The title compound（S）-N-（hexahydro-2-oxo-1H-azepin-3-yl）-3-phenyl-2-propenamide（C15H18N2O2, Mr = 258.31） was synthesized by the reaction of（S）-α-amino-ε-caprolactam with 3-phenyl-2- propenoyl chloride. Its c...The title compound（S）-N-（hexahydro-2-oxo-1H-azepin-3-yl）-3-phenyl-2-propenamide（C15H18N2O2, Mr = 258.31） was synthesized by the reaction of（S）-α-amino-ε-caprolactam with 3-phenyl-2- propenoyl chloride. Its chemical structure was determined by 1H NMR, 13C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the monoclinic system, space group P21/n with a = 14.957（3）, b = 4.884（1）, c = 18.630（4）, β = 95.91（3）o, V = 1353.7（5）3, Z = 4, Dc = 1.267 g/cm^3, μ = 0.085 mm-1, F（000） = 552, R = 0.0671 and wR = 0.1547 for 2473 observed reflections with I 〉 2σ（I）.展开更多
基金Supported by the National Key Basic Research Program of China(973 Program)(2012CB725204 and 2012CB721104)the Natural Science Foundation of Jiangsu Province(No.BK20130913)+1 种基金Program for Changjiang Scholars and Innovative Research Team in University(No.IRT1066)the Priority Academic Program Development of Jiangsu Higher Education Institution
文摘The title compound（S）-N-（hexahydro-2-oxo-1H-azepin-3-yl）-3-phenyl-2-propenamide（C15H18N2O2, Mr = 258.31） was synthesized by the reaction of（S）-α-amino-ε-caprolactam with 3-phenyl-2- propenoyl chloride. Its chemical structure was determined by 1H NMR, 13C NMR, H RMS and X-ray single-crystal diffraction. The crystal belongs to the monoclinic system, space group P21/n with a = 14.957（3）, b = 4.884（1）, c = 18.630（4）, β = 95.91（3）o, V = 1353.7（5）3, Z = 4, Dc = 1.267 g/cm^3, μ = 0.085 mm-1, F（000） = 552, R = 0.0671 and wR = 0.1547 for 2473 observed reflections with I 〉 2σ（I）.
