Gas-Fluid and Fluid-Solid Phase Instability for Restricted Primitive Model

By considering the fluctuation of grand potential f~ around equilibrium with respect to small one-particle density fluctuations δpα（r→）, the phase instability of restricted primitive model （RPM） of ionic systems is investigated. We use the integral equation theory to calculate the direct correlation functions in the reference hypernetted chain approximation and obtain the spinodai line of RPM. Our anaiysis explicitly indicates that the gas-fluid phase instability is induced by k = 0 fluctuation mode, while the fluid-solid phase instability is related to k ≠ 0 fluctuation modes. The spinodai line is qualitatively consistent with the result of computer simulations by others.

Analysis-Prediction Experiments over Indian Region Using Primitive Equation Barotropic Model

The impact of initial guess and grid resolutions on the analysis and prediction has been investigated over the Indian region. For this purpose, an univariate objective analysis scheme and a primitive equation barotropic model have been used. The impact of initial guess and the resolutions on analysis and prediction is discussed.

A Regional Spectral Nested Multilevel Primitive Equation Model

By means of vertical normal modes a regional nested multilevel primitive equation model can be reduced to several sets of shallow water equations characterized by various equivalent depths. Therefore, time integration of the model in spectral form can be performed in the manner similar to those used in the spectral nested shallow water equation model case.

THE FORMULATION OF FIDELITY SCHEMES OF PHYSICAL CONSERVATION LAWS AND IMPROVEMENTS ON A TRADITIONAL SPECTRAL MODEL OF BAROCLINIC PRIMITIVE EQUATIONS FOR NUMERICAL PREDICTION

In this paper,two formulation theorems of time-difference fidelity schemes for general quadratic and cubic physical conservation laws are respectively constructed and proved,with earlier major conserving time-discretized schemes given as special cases.These two theorems can provide new mathematical basis for solving basic formulation problems of more types of conservative time- discrete fidelity schemes,and even for formulating conservative temporal-spatial discrete fidelity schemes by combining existing instantly conserving space-discretized schemes.Besides.the two theorems can also solve two large categories of problems about linear and nonlinear computational instability. The traditional global spectral-vertical finite-difference semi-implicit model for baroclinic primitive equations is currently used in many countries in the world for operational weather forecast and numerical simulations of general circulation.The present work,however,based on Theorem 2 formulated in this paper,develops and realizes a high-order total energy conserving semi-implicit time-difference fidelity scheme for global spectral-vertical finite-difference model of baroclinic primitive equations.Prior to this,such a basic formulation problem remains unsolved for long,whether in terms of theory or practice.The total energy conserving semi-implicit scheme formulated here is applicable to real data long-term numerical integration. The experiment of thirteen FGGE data 30-day numerical integration indicates that the new type of total energy conserving semi-implicit fidelity scheme can surely modify the systematic deviation of energy and mass conserving of the traditional scheme.It should be particularly noted that,under the experiment conditions of the present work,the systematic errors induced by the violation of physical laws of conservation in the time-discretized process regarding the traditional scheme designs(called type Z errors for short)can contribute up to one-third of the total systematic root-mean-square(RMS)error at the end of second week of the integration and exceed one half of the total amount four weeks afterwards.In contrast,by realizing a total energy conserving semi-implicit fidelity scheme and thereby eliminating corresponding type Z errors, roughly an average of one-fourth of the RMS errors in the traditional forecast cases can be reduced at the end of second week of the integration,and averagely more than one-third reduced at integral time of four weeks afterwards.In addition,experiment results also reveal that,in a sense,the effects of type Z errors are no less great than that of the real topographic forcing of the model.The prospects of the new type of total energy conserving fidelity schemes are very encouraging.

Recent Advances in the Use of Statistical Mechanics to Establish Molecular Thermodynamic Models for Electrolyte Solutions

Based on statistical mechanics, a review of recent theoretical studies of real electrolyte solutions is presented from three aspects, namely, molecular simulation, mean spherical approximation (MSA), and perturbation theory. Recent advances in studies of three kinds of electrostatic potentials of mean force, three kinds of internal energies (ion-ion, ion-dipole, and dipole-dipole interactions), and three kinds of electro-lyte models (primitive, non-primitive, and solvent primitive models) are introduced. The advantages and dis-advantages between primitive and non-primitive models, and between MSA and perturbation theory are dis-cussed. Some new equations of state (EOSs) based on MSA and perturbation theory for real electrolyte so-lutions are introduced. The one-Yukawa EOS and the two-Yukawa EOS for charged colloid systems are presented.

Recent Advances in Study on Thermodynamic Models for Real Systems Including Electrolytes

A comprehensive review of recent advances in study on thermodynamic models for real electrolyte solutions is presented. The differences between primitive and non-primitive electrolyte models are demonstrated. Some new thermodynamic models for electrolyte solutions based on the mean spherical approximation and perturbation theory are introduced. An extended scaled-particle theory and modified CleggPitzer equation are presented for physical and chemical absorption processes with mixed solvents, respectively. A pseudo one-component two-Yukawa equation of state is used for the aqueous two-phase extraction process in charged colloidal systems.