者 孙丽 潘孟美 尚真真 《人工晶体学报》 CAS 北大核心 2024年第8期1386-1393,共8页
采用基于密度泛函理论的第一性原理研究了—F官能团对Janus型MXene二维材料CrVC的结构、电子性质和磁性的影响。计算结果表明,—F官能团改变了CrVC的电子性质和磁性,CrVCF_(2)的9种可能结构的基态是铁磁态,其中CrVCF_(2)-33结构的能量最... 采用基于密度泛函理论的第一性原理研究了—F官能团对Janus型MXene二维材料CrVC的结构、电子性质和磁性的影响。计算结果表明,—F官能团改变了CrVC的电子性质和磁性,CrVCF_(2)的9种可能结构的基态是铁磁态,其中CrVCF_(2)-33结构的能量最低,是最为稳定的基态结构,其磁矩为5.01μ_(B),带隙为0.099 eV,具有半导体特性。在施加-4%~+4%的双轴拉伸与压缩应变时,CrVCF_(2)-33的总磁矩保持不变;能量随着压缩或拉伸应变的增大而变大,但变化的幅度低于0.2 eV;带隙在应变的作用下会发生改变,当拉伸应变为2.4%时,带隙减小到0.005 eV,接近于零,可看作是自旋零带隙半导体。由此可知,适度的应变可调节CrVCF_(2)材料的电子能带结构,甚至可形成自旋零带隙半导体,这在自旋电子学领域具有潜在的应用价值。 展开更多
关键词 第一性原理 MXene材料 —F官能团 电子结构 磁性 应变
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团簇MnPS_(3)电子性质分析
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作者 原琳 方志刚 +2 位作者 刘立娥 魏代霞 宋静丽 《广西师范大学学报(自然科学版)》 CAS 北大核心 2024年第2期159-165,共7页
为探究团簇MnPS_(3)的电子性质,设计出团簇MnPS_(3)模型,运用密度泛函理论,在B3LYP/def2-tzvp水平下对其进行优化处理,最终得到9种优化构型;利用原子电荷量、布居数以及电子自旋密度对团簇MnPS_(3)的电子性质进行综合分析。实验结果表明... 为探究团簇MnPS_(3)的电子性质,设计出团簇MnPS_(3)模型,运用密度泛函理论,在B3LYP/def2-tzvp水平下对其进行优化处理,最终得到9种优化构型;利用原子电荷量、布居数以及电子自旋密度对团簇MnPS_(3)的电子性质进行综合分析。实验结果表明,由团簇MnPS_(3)布居数可知,电子主要由Mn原子的3d轨道、P原子的3s和3p轨道以及S原子的3s轨道流向剩余轨道;由团簇各原子的电荷量可知,Mn和P是电子的主要提供者,且Mn的失电子能力强于P,S则是电子的主要接受者;由团簇MnPS_(3)电子自旋密度可知,若原子间电子均匀分布以及原子间存在更多自旋向下的电子,则可能使团簇MnPS_(3)具有更良好的稳定性。 展开更多
关键词 MnPS_(3) 二维磁性材料 布居数 电子自旋密度 拓扑学 密度泛函理论
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锰基金属有机框架材料{[Mn_(2)(ina)_(4)(H_(2)O)_(2)]·2EtOH}_(n)的电子结构、磁性和吸附性能的理论研究
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作者 张坚 李萍 《原子与分子物理学报》 CAS 北大核心 2024年第2期73-79,共7页
本文采用密度泛函理论研究了锰基金属有机框架(Mn-MOF)材料{[Mn_(2)(ina)_(4)(H_(2)O)_(2)]·2EtOH}_(n)的电子性质,磁学性质及吸附二氧化碳的性能,结果表明:该Mn-MOF材料是一种反铁磁耦合材料,其高的CO_(2)结合亲和力主要归因于CO_... 本文采用密度泛函理论研究了锰基金属有机框架(Mn-MOF)材料{[Mn_(2)(ina)_(4)(H_(2)O)_(2)]·2EtOH}_(n)的电子性质,磁学性质及吸附二氧化碳的性能,结果表明:该Mn-MOF材料是一种反铁磁耦合材料,其高的CO_(2)结合亲和力主要归因于CO_(2)(作为Lewis碱的氧孤对电子)到不饱和金属位点(Lewis酸)的较高电荷转移.本文也对实验中报道的对CO_(2)/N_(2)烟气混合物有高选择性CO_(2)吸附能力进行了验证,理论计算值与实验值有着很好的一致性. 展开更多
关键词 金属有机框架材料 密度泛函理论 磁性 二氧化碳吸附
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磁性粉体在新型功能材料领域的应用进展
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作者 马启航 李海燕 +1 位作者 李佳妮 冯效迁 《辽宁化工》 CAS 2024年第10期1556-1559,共4页
近年来,随着工业的进步和科技的发展,磁性粉体材料在新型功能材料领域的应用愈发广泛,例如磁性粉体包覆高分子树脂后可作为磁性树脂应用于水处理领域;可作为催化剂使用,拥有可通过外磁场回收的优势;也可在经过表面修饰后作为靶向剂或药... 近年来,随着工业的进步和科技的发展,磁性粉体材料在新型功能材料领域的应用愈发广泛,例如磁性粉体包覆高分子树脂后可作为磁性树脂应用于水处理领域;可作为催化剂使用,拥有可通过外磁场回收的优势;也可在经过表面修饰后作为靶向剂或药物载体应用于生物医药领域。对磁性粉体材料近年来在功能材料领域的应用进展进行全面综述,并对未来发展方向进行了展望。 展开更多
