Effect of Pouring Temperature by a Novel Micro Fused-Casting on Microstructure and Properties of ZL101 Semisolid Slurry

A novel micro fused-casting(MFC)process is developed for semisolid aluminum alloy slurry.The microstructure evolution and properties of semisolid ZL101 aluminum alloy slurry with difierent pouring temperature by MFC are investigated in this paper.During the cooling process,the effects of the pouring temperature on microstructure and properties is primarily analyzed.The microstructure of the semisolid ZL101 aluminum alloy is more homogeneous and the grain is smaller under proper pouring temperature.Temperature of liquids and solids of ZL101 aluminum alloy is measured by difierential scanning calorimetry(DSC).Distribution and characteristics of the microstructure of samples are examined by optical microscope(OM),scanning electron microscopy(SEM)equipped with energy dispersive spectrometer(EDS).The results show that the ZL101 semisolid slurry fabricated by MFC presents uniform shape and good grain size under the pouring temperature of 594°C and the stirring velocity of 600 r/min,and the fine grains of the primary a-Al phase with average grain size of 55μm and shape factor up to 0.67 were obtained.Besides,the ultimate tensile strength and the average Vickers hardness for semisolid ZL101 aluminum slurry are 178.19±1.37 MPa and 86.15±1.16 HV,respectively.

Effect of nanocomposite pour point depressant EVAL/CNT on flow properties of waxy crude oil

The nanocomposite EVAL-CNT was produced by chemical grafting in the solution system through the esterification of ethylene-vinyl alcohol copolymer (EVAL) and carboxylated multi-walled carbon nanotubes (O-MWCNT), and its structural properties were characterized. The improvement of the rheological properties of the waxy oil system by the novel pour point depressant was investigated using macroscopic rheological measurements and microscopic observations. The results showed that EVAL-CNT nanocomposite pour point depressant (PPD) could significantly reduce the pour point and improve the low temperature fluidity of crude oil and had better performance than EVAL-GO at the same addition level. The best effect was achieved at the dosing concentration of 400 ppm, which reduced the pour point by 13 ℃ and the low-temperature viscosity by 85.4%. The nanocomposites dispersed in the oil phase influenced the precipitation and crystallization of wax molecules through heterogeneous crystallization templates, which led to the increase of wax crystal size and compact structure and changed the wax crystal morphology, which had a better effect on the rheological properties of waxy oil.

Pour和“倒”的词汇语义及其运动事件表达

英汉语位移动词pour和"倒"融合了位移、使因和容器概念。基于语料统计发现:(1)英汉语致使移动句是基本运动事件表达句,英汉语双宾句、英语pour full句、汉语"倒满"句体现了副事件融合的扩展模式。(2)英汉语的终点路径均呈优势分布。(3)位移终点INTO在英语双宾句缺省表达,而汉语使用"给"表达位移目标TO和位移终点INTO;汉语双宾结构中,"给X"在动词前呈优势分布。(4)英语用full表达"内部充满"的结果语义,而汉语用"满"编码"表面布满"和"内部充满"的概念语义;在表达"内部充满"的结果路径语义时,英汉语主体-背景均逆序表达。

Research on semi-solid slurry of a hypoeutectic Al-Si alloy prepared by low superheat pouring and weak electromagnetic stirring

The semi-solid slurry of a hypoeutectic Al-Si alloy was manufactured by low superheat pouring and weak electromagnetic stirring. The effects of pouting temperature and stirring power on the semi-solid slurry were investigated. The results indicated that the semi-solid slurry to satisfy rheocasting can be manufactured by low superheat pouring and weak electromagnetic stirring. The pouring temperature （or superheat） and the stirring power remarkably affected the morphology of primary α-Al and the size of primary α-Al, and there is no obvious effect of stirring time on primary α-Al. Compared with the samples made by low superheat pouring with no stirring, the nucleation rate, particle morphology and grain size of primary α-Al in A356 were markedly improved by low superheat pouring and weak electromagnetic stirring. On the condition of weak electromagnetic stirring, the pouring temperature with low superheat can be suitably raised to reach the effectiveness obtained from the lower pouring temperature without stirring.

