Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions...Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions in China,are challenged by the huge demand for steel.Carbon and pollutants often share common emission sources,indicating that emission reduction could be achieved synergistically.Here,we explored the inherent potential of measures to adjust feedstock composition and technological structure and to control the size of the ISI to achieve carbon emission reduction(CER)and pollution emission reduction(PER).We investigated five typical pollutants in this study,namely,petroleum hydrocarbon pollutants and chemical oxygen demand in wastewater,particulate matter,SO_(2),and NO_(x) in off gases,and examined synergies between CER and PER by employing cross elasticity for the period between 2022 and 2035.The results suggest that a reduction of 8.7%-11.7%in carbon emissions and 20%-31%in pollution emissions(except for particulate matter emissions)could be achieved by 2025 under a high steel scrap ratio(SSR)scenario.Here,the SSR and electric arc furnace(EAF)ratio serve critical roles in enhancing synergies between CER and PER(which vary with the type of pollutant).However,subject to a limited volume of steel scrap,a focused increase in the EAF ratio with neglection of the available supply of steel scrap to EAF facilities would lead to an increase carbon and pollution emissions.Although CER can be achieved through SSR and EAF ratio optimization,only when the crude steel production growth rate remains below 2.2%can these optimization measures maintain the emissions in 2030 at a similar level to that in 2021.Therefore,the synergistic effects between PER and CER should be considered when formulating a development route for the ISI in the future.展开更多
How to ensure the reliable operation of the complex and huge electrical system composed of a large number of electrical equipment in iron and steel enterprises?Combined with working experience,the author introduces fo...How to ensure the reliable operation of the complex and huge electrical system composed of a large number of electrical equipment in iron and steel enterprises?Combined with working experience,the author introduces four main factors affecting the normal operation of equipment,analyzes five main problems existing in the operation and management of electrical equipment,and puts forward corresponding improvement measures,so as to improve the management level of electrical equipment in iron and steel enterprises.展开更多
China's economic growth is heavily influenced by exports, while reconciling environmental regulation and economic growth requires handling the relationship between environmental regulation and industrial competitiven...China's economic growth is heavily influenced by exports, while reconciling environmental regulation and economic growth requires handling the relationship between environmental regulation and industrial competitiveness well. The effects of environmental regulation on industrial competitiveness are largely subject to the institutional design of environmental regulation. Despite numerous studies on the relationship between environmental regulation and industrial competitiveness, a consensus has yet to be reached. Aside from differences in research methodology, these studies failed to give sufficient consideration to the impact of environmental regulation on industrial competitiveness. Such effects can be negative or positive depending on the design of environmental regulatory policy. This paper has investigated the relationship between environmental regulation and the competitiveness of China's iron and steel industry and discovered that tighter environmental regulation does not diminish the competitiveness of the iron and steel industry since the policy design of environmental regulation accommodates the tolerance of advanced production capacity and includes a reasonable cost sharing mechanism. This discovery is of important reference for China to develop rational policy design to balance the relationship between environmental regulation and industrial competitiveness.展开更多
This paper establishes a model for the production cost of iron and steel enterprise.The variation rule of the production cost versus the iron/steel ratio for two cases, namely,fixed steel production and a fixed amount...This paper establishes a model for the production cost of iron and steel enterprise.The variation rule of the production cost versus the iron/steel ratio for two cases, namely,fixed steel production and a fixed amount of molten iron,is analyzed,and the concept of a steel scrap threshold price is proposed.According to the analysis results,when the steel scrap unit price exceeds the steel scrap threshold price, an increase in the iron/steel ratio can reduce the production cost,and vice versa.When the gap between the steel scrap unit price and the steel scrap threshold price is relatively large, the impact of the iron/steel ratio on the production cost is more prominent.According to the calculation example,when steel production is fixed (284 358 t/month)and the steel scrap unit price is 263.2 yuan/t more than the steel scrap threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 750 000 yuan (2.63 yuan/t).When the amount of molten iron is fixed (270 425 t/month)and the steel scrap unit price is 140.7 yuan/t more than the threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 430 000 yuan (1.5 yuan/t).The results indicate that iron and steel enterprise should adjust the production strategy in time when the scrap price fluctuates, and then the production cost will be reduced.展开更多
