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Diagenetic history and porosity evolution of the Middle Permian clastic-carbonate mixed system,Indus Basin,Pakistan:Implications for reservoir development
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作者 Bilal Wadood Suleman Khan +4 位作者 Michael Wagreich Torsten Vennemann Hong Li Matee Ullah Katerina Schöpfer 《Energy Geoscience》 EI 2024年第4期156-173,共18页
This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin,Pakistan.Multiple data sets including outcrop,petrography,cathodolumin... This study deals with unraveling the diagenesis-induced porosity evolution in a mixed clastic-carbonate sequence of the Middle Permian Indus Basin,Pakistan.Multiple data sets including outcrop,petrography,cathodoluminescence,scanning electron microscopy(SEM),mineralogy,and geochemical isotopic compositions were integrated to establish a link between porosity evolution and diagenesis.The spatial thickness and facies variations of the strata at outcrop scale are inherently controlled by the underlying bathymetry of the basin with deepening westward trend.The low values ofδ^(18)O of the target strata,relative to average values of the Permian carbonate,hints to diagenetic alteration in the strata.The data sets used in this study reveal modification of the strata in four environments,that is,i)early marine diagenesis indicated by micritization,pervasive dolomitization and isopachous fibrous cements,followed by ii)meteoric dissolution,and iii)shallow burial diagenetic processes including the precipitation of blocky cement,compaction of skeletal and non-skeletal allochems,and stylolites,and iv)a deep burial environment,characterized by pressure solution,and micro-fractures.The clastic intervals host subangular to subrounded quartz grains,floating textures,and almost complete absence of deleterious clay minerals,consequently resulting in the preservation of primary porosity.The primary porosity of carbonate intervals is preserved in the form of intercrystalline and intracrystalline porosity.The secondary porosity evolved through various diagenetic phases in the form of fractures and dissolution.The diagenetic solution mediated by organic matter in carbonates may have experienced both bacterial decomposition and thermochemical sulfate reduction,precipitating sulfides within the pores.The plug porosity/permeability analyses generally suggest high porosity in the siliciclastic unit,and carbonates with wackestone fabric while lower values were observed for the inner shelf pure carbonate facies.However,both intervals show very low permeability values probably due to isolated moldic pores and intense micritization.Therefore,clastic intervals may provide an opportunity to serve as a moderate reservoir;however,the carbonate intervals possess very low permeability values and could generally be considered as low-moderate reservoir potential. 展开更多
关键词 Reservoir DIAGENESIS porosity PERMIAN Indus Basin
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Highly mass activity electrocatalysts with ultralow Pt loading on carbon black for hydrogen evolution reaction
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作者 Shaorou Ke Yajing Zhao +6 位作者 Xin Min Yanghong Li Ruiyu Mi Yangai Liu Xiaowen Wu Minghao Fang Zhaohui Huang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期182-190,共9页
Pt-based nanocatalysts offer excellent prospects for various industries.However,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge.In this s... Pt-based nanocatalysts offer excellent prospects for various industries.However,the low loading of Pt with excellent performance for efficient and stable nanocatalysts still presents a considerable challenge.In this study,nanocatalysts with ultralow Pt content,excellent performance,and carbon black as support were prepared through in-situ synthesis.These~2-nm particles uniformly and stably dispersed on carbon black because of the strong s-p-d orbital hybridizations between carbon black and Pt,which suppressed the agglomeration of Pt ions.This unique structure is beneficial for the hydrogen evolution reaction.The catalysts exhibited remarkable catalytic activity for hydrogen evolution reaction,exhibiting a potential of 100 mV at 100 mA·cm^(-2),which is comparable to those of commercial Pt/C catalysts.Mass activity(1.61 A/mg)was four times that of a commercial Pt/C catalyst(0.37 A/mg).The ultralow Pt loading(6.84wt%)paves the way for the development of next-generation electrocatalysts. 展开更多
关键词 hydrogen evolution reaction ultralow platinum in-situ synthesis ULTRASOUND
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Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis
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作者 Jie Wang Wei Wang +4 位作者 Xuheng Chen Junfang Bao Qiuyue Hao Heng Zheng Runsheng Xu 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期58-69,共12页
