Occurrence,Spatial Distribution,Sources and Risk Assessment of Per-and Polyfluoroalkyl Substances in Surface Sediments of the Yellow River Delta Wetland

Per-and polyfluoroalkyl substances(PFASs)are emerging persistent organic pollutants(POPs).In this study,47 surface sediment samples were collected from the Yellow River Delta wetland(YRDW)to investigate the occurrence,spatial distribution,potential sources,and ecological risks of PFASs.Twenty-three out of 26 targeted PFASs were detected in surface sediment samples from the YRDW,with totalΣ23PFASs concentrations ranging from 0.23 to 16.30 ng g^(-1) dw and a median value of 2.27 ng g^(-1) dw.Perfluorooctanoic acid(PFOA),perfluorobutanoic acid(PFBA)and perfluorooctanesulfonic acid(PFOS)were the main contaminants.The detection frequency and concentration of perfluoroalkyl carboxylic acids(PFCAs)were higher than those of perfluoroal-kanesulfonic acids(PFSAs),while those of long-chain PFASs were higher than those of short-chain PFASs.The emerging PFASs substitutes were dominated by 6:2 chlorinated polyfluoroalkyl ether sulfonic acid(6:2 Cl-PFESA).The distribution of PFASs is significantly influenced by the total organic carbon content in the sediments.The concentration of PFASs seems to be related to human activities,with high concentration levels of PFASs near locations such as beaches and villages.By using a positive matrix factorization model,the potential sources of PFASs in the region were identified as metal plating mist inhibitor and fluoropolymer manufacturing sources,metal plating industry and firefighting foam and textile treatment sources,and food packaging material sources.The risk assessment indicated that PFASs in YRDW sediments do not pose a significant ecological risk to benthic organisms in the region overall,but PFOA and PFOS exert a low to moderate risk at individual stations.

Activity Pattern and Habitat Use of Shorebirds in an Artificial Wetland Complex:A Case Study of Breeding Pied Avocet in the Yellow River Delta,China

With the loss of substantial natural wetlands in coastal zones,artificial wetlands provide alternative habitats for many shorebirds.Scientific management of artificial wetlands used by shorebirds plays an important role in maintaining the stability of shorebird population.Satellite tracking technique can obtain high-precision location information of individuals day and night,providing a good technical support for the study of quantitative relationship between waterfowls and their habitats.In this study,satellite tracking method,Remote Sensing(RS)and Geographic Information System(GIS)technology were used to analyze the activity pattern and habitat utilization characteristics of Pied Avocet during breeding period in an artificial wetland complex in the Yellow River Delta(YRD),China.The results showed that the breeding Pied Avocets had a small range of activity,with a total core and main home range of 33.10 km^(2) and 216.30 km^(2),respectively.This species tended to forage in the pond and salt pan during the day and night,respectively,with an unfixed staying time in the breeding ground.The distance between breeding ground and feeding ground was less than 6 km.It is emphasized that in addition to improving the conditions of the remaining natural habitats,effective managing artificial habitats is a priority for shorebird conservation.This research could provide reference for the management of artificial wetlands in coastal zones and supply technique support for the protection of shorebirds and their habitats,and alleviate human-bird conflicts and sustainable development of coastal zones.

Persistence of fertilization effects on soil organic carbon in degraded alpine wetlands in the Yellow River source region

In the restoration of degraded wetlands,fertilization can improve the vegetation-soil-microorganisms complex,thereby affecting the organic carbon content.However,it is currently unclear whether these effects are sustainable.This study employed Biolog-Eco surveys to investigate the changes in vegetation characteristics,soil physicochemical properties,and soil microbial functional diversity in degraded alpine wetlands of the source region of the Yellow River at 3 and 15 months after the application of nitrogen,phosphorus,and organic mixed fertilizer.The following results were obtained:The addition of nitrogen fertilizer and organic compost significantly affects the soil organic carbon content in degraded wetlands.Three months after fertilization,nitrogen addition increases soil organic carbon in both lightly and severely degraded wetlands,whereas after 15 months,organic compost enhanced the soil organic carbon level in severely degraded wetlands.Structural equation modeling indicates that fertilization decreases the soil pH and directly or indirectly influences the soil organic carbon levels through variations in the soil water content and the aboveground biomass of vegetation.Three months after fertilization,nitrogen fertilizer showed a direct positive effect on soil organic carbon.However,organic mixed fertilizer indirectly reduced soil organic carbon by increasing biomass and decreasing soil moisture.After 15 months,none of the fertilizers significantly affected the soil organic carbon level.In summary,it can be inferred that the addition of nitrogen fertilizer lacks sustainability in positively influencing the organic carbon content.