The feasibility of steel slag used as an iron fertilizer was studied in a pot experiment with corn. Slag alone or acidified slag was added to two Fe-deficient calcareous soils at different rates. Results showed that m...The feasibility of steel slag used as an iron fertilizer was studied in a pot experiment with corn. Slag alone or acidified slag was added to two Fe-deficient calcareous soils at different rates. Results showed that moderate rates (10 and 20 g kg-1) of slag or acidified slag substantially increased corn dry matter yield and Fe uptake. Application of steel slag increased the residual concentration of ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA) extractable Fe in the soils. The increase of extractable Fe was usually proportional to the application rate, and enhanced by the acidification of slag. Steel slag appeared to be a promising and inexpensive source of Fe to alleviate crop Fe chlorosis in Fe-deficient calcareous soils.展开更多
Recently procured outstanding achievements in iron and steel industry in China are presented by data or facts in steel output, energy consumption, technical and economical indicators and advanced technologies that are...Recently procured outstanding achievements in iron and steel industry in China are presented by data or facts in steel output, energy consumption, technical and economical indicators and advanced technologies that are being adopted. The latest achievements in refractonries for this biggest user industry are reviewed, covering new refractories for CDQ coke oven, BF hearth, AOD Lining, long life tundish, SEN for clean steel making and regenerative reheating furnace . The reciprocal relationship is obvious that the rapid development of iron and steel industry has given an impetus to the advance of refractories industry, which in return has contributed greatly to the former.展开更多
In the past 25 years in China, to meet with the rapid increase in steel production accompanied by adoption of advanced metallurgical technologies, there has been fast development of China' s refractories industry in ...In the past 25 years in China, to meet with the rapid increase in steel production accompanied by adoption of advanced metallurgical technologies, there has been fast development of China' s refractories industry in production capacity, in quality improvement and in development of new products. Sophisticated high performance refractory materials mainly based on our rich reserves of magncsite, bauxite and flake graphite have been developed, such as carbon-bonded products, high purity oxide products, bauxite-based low creep and high strength high alumina bricks and LC, ULC and ZC castables. They have been used in blast furnaces, BOFs, EAFs, secondary refining and continuous casting with considerable improvement in service pecformance.展开更多
In order to solve internal logistics problems of iron and steel works,such as low transportation efficiency of vehicles and high transportation cost,the production process and traditional transportation style of iron ...In order to solve internal logistics problems of iron and steel works,such as low transportation efficiency of vehicles and high transportation cost,the production process and traditional transportation style of iron and steel works were introduced.The internal transport tasks of iron and steel works were grouped based on cluster analysis according to demand time of the transportation.An improved vehicle scheduling model of semi-trailer swap transport among loading nodes and unloading nodes in one task group was set up.The algorithm was designed to solve the vehicle routing problem with simultaneous pick-up and delivery(VRPSPD) problem based on semi-trailer swap transport.A solving program was written by MATLAB software and the method to figure out the optimal path of each grouping was obtained.The dropping and pulling transportation plan of the tractor was designed.And an example of semi-trailer swap transport in iron and steel works was given.The results indicate that semi-trailer swap transport can decrease the numbers of vehicles and drivers by 54.5% and 88.6% respectively compared with decentralized scheduling in iron and steel works,and the total distance traveled reduces by 43.5%.The semi-trailer swap transport can help the iron and steel works develop the production in intension.展开更多
Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this ori...Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel, cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components.展开更多
China has the biggest rare earths resource in the world,no wonder she pays much at-tention to the application of rare earth metals (REM).The application of REM in iron andsteel in China began at the end of 1950’s.The...China has the biggest rare earths resource in the world,no wonder she pays much at-tention to the application of rare earth metals (REM).The application of REM in iron andsteel in China began at the end of 1950’s.The production of REM-treated iron and steelhad been made steady progress in the period of 1980’s.The production of REM-treatediron and steel in 1989 was 1.4 million tons and 250,000 tons respectively.The interest oftreating steel with REM in China keeps growing even in these years,It comes from the nat-展开更多