The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the micro... The utilization of iron coke provides a green pathway for low-carbon ironmaking.To uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was investigated.Furthermore,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric method.The findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and interconnect.This provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron coke.Accelerating the heating rate in non-isothermal gasification can enhance the reactivity of iron coke.The metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon atoms.The kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore structure.Moreover,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%. 展开更多
关键词 low-carbon ironmaking iron coke GASIFICATION structural evolution kinetic model
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Catalyst–Support Interaction in Polyaniline‑Supported Ni_(3)Fe Oxide to Boost Oxygen Evolution Activities for Rechargeable Zn‑Air Batteries
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作者 Xiaohong Zou Qian Lu +8 位作者 Mingcong Tang Jie Wu Kouer Zhang Wenzhi Li Yunxia Hu Xiaomin Xu Xiao Zhang Zongping Shao Liang An 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期176-190,共15页
Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3... Catalyst–support interaction plays a crucial role in improving the catalytic activity of oxygen evolution reaction(OER).Here we modulate the catalyst–support interaction in polyaniline-supported Ni_(3)Fe oxide(Ni_(3)Fe oxide/PANI)with a robust hetero-interface,which significantly improves oxygen evolution activities with an overpotential of 270 mV at 10 mA cm^(-2)and specific activity of 2.08 mA cm_(ECSA)^(-2)at overpotential of 300 mV,3.84-fold that of Ni_(3)Fe oxide.It is revealed that the catalyst–support interaction between Ni_(3)Fe oxide and PANI support enhances the Ni–O covalency via the interfacial Ni–N bond,thus promoting the charge and mass transfer on Ni_(3)Fe oxide.Considering the excellent activity and stability,rechargeable Zn-air batteries with optimum Ni_(3)Fe oxide/PANI are assembled,delivering a low charge voltage of 1.95 V to cycle for 400 h at 10 mA cm^(-2).The regulation of the effect of catalyst–support interaction on catalytic activity provides new possibilities for the future design of highly efficient OER catalysts. 展开更多
关键词 Catalyst-support interaction Supported catalysts HETEROINTERFACE Oxygen evolution reaction Zn-air batteries
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Low‑Temperature Oxidation Induced Phase Evolution with Gradient Magnetic Heterointerfaces for Superior Electromagnetic Wave Absorption
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作者 Zizhuang He Lingzi Shi +6 位作者 Ran Sun Lianfei Ding Mukun He Jiaming Li Hua Guo Tiande Gao Panbo Liu 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期191-204,共14页
Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significan... Gradient magnetic heterointerfaces have injected infinite vitality in optimizing impedance matching,adjusting dielectric/magnetic resonance and promoting electromagnetic(EM)wave absorption,but still exist a significant challenging in regulating local phase evolution.Herein,accordion-shaped Co/Co_(3)O_(4)@N-doped carbon nanosheets(Co/Co_(3)O_(4)@NC)with gradient magnetic heterointerfaces have been fabricated via the cooperative high-temperature carbonization and lowtemperature oxidation process.The results indicate that the surface epitaxial growth of crystal Co_(3)O_(4) domains on local Co nanoparticles realizes the adjustment of magnetic-heteroatomic components,which are beneficial for optimizing impedance matching and interfacial polarization.Moreover,gradient magnetic heterointerfaces simultaneously realize magnetic coupling,and long-range magnetic diffraction.Specifically,the synthesized Co/Co_(3)O_(4)@NC absorbents display the strong electromagnetic wave attenuation capability of−53.5 dB at a thickness of 3.0 mm with an effective absorption bandwidth of 5.36 GHz,both are superior to those of single magnetic domains embedded in carbon matrix.This design concept provides us an inspiration in optimizing interfacial polarization,regulating magnetic coupling and promoting electromagnetic wave absorption. 展开更多
关键词 Magnetic heterointerfaces Phase evolution Interfacial polarization Magnetic coupling Electromagnetic wave absorption
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Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization
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作者 Xing Wang Wei Pi +3 位作者 Sheng Hu Haifeng Bao Na Yao Wei Luo 《Nano-Micro Letters》 SCIE EI CAS 2025年第1期281-292,共12页
Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal int... Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts.By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in AEMWEs.Herein,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this work.Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER performance.More critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h. 展开更多
关键词 NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer
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Sandstone Diagenesis and Porosity Evolution of Paleogene in Huimin Depression 被引量:10
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作者 朱筱敏 钟大康 +1 位作者 张琴 张莉 《Petroleum Science》 SCIE CAS CSCD 2004年第3期23-29,共7页
The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, ... The sandstones of the paleogene in the Huimin Depression have undergone numerous diagenetic processes, such as compaction, cementation, dissolution, metasomasis and recrystallization. The first three — compaction, cementation and dissolution — affect reservoir properties most intensively. An average porosity loss due to compaction is 0.78% per 100 meters, slightly higher in the central and southern parts and lower in the northern. Cementation has resulted in the porosity loss from 8% to 20% at a depth below 1,500 meters. Dissolution, which in most cases is the dissolution of feldspar and of carbonate cement, primarily occurs in two depth intervals, from 1,400 to 2,500 meters and 2,700 to 4,000 meters respectively. New porosity is created through dissolution from 4% to 14%. The sandstones experienced stage A and stage B of early diagenesis and stage A of late diagenesis. At present, most of them are experiencing Phase A2 of late diagenesis. The types of pores in the sand reservoir can be grouped into primary and secondary ones. 展开更多
关键词 DIAGENESIS porosity evolution secondary porosity Huimin Depression
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Diagenesis of the Triassic Yanchang Formation Tight Sandstone Reservoir in the Xifeng–Ansai Area of Ordos Basin and its Porosity Evolution 被引量:11
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作者 LIU Mingjie LIU Zhen +1 位作者 WANG Peng PAN Gaofeng 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2016年第3期956-970,共15页
This work aims to reveal the evolution of the porosity in the Triassic Yanchang Formation tight sandstone reservoir of the Xifeng-Ansai area of Ordos Basin. Based on destructive diagenesis (compaction and cementation... This work aims to reveal the evolution of the porosity in the Triassic Yanchang Formation tight sandstone reservoir of the Xifeng-Ansai area of Ordos Basin. Based on destructive diagenesis (compaction and cementation) and constructive diagenesis (dissolution) of sandstone reservoirs, this study analyzed the diagenesis characteristics of the tight sandstone reservoirs in this area, and discussed the relationship between sandstone diagenesis and porosity evolution in combination with present porosity profile characteristics of sandstone reservoir. The effect simulation principle was employed for the mathematical derivation and simulation of the evolution of porosity in the Yanchang Formation tight sandstone reservoirs. The result shows that compaction always occurs in tight sandstone reservoirs in the Yanchang Formation, and cementation occurs when the burial depth increases to a certain value and remains ever since. Dissolution occurs only at a certain stage of the evolution with window features. In the corresponding present porosity profile, diagenesis is characterized by segmentation. From the shallow to the deep, compaction, compaction, cementation and dissolution, compaction and cementation occur successively. Therefore, the evolution of sandstone porosity can be divided into normal compaction section, acidification and incremental porosity section, and normal compaction section after dissolution. The results show that the evolution of sandstone porosity can be decomposed into porosity reduction model and porosity increase model. The superposition of the two models at the same depth in the three stages or in the same geological time can constitute the evolution simulation of the total porosity in sandstone reservoirs. By simulating the evolution of sandstone reservoir porosity of the eighth member in Xifeng area and the sixth member in Ansai area, it shows that they are similar in the evolution process and trend. The difference is caused by the regional uplift or subsidence and burial depth. 展开更多
关键词 tight sandstone DIAGENESIS porosity evolution effect simulation Yanchang Formation Ordos Basin
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Quantification and timing of porosity evolution in tight sand gas reservoirs:an example from the Middle Jurassic Shaximiao Formation,western Sichuan,China 被引量:15
