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北京市冬季部分住宅室内PM_(10)中化学元素研究 被引量:9
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作者 赵厚银 邵龙义 姚强 《环境与健康杂志》 CAS CSCD 北大核心 2006年第1期14-17,共4页
目的研究北京市部分住宅室内空气中PM10的化学元素成分,并探讨各元素的来源。方法2002年12月—2003年3月应用撞击式采样器在北京市4户吸烟和非吸烟室内采集PM10样品,使用质子诱导X射线荧光法(PIXE)和富集因子法分析Al、Si、P、S、Cl等1... 目的研究北京市部分住宅室内空气中PM10的化学元素成分,并探讨各元素的来源。方法2002年12月—2003年3月应用撞击式采样器在北京市4户吸烟和非吸烟室内采集PM10样品,使用质子诱导X射线荧光法(PIXE)和富集因子法分析Al、Si、P、S、Cl等19种元素的平均质量浓度及富集特征。结果吸烟室内空气中PM10的19种元素的总浓度明显高于非吸烟室内,特别是K、S的浓度是非吸烟室内的2~4倍。室内空气中PM10的元素质量浓度主要由Al、Si、S、K、Ca、Fe等6种元素贡献,其中,吸烟室内K和S占分析元素总量的71.50%,而在非吸烟室内Al、Si和Ca占57.06%。结论Al、Si、Ca、Ti、Fe等来自自然源,而S、Zn、Pb、Cr、Cu、As、Cl、P等来自人为源,如吸烟、燃煤、燃油等。 展开更多
关键词 空气污染 室内 颗粒物 X射线荧光 富集因子
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A Comparison Analysis of Chemical Composition of Aerosols in the Dust and Non-Dust Periods in Beijing 被引量:12
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作者 张仁健 徐永福 韩志伟 《Advances in Atmospheric Sciences》 SCIE CAS CSCD 2004年第2期300-305,共6页
Dust events occurred frequently in Beijing in recent years. In this work, 120 aerosol samples were collected in two typical dust events (21-22 March and 15 May) and a non-dust period in Beijing from March to May 2001.... Dust events occurred frequently in Beijing in recent years. In this work, 120 aerosol samples were collected in two typical dust events (21-22 March and 15 May) and a non-dust period in Beijing from March to May 2001. Samples were analyzed for major elemental components by the Proton Induced X-ray Emission (PIXE) method. Results show that the enrichment factors of crustal elements such as Mg, Al, and Ti had little differences between the dust period and the non-dust period in Beijing, while the enrichment factors of other elements that have a relation to anthropogenic emissions were very low during the dust period. The results derived by using multivariate factor analysis from the observation data show that the sources such as soil dust, industry, and fuel combustion were among the major contributors to the particles in Beijing. 展开更多
关键词 DUST AEROSOL chemical composition proton induced x-ray Emission method
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Main chemical ingredients of the celadon glaze from Qingliangsi kiln and Zhanggongxiang kiln 被引量:2
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作者 ZHAO Weijuan1, LU Xiaoke1, LI Guoxia1, GUO Min1, XIE Jianzhong1, GAO Zhengyao1, SUN Xinmin2, GUO Musen2, CHENG Huansheng3 & ZHANG Bin3 1. Faculty of Physical Engineering, Zhengzhou University, Zhengzhou 450052, China 2. Research Institute of Cultural Relic and Archaeology, Henan Province, Zhengzhou 450004, China 3. Research Institute of Modern Physics, Fudan University, Shanghai 200433, China 《Science China(Physics,Mechanics & Astronomy)》 SCIE EI CAS 2006年第4期487-495,共9页
The proton induced X-ray emission (PIXE) is used to determine the chemical ingredients of seven main elements in the samples of Ru Guan porcelain glazes and Ru Civil porcelain from Qingliangsi kiln in Baofeng County a... The proton induced X-ray emission (PIXE) is used to determine the chemical ingredients of seven main elements in the samples of Ru Guan porcelain glazes and Ru Civil porcelain from Qingliangsi kiln in Baofeng County and the samples of celadon glaze from Zhanggongxiang kiln in Ruzhou City. The PIXE data are then analyzed by scatter analysis and fuzzy cluster method for determining their classification and provenance. The results show that there are obvious differences between the ingredients of glaze material of Ru Guan porcelain and Ru Civil porcelain from Qingliangsi kiln, of which the former ingredients are stable and its source is localized, and that the sources and ingredients of the glaze of Ru Guan porcelain and those of celadon glaze from Zhanggongxiang kiln are not wholly the same, of which the latter sources are much scattering. 展开更多
关键词 Zhanggongxiang kiln Qingliangsi kiln the source of RAW material the proton induced x-ray emission.
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