The effects of sphere size on the microstructural and mechanical properties of ductile iron–steel hollow sphere(DI–SHS) syntactic foams were investigated in this study. The SHSs were manufactured by fluidized-bed ...The effects of sphere size on the microstructural and mechanical properties of ductile iron–steel hollow sphere(DI–SHS) syntactic foams were investigated in this study. The SHSs were manufactured by fluidized-bed coating via the Fe-based commercial powder–binder suspension onto expanded polystyrene spheres(EPSs). Afterwards, the DI–SHS syntactic foams were produced via a sand-mold casting process. The microstructures of specimens were investigated by optical microscopy, scanning electron microscopy(SEM), and energy-dispersive X-ray spectroscopy(EDS). The microscopic evaluations of specimens reveal distinct regions composed of the DI matrix, SHS shells, and compatible interface. As a result, the microstructures and graphite morphologies of the DI matrix depend on sphere size. When the sphere size decreases, the area fractions of cementite and graphite phases are observed to increase and decrease, respectively. Compression tests were subsequently conducted at ambient temperature on the DI–SHS syntactic foams. The results reveal that the compression behavior of the syntactic foams is enhanced with increasing sphere size. Furthermore, the compressed specimens demonstrate that microcracks start and grow from the interface region.展开更多
BAIRD SPECTROVAC 2000(DV 5) consisting of new type of HR-400 high repeat rate spark spectrosource, air cooled sample stand and an annular purged tungsten counter electrode has been used continuously in the la...BAIRD SPECTROVAC 2000(DV 5) consisting of new type of HR-400 high repeat rate spark spectrosource, air cooled sample stand and an annular purged tungsten counter electrode has been used continuously in the lab for many years and resulted in good economic benefits. The paper describes the application of the spectrometer in quantitative analysis of cast iron and steel products, and the experience and technique may be helpful to those who are using the same kind of instrument.展开更多
The effect of ball scribing on iron loss of conventional grain-oriented ( CGO) and high-permeability grain-oriented ( HGO) electrical steel was investigated. In this paper,ball scribing was achieved by self- designed ...The effect of ball scribing on iron loss of conventional grain-oriented ( CGO) and high-permeability grain-oriented ( HGO) electrical steel was investigated. In this paper,ball scribing was achieved by self- designed ball scribing instrument and a computer-controlled system capable of providing high accuracy and automatic measurements was developed for the magnetisation and measurement at high and low flux densities. The results showed that after ball scribing,iron loss of two types of steel ( C711 and H668 ) apparently decreases ( 5. 5% and 8. 2% respectively after 16mm scribing at 1. 2T) ,and at high and low flux densities, CGO and HGO electrical steel performs differently. Through the formation and development of free magnetic poles and secondary magnetic domains due to compressive stress,primary magnetic domain spacing of grain- oriented electrical steel becomes smaller,which reflects as a reduction of iron loss in the macroscopic magnetic properties. Through iron loss formula derivation,the effect of domain refinement on grain-oriented electrical steel was also interpreted.展开更多
In the present study, pure iron/copper composite metal cladding was deposited onto carbon steel by tungsten inert gas welding. The study focused on interfacial morphological, microstructural, and mechanical analyses o...In the present study, pure iron/copper composite metal cladding was deposited onto carbon steel by tungsten inert gas welding. The study focused on interfacial morphological, microstructural, and mechanical analyses of the composite cladding layers. Iron liquid–solid-phase zones were formed at copper/steel and iron interfaces because of the melting of the steel substrate and iron. Iron concentrated in the copper cladding layer was observed to exhibit belt, globule, and dendrite morphologies. The appearance of iron-rich globules indicated the occurrence of liquid phase separation(LPS) prior to solidification, and iron-rich dendrites crystallized without the occurrence of LPS. The maximum microhardness of the iron/steel interface was lower than that of the copper/steel interface because of the diffusion of elemental carbon. All samples fractured in the cladding layers. Because of a relatively lower strength of the copper layer, a short plateau region appeared when shear movement was from copper to iron.展开更多
In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadf...In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadfield steel. The hardness and unnotched charpy impact strength of the HC-Wi alloy and Hadfield steel were examined at ambient temperature in the as-cast and heat-treated conditions. A pin-on-disc test at linear speed of 1.18 m/s and a 10 N normal load was employed to evaluate the wear behavior of both steel samples. Microstructural results showed that varying the carbon level in HC-Wi alloys can affect the chromium carbide morphology and its distribution in the austenite matrix which leads to considerable changes of the mechanical properties. Abrasion test showed that HC-Wi alloys have superior wear resistance, about three times of the Hadfield steel.展开更多