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作者 Zheng-Xiang Lü Su-Juan Ye +2 位作者 Xiang Yang Rong Li Yuan-Hua Qing 《Petroleum Science》 SCIE CAS CSCD 2015年第2期207-217,共11页
The diagenesis and porosity evolution of the Middle Jurassic Shaximiao sandstones were analyzed based on petrographic observations, X-ray diffractometry, scanning electron microscopy observations, carbon and oxygen st... The diagenesis and porosity evolution of the Middle Jurassic Shaximiao sandstones were analyzed based on petrographic observations, X-ray diffractometry, scanning electron microscopy observations, carbon and oxygen stable isotope geochemistry, fluid inclusion mi- crothermometry, and thermal and burial history modeling results. The point count data show that secondary pores (av. 5.5 %) are more abundant than primary pores (av. 3.7 %) and are thus the dominant pore type in the Shaximiao sandstones. Analysis of porosity evolution indicates that alteration of sandstones mainly occurred during two paragenetic stages. Mechanical compaction and cementa- tion by early chlorite, calcite, and quartz typically decrease the depositional porosity (40.9 %) by an average of 37.2 %, leaving porosity of 3.7 % after stage I (〈85 ℃, 175-145 Ma). The original intergranular porosity loss due to compaction is calculated to be 29.3 %, suggesting that mechanical compaction is the most significant diagenetic process in primary porosity destruction. Stage II can be further divided into two sub-stages (Stage IIa and Stage IIb). Stage IIa (85-120 ℃, 145-125 Ma) is characterized by late dissolution, which enhanced porosity by 8.8 %, and the porosity increased from 3.7 % to 12.5 %. During stage IIb (〉120 ℃, 125-0 Ma), the precipitation of late chlorite, calcite, quartz, and kaolinite destroyed 3.3 % porosity, leaving porosity of 9.2 % in the rock today. 展开更多
关键词 DIAGENESIS porosity evolution -Tight gas sandstones JURASSIC Western Sichuan
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Porosity model and pore evolution of transitional shales:an example from the Southern North China Basin 被引量:5
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作者 Xiao-Guang Yang Shao-Bin Guo 《Petroleum Science》 SCIE CAS CSCD 2020年第6期1512-1526,共15页
The evolution of shale reservoirs is mainly related to two functions:mechanical compaction controlled by ground stress and chemical compaction controlled by thermal effect.Thermal simulation experiments were conducted... The evolution of shale reservoirs is mainly related to two functions:mechanical compaction controlled by ground stress and chemical compaction controlled by thermal effect.Thermal simulation experiments were conducted to simulate the chemical compaction of marine-continental transitional shale,and X-ray diffraction(XRD),CO2 adsorption,N2 adsorption and high-pressure mercury injection(MIP)were then used to characterize shale diagenesis and porosity.Moreover,simulations of mechanical compaction adhering to mathematical models were performed,and a shale compaction model was proposed considering clay content and kaolinite proportions.The advantage of this model is that the change in shale compressibility,which is caused by the transformation of clay minerals during thermal evolution,may be considered.The combination of the thermal simulation and compaction model may depict the interactions between chemical and mechanical compaction.Such interactions may then express the pore evolution of shale in actual conditions of formation.Accordingly,the obtained results demonstrated that shales having low kaolinite possess higher porosity at the same burial depth and clay mineral content,proving that other clay minerals such as illite-smectite mixed layers(I/S)and illite are conducive to the development of pores.Shales possessing a high clay mineral content have a higher porosity in shallow layers(<3500 m)and a lower porosity in deep layers(>3500 m).Both the amount and location of the increase in porosity differ at different geothermal gradients.High geothermal gradients favor the preservation of high porosity in shale at an appropriate Ro.The pore evolution of the marine-continental transitional shale is divided into five stages.Stage 2 possesses an Ro of 1.0%-1.6%and has high porosity along with a high specific surface area.Stage 3 has an Ro of 1.6%-2.0%and contains a higher porosity with a low specific surface area.Finally,Stage 4 has an Ro of 2.0%-2.9%with a low porosity and high specific surface area. 展开更多
关键词 Thermal simulation porosity model Pore evolution Transitional shale Southern North China Basin Shanxi formation
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Porosity Formation and Evolution of the Deeply Buried Lower Triassic Feixianguan Formation, Puguang Gas Field, NE Sichuan Basin, China 被引量:3
