A Study on the Kinetics of the Europium Electrochemistry Reduction 1.The Polarization Properties of Europium Reduced at the Cathode

This article studies the polarization properties of the cathode reduction of Eu in the Sm-Eu-Gd chloride system by using a constant potential method.As the feed concentration,temperature,and stirring rate of the system change,the system can gradually turn from chemical polarization to concentration polarization,and there would be a higher limiting current.As to the effects of acidity,only at a rather higher pH there will be a typical polarization property.The study can give some bases for the Eu electroreduction technlolgy parameter selection.

Polarization properties of porous anodic alumina with Y-branched Cu nanowires

Porous anodic alumina （PAA） templates with branch structure are fabricated by the two-step anodic oxidation processes, and then the Y-branched Cu nanowires are synthesized in the templates using an alternating current （AC） deposition method. We observe the morphology image of the samples by scanning electron microscopy （SEM）, and measure the transmission spectrum and the polarization spectrum of the samples by the spectrophotometer. The results show that PAA films with Y-branched Cu nanowires have better transmittance in the near infrared region. An extinction ratio of 15 - 18 dB and an insertion loss of 0.1 - 0.4 dB are obtained in this region. Therefore PAA with Y-branched Cu nanowires can be used as a near-infrared micropolarizer, and this kind of micropolarizer would have a promising future in the field of photoelectricity integration.

Tight Focusing Properties of Radially Polarized Gaussian Beams with Pair of Vortices

The tight focusing properties of a radially polarized Gaussian beam with a nested pair of vortices having a radial wave front distribution are investigated theoretically by the vector diffraction theory. The results show that the optical intensity in the focal region can be altered considerably by changing the location of the vortices nested in a radially polarized Gaussian beam. It is noted that focal evolution from one annular focal pattern to a highly confined focal spot in the transverse direction is observed corresponding to the change in the location of the optical vortices in the input plane. It is also observed that the generated focal hole or spot lead to a focal shift along the optical axis remarkably under proper radial phase modulation. Hence the proposed system may be applied to construct tunable optical traps for both high and low refractive index particles.

Investigations of mechanical, electronic, and magnetic properties of non-magnetic MgTe and ferro-magnetic Mg_(0.75)T M_(0.25)Te (TM = Fe, Co, Ni): An ab-initio calculation

The mechanical, electronic and magnetic properties of non-magnetic MgTe and ferro-magnetic （FM） Mgo.75 TM025 Te （TM = Fe, Co, Ni） in the zinc-blende phase are studied by ab-initio calculations for the first time. We use the generalized gradient approximation functional for computing the structural stability, and mechanical properties, while the modified Becke and Johnson local （spin） density approximation （mBJLDA） is utilized for determining the electronic and magnetic properties. By comparing the energies of non-magnetic and FM calculations, we find that the compounds are stable in the FM phase, which is confirmed by their structural stabilities in terms of enthalpy of formation. Detailed descriptions of elastic properties of Mgo.75TMo.25Te alloys in the FM phase are also presented. For electronic properties, the spin- polarized electronic band structures and density of states are computed, showing that these compounds are direct bandgap materials with strong hybridizations of TM 3d states and Te p states. Further, the ferromagnetism is discussed in terms of the Zener free electron model, RKKY model and double exchange model. The charge density contours in the （110） plane are calculated to study bonding properties. The spin exchange splitting and crystal field splitting energies are also calculated. The distribution of electron spin density is employed in computing the magnetic moments appearing at the magnetic sites （Fe, Co, Ni）, as well as at the non-magnetic sites （Mg, Te）. It is found that the p-d hybridization causes not only magnetic moments on the magnetic sites but also induces negligibly small magnetic moments at the non-magnetic sites.

Tight Focusing Properties of Azimuthally Polarized Pair of Vortex Beams through a Dielectric Interface

Tight focusing properties of an azimuthally polarized Gaussian beam with a pair of vortices through a dielectric interface is theoretically investigated by vector diffraction theory. For the incident beam with a pair of vortices of opposite topological charges, the vortices move toward each other, annihilate and revive in the vicinity of focal plane, which results in the generation of many novel focal patterns. The usable focal structures generated through the tight focusing of the double-vortex beams may find applications in micro-particle trapping, manipulation, and material processing, etc.