Effects of Vegetation Restoration Age on Soil C:N:P Stoichiometry in Yellow River Delta Coastal Wetland of China

Vegetation restoration can alter carbon(C),nitrogen(N),and phosphorus(P)cycles in coastal wetlands affecting C:N:P stoichiometry.However,the effects of restoration age on soil C:N:P stoichiometry are unclear.In this study,we examined the re-sponses of soil C,N,and P contents and their stoichiometric ratios to vegetation restoration age,focusing on below-ground processes and their relationships to aboveground vegetation community characteristics.We conducted an analysis of temporal gradients based on the'space for time'method to synthesize the effects of restoration age on soil C:N:P stoichiometry in the Yellow River Delta wetland of China.The findings suggest that the combined effects of restoration age and soil depth create complex patterns of shifting soil C:N:P stoichiometry.Specifically,restoration age significantly increased all topsoil C:N:P stoichiometries,except for soil total phosphorus(TP)and the C:N ratio,and slightly affected subsoil C:N:P stoichiometry.The effects of restoration age on the soil C:N ratio was well constrained owing to the coupled relationship between soil organic carbon(SOC)and total nitrogen(TN)contents,while soil TP con-tent was closely related to changes in plant species diversity.Importantly,we found that the topsoil C:N:P stoichiometry was signific-antly affected by plant species diversity,whereas the subsoil C:N:P stoichiometry was more easily regulated by pH and electric con-ductivity(EC).Overall,this study shows that vegetation restoration age elevated SOC and N contents and alleviated N limitation,which is useful for further assessing soil C:N:P stoichiometry in coastal restoration wetlands.

Ecological Restoration and Landscape Construction of Wetland——A Case Study of Planning and Design of Mi River Wetland Park in Linqu of Shandong

Based on geological characteristic of Mi River Wetland Park in Linqu of Shandong,the paper had illustrated historical and cultural spirits of Linqu,and then proposed planning strategies and contents of Mi River Wetland Park.It discussed new approaches for wetland restoration and landscape construction from the perspectives of ecological restoration of wetland system,overall construction of leisure system,and full display of regional characteristic.The construction of wetland system laid stress on water system design,terrain treatment,vegetation construction,and biological diversity creation.Wetland system would be overlaid with leisure system,divided into wetland leisure zone,wetland entertainment zone,humanity landscape zone,wetland science popular zone and wetland experience zone,all of which would be constructed with characteristic respectively.On the basis of site character,the paper had searched an energy balance and substance transformation method between rivers,plants,earth and humans,of certain practicality.

Survey on Bio-resources of Zhengzhou Yellow River Wetland and Protective Measures

Upon the basis of comprehensive survey on the bio-resources of Zhengzhou Yellow River Wetland Nature Reserve,we analyzed the relationship between wetland ecology and bio-resource protection,the problems encountering wetland development and protection,and further put forward corresponding protective measures.

Protection and Cultivation Planning of Songhua River Wetland in Harbin City of China

By adopting combined method of zoning protection and sorting protection,protection and cultivation planning of Songhua River Wetland in Harbin had been conducted.It emphasized that diversity and stability of resources should be protected,completeness and originality of resources be protected and ecological system be recovered and protected.On this basis,different protection and development strategies had been carried out on different zones including ecological landscape protection zone,natural landscape protection zone,scenery recovery zone,scenery appreciating zone and development control zone;and then specialized cultivation planning had been conducted on wetland resource,animal resources,water landscape,wetland recovery and so on.At the same time,it should control peripheral protection belt,so as to highlight urban landscape pattern of "river·island·city",and realize harmonious development target of "people·landscape·city".It stressed that protection and cultivation of valuable urban wetland resource were important contents of urban ecological construction.It should introduce new theories and methods into researches on theories and concrete methods according to local conditions,so as to effectively conduct protection and planning,and propose scientific and operational suggestions for later planning.

