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铁掺杂PrBa_2Cu_3O_7的化学键性质和Mssbauer谱研究
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作者 高发明 张思远 《分子科学学报》 CAS CSCD 2001年第2期77-81,共5页
利用电介质的平均能带模型计算了PrBa2 Cu3O7的化学键参数 ,得到Cu(1 )—O键的平均共价性为 0 .4 1 ,Cu(2 )—O键的平均共价性为 0 .2 8.应用由共价性和极化率定义的化学环境因子计算了5 7Fe在PrBa2 Cu3O7中的M ssbauer同质异能位移 ,... 利用电介质的平均能带模型计算了PrBa2 Cu3O7的化学键参数 ,得到Cu(1 )—O键的平均共价性为 0 .4 1 ,Cu(2 )—O键的平均共价性为 0 .2 8.应用由共价性和极化率定义的化学环境因子计算了5 7Fe在PrBa2 Cu3O7中的M ssbauer同质异能位移 ,确定了5 7Fe在PrBa2 Cu3O7中的价态和占位情况 . 展开更多
关键词 超导体 prba2cu3o7 化学键 Mossbauer效应 铁掺杂 同质异能位移
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PrBa_2Cu_3O_(7-δ)的制备和电子结构
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作者 王顺喜 何振辉 +4 位作者 张其瑞 赵慧卿 钱逸泰 陈祖耀 季明荣 《物理学报》 SCIE EI CAS CSCD 北大核心 1989年第6期1021-1025,共5页
采用固相反应法制备了正交单相PrBa_2Cu_3O_(7-8)样品.运用标准直流四引线法测量了该样品的电阻,发现它随温度的变化呈半导体行为.通过XPS测量表明,样品中明显合有Pr^(4+).最后从能带结构讨论了PtBa_2Cu_30_(7-8)不超导的原因.
关键词 prba2cu3o7 制备 电子结构
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X-ray diffraction study on YBa_2Cu_3O_7/PrBa_2Cu_3O_7 superlattices with thinner YBCO layers
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作者 李可斌 姚伟国 戚震中 《Chinese Science Bulletin》 SCIE EI CAS 1995年第19期1608-1612,共5页
With the development of the technique of preparing thin film, artificial superlattices of high-T<sub>c</sub>oxides, especially (YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7</sub&... With the development of the technique of preparing thin film, artificial superlattices of high-T<sub>c</sub>oxides, especially (YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7</sub>)<sub>n</sub>/(PrBa<sub>2</sub>Cu<sub>3</sub>O<sub>7</sub>)<sub>m</sub>, have attracted much attention due to the possibilities of studying a variety of superconducting physical properties otherwise inaccessible. One of the many interesting characteristics of this system is the reduction of T<sub>c</sub> with increase of the thickness of the PrBCO layer in superlattices with thin YBCO layer, which has been observed by many groups. Several theoretical models have been proposed to account for this interesting phenomenon, including a spin polaron model, 展开更多
关键词 X-ray DIFFRACTION YBa2cu3o7/prba2cu3o7 super LATTICES stractural characteristics.
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Structure and transport studies on nanometer YBCO/PBCGO multilayers
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作者 CHEN Tar-Pin WU Ke +8 位作者 LI Qi CHEN Ben WANG ShonZeng KANDEL Hom SOO YuChong TIPPARACH Udom CUI JingBiao SEQ HyeWon CHEN ChiJen 《Chinese Science Bulletin》 SCIE EI CAS 2009年第15期2698-2702,共5页
We have fabricated M doped (M = Al, Co, Fe, Ga, Ni and Zn) PrBa2Cu3O7 (PBCO), i.e. PrBa2(Cu1-xMx)3O7. The doping levels x are 0.05, 0.10, 0.15, and 0.20. X-ray data indicated no significant second phase for substituti... We have fabricated M doped (M = Al, Co, Fe, Ga, Ni and Zn) PrBa2Cu3O7 (PBCO), i.e. PrBa2(Cu1-xMx)3O7. The doping levels x are 0.05, 0.10, 0.15, and 0.20. X-ray data indicated no significant second phase for substituting Cu by Al, Co, Fe and Ga up to 20%. However impurity phases were detected for Ni and Zn substituted samples with doping levels equal to and higher than 15%. At 77 K the electrical resistivity of these compounds is orders in magnitude higher than that of PBCO. We also found that although the lattice parameters in the doped samples differ from PBCO, all samples remain orthorhombic. The lattice parameters of the doped sample are very close to those of YBa2Cu3O7-δ (YBCO) and PBCO. For this reason these compounds are better materials to be used as the I-layer for YBCO SIS junctions. Results of structural and transport studies on 2000 thick PrBa2[Cu0.80G0.2]3O7 (PBCGO) and YBCO/PBCGO multilayers are presented in this paper. 展开更多
关键词 纳米结构 多层膜 超导 运输 prba2cu3o7 LATTICE 钇钡铜氧 锌掺杂
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