The hardening characteristics of medium carbon steel and ductile cast iron using neem oil as quenching medium has been investigated. The samples were quenched to room temperature in Neem oil. To compare the effectiven...The hardening characteristics of medium carbon steel and ductile cast iron using neem oil as quenching medium has been investigated. The samples were quenched to room temperature in Neem oil. To compare the effectiveness of the neem oil samples were also quenched in water and SAE engine oil the commercial quenchants. The microstructures and mechanical properties of the quenched samples were used to determine the quench severity of the neem oil. The result shows that hardness value of the medium carbon steel increased from 18.30HVN in the as-cast condition to 21.60, 20.30and 20.70HVN while that of ductile cast iron samples increased from 18.90HVN in the as-cast condition to 22.65, 20.30 and 21.30HVN for water, neem oil and SAE40 engine oil respectively. The as-received steel sample gave the highest impact strength value and water quenched sample gave the least impact strength. The impact strength of the medium carbon steel samples is 50.84, 41.35, 30.50 and 45.15 Joule and that of ductile iron is 2.71, 1.02, 0.68 and 1.70 Joule for as-cast condition, neem oil, water and SAE 40 engine oil quenched respectively. The microstructure of the samples quenched in the Neem oil revealed the formation of martensite. Hence, neem oil can be used where cooling severity less than that of water but greater than SAE 40 engine oil is required for hardening of plain carbon steels and ductile cast iron.展开更多
The use of econometric methods to analyze the relationship between our country steel price index and the international iron ore freight rate,time series stationarity test,cointegration test,Granger test of causality a...The use of econometric methods to analyze the relationship between our country steel price index and the international iron ore freight rate,time series stationarity test,cointegration test,Granger test of causality and model parameter estimation tools use,find that there is Granger causality between our country steel price index and the international iron ore freight rate,China' s steel price fluctuations to some extent affect the international iron ore freight.展开更多
To make full use of the gas resource, stabilize the pipe network pressure, and obtain higher economic benefits in the iron and steel industry, the surplus gas prediction and scheduling models were proposed. Before app...To make full use of the gas resource, stabilize the pipe network pressure, and obtain higher economic benefits in the iron and steel industry, the surplus gas prediction and scheduling models were proposed. Before applying the forecasting techniques, a support vector classifier was first used to classify the data, and then the filtering was used to create separate trend and volatility sequences. After forecasting, the Markov chain transition probability matrix was introduced to adjust the residual. Simulation results using surplus gas data from an iron and steel enterprise demonstrate that the constructed SVC-HP-ENN-LSSVM-MC prediction model prediction is accurate, and that the classification accuracy is high under different conditions. Based on this, the scheduling model was constructed for surplus gas operating, and it has been used to investigate the comprehensive measures for managing the operational probabilistic risk and optimize the economic benefit at various working conditions and implementations. It has extended the concepts of traditional surplus gas dispatching systems, and provides a method for enterprises to determine optimal schedules.展开更多
基金supported by the National Key Research and Development Program of China(2019YFC1904800)the National Natural Science Foundation of China(72274105).
文摘Decarbonization and decontamination of the iron and steel industry(ISI),which contributes up to 15%to anthropogenic CO_(2) emissions(or carbon emissions)and significant proportions of air and water pollutant emissions in China,are challenged by the huge demand for steel.Carbon and pollutants often share common emission sources,indicating that emission reduction could be achieved synergistically.Here,we explored the inherent potential of measures to adjust feedstock composition and technological structure and to control the size of the ISI to achieve carbon emission reduction(CER)and pollution emission reduction(PER).We investigated five typical pollutants in this study,namely,petroleum hydrocarbon pollutants and chemical oxygen demand in wastewater,particulate matter,SO_(2),and NO_(x) in off gases,and examined synergies between CER and PER by employing cross elasticity for the period between 2022 and 2035.The results suggest that a reduction of 8.7%-11.7%in carbon emissions and 20%-31%in pollution emissions(except for particulate matter emissions)could be achieved by 2025 under a high steel scrap ratio(SSR)scenario.Here,the SSR and electric arc furnace(EAF)ratio serve critical roles in enhancing synergies between CER and PER(which vary with the type of pollutant).However,subject to a limited volume of steel scrap,a focused increase in the EAF ratio with neglection of the available supply of steel scrap to EAF facilities would lead to an increase carbon and pollution emissions.Although CER can be achieved through SSR and EAF ratio optimization,only when the crude steel production growth rate remains below 2.2%can these optimization measures maintain the emissions in 2030 at a similar level to that in 2021.Therefore,the synergistic effects between PER and CER should be considered when formulating a development route for the ISI in the future.