Activities of Urease and Phosphatase in Integrated Vertical Flow Constructed Wetland and Purification Effect of Black and Malodorous River

[Objective]The activities of urease and phosphatase in integrated vertical flow constructed wetland and purification effect of black and malodorous river were studied.[Method]Honeycomb stone and soft filler were used as matrix,the biological grid integrated vertical flow constructed wetland system was built to strengthen treatment for black and malodorous river,and the activities of urease and phosphatase of two fillers in different functional areas of constructed wetland were tested to study the film formation property of two fillers in different functional areas.[Result]Both urease and phosphatase activities on biofilm of soft filler were significantly higher than on biofilm of honeycomb stone filler;indicating that choosing soft filler was more advantageous to the growth of biofilm;and urease activity had significant correlation with total nitrogen removal rate,while phosphatase activity had no significant correlation with total phosphorus removal rate.[Conclusion]This study provided evidences for utilizing the activities of urease and phosphatase to evaluate the purification effect of black and malodorous river and choose appropriate filler.

Effect of Different Land Use Patterns on Physical Properties of Soil Water in Yellow River Wetland in Shaanxi Province

[Objective] This study was to reveal the effect of different land use patterns on physical characteristics of soil water in the Yellow River wetland in Shaanxi Province.[Method]Taking Yellow River wetland in Shaanxi Province as experimental plot,we compared the physical properties of the soil water under different land use patterns and studied the physical properties and the change law of soil water during the wetland degeneration process.[Result]Under different land use patterns,soil bulk density rose with the increase of soil depth.During the degeneration process of from river wetland to reclaimed wetland（paddy field）,finally to abandoned land owing to salinization,the mean soil bulk density reduced correspondingly from 1.474 to 1.522 g/cm3,finally to 1.593 g/cm3 when abandoned.Accompanying wetland degeneration,soil became compact increasingly,and the indicators of soil porosity（total porosity,capillary porosity,non-capillary porosity）were also reduced with the change of land use patterns,in which,capillary porosity and total porosity reached the extremely significant level with the change of land use patterns,and non-capillary porosity reached significant level.The changes of soil porosity condition accelerated the deterioration of wetland.Under different land use patterns,the maximum soil moisture capacity,capillary moisture capacity and minimum moisture capacity all showed a similar change law.Compared with wetland,the maximum soil moisture capacity of reclaimed land（paddy field）and salinized land respectively decreased by 5.7% and 22.3%,capillary moisture capacity by 0.2% and 19.4%,minimum moisture capacity by 2.7% and 15.9%.Of the three land use patterns,wetland displayed both higher water holding capacity and water drainage capacity over reclaimed land（paddy field）and salinized land.By comparison with wetland,the reclaimed land（paddy field）and salinized land respectively decreased by 12.4% and 15.2% in total water holding capacity,and by 2.7% and 15.9% in total water drainage capacity.[Conclusion]To conserve the water resource in Yellow River wetland,regulate the hydrological cycle and enhance drought and water logging resistances,it should be noted that reasonable countermeasures be taken to exploit the state-owned forest land and paddy field around the wetland and the related resources.

Landscape planning and ecology construction of wetland comprehensive protected area system in the Sanjiang Plain

Wetland is one of the richest biodiversity areas in the earth. The main purpose of establishing wetland protected area is to protect biodiversity, and the protection of ecosystem diversity and landscape diversity is the key to protect biodiversity. In order to protect regional ecosystem and landscape, it is a good way to establish wetland comprehensive protected area which connected wetland nature reserves by habitat corridors. The Sanjiang Plain as a study area, its landscape evaluation index system on wetland protected area was studied, and some problems on landscape planning and ecology construction were further approached in this paper.It showed that establishing wetland comprehensive protected area is very important to protect regional wetlands, to maintain ecological balance, and to improve the sustainable development of agriculture and industry in this region.

