Preparation, Characterization and Luminescent Properties of MCM-41 Type Materials Impregnated with Rare Earth Complex

Hybrid materials incorporating Eu-(TTA)(3). 2H(2)O (7hereafter designated as Eu-TTA, with TTA: thenoyltrifluoroacetone) in unmodified or modified MCM-41 by 3-aminopropyl-triethoxysilane (APTES) were prepared by impregnation method. The obtained materials were characterized using X-ray diffraction (XRD), IR and diffuse reflectance spectroscopy and luminescence spectra. All the hybrid samples exhibited the characteristic emission bands of EU3+ under UV light excitation at room temperature, and the excitation spectra showed significant blue-shifts compared to the pure rare-earth complex. Although the red emission intensity in the modified hybrid was almost the half of the red emission intensity in the pure Eu-TTA complex at room temperature, the hybrid showed a much higher thermal stability due to the shielding character of the MCM-41 host.

A New Type Anticorrosion Coating for Ocean Reinforced Concrete Structures

Corrosion of reinforced concrete structures is a serious problem in ocean engineering. As an orientation of study, anticorrosion coating technique is developed and widely applied, but many problems need to be solved. LSW-2 type anticorrosion coating for maritime reinforced concrete structures is characterized by sea water resistance, salt fog resistance, moisture and heal resistance as well as impermeability to chlorions. The new type coating can be applied to wet concrete surface by conventional construction technique. It is a breakthrough in solving the above mentioned problem. The paper mainly introduces the test results, the property indices, coating procedure, construction technique and economic benefit of Ihe coating.

Electrical Transport Properties of Type-Ⅷ Sn-Based Single-Crystalline Clathrates (Eu/Ba)8Ga16Sn30 Prepared by Ga Flux Method

Single-crystalline samples of Eu/Ba-filled Sn-based type-Ⅷ clathrate are prepared by the Ga flux method with different stoichiometric ratios. The electrical transport properties of the samples are optimized by Eu doping. Results indicate that Eu atoms tend to replace Ba atoms. With the increase of the Eu initial content, the carrier density increases and the carrier mobility decreases, which leads to an increase of the Seebeck coefficient. By contrast, the electrical conductivity decreases. Finally, the sample with Eu initial content of x = 0.75 behaves with excellent electrical properties, which shows a maximal power factor of 1.51 mW·m^-1K^-2 at 480K, and the highest ZT achieved is 0.87 near the temperature of 483K.

STUDIES ON THE PROPERTIES OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS Ⅲ TRANSMETALLATION REACTION OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS WITH METALLIC TIN

The transmetallation reaction of 4 Schiff base type arylmercury compounds with metallic tin has been carried out in refluxing xylene.It was found that the reaction proceeds in the same manner as that of chloro[2-(phenylazo)phenyl]mercury(Ⅱ) to give dichlorobisaryltin(Ⅳ).The ~1H NMR spectra of the products provide evidence for the presence of N→Sn intramolecular coordination.The formation of dichlorobisaryltin(Ⅳ)as a unique product probably arises from the N→Sn intramolecular coordination which results in the increasing of the stability of the molecule.

Effect of In_xGa_(1-x)As Interlayer on Surface Morphology and Optical Properties of GaSb/InGaAs Type-Ⅱ Quantum Dots Grown on InP (100) Substrates

The effects of indium composition in InGaAs interlayer and on optical properties of GaSb/InGaAs QD material on morphology of GaSb/InGaAs quantum dots （QDs） system are studied. AFM images show that the change of the indium composition in InGaAs interlayer can alter the GaSb QD morphology. It is found that low indium composition in InGaAs interlayer can promote the formation of QDs, while high indium composition can inhibit the formation of QDs. The photoluminescence （PL） spectra of GaSb/InGaAs QDs at 8 K under low excitation power indicate that the third root of the excitation power is linear with the peak position, which provides a direct evidence for their luminescence belonging to type-Ⅱ material optical transition. The PL spectra at 8 K under an excitation power of 90row show that the optical properties of GaSb/InGaAs QD material system can be affected by the indium composition in the InGaAs interlayer, and the PL peak position is linear with the indium composition. The optical properties of GaSb/InGaAs QDs can be improved by adjusting the indium composition in the InGaAs interlayer.