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作者 Xuefeng Zhang Tonglou Guo +2 位作者 Bo Liu Xiaoyue Fu Shuanglin Wu 《Open Journal of Geology》 2013年第4期300-312,共13页
The deeply buried shoal dolomite reservoirs of the Lower Triassic Feixianguan Formation, giant Puguang Gas Field, NE Sichuan Basin, are exceptionally porous. The influences of diageneses on pore evolution are studied.... The deeply buried shoal dolomite reservoirs of the Lower Triassic Feixianguan Formation, giant Puguang Gas Field, NE Sichuan Basin, are exceptionally porous. The influences of diageneses on pore evolution are studied. Through petrologic investigation, diagenetic phases are divided into four stages, i.e., near-surface, pre-oil window, oil window, and gas window. The Adobe Photoshop system is used to quantify the rock texture components, porosity constitutions and the influences of diageneses on reservoir porosity. Porosity evolution curves are quantitatively recovered. The Feixianguan reservoir porosities are mainly created by early meteoric dissolution, dolomitization, and organic acids dissolution. Dissolution during deep burial is insignificant. Pores are formed in near-surface and pre-oil window stages and effectively preserved till present. This result may be of great significance to the further exploration of deeply buried carbonate reservoirs not only in NE Sichuan Basin, but also around the world. 展开更多
关键词 porosity evolution DIAGENESIS Lower TRIASSIC Feixianguan Formation Puguang Gas Field SICHUAN Basin
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Laser ablation in situ U-Pb dating and its application to diagenesis-porosity evolution of carbonate reservoirs 被引量:8
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作者 SHEN Anjiang HU Anping +4 位作者 CHENG Ting LIANG Feng PAN Wenqing FENG Yuexing ZHAO Jianxin 《Petroleum Exploration and Development》 2019年第6期1127-1140,共14页
Through the development and calibration of a reference material which is 209.8 Ma old using a newly-developed Laser Ablation(LA)Multi-Collector Inductively Coupled Plasma Mass Spectrometry(MC-ICP-MS)technique,we succe... Through the development and calibration of a reference material which is 209.8 Ma old using a newly-developed Laser Ablation(LA)Multi-Collector Inductively Coupled Plasma Mass Spectrometry(MC-ICP-MS)technique,we successfully overcome the difficulty in sampling and dating ultra-low U-Pb ancient marine carbonates,which was previously untenable by isotope dilution(ID)methods.We developed the LA-MC-ICP-MS in situ U-Pb dating technique for ancient marine carbonates for the study of diagenesis-porosity evolution history in Sinian Dengying Formation,Sichuan Basin.By systematically dating of dolomitic cements from vugs,matrix pores and fractures,we found that the burial and diagenetic process of dolomite reservoirs in Sinian Dengying Formation was characterized by progressive filling-up of primary pores and epigenic dissolution vugs.The filling of vugs happened in three stages,early Caledonian,late Hercynian-Indosinian and Yanshanian-Himalayan,while the filling of matrix pores mainly took place in early Caledonian.The unfilled residual vugs,pores and fractures constitute the main reservoir sapce.Based on the above knowledge,we established the diagenesis-porosity evolution history of the dolomite reservoir in Sinian Dengying Formation,Sichuan Basin.These findings are highly consistent with the tectonic-burial and basin thermal histories of the study area.Our study confirmed the reliability of this in situ U-Pb dating technique,which provides an effective way for the investigation of diagenesis-porosity evolution history and evaluation of porosity in ancient marine carbonate reservoirs before hydrocarbon migration. 展开更多
关键词 laser ablation in-situ U-PB DATING SICHUAN Basin SINIAN Dengying Formation diagenesis-porosity evolution CARBONATES
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Numerical Simulation of Microporosity Evolution of Aluminum Alloy Castings 被引量:2
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作者 Shuyong DONG, Shoumei XIONG and Baicheng LIUDepartment of Mechanical Engineering, Tsinghua University, Beijing 100084, China 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2004年第1期23-26,共4页
A mathematical model to calculate the size and distribution of microporosities was studied and coupled with a stochastic microstructure evolution model. The model incorporates various solidification phenomena such as ... A mathematical model to calculate the size and distribution of microporosities was studied and coupled with a stochastic microstructure evolution model. The model incorporates various solidification phenomena such as grain structure evolution, solidification shrinkage, interdendritic fluid flow and formation and growth of pores during solidification processes. The nucleation and growth of grains were modeled with a cellular automaton method that utilizes the results from a macro scale modeling of the solidification process. Experiments were made to validate the proposed models. The calculated results of aluminum alloy castings agreed with the experimental measurements. 展开更多