Changes of Coastal Wetland Ecosystems in the Yellow River Delta and Protection Countermeasures to Them

Coastal wetlands in the Yellow River Delta are typical new wetland ecosystems in warm temperate zone. In recent years, influenced by natural and human factors, these coastal wetlands in the Yellow River Delta have undergone changes of landscape fragmentation, vegetation degradation, pollution, species reduction, and harmful exotic species invasion. These changes have influenced sustainable and healthy development of marine economy of the Yellow River Delta. To protect natural ecological environment of the Yellow River Delta, the authors recommended that it should establish and improve policies, laws and regulations of wetland protection; carry out wetland resource investigation and assessment and monitoring; strengthen comprehensive protection and control of wetland; reduce wetland degradation and promote sustainable use of wetland.

Correlation of eco-hydrographic benefit and height increment of Robinia pseudoacacia stand with climatic environmental factors in Yellow River Delta Wetland of China

The relationship between eco-hydrographic benefit of forest vegetation and climatic environmental factors is one of the focuses in the research on environmental protection and ecosystem countermeasures in Wetland. The runoff, sediment and soil moisture rate dynamics in Robinia pseudoacacia plantation and its clearcut area were investigated in the natural runoff experiment plots in Yellow River Delta Wet- land, Shandong Province, China. The correlation of height increment ofR. pseudoacacia with nine climate factors such as light, water, heat, etc. was analyzed by stepwise regression analysis. The results showed that the amounts of runoff and sediment in clearcut area of R. pseudoacacia were 53.9%-150.8% and 172.8%-387.1% higher than that in Robinia pseudoacacia plantation, respectively. The runoff peak value in R. pseudoacacia stand was obviously lower than that in clerarcut area, meantime, the occurrence of runoffpeak in R. pseudoacacia stand was 25 min later than in its clerarcut area. The soil moisture rates in R. pseudoacacia stand and its clearcut varied periodically with annual rainfall precipitation in both dry season and humid season. The annual mean soil moisture rate in R. pseudoacacia stand was 23.3%-25.6% higher than that in its clearcut area. Meanwhile, a regression model reflecting the correlation between the height increment of R. pseudoacacia and climatic factors was developed by stepwise regression procedure method. It showed that the light was the most important factor for the height increment ofR. pseudoacacia, followed by water and heat factors.

Performance of Subsurface Constructed Wetland in River Rehabilitation

[ Objective] This study was to research the treatment effect of different media in undercurrent wetland on contamination, so as to pro- vide reference for rehabitating water body of river along small towns. [ Method ] Three different media of gravel, cobblestone and shale were used to rehabilitate water quality of contaminated river. [ Result ] Gravel, cobblestone and shale all performed well in removing TN, TP and CODw,, in contaminated water, of which gravel stuffed undercurrent wetland run best, averagely removing 49.4% TN, 34.7% and 48. 5% COD~, respectively. [ Conclusion] Undercurrent constructed wetland can effectively improve the water quality of contaminated river, and it is cheaper in cost and simpler in operation, thus suitable for generalizing in small towns of China.

Treatment Efficiencies of Constructed Wetlands for Eutrophic Landscape River Water

The efficiencies of two types of constructed wetlands for the treatment of low-concentration polluted eutrophic land- scape river water were studied in the western section of the Qingyuan River at the Minhang campus of Shanghai Jiaotong University.The first wetland was a single-stage system using gravel as a filtration medium,and the second was a three- stage system filled with combinations of gravel,zeolite,and fly ash.Results from parallel operations of the wetlands showed that the three-stage constructed wetland could remove organics,nitrogen, and phosphorus successfully.At the same time,it could also decrease ammoniacal odour in the effluent.Compared to the single-stage constructed wetland,it had better nutrient removal efficiencies with a higher removal of 19.37%-65.27% for total phosphorus (TP) and 21.56%- 62.94% for total nitrogen (TN),respectively,during the operation period of 14 weeks.In terms of removal of chemical oxygen demand (COD), turbidity,and blue-green algae,these two wetland systems had equivalent performances.It was also found that in the western section of the test river,in which the two constructed wetlands were located, the water quality was much better than that in the eastern and middle sections without constructed wetland because COD,TN, and TP were all in a relatively lower level and the eutrophication could be prevented completely in the western section.