STUDIES ON THE PROPERTIES OF SCHIFF BASE TYPE ARYLMERCURY COMPOUNDS.II ^(199)Hg NMR SPECTRA OF MERCURATED DERIVATIVES OF SUBSTITUTED BENZYLIDENEANILINES

^(199)Hg NHR spectra of 18 Schiff base type arylmercury compounds have been studied.It was further confirmed that in the molecule of XC_6H_4CH=NC_6H_3-2-HgC1-4-CH_3 there exists an intramolecular N→Hg coordination via a four-membered ring.For the series of XC_6H_4CH=NC_6H_3-2-HgCl-4-CH_3(X is a para-or mera-substituent),there is a good linear correlation between δ^(199)Hg and Hammett's o constants.The influence of substituents of C-pheny1 ring on the δ ^(199)Hg can be explained in terms of the intramolecular N→Hg coordination.

Research on strong earthquake type division and forecast method for subsequent strong earthquakes

The relationships between energy, amplitude and frequency of eanhquake are correlative with the property of the seismic source. And the grade of the correlativity can be used as an index to distinguish the types of strong earth quakes. Primarily the strong earthquake can be divided into three types of main-after earthquakes, double-main earthquakes and swarm of strong earthquake. There are similarity and a certain repeatability at the quantificational indexes of hypocenter property between the same type of strong earthquakes, which supply basis for the forecast of subsequent strong shocks. The reference indexes of after strong shock forecast which are valuable for the applica tions of the method of type-divided forecast come from the analysis about more than fifty strong shock wide-band (BPZ wave) recording data of CDSN from 1988 to 1997.

The Relationship between Microtexture Types and Indices of Physico-Mechanical Properties of Loess in China

The paper deals mainly with the relationship between the microtexture types and the indices of physicomechanical properties of loess. The results of study demonstrate that the study of microtextures of loess is of importance in the prediction and preliminary evaluation of engineering geological properties of loess in a region.

Structures and Magnetic Properties of Europium-Transition Metal-Gallium Ternary Intermetallic Compounds with 1:3 Type

The crystal structures and magnetic properties of novel Eu TrGa3-r （T=Pd, It, Rh） in termetallic compounds are investigated by using powder x-ray diffraction and magnetic measurements. EuTrGa3-r crystallizes in orthorhombic structure with space group of Cmcm and Z = 4. There are four kinds of nonequivalent 4c crystal positions in EuTrGaa-r unit cell, which are occupied by 4Eu, 4GaⅠ, 4（GaⅡ, T） and 4GaⅢ, respectively. EuTrGa3-r ex- hibits the complex magnetic states in low-temperature regime, with the three-, two- and one-antiferromagnetic transitions occurring for T=Ir, T=Rh and T=Pd, respectively. It might be due to the Kondo effect： a localized antiferromagnetic interaction of the isolated impurity spins with the surrounding conduction electrons at low-temperature regime.

Plate reinforced square hollow section X-joints subjected to in-plane moment

The static test of 13 square hollow section(SHS) X-joints with different β and different types of plate reinforcement under in-plane moment in brace was carried out. Experimental test schemes, failure modes of specimens, moment-vertical displacement curves, moment-deformation of the chord, and strain strength distribution curves were presented. The effect of β and plate reinforcement types on in-plane flexural property of SHS X-joints was studied. Results show that punching shear of chord face disappears, brace material fracture appears and concave and convex deformation of chord decrease when either collar plates or doubler plates were welded on chord face. Moment-vertical displacement curves of all specimens have obvious elastic, elastic-plastic and plastic stages. As β increases, the in-plane flexural ultimate capacity and initial stiffness of joints of the same plate reinforcement type increase, but ductility of joints decreases. With the same β, the in-plane flexural initial stiffness and ultimate capacity of doubler plate reinforced joints, collar plate reinforced joints, and unreinforced joints decrease progressively. Thickness of reinforcement plate has no obvious effect on in-plane flexural initial stiffness and ultimate capacity of joints. As thickness of reinforcement plate increases, the ductility of reinforced X-joints decreases. The concave and convex deformation of every specimen has good symmetry;as β increases, the yield and ultimate deformation of chord decrease.