关键词 Numerical simulation Microporosity evolution Aluminum alloy castings
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Meso-damage evolution and mechanical characteristics of low-porosity sedimentary rocks under uniaxial compression 被引量:7
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作者 Jian-hua HU Dong-jie YANG 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2020年第4期1071-1077,共7页
Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and a... Low pore sedimentary rocks(from Guangxi, China) were subjected to uniaxial compression loading experiment under different initial stresses. The rock samples were investigated by nuclear magnetic resonance before and after the loading. The relationships between the mesoscopic rock damage and macroscopic mechanical parameters were established, and the initial damage stress of the low-porosity sedimentary rock was determined. The results showed that this type of rock has the initial stress of damage. When the initial loading stress is lower than the initial stress of damage, the T2 spectrum area of the rock sample gradually decreases, and the primary pores of the rock are further closed under the stress. The range of the initial stress of damage for this type of rock is 8-16 MPa. When the loading stress exceeds the initial stress of damage, the T2 spectrum area gradually increases, indicating that the porosity of the rock increases and microscopic damage of the rock appears. The rock damage degree is defined, and the nonlinear function between the rock damage degree and the initial loading stress is established. 展开更多
关键词 uniaxial compressive strength porosity T2 spectrum area rock damage degree
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Effects of axial static stress on stress wave propagation in rock considering porosity compaction and damage evolution 被引量:7
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作者 JIN Jie-fang YUAN Wei +1 位作者 WU Yue GUO Zhong-qun 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第2期592-607,共16页
A wave equation of rock under axial static stress is established using the equivalent medium method by modifying the Kelvin-Voigt model.The analytical formulas of longitudinal velocity,space and time attenuation coeff... A wave equation of rock under axial static stress is established using the equivalent medium method by modifying the Kelvin-Voigt model.The analytical formulas of longitudinal velocity,space and time attenuation coefficients and response frequency are obtained by solving the equation using the harmonic method.A series of experiments on stress wave propagation through rock under different axial static stresses have been conducted.The proposed models of stress wave propagation are then verified by comparing experimental results with theoretical solutions.Based on the verified theoretical models,the influences of axial static stress on longitudinal velocity,space and time attenuation coefficients and response frequency are investigated by detailed parametric studies.The results show that the proposed theoretical models can be used to effectively investigate the effects of axial static stress on the stress wave propagation in rock.The axial static stress influences stress wave propagation characteristics of porous rock by varying the level of rock porosity and damage.Moreover,the initial porosity,initial elastic modulus of the rock voids and skeleton,viscous coefficient and vibration frequency have significant effects on the P-wave velocity,attenuation characteristics and response frequency of the stress wave in porous rock under axial static stress. 展开更多
关键词 stress wave propagation axial static stress porosity compaction space and time attenuation response frequency
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Diagenesis and porosity evolution of sandstone reservoirs in the East II part of Sulige gas field, Ordos Basin 被引量:21
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作者 Yang Renchao Fan Aiping Han Zuozhen Wang Xiuping 《International Journal of Mining Science and Technology》 SCIE EI 2012年第3期311-316,共6页