文摘How to ensure the reliable operation of the complex and huge electrical system composed of a large number of electrical equipment in iron and steel enterprises?Combined with working experience,the author introduces four main factors affecting the normal operation of equipment,analyzes five main problems existing in the operation and management of electrical equipment,and puts forward corresponding improvement measures,so as to improve the management level of electrical equipment in iron and steel enterprises.
文摘China's economic growth is heavily influenced by exports, while reconciling environmental regulation and economic growth requires handling the relationship between environmental regulation and industrial competitiveness well. The effects of environmental regulation on industrial competitiveness are largely subject to the institutional design of environmental regulation. Despite numerous studies on the relationship between environmental regulation and industrial competitiveness, a consensus has yet to be reached. Aside from differences in research methodology, these studies failed to give sufficient consideration to the impact of environmental regulation on industrial competitiveness. Such effects can be negative or positive depending on the design of environmental regulatory policy. This paper has investigated the relationship between environmental regulation and the competitiveness of China's iron and steel industry and discovered that tighter environmental regulation does not diminish the competitiveness of the iron and steel industry since the policy design of environmental regulation accommodates the tolerance of advanced production capacity and includes a reasonable cost sharing mechanism. This discovery is of important reference for China to develop rational policy design to balance the relationship between environmental regulation and industrial competitiveness.
基金The National Key Technology R&D Program during the 12th Five-Year Plan Period(No.2012BAF10B05)
文摘This paper establishes a model for the production cost of iron and steel enterprise.The variation rule of the production cost versus the iron/steel ratio for two cases, namely,fixed steel production and a fixed amount of molten iron,is analyzed,and the concept of a steel scrap threshold price is proposed.According to the analysis results,when the steel scrap unit price exceeds the steel scrap threshold price, an increase in the iron/steel ratio can reduce the production cost,and vice versa.When the gap between the steel scrap unit price and the steel scrap threshold price is relatively large, the impact of the iron/steel ratio on the production cost is more prominent.According to the calculation example,when steel production is fixed (284 358 t/month)and the steel scrap unit price is 263.2 yuan/t more than the steel scrap threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 750 000 yuan (2.63 yuan/t).When the amount of molten iron is fixed (270 425 t/month)and the steel scrap unit price is 140.7 yuan/t more than the threshold price,an increase of 0.01 in the iron/steel ratio causes a monthly production cost reduction of approximately 430 000 yuan (1.5 yuan/t).The results indicate that iron and steel enterprise should adjust the production strategy in time when the scrap price fluctuates, and then the production cost will be reduced.
基金Project supported by the National Natural Science Foundation of China (No. 30270800).
文摘The feasibility of steel slag used as an iron fertilizer was studied in a pot experiment with corn. Slag alone or acidified slag was added to two Fe-deficient calcareous soils at different rates. Results showed that moderate rates (10 and 20 g kg-1) of slag or acidified slag substantially increased corn dry matter yield and Fe uptake. Application of steel slag increased the residual concentration of ammonium bicarbonate-diethylenetriamine pentaacetic acid (AB-DTPA) extractable Fe in the soils. The increase of extractable Fe was usually proportional to the application rate, and enhanced by the acidification of slag. Steel slag appeared to be a promising and inexpensive source of Fe to alleviate crop Fe chlorosis in Fe-deficient calcareous soils.
文摘Recently procured outstanding achievements in iron and steel industry in China are presented by data or facts in steel output, energy consumption, technical and economical indicators and advanced technologies that are being adopted. The latest achievements in refractonries for this biggest user industry are reviewed, covering new refractories for CDQ coke oven, BF hearth, AOD Lining, long life tundish, SEN for clean steel making and regenerative reheating furnace . The reciprocal relationship is obvious that the rapid development of iron and steel industry has given an impetus to the advance of refractories industry, which in return has contributed greatly to the former.
文摘In the past 25 years in China, to meet with the rapid increase in steel production accompanied by adoption of advanced metallurgical technologies, there has been fast development of China' s refractories industry in production capacity, in quality improvement and in development of new products. Sophisticated high performance refractory materials mainly based on our rich reserves of magncsite, bauxite and flake graphite have been developed, such as carbon-bonded products, high purity oxide products, bauxite-based low creep and high strength high alumina bricks and LC, ULC and ZC castables. They have been used in blast furnaces, BOFs, EAFs, secondary refining and continuous casting with considerable improvement in service pecformance.