Manufacture technique of semi-solid slurry of hypoeutectic Al-Si alloy by low superheat pouring and weak electromagnetic stirring

The semi-solid slurry of hypoeutectic Al-Si alloy was manufactured by low superheat pouring and weak electromagnetic stirring. The effects of pouring temperature and stirring power on the semi-solid slurry making process were investigated. The results indicate that the semi-solid slurry to satisfy rheocasting requirement can be made by a combination of low superheat pouring and weak electromagnetic stirring. The pouring temperature (or superheat) and the stirring power significantly affect the morphology and the size of primary α-Al, while there is no obvious effect of the stirring time on primary α-Al. Compared with the samples made by low superheat pouring without stirring, the nucleation rate, particle morphology and grain size of primary α-Al in A356 Al alloy are markedly improved by a process of applying both low superheat pouring and weak electromagnetic stirring. Under the condition of weak electromagnetic stirring applied, the pouring temperature with low superheat can be equivalently to reach the effectiveness obtained from the even lower pouring temperature without stirring.

EFFECT OF GRAIN REFINING ON PRIMARYαPHASE IN SEMI-SOLID A356 ALLOY PREPARED BY LOW SUPERHEAT POURING AND SLIGHT ELECTROMAGNETIC STIRRING

The semi-solid slurry of A356 alloy, which is grain-refined by Al-Ti-B master alloy, is prepared by low superheat pouring and slight electromagnetic stirring. The effects of grain refining on the morphology and the grain size of the primary α phase in the slurry manufactured are researched. The results indicate that the slurry with particle-like and rosette-like primary α phases can be prepared by low superheat pouring and slight electromagnetic stirring from liquid A356 alloy grain-refined, in which the pouring temperature can be suitably raised. Compared with the A356 samples without grain refining, the grain size and particle morphology of primary α phase as well as the distribution of the grain with particle-like or rosette-like along radial in the ingot in A356 are markedly improved by grain refining.

Rheological Properties of Waxy Crude at a Low Temperature in the Presence of Pour Point Depressants

Pour point depressants （PPD） are used to improve the theology of waxy crude. The affect of various factors on the theological properties, and the thermal characteristics of waxy crude treated by PPD have been investigated. The conclusions are as follows： PPD can reduce the pour point and abnormal point of waxy crude, broaden the temperature range of Newtonian fluid of waxy crude, and lower greatly the viscosity of non-Newtonian fluid of waxy crude. The influence of reheating and high-rate shear on the effect of PPD mainly depends on their temperature. When the reheating temperature is more than the abnormal point of crude by 10℃, the reheating process has little effect on the modification effect of PPD. However, when the reheating temperature is below the abnormal point of crude, the reheating process will reduce the modification effect of PPD. When temperature is above the abnormal point of crude, the high-rate shear has little effect on the modification effect of PPD. At a temperature range where a lot of wax is precipitating, high-rate shear will greatly reduce the modification effect of PPD.

Synthesis of new EVA graft copolymer and its pour point depressant performance evaluation for Daqing crude oil

EVA was widely used as the pour point depressant for waxy oil.In order to improve its effect,some graft copolymerization methods should be used to modify EVA's property.EVA has long side chains and nitrogen polar groups to enforce its adaptability and effect of waxy oil.The pure amine,maleicanhydride and their reaction product were tested using infrared spectra and the NMR spectral.The results show that when the modified EVA is added into oil,the wax deposits not only on the main chain but also on the side chains.And the polar groups have the function to avoid and resist the wax crystals connection each other to form the net.Using the reaction product of maleicanhydride and high carbonic amine(C12,C16,C18 amine) as the graft component,the toluene as the solvent and BPO as the initiator,the series of new EVA graft copolymer with special side chains are prepared under controlled condition.A series of cylmaleimide exist indeed in modified EVA and the highest grafted percentage is 18.8%.EVA-16,the new graft copolymer,is better than EVA about 3 ℃ more in depressant the pour-point of Daqing waxy crude oil.