It is becoming an important controlling factor of gas exploration and exploitation in the east part of Sulige gas field in the Ordos Basin where the reservoir of main gas formations is tight sandstones. Employing expe... It is becoming an important controlling factor of gas exploration and exploitation in the east part of Sulige gas field in the Ordos Basin where the reservoir of main gas formations is tight sandstones. Employing experimental methods of slice identification, casting slice, scan electron microscope, and X-ray diffrac- tions, we studied the characteristics of petrology and diagenesis on reservoirs in Shanl section of Shanxi formation and He8 section of Shihezi formation of the Permian system in the East II part of Sulige gas field. The results include: (1) the main sandstones in these areas are dominated by lithic sandstone and litbic silicarenite with low grade of maturity; (2) the diagenesis of sandstone in these areas mainly include compaction, cementation, corrosion and alteration. Conclusions are as follows: (1) the diagenetic stage reached period B of the middle diagenetic stage; (2) the early diagenetic compaction is one of the main factors to decreasing porosity; (3) the secondary pores formed by corrosion in acidity medium con- ditions in period A of the middle diagenetic stage can distinctly ameliorate the poor reservoir capability of sandstone and, (4) cementation in period B of the middle diagenetic stage is the most important factor leading; to poor physical property of sandstone reservoirs. 展开更多
关键词 Ordos BasinPermianSandstone reservoirsDiagenesisporosity evolution
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Evolution of pore fluid of low porosity and permeability reservoir in Qinnan Sag:a case study of 29-2 structurein Qinhuangdao area 被引量:1
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作者 XU Simeng PENG Xiaolei +4 位作者 LIU Na LIU Li WANG Qingbin LIU Xiaojian JIN Xiaoyan 《Global Geology》 2017年第2期80-88,共9页
The southeast depression of Qinnan Sag is a potential oil-gas exploration region in the Bohai Sea area. With the analysis of large quantity of rock thin sections,scanning electron microscope and the physical property ... The southeast depression of Qinnan Sag is a potential oil-gas exploration region in the Bohai Sea area. With the analysis of large quantity of rock thin sections,scanning electron microscope and the physical property data of reservoir,the authors studied the petrological characteristics and the evolution of pore and fluid of sandstone in the deeper strata in 29-2 structure in Qinhuangdao area. The results show that the evolutionary tendency of Paleogene sandstone reservoir porous fluid in research area is changed from alkaline porous fluid to acidic porous fluid,and back to alkaline porous fluid. There are three stages of reservoir porous evolution in Qinhuangdao area,namely sharp decrease in porosity due to mechanical compaction,increase in porosity because of corrosion and dissolution,and remarkable reduction owing to carbonate cementation. 展开更多
关键词 Qinnan Sag Paleogene reservoir petrological characteristics evolution pore fluid
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Evolution of Authigenic Minerals and Porosity in the Deep Formation of Paleogene of Jiyang Sub-basin
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作者 Jing Yuan College of Geoscience and Information,China University of Petroleum,Qingdao 266555,China. 《地学前缘》 EI CAS CSCD 北大核心 2009年第S1期142-143,共2页
The clastic rocks in the depth of 2800-6000 m of the Paleogene in Jiyang sub-basin had undergone the middle diagenesis and late diagenesis.The reservoirs in main areas of the sub-basin developed 2-6 secondary pores zo... The clastic rocks in the depth of 2800-6000 m of the Paleogene in Jiyang sub-basin had undergone the middle diagenesis and late diagenesis.The reservoirs in main areas of the sub-basin developed 2-6 secondary pores zones.The reservoirs in the stage A of middle diagenesis of Bonan fault zone in Zhanhua depression and of the gentle slope belt of Chezhen depression are controlled by the acidic diagenetic medium and developed one secondary pores zone in each diagenetic sub-stage respectively.The contents ofautogenic quartz,pyrite and kaolinite are quite high in these reservoirs.The reservoirs’ 展开更多
关键词 AUTHIGENIC minerals secondary pores porosity evolution DIAGENETIC medium DEEP formation Jiyang sub-basin
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Episodic dolomitization of Paleozoic limestones in the Kinta Valley,Malaysia:Implications on porosity evolution and reservoir properties
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作者 Poon Xin Hui Mu.Ramkumar +2 位作者 R.Nagarajan Manoj J.Mathew T.F.Ng 《Energy Geoscience》 2021年第4期298-307,共10页