Twin-wire SAW welding of 70 kg class high strength steel

The twin-wire SAW welding process was investigated using Baosteel 70 kg class high strength steel, and the properties of the joints were studied using conventional single and double-faced grooves as well as an optimized groove. The results showed that by using an optimized double-faced groove, a small root face, and no back gouging, a small welding heat input was achieved and thus the joint strength and toughness were improved significantly. Also, removing back gouging reduced the labor required in the process. The weld reinforcement and deformation were observed to be rather small.

Coburn Type Operators and Compact Perturbations

A bounded linear operator T acting on a Hilbert space is called Coburn operator if ker(T-λ) = {0} or ker(T-λ)*= {0} for each λ∈ C. In this paper, the authors define other Coburn type properties for Hilbert space operators and investigate the compact perturbations of operators with Coburn type properties. They characterize those operators for which has arbitrarily small compact perturbation to have some fixed Coburn property.Moreover, they study the stability of these properties under small compact perturbations.

Studies on the syntheses and properties of Schiff base type crown ethers

Eight bis-,two tris-and two mono-crown ethers of Schiff base type have been pre- parcd by the reaction of 4'-formylbenzo-15-crown-5 with diamincs.Conductivity measurements show that the bis-crown ethers form 1:1 complexes(crown cther unit:metal ion)with sodium ion and 2:1 complexes with potassium,rubidium and ammonium ion,respectively.

Record high photoresponse observed in CdS-black phosphorous van der Waals heterojunction photodiode

Two-dimensional(2D)materials have recently received great attention for their atomic thin thickness and thus derived outstanding electrical,optical and optoelectronic properties.Moreover,the dangling-bond-free surfaces of 2D materials enable the direct integration of different materials with various properties through van der Waals(vdW)forces into vdW heterostructures,providing new opportunities for constructing new type devices with superior performances.In this study,we report the vertical assembly of n-type CdS and p-type BP into p-n junctions.The electrically tunable heterojunction device shows a high current rectifying ratio up to8×103at a low bias voltage range of±1 V and an ideality factor of 1.5.More interestingly,the CdS/BP vdW heterojunction exhibits an ultra-high photoresponsivity up to 9.2×105A W-1and an ultra-high specific detectivity of 3.2×1013Jones with a low bias voltage of 1.0 V,which is among the highest in the reported results of 2D heterostructures.While operated at a self-powered mode,the device also exhibits excellent photodetection performances with a high photoresponsivity of0.27 A W-1and a high external quantum efficiency of 76%.Time-resolved photoresponse characterizations indicate that the device possesses a fast response time of about 10 ms.The developed CdS/BP vdW heterojunctions will find potential applications in the next-generation nanoscale electronics and optoelectronics applications.

On the properties of some sets of von Neumann algebras under perturbation

Let L be a type II1 factor with separable predual and r be a normal faithful tracial state of c~. We first show that the set of subfactors of L with property F, the set of type II1 subfactors of L with similarity property and the set of all McDuff sub/actors of t are open and closed in the Hausdorff metric d2 induced by the trace norm; then we show that the set of all hyperfinite von Neumann subalgebras of L is closed in d2. We also consider the connection of perturbation of operator algebras under d2 with the fundamental group and the generator problem of type II1 factors. When M is a finite yon Neumann algebra with a normal faithful trace, the set of all von Neumann subalgebras B of M such that B ∪→ M is rigid is closed in the Hausdorff metric d2.

Some Properties of the Injective Tensor Product of Banach Spaces

Let X and Y be Banach spaces such that X has an unconditional basis. Then X Y, the injective tensor product of X and Y, has the Radon-Nikodym property （respectively, the analytic Radon-Nikodym property, the near Radon-Nikodym property, non-containment of a copy of co, weakly sequential completeness） if and only if both X and Y have the same property and each continuous linear operator from the predual of X to Y is compact.