Numerical simulation on multiple pouring process for a 292 t steel ingot

A ladle-tundish-mould transportation model considering the entire multiple pouring(MP) process is proposed. Numerical simulation is carried out to study the carbon distribution and variation in both the tundish and the mould for making a 292 t steel ingot. Firstly, the fluid flow as well as the heat and mass transfer of the molten steel in the tundish is simulated based on the multiphase transient turbulence model. Then, the carbon mixing in the mould is calculated by using the species concentration at the tundish outlet as the inlet condition during the teeming process. The results show a high concentration of carbon at the bottom and a low concentration of carbon at the top of the mould after a MP process with carbon content high in the first ladle and low in the last ladle. Such carbon concentration distribution would help reduce the negative segregation at the bottom and the positive segregation at the top of the solidified ingot.

Effect of Pouring Temperature on Microstructure and Properties of A356 Alloy Strip by a Novel Semisolid Micro Fused-Casting for Metal

A novel semisolid micro fused-casting(MFC) for preparing A356 alloy strips is proposed, and the effects of process parameters of pouring temperature on the microstructure and properties of A356 alloy strips are investigated. MFC means that the semisolid metal slurry was pressed out from the outlet of bottom of crucible to the movable plate, and directly solidified and formed layer by layer. The microstructure and properties of A356 semisolid alloy slurry were influenced by the cooling conditions. Results show that the aluminu alloy A356 strip samples fabricated by micro fused-casting had good performances and uniform structures with the pouring temperature at 595 ℃ and the substrate movement speed at 18 mm/s. The fine grains of the primary a-Al phase with average grain size of 53 μm and shape factor up to 0.72 was obtained, the ultimate tensile strength of the aluminum alloy A356 strip reaches 243.79±3.91 MPa, while the average vickers hardness is 82.65±1.86 HV.

Refinement of primary Si grains in Al–20%Si alloy slurry through serpentine channel pouring process

In this study, a serpentine channel pouring process was used to prepare the semi-solid A1-20%Si alloy slurry and refine primary Si grains in the alloy. The effects of the pouring temperature, number of curves in the serpentine channel, and material of the serpentine channel on the size of primary Si grains in the semi-solid A1-20%Si alloy slurry were investigated. The results showed that the pouting temperature, number of the curves, and material of the channel strongly affected the size and distribution of the primary Si grains. The pouring tempera- ture exerted the strongest effect, followed by the number of the curves and then the material of the channel. Under experimental conditions of a four-curve copper channel and a pouring temperature of 701℃, primary Si grains in the semi-solid A1-20%Si alloy slurry were refined to the greatest extent, and the lath-like grains were changed into granular grains. Moreover, the equivalent grain diameter and the average shape coefficient of primary Si grains in the satisfactory semi-solid A1-20%Si alloy slurry were 24.4 μm and 0.89, respectively. Finally, the re- finement mechanism and distribution rule of primary Si grains in the slurry prepared through the serpentine channel pouring process were analyzed and discussed.

Refinement of primary Si grains of A390 alloy slurry through serpentine channel pouring process

In this paper, the serpentine channel pouring process for preparing a semi-solid A390 alloy slurry and refining the primary Si grains of the A390 alloy, was used. The effects of the pouring temperature, the cooling water flow and the number of the curves on the size of the primary Si grains in the semi-solid A390 alloy slurry were investigated. The results show that the pouring temperature, the cooling water flow and the number of the curves have a major effect on the size and the distribution of primary Si grains. Under the experimental condition of the four-curve copper channel whose cooling water flow was 500 L·h-1 and the pouring temperature was 690 oC, the primary Si grains of the semi-solid A390 alloy slurry were refined to the greatest extent and the lath-like grains were changed into granular ones. Additionally, the equivalent grain diameter and the average shape factor of the primary Si grains of the satisfactory semi-solid A390 alloy slurry are 18.6 μm and 0.8, respectively. Further, the refinement mechanism of the primary Si grains through the serpentine channel pouring process was analyzed and discussed. In summary, the primary Si nuclei could be easily precipitated due to the chilling effect of the channel inner wall, thus the primary Si grains were greatly refined. Meanwhile, the subsequent alloy melt fluid also promoted the separation of primary Si grains from the inner wall, further refining the primary Si grains.