Carbonates undergo a variety of physical,mineralogical,chemical changes during depositional and postdepositional stages that are of interest to exploration geologists and sedimentologists.World over,about 60%of hydroc... Carbonates undergo a variety of physical,mineralogical,chemical changes during depositional and postdepositional stages that are of interest to exploration geologists and sedimentologists.World over,about 60%of hydrocarbon reserves occur in carbonates with the dominant proportion associated with dolomitic reservoirs,in particular fault-associated dolomites which appear to be proven hydrocarbon reservoirs.Dolomitization as the critical diagenetic process thus plays an important role in determining reservoir characteristics and in designing exploration strategies.The buried Paleozoic dolomites exhibit relatively higher porosity than their counterparts,Paleozoic limestones.Fault-associated dolomites are usually targets of hydrocarbon exploration due to their good reservoir quality.High heterogeneity in carbonate reservoirs due to varied porosity types and distribution makes reservoir characterization a daunting task.However,the key elements that control porosity development and evolution in these dolomites remain debatable.Studying the influence of multiphase dolomitization,associated diagenetic events,hydrothermal alteration and their causative thermo-tectonic events on porosity evolution and reservoir quality is essential to understanding the critical processes and controlling factors that result in diverse impacts on reservoir quality.In this paper,an attempt is made to characterize dolomitization in homogeneous carbonate mud and its relationship with porosity evolution and reservoir property.In the field,six facies types excluding host limestone are recognized,which are in turn characterized into seven petrographically recognizable phases,namely the host limestone,early replacement dolomite,sucrosic dolomite,metamorphosed dolomite,late replacement dolomite,brecciated limestone and dolomite and late stage calcite.Mineralogical analyses reveal the dominance of stoichiometric dolomites,followed by calcareous dolomites and magnesium calcites.Among all the field-based facies and petrographic phases,the sucrosic dolomites show appreciable porosity within a range from 4%to 8%,whereas the other phases show either nil or insignificant porosity under megascopic and petrographic observations.Our study confirms that in the process of dolomitization that substantially modifies porosity,dolomitic crystal morphologies play a significant role in enhancing or reducing the porosity. 展开更多
关键词 DOLOMITIZATION porosity evolution PALEOZOIC Kinta Valley MALAYSIA
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Diagenesis-porosity evolution and“sweet spot”distribution of low permeability reservoirs:A case study from Oligocene Zhuhai Formation in Wenchang A sag,Pear River Mouth Basin,northern South China Sea 被引量:1
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作者 YOU Li XU Shouli +3 位作者 LI Cai ZHANG Yingzhao ZHAO Zhanjie ZHU Peiyuan 《Petroleum Exploration and Development》 2018年第2期251-263,共13页
The characteristics of low permeability reservoirs and distribution of sweet spots in the Oligocene Zhuhai Formation of Wenchang A sag, Pearl River Basin were investigated by core observation and thin section analysis... The characteristics of low permeability reservoirs and distribution of sweet spots in the Oligocene Zhuhai Formation of Wenchang A sag, Pearl River Basin were investigated by core observation and thin section analysis. The study results show that there develop the fine, medium and coarse sandstone reservoirs of tidal flat–fan delta facies, which are of mostly low permeability and locally medium permeability. There are two kinds of pore evolution patterns: oil charging first and densification later, the reservoirs featuring this pattern are mainly in the third member of Zhuhai Formation between the south fault zone and the sixth fault zone, and the pattern of densification first and gas charging later is widespread across the study area. Strong compaction and local calcium cementation are the key factors causing low permeability of the reservoirs in the Zhuhai Formation. Thick and coarse grain sand sedimentary body is the precondition to form "sweet spot" reservoirs. Weak compaction and cementation, dissolution, early hydrocarbon filling and authigenic chlorite coating are the main factors controlling formation of "sweet spot" reservoir. It is predicted that there develop between the south fault and sixth fault zones the Class Ⅰ "sweet spot" in medium compaction zone, Class Ⅱ "sweet spot" in nearly strong compaction zone, Class Ⅲ "sweet spot" reservoir in the nearly strong to strong compaction zone with oil charging at early stage, and Class IV "sweet spot" reservoir in the strong compaction and authigenic chlorite coating protection zone in the sixth fault zone. 展开更多
关键词 low permeability reservoir pore evolution hydrocarbon charging 'sweet spot' DISTRIBUTION Zhuhai Formation OLIGOCENE Wenchang A SAG northern South China Sea
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