Properties of One-Dimensional Highly Polarized Fermi Gases

Using both the exact Bethe ansatz method and the variational method, we study properties of the one-dimensional Fermi polaron. We focus on the binding energy, effective mass, momentum distributions, Tan contact and correlation functions. As the attraction increases, the impurity is more tightly bound and correlated with the surrounding particles, and the size of formed polaron decreases. In addition, compared with the Bethe ansatz method, the variational method is totally qualified to study the one-dimensional Fermi polaron. The intrinsic reason is that the number of particle-hole excitations in a Fermi sea, caused by a single impurity, is always rather small. The variational method can be well extended to other impurity systems.

Effects of Al and Sn on electrochemical properties of Mg-6%Al-1%Sn (mass fraction) magnesium alloy as anode in 3.5%NaCl solution

Mg-6%Al-1%Sn(mass fraction) alloy is a newly developed anode material for seawater activated batteries. The electrochemical properties of Mg-1%Sn, Mg-6%Al and Mg-6%Al-1%Sn alloys are measured by galvanostatic and potentiodynamic tests. Scanning electron microscopy(SEM) with energy dispersive spectrometry(EDS) is used to characterize the microstructures of the experimental alloys. The results show that the Mg-6%Al-1%Sn alloy obtains more negative discharge potential(-1.38 V(vs SCE)) in hot-rolled condition. This is attributed to the fine dynamically recrystallized grains during the hot rolling process. After the experimental alloys are annealed at 473 K for 1 h, the discharge potentials of Mg-6%Al-1%Sn alloy are more negative than those of Mg-6%Al alloy under different current densities. After annealing at 673 K, the discharge potentials of Mg-6%Al-1%Sn alloy become more positive than those of Mg-6%Al alloy. Such phenomenon is due to the coarse grains and the second phase Mg2 Sn. The discharge potentials of Mg-1%Sn shift positively obviously in the discharge process compared with Mg-6%Al-1%Sn alloy. This is due to the corrosion products pasting on the discharge surface, which leads to anode polarization.

Tight Focusing Properties of Phase Modulated Radially Polarized Laguerre Bessel Gaussian Beam

We propose a new approach for generating a multiple focal spot segment of subwavelength size, by tight focusing of a phase modulated radially polarized Laguerre Bessel Gaussian beam. The focusing properties are investigated theoretically by .vector diffraction theory. We observe that the focal segment with multiple focal structures is separated with different axial distances and a super long dark channel can be generated by properly tuning the phase of the incident radially polarized Laguerre Bessel Gaussian beam. We presume that such multiple focal patterns and high intense beam may find applications in atom optics, optical manipulations and multiple optical trapping.

Electrical and dielectric characterization of Au/ZnO/n-Si device depending frequency and voltage

Au/Zn O/n-type Si device is obtained using atomic layer deposition（ALD） for Zn O layer, and some main electrical parameters are investigated, such as surface/interface state（Nss）, barrier height（Φb）, series resistance（Rs）, donor concentration（Nd）, and dielectric characterization depending on frequency or voltage. These parameters are acquired by use of impedance spectroscopy measurements at frequencies ranging from 10 k Hz to 1 MHz and the direct current（DC） bias voltages in a range from-2 V to ＋2 V at room temperature are used. The main electrical parameters and dielectric parameters,such as dielectric constant（ε＂）, dielectric loss（ε＂）, loss tangent（tan δ）, the real and imaginary parts of electric modulus（M and M）, and alternating current（AC） electrical conductivity（σ） are affected by changing voltage and frequency. The characterizations show that some main electrical parameters usually decrease with increasing frequency because charge carriers at surface states have not enough time to fallow an external AC signal at high frequencies, and all dielectric parameters strongly depend on the voltage and frequency especially in the depletion and accumulation regions. Consequently, it can be concluded that interfacial polarization and interface charges can easily follow AC signal at low frequencies.