关键词 磁性粉体 功能材料 水处理 催化 生物医药
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放电等离子烧结技术的发展和应用 被引量:148
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作者 张久兴 刘科高 周美玲 《粉末冶金技术》 EI CAS CSCD 北大核心 2002年第3期129-134,共6页
放电等离子烧结 (SPS)是一种快速、低温、节能、环保的材料制备新技术。本文综述了SPS在国内外的发展和应用 ,介绍了SPS的原理、特点及在新材料制备加工中的应用。
关键词 放电等离子烧结 发展 应用
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磁性高分子材料的研究及应用进展 被引量:16
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作者 陶长元 吴玲 +1 位作者 杜军 迟海声 《材料导报》 EI CAS CSCD 2003年第4期50-53,共4页
磁性高分子材料分为复合型和结构型两类,分别阐述了复合型和结构型磁性高分子材料的研究和应用现状,强调了磁性高分子材料的发展意义,井对其理论和应用领域的开拓前景进行了展望。
关键词 磁性高分子材料 功能材料 复合型高分子材料 结构型高分子材料
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Fe3O4@ABc复合材料的制备及其对水中甲基橙的吸附 被引量:9
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作者 王向辉 石建军 +3 位作者 游诚航 颜慧琼 史载锋 林强 《精细化工》 EI CAS CSCD 北大核心 2020年第7期1422-1428,共7页
以Fe3O4纳米粒子和海藻生物质炭(ABc)为原料,采用共沉淀法制备了磁性海藻生物质炭(Fe3O4@ABc)复合材料,并用于甲基橙(MO)的吸附。通过XRD、SEM、TEM、FTIR和VSM对Fe3O4@ABc复合材料进行了表征。考察了溶液pH、吸附剂添加量对MO吸附性能... 以Fe3O4纳米粒子和海藻生物质炭(ABc)为原料,采用共沉淀法制备了磁性海藻生物质炭(Fe3O4@ABc)复合材料,并用于甲基橙(MO)的吸附。通过XRD、SEM、TEM、FTIR和VSM对Fe3O4@ABc复合材料进行了表征。考察了溶液pH、吸附剂添加量对MO吸附性能的影响,并进行了吸附动力学和等温吸附模型拟合。结果表明,Fe3O4纳米粒子成功复合到ABc表面,Fe3O4@ABc复合材料具有超顺磁性,在外在磁场的作用下能够快速分离;当m(ABc)∶m(Fe3O4)=2∶1时,制备的Fe3O4@ABc复合材料比表面积为622.88m2/g,平均孔径1.55 nm,具有良好的MO去除效果。当MO质量浓度为100 mg/L,Fe3O4@ABc添加量为10 mg,pH为3,吸附时间240 min,MO的去除率为96.14%。制备的Fe3O4@ABc复合材料对MO的吸附过程符合拟一级动力学模型,吸附等温线符合Freundlich模型,并以物理吸附为主,化学吸附为辅。 展开更多
关键词 海藻生物质炭 吸附 甲基橙 磁性功能材料
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溶剂蒸发法制备磁性微胶囊及其相关性能 被引量:8
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作者 陈红苗 罗艳 +3 位作者 钟毅 胡翔 万瑄 金宇 《精细化工》 EI CAS CSCD 北大核心 2012年第9期844-849,共6页
将共沉淀法所得纳米OA-Fe3O4(油酸改性Fe3O4)分散于不同介质中形成磁流体作为芯材,以PMMA(聚甲基丙烯酸甲酯)作为壁材,采用溶剂蒸发法制备磁性微胶囊。对不同芯材及乳化剂进行筛选;考察乳化剂用量、m(芯材)∶m(壁材)及乳化转速对微胶囊... 将共沉淀法所得纳米OA-Fe3O4(油酸改性Fe3O4)分散于不同介质中形成磁流体作为芯材,以PMMA(聚甲基丙烯酸甲酯)作为壁材,采用溶剂蒸发法制备磁性微胶囊。对不同芯材及乳化剂进行筛选;考察乳化剂用量、m(芯材)∶m(壁材)及乳化转速对微胶囊制备的影响。通过XRD、FTIR、TEM、SEM、光学显微镜、VSM(振动样品磁强计)对纳米OA-Fe3O4和磁性微胶囊的有效成分、形貌、热性能、磁性能进行分析表征。结果表明,共沉淀法制备的纳米颗粒有效成分为Fe3O4,且可形成稳定磁流体。OA-Fe3O4粒径在3~15 nm,比饱和磁化强度为43.3 emu/g,具有顺磁性。以分散在n-C16H34的OA-Fe3O4磁流体为芯材,w〔SDS(十二烷基硫酸钠)〕=2%的水溶液为乳化剂,m(芯材)∶m(壁材)=5∶1,乳化转速800 r/min条件下可制得外形规整,壁厚1~2μm,且粒径集中于(10±2)μm的磁性微胶囊。该胶囊比饱和磁化强度为36.9 emu/g,具有良好的磁响应性。 展开更多
关键词 溶剂蒸发法 磁性微胶囊 制备条件 结构形态 磁响应 功能材料
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