Nitrogen Biological Cycle Characteristics of Seepweed(Suaeda salsa) Wetland in Intertidal Zone of Huanghe(Yellow) River Estuary

From April 2008 to November 2009, the nitrogen （N） cycle of plant-soil system in seepweed （Suaeda salsa） wetland in the intertidal zone of the Huanghe （Yellow） River estuary was studied. Results showed that soil N had sig- nificant seasonal fluctuations and vertical distribution, and the net N mineralization rates in topsoil were significantly different in growing season （p 〈 0.01）. The N/P ratio （9.87 ±1.23） of S. salsa was less than 14, indicating that plant growth was limited by N. The N accumulated in S. salsa litter at all times during decomposition, which was ascribed to the N immobilization by microbes from the environment. Soil organic N was the main N stock of plant-soil system, accounting for 97.35% of the total N stock. The N absorption and utilization coefficients of S. salsa were very low （0.0145 and 0.3844, respectively）, while the N cycle coefficient was high （0.7108）. The results of the N turnovers among compartments of S. salsa wetland showed that the N uptake amount of aboveground part and root were 7.764 g/m2and 4.332 g/m2, respectively. The N translocation amounts from aboveground part to root and from root to soil were 3.881 g/m2 and 0.626 g/m2, respectively. The N translocation amount from aboveground living body to litter was 3.883 g/m2, the annual N return amount from litter to soil was more than 0.125（-） g/m2 （minus represented immobili- zation）, and the net N mineralization amount in topsoil （0-15 cm） in growing season was 1.190 g/m2. The assessment of N biological cycle status orS. salsa wetland indicated that N was a very important limiting factor and the ecosystem was situated in unstable and vulnerable status. The S. salsa was seemingly well adapted to the low-nutrient status and vulnerable habitat, and the N quantitative relationships determined in the compartment model might provide scientific base for us to reveal the special adaptive strategy orS. salsa to the vulnerable habitat in the following studies.

Effect of Hydrological Connectivity on Soil Carbon Storage in the Yellow River Delta Wetlands of China

Hydrological connectivity has significant effects on the functions of estuarine wetland ecosystem.This study aimed to examine the dynamics of hydrological connectivity and its impact on soil carbon pool in the Yellow River Delta,China.We calculated the hydrological connectivity based on the hydraulic resistance and graph theory,and measured soil total carbon and organic carbon under four different hydrological connectivity gradients(Ⅰ0‒0.03,Ⅱ0.03‒0.06,Ⅲ0.06‒0.12,Ⅳ0.12‒0.39).The results showed that hydrological connectivity increased in the north shore of the Yellow River and the south tidal flat from 2007 to 2018,which concentrated in the mainstream of the Yellow River and the tidal creek.High hydrological connectivity was maintained in the wetland restoration area.The soil total carbon storage and organic carbon storage significantly increased with increasing hydrological connectivity fromⅠtoⅢgradient and decreased inⅣgradient.The highest soil total carbon storage of 0‒30 cm depth was 5172.34 g/m^(2),and organic carbon storage 2764.31 g/m^(2)inⅢgradient.The hydrological connectivity changed with temporal and spatial change during 2007‒2018 and had a noticeable impact on soil carbon storage in the Yellow River Delta.The results indicated that appropriate hydrological connectivity,i.e.0.08,could effectively promote soil carbon storage.

Planning and Ecological Landscape Design of Urban Constructed Wetland

In addition to purifying water, constructed wetland has become an important ecological landscape in city. The characteristics and key design points of constructed wetland under the ecological principles were explored, taking the Jingyue Lake in Zhongxiang City, Hubei Province for example, treatment processes were designed for different infl ow waters on the basis of site analysis to facilitate the water environment control and ecological landscape construction, ecological theories were applied to explore functional layouts and landscape designs of wetland, to build a favorable ecological environment of urban wetland and design outstanding wetland ecological landscapes.