Effect of Pouring Process on the Microstructures of Semi-Solid AlSi_7Mg Alloy

The effect of different pouring temperatures and different pouring heights, the distance between the mouth of the pouring ladle and the top of the mold, on the microstructure of AlSi7Mg alloy have been researched in the paper. When the pouring temperature is close to the liquidus temperature, the primary alpha -Al in 'the billets of AlSi7Mg alloy solidified into spherical and nodular fine grains distributed homogeneously. The optimum pouring temperature for semi-solid AlSi7Mg billet with spherical or nodular primary alpha -Al is 615 degreesC. At the same pouring temperature, the higher the pouring ladle, the more easily the spherical and nodular primary alpha -Al obtained in the semi-solid AlSi7Mg billet. When the pouring temperature is close to the liquidus temperature and the pouring ladle is relatively high, it is the great cooling rate, the flow of the molten allay caused by pouring and the large simultaneous solidification region induced by the near liquidus temperature, that promote the formation of spherical or nodular primary cr-Al.

Influence of pouring methods on filling process,microstructure and mechanical properties of AZ91 Mg alloy pipe by horizontal centrifugal casting

Pouring position as the input heat source has great infl uence on the temperature fi eld evolution. In this study, the Flow3 D simulation software was applied to investigate the infl uence of pouring methods(with fi xed or moving pouring channel) on AZ91 Mg alloy horizontal centrifugal casting(HCC) process. The simulation results show that the moving pouring channel method can effectively increase the cooling rate and formability of casting pipe. The casting experiment shows that an AZ91 Mg alloy casting pipe with homogeneous microstructure and clear contour was obtained by the moving pouring channel method, and the grain size of the casting pipe is signifi cantly decreased. Meanwhile, serious macro-segregation appeared in the AZ91 casting pipe by the fi xed pouring channel HCC process. Compared with the fi xed pouring channel, the moving pouring channel can remarkably improve the ultimate tensile strength and elongation of the AZ91 HCC pipe from 142.2 MPa to 201.5 MPa and 6.2% to 6.7%, respectively.

Effect of pouring height on the solidified microstructure of AlSi7Mg alloy

The effect of different pouring heights and evenly soaking process in the liquidus and solidus range on the solidified microstructure of AlSi7Mg alloy has been studied. The results show that if the pouring temperature is 630 or 650℃ and the pouring height is 40 mm, the microstructure of the solidified melt is not homogeneous and there are many rosette-like primary α-Al grains. But if the pouring height is increased to 400 mm, the solidified microstructure becomes more homogeneous and favorable to obtain spherical primary α-Al grains in the solidified melt. With further being evenly soaked in the liquidus and solidus range for some time, the temperature difference between the melt center and the melt periphery can be controlled within ±2℃ and the primary α-Al grains will evolve into more spherical grains. The theoretical analysis indicates that the higher pouring height promotes the melt flow motion and makes the temperature field in the melt more homogeneous and restrains the large rosette primary α-Al grains. This flow motion can also promote the ripening effect and the primary α-Al grains in the melt are gradually changed into spherical grains. It can be concluded from the experiments that pouring at an appropriate superheat and from a proper height is a good new method for preparing the semisolid slurry of AlSi7Mg alloy, its process control is easy and the preparation cost is lower.

Microstructural characteristics of in situ Mg_2Si/Al-Si composite by low superheat pouring

To control the morphology and size of the primary and eutectic Mg2Si phases in in situ Mg2Si/Al-Si composite and achieve a feasible and reliable technique to produce appropriate feedstock for the thixo-casting and rheo-casting of this type of material,three Al-Si matrix composites reinforced by 5wt.%,9wt.%and 17wt.%Mg2Si with hypoeutectic,eutectic and hypereutectic compositions were prepared by the low superheat pouring(LSP)process.The effects of the pouring temperature(superheat)on the morphology and size distribution of primary phases(primaryα-Al and Mg2Si),binary(α-Al+Mg2Si)eutectic cell and eutectic Mg2Si were investigated.The experimental results show that low pouring temperature(superheat)not only refines the grain structure of the primaryα-Al and binary(α-Al+Mg2Si)eutectic cell in three composites and promotes the formation of more nondendritic structural semi-solid metal(SSM)slurry of these phases;but also refines the primary and eutectic Mg2Si phases,which seems to be attributed to the creation of an ideal condition for the nucleation and the acquisition of a high survival of nuclei caused by the LSP process.