基金Project(70671108) supported by the National Natural Science Foundation of China
文摘In order to solve internal logistics problems of iron and steel works,such as low transportation efficiency of vehicles and high transportation cost,the production process and traditional transportation style of iron and steel works were introduced.The internal transport tasks of iron and steel works were grouped based on cluster analysis according to demand time of the transportation.An improved vehicle scheduling model of semi-trailer swap transport among loading nodes and unloading nodes in one task group was set up.The algorithm was designed to solve the vehicle routing problem with simultaneous pick-up and delivery(VRPSPD) problem based on semi-trailer swap transport.A solving program was written by MATLAB software and the method to figure out the optimal path of each grouping was obtained.The dropping and pulling transportation plan of the tractor was designed.And an example of semi-trailer swap transport in iron and steel works was given.The results indicate that semi-trailer swap transport can decrease the numbers of vehicles and drivers by 54.5% and 88.6% respectively compared with decentralized scheduling in iron and steel works,and the total distance traveled reduces by 43.5%.The semi-trailer swap transport can help the iron and steel works develop the production in intension.
文摘Electrolytic hardening process was developed in USSR in the 1950s. The process was developed but was not commercially exploited. There is no evidence of work done on this process in India. The author has done this original work applied to different materials like steel, cast iron and aluminum-bronze. This paper gives details of microstructural transformations along with hardness value achieved. There is vital scope for this process to become viable for surface hardening and selective hardening of small components.
文摘China has the biggest rare earths resource in the world,no wonder she pays much at-tention to the application of rare earth metals (REM).The application of REM in iron andsteel in China began at the end of 1950’s.The production of REM-treated iron and steelhad been made steady progress in the period of 1980’s.The production of REM-treatediron and steel in 1989 was 1.4 million tons and 250,000 tons respectively.The interest oftreating steel with REM in China keeps growing even in these years,It comes from the nat-
文摘The effects of sphere size on the microstructural and mechanical properties of ductile iron–steel hollow sphere(DI–SHS) syntactic foams were investigated in this study. The SHSs were manufactured by fluidized-bed coating via the Fe-based commercial powder–binder suspension onto expanded polystyrene spheres(EPSs). Afterwards, the DI–SHS syntactic foams were produced via a sand-mold casting process. The microstructures of specimens were investigated by optical microscopy, scanning electron microscopy(SEM), and energy-dispersive X-ray spectroscopy(EDS). The microscopic evaluations of specimens reveal distinct regions composed of the DI matrix, SHS shells, and compatible interface. As a result, the microstructures and graphite morphologies of the DI matrix depend on sphere size. When the sphere size decreases, the area fractions of cementite and graphite phases are observed to increase and decrease, respectively. Compression tests were subsequently conducted at ambient temperature on the DI–SHS syntactic foams. The results reveal that the compression behavior of the syntactic foams is enhanced with increasing sphere size. Furthermore, the compressed specimens demonstrate that microcracks start and grow from the interface region.
文摘BAIRD SPECTROVAC 2000(DV 5) consisting of new type of HR-400 high repeat rate spark spectrosource, air cooled sample stand and an annular purged tungsten counter electrode has been used continuously in the lab for many years and resulted in good economic benefits. The paper describes the application of the spectrometer in quantitative analysis of cast iron and steel products, and the experience and technique may be helpful to those who are using the same kind of instrument.
基金Sponsored by the National Natural Science Foundation of China (Grant No. 51174057 and 51274062)National High Technology Research and Development Program (Grant No. 2012AA03A503)
文摘The effect of ball scribing on iron loss of conventional grain-oriented ( CGO) and high-permeability grain-oriented ( HGO) electrical steel was investigated. In this paper,ball scribing was achieved by self- designed ball scribing instrument and a computer-controlled system capable of providing high accuracy and automatic measurements was developed for the magnetisation and measurement at high and low flux densities. The results showed that after ball scribing,iron loss of two types of steel ( C711 and H668 ) apparently decreases ( 5. 5% and 8. 2% respectively after 16mm scribing at 1. 2T) ,and at high and low flux densities, CGO and HGO electrical steel performs differently. Through the formation and development of free magnetic poles and secondary magnetic domains due to compressive stress,primary magnetic domain spacing of grain- oriented electrical steel becomes smaller,which reflects as a reduction of iron loss in the macroscopic magnetic properties. Through iron loss formula derivation,the effect of domain refinement on grain-oriented electrical steel was also interpreted.