Effects of Reclamation on Soil Carbon and Nitrogen in Coastal Wetlands of Liaohe River Delta,China

To evaluate the influence of wetland reclamation on vertical distribution of carbon and nitrogen in coastal wetland soils, we measured the soil organic carbon(SOC), soil total nitrogen(STN) and selected soil properties at five sampling plots(reed marsh, paddy field, corn field, forest land and oil-polluted wetland) in the Liaohe River estuary in September 2013. The results showed that reclamation significantly changed the contents of SOC and STN in the Liaohe River estuary(P < 0.001). The SOC concentrations were in the order: oil-polluted wetland > corn field > paddy field > forest land > reed marsh, with mean values of 52.17, 13.14, 11.46, 6.44 and 6.16 g/kg, respectively. STN followed a similar order as SOC, with mean values of 1351.14, 741.04, 632.32, 496.17 and 390.90 mg/kg, respectively. Interaction of reclamation types and soil depth had significant effects on SOC and STN, while soil depth had significant effects on SOC, but not on STN. The contents of SOC and STN were negatively correlated with pH and redox potential(Eh) in reed marsh and corn field, while the SOC and STN in paddy field had positive correlations with electrical conductivity(EC). Dissolved organic carbon(DOC), ammonium nitrogen(NH_4^+-N) and nitrate nitrogen(NO_3~–-N) were also significantly changed by human activities. NH_4^+-N and NO_3~–-N increased to different degrees, and forest land had the highest NO_3~–-N concentration and lowest DOC concentration, which could have been caused by differences in soil aeration and fertilization. Overall, the results indicate that reed harvest increased soil carbon and nitrogen release in the Liaohe River Estuary, while oil pollution significantly increased the SOC and STN; however, these cannot be used as indicators of soil fertility and quality because of the serious oil pollution.

Investigation on Water Pollution of Four Rivers in Coastal Wetland of Yellow River Estuary

[Objective] The study aimed at analysing water pollution of four rivers in coastal wetland of Yellow River estuary. [Method] Taking four seriously polluted rivers (Guangli River, Shenxian Ditch, Tiao River and Chao River) in coastal wetland of Yellow River estuary as study objects, water samples were collected from the four rivers in May (dry period), August (wet period) and November (normal period) in 2009 and 2010 respectively, then pollution indices like nutritive salts, COD, chlorophyll-a, petroleum, etc. were measured. Afterwards, the status quo of water pollution was assessed based on Nemero index and comprehensive trophic level index (TLI), so as to find out the integral status quo of water quality of wetland rivers and damages to aquatic ecological environment. [Result] On the whole, water pollution of four rivers in coastal wetland of Yellow River estuary was serious, in the eutrophication state, and the main pollutants were TN, TP, NH+4-N and petroleum. In addition, excessive N and P in the four rivers resulted in water eutrophication of Bohai Bay, so further leading to ride tide, which destroyed the coastal ecological environment of Bohai Sea. Moreover, compared with historical data, water pollution by nitrogen and phosphorus became more serious, while there was no obvious aggravation in the water pollution by petroleum. In a word, water pollution wasn’t optimistic on the whole. [Conclusion] The research could provide theoretical bases for the protection and utilization of river water in coastal wetland of Yellow River estuary and its coastal sea area.

Optimizing Rank of Landscape Planning Works of Urban Wetland Park

Classifying and ranking the huge amounts of landscape planning works of urban wetland park is always difficult due to the multi-functions （ecological, leisure, educational and disaster prevention） of the urban wetland park. Therefore, an optimizing rank system is urgently needed. Analytic Hierarchy Process （AHP） and Technique for Order Preference by Similarity to Ideal Solution （TOPSIS） models were used to rank the planning works of 30 urban wetland park based on four mainly factors, which included landscape ecological planning, landscape planning, ecological planning and economic planning. The study indicated that the AHP- TOPSIS model had good discrimination in the classification and ranking of landscape planning works of urban wetland park and it was also applicable to the planning works of other urban greenbelts.