Efficiency of Amphoteric Surfactants as Flow Improvers and Pour Point Depressants

Some amphoteric surfactants (N-Decyl-N-benzyl-N-methylglycine(AB) and N-Dodecyl-N-benzyl-N-methylglycine(CD) were prepared in the laboratory. The physicochemical chemical characteristics were investigated. The adsorption behavior of these surfactants at oil/air interface was investigated by measuring the surface tension and interfacial tension as function of concentration. Surface properties, in particular the critical micelle concentration (CMC), the maximum surface excess (ΓCMC) and the minimum surface area (AMIN) were measured. It is found that the surface and thermodynamic properties of the prepared surfactants depend on their hydrocarbon chain length. Also it is found that there is a good relation between surface properties of the additive and their efficiency in depressing the pour point. The mechanism of the depressants action has been suggested according the adsorption of each additive. Adsorption of the additive on the surface of the wax particles inhibits their growth and alters the crystal habits through micelle core. As the results the surface and thermodynamic parameters confirm the suggested mechanism and the decreasing of pour point. This is resulted in a multilayer, more isotropic wax crystal, and thus only a fixed amount of wax separates at any given temperatures. The results were discussed in terms of adsorption isotherm.

Synthesis of comb bipolymers and their pour point depressing properties

A bipolymer maleic anhydride-methyl acrylate （MAMA） was synthesized from maleic anhydride and methyl acrylate based on molecular design.MAMA further reacted with oleylamine or octadecyl alcohol to generate two comb polymers called Oleamide-MAMA （NMAMA） and OctadecanolMAMA （OMAMA）,respectively.The structure of both the polymers was confirmed by their infrared spectral analysis （IR）,gel permeation chromatography analysis （GPC） and differential scanning calorimeter （DSC）.Moreover,the pour point depressing （PPD） properties of these comb polymers were examined experimentally.Experimental results showed that besides the molecular weight and concentration of the polymers,the length of side chains and the number of functional groups also had great influence on the pour point depressing performance.The π bonds and hydrogen bonds between depressants were the key factors for improving the pour point depressing properties.These results suggest that both OMAMA and NMAMA are potential pour point depressants for industry.

Effect of pouring temperature on thixotropic microstructure formation of AZ91

The effect of pouring temperature on thixotropic microstructure of AZ91 was investigated.The results show that the pouring temperature has a pronounced effect both on microstructural morphology and grain size.By decreasing the pouring temperature,the morphology of grains changes from coarse dendritic to fine dendritic structure.The fine dendritic structure that was obtained at low pouring temperature developed into a globular structure with a grain size of 60 μm,if the AZ91 was partially remelted and held isothermally at the semisolid state(575 ℃).On the other hand,if the alloy was poured at a high superheat,the particles were irregular and interconnected with a grain size of 180 μm even after 20 min of isothermal holding.

Effects of Pouring Temperature on Interfacial Reaction between Ti-47-5Al-2-5V-1Cr Alloy and Mold during Centrifugal Casting

Pouring temperature and time are the most important influencing factors on interfacial reaction during the centrifugal casting. When cast at high temperatures, the crucible becomes brittle and prone to cracking, and shows a low stability. In this paper, we studied the centrifugal casting of Ti-47.5-Al-2.5V-1Cr alloy, and explored the effects of pouring temperature on the interfacial reaction. Castings at 1 600, 1 650, and 1 700 ℃ were obtained by controlling the other parameters constant in the experiments. The microstructure, elemental distribution, thickness of the reaction layer and phase composition of the castings at the interface were studied. The results show that the thickness at the interfacial reaction layer is increased by raising the pouring temperature. The elements in the mold and the matrix were double-diffused and reacted at the interface during the casting process, and formed solid solutions with the precipitation of many new phases such as AlOand TiO. The roughness of interface structure and layer thickness of reaction increase with the rise of temperature, and the interfacial reaction is more intense. There is a minimum layer thickness of the reaction layer that is 80 μm when the temperature is 1 600 ℃.