基金financially supported by the National Natural Science Foundation of China (No. 51575132)
文摘In the present study, pure iron/copper composite metal cladding was deposited onto carbon steel by tungsten inert gas welding. The study focused on interfacial morphological, microstructural, and mechanical analyses of the composite cladding layers. Iron liquid–solid-phase zones were formed at copper/steel and iron interfaces because of the melting of the steel substrate and iron. Iron concentrated in the copper cladding layer was observed to exhibit belt, globule, and dendrite morphologies. The appearance of iron-rich globules indicated the occurrence of liquid phase separation(LPS) prior to solidification, and iron-rich dendrites crystallized without the occurrence of LPS. The maximum microhardness of the iron/steel interface was lower than that of the copper/steel interface because of the diffusion of elemental carbon. All samples fractured in the cladding layers. Because of a relatively lower strength of the copper layer, a short plateau region appeared when shear movement was from copper to iron.
文摘In this study, high chromium white iron (HC-Wi) alloy and the Hadfield steel were studied. The microstructure of this high-chromium iron was studied using Metallurgical optical microscopy (OM) and compared to the Hadfield steel. The hardness and unnotched charpy impact strength of the HC-Wi alloy and Hadfield steel were examined at ambient temperature in the as-cast and heat-treated conditions. A pin-on-disc test at linear speed of 1.18 m/s and a 10 N normal load was employed to evaluate the wear behavior of both steel samples. Microstructural results showed that varying the carbon level in HC-Wi alloys can affect the chromium carbide morphology and its distribution in the austenite matrix which leads to considerable changes of the mechanical properties. Abrasion test showed that HC-Wi alloys have superior wear resistance, about three times of the Hadfield steel.
文摘The hardening characteristics of medium carbon steel and ductile cast iron using neem oil as quenching medium has been investigated. The samples were quenched to room temperature in Neem oil. To compare the effectiveness of the neem oil samples were also quenched in water and SAE engine oil the commercial quenchants. The microstructures and mechanical properties of the quenched samples were used to determine the quench severity of the neem oil. The result shows that hardness value of the medium carbon steel increased from 18.30HVN in the as-cast condition to 21.60, 20.30and 20.70HVN while that of ductile cast iron samples increased from 18.90HVN in the as-cast condition to 22.65, 20.30 and 21.30HVN for water, neem oil and SAE40 engine oil respectively. The as-received steel sample gave the highest impact strength value and water quenched sample gave the least impact strength. The impact strength of the medium carbon steel samples is 50.84, 41.35, 30.50 and 45.15 Joule and that of ductile iron is 2.71, 1.02, 0.68 and 1.70 Joule for as-cast condition, neem oil, water and SAE 40 engine oil quenched respectively. The microstructure of the samples quenched in the Neem oil revealed the formation of martensite. Hence, neem oil can be used where cooling severity less than that of water but greater than SAE 40 engine oil is required for hardening of plain carbon steels and ductile cast iron.
文摘The use of econometric methods to analyze the relationship between our country steel price index and the international iron ore freight rate,time series stationarity test,cointegration test,Granger test of causality and model parameter estimation tools use,find that there is Granger causality between our country steel price index and the international iron ore freight rate,China' s steel price fluctuations to some extent affect the international iron ore freight.
基金Project(51204082)supported by the National Natural Science Foundation of ChinaProject(KKSY201458118)supported by the Talent Cultivation Project of Kuning University of Science and Technology,China
文摘To make full use of the gas resource, stabilize the pipe network pressure, and obtain higher economic benefits in the iron and steel industry, the surplus gas prediction and scheduling models were proposed. Before applying the forecasting techniques, a support vector classifier was first used to classify the data, and then the filtering was used to create separate trend and volatility sequences. After forecasting, the Markov chain transition probability matrix was introduced to adjust the residual. Simulation results using surplus gas data from an iron and steel enterprise demonstrate that the constructed SVC-HP-ENN-LSSVM-MC prediction model prediction is accurate, and that the classification accuracy is high under different conditions. Based on this, the scheduling model was constructed for surplus gas operating, and it has been used to investigate the comprehensive measures for managing the operational probabilistic risk and optimize the economic benefit at various working conditions and implementations. It has extended the concepts of traditional surplus gas dispatching systems, and provides a method for enterprises to determine optimal schedules.