Composition analysis of colored dissolved organic matter in Taihu Lake based on three dimension excitation-emission fuorescence matrix and PARAFAC model, and the potential application in water quality monitoring

Taihu Lake is one of the five biggest lakes in China. Surface water samples from 26 sampling sites of Taihu Lake were collected. Furthermore wet chemical analysis （CODCr and BOD5） and measurement of three dimensional excitation-emission matrix （3DEEM） spectra in the laboratory have been conducted. Using parallel factor analysis （PARAFAC） model, three components of colored dissolved organic matter （CDOM） have been identified successfully, based on the analysis of 3DEEM data. The characteristics of the three components also have been described by comparing them to some components of CDOM, identified in earlier researches. Meanwhile, spatial variations of concentration for the three components in Taihu Lake have been analyzed, and the result indicates that the concentration of component 1 depends more on the situation of wastewater pollution and can be used as the indicator of wastewater pollution. The relationship between the concentrations of the three components and results of the wet chemical analysis show that none of the three components can be used as indicators of gross organic matter in water. However, the concentrations of all the three components have obvious linear relationships with the BOD5 value, especially for component 1 （r = 0.72878）. Finally, the potential applications of the composition analysis based on 3DEEM and PARAFAC model in water quality monitoring have been illuminated.

Hydrochemical characteristics and water quality evaluation of shallow groundwater in Suxian mining area,Huaibei coalfield,China

The aim of this study is to evaluate the hydrogeochemical characteristics and water environmental quality of shallow groundwater in the Suxian mining area of Huaibei coalfield,China.The natural formation process of shallow groundwater in Suxian is explored using Piper trilinear charts and Gibbs diagrams,and by examining the ratios between the major ions.United States Salinity Laboratory(USSL)charts,Wilcox diagrams,and the water quality index(WQI)are further employed to quantify the differences in water quality.The results reveal that the main hydrochemical facies of groundwater are HC03-Ca,and that silicate dissolution is the main factor controlling the ion content in shallow groundwater.The USSL charts and Wilcox diagrams show that most of the water samples would be acceptable for use in irrigation systems.The WQI results for each water sample are compared and analyzed,and the quality of groundwater samples around collapse ponds is found to be relatively poor.

Water quality variation of mining-subsidence lake during the initial stage： cases study of Zhangji and Guqiao Mines

Four quarters＇ water collecting and monitoring samples were done in the mining subsidence lakes of different water storing periods （ 2 to 7 years）, considering the water storing time and pollution sources state of the subsidence lakes. The following indexes were discussed such as organic indexes （TOC, CODM,, BOD, COD）, nutrient salts （TN, NH4^＋, NO3, NO,, Kjeldahl Nitrogen, TP, PO4^3- ）, etc. It is shown that water quality of the mining subsidence lake during the initial stage （ 2 years to 7 years） can stay relatively stable with a fluctuation during different quarters in a year, which can reach class Ill or IV of the Surthcc Water Environmental Quality Standard.

Biological Evaluation Based Quality Management of Water Resources in Small Xingkai Lake

Taking the water ecosystem of Small Xingkai Lake as research object,through the survey and analysis of aquatic organism indicators,this paper established an ecosystem integrity evaluation system with the biological integrity as the criterion layer. Using the index of biological integrity and comprehensive health index,it evaluated the health status of water ecosystem of Small Xingkai Lake.

Assessment on reliability of water quality in water distribution systems

Water leaving the treatment works is usually of a high quality but its properties change during the transportation stage. Increasing awareness of the quality of the service provided within the water industry today and assessing the reliability of the water quality in a distribution system has become a major significance for decision on system operation based on water quality in distribution networks. Using together a water age model, a chlorine decay model and a model of acceptable maximum water age can assess the reliability of the water quality in a distribution system. First, the nodal water age values in a certain complex distribution system can be calculated by the water age model. Then, the acceptable maximum water age value in the distribution system is obtained based on the chlorine decay model. The nodes at which the water age values are below the maximum value are regarded as reliable nodes. Finally, the reliability index on the percentile weighted by the nodal demands reflects the reliability of the water quality in the distribution system. The approach has been applied in a real water distribution network. The contour plot based on the water age values determines a surface of the reliability of the water quality. At any time, this surface is used to locate high water age but poor reliability areas, which identify parts of the network that may be of poor water quality. As a result, the contour water age provides a valuable aid for a straight insight into the water quality in the distribution system.

Comprehensive Evaluation of Water Quality of Rivers in Binzhou Based on RAGA-PPCE Model

The water quality of main rivers in Binzhou City,Shandong Province was comprehensively evaluated based on RAGA-PPCE model. Six main factors such as ammonia nitrogen(NH-N),total phosphorus(TP),total nitrogen(TN),chemical oxygen demand(COD),dissolved oxygen(DO) and p H were used to establish the evaluation and classification standards of water quality. The results show that the evaluation results of water quality by RAGA-PPCE model and the fuzzy comprehensive evaluation method are basically the same. The evaluation results of RAGA-PPCE model are objective and reasonable and can be applied to the comprehensive evaluation of water quality.

Study on the Quality Characteristics of Gas Field Water in Eastern Sichuan

Gas field water is the formation water produced together with natural gas in the process of natural gas exploitation.The gas field water treated is difficult to reach the standard due to its wide sources,numerous types and complex composition.In addition,it can pollute soil,surface water and groundwater.In this study,the quality and pollution characteristics of gas field water in eastern Sichuan were studied by conventional water quality determination and GC-MS.The results show that the main components of gas field water in eastern Sichuan were chloride,COD Cr,SS,anionic surfactant,sulfide and other substances.The gas field water could be divided into two types according to the characteristics of water quality,of which one had high mineralization and high organic compounds,and the other had high sulfur and high organic compounds.There were 17 kinds of organic pollutants in the gas field water,mainly including alkanes,alcohols,esters and a small amount of acids.

Study on the Reservoir Water Quality Change Rule in Northern China

Water quality index of reservoir source water were tracked during three years in a north frigid area,the effect on supplied water quality was also studied.Based on the analysis of the monitoring data during the same season,the reservoir source water had typical and seasonal variation characteristics that was divided into four periods including the icebound period,spring period(or peach blossom period),stable period in summer and autumn and winter period.The icebound period was charactered by the typical low temperature and turbidity,pH and oxygen consumption decreased gradually showed that the gradually anaerobic trend existed in the reservoir.In May as the reservoir completely thawed,upstream water inflow and the total pollutant in the reservoir gradually increased,but the bottom of reservoir bottom was stable in the anaerobic state temporarily.The state completely disappeared,various index increased significantly in the middle of July.The water had high chroma characteristics,chroma and turbidity increased significantly in the summer and autumn(7-11months),but stability of water quality was poor because of rainfall.The reservoir gradually froze after the middle of November and the flow of water decreased.The peak of chroma appeared a month later than the water temperature.Due to the water turbidity was low,and the floc was small and light,the conventional water purification process design based on removal of turbidity achieved removal of chroma through a lot dosing of coagulant.

Water quality assessment for Ulansuhai Lake using fuzzy clustering and pattern recognition

Water quality assessment of lakes is important to determine functional zones of water use.Considering the fuzziness during the partitioning process for lake water quality in an arid area,a multiplex model of fuzzy clustering with pattern recognition was developed by integrating transitive closure method,ISODATA algorithm in fuzzy clustering and fuzzy pattern recognition.The model was applied to partition the Ulansuhai Lake,a typical shallow lake in arid climate zone in the west part of Inner Mongolia,China and grade the condition of water quality divisions.The results showed that the partition well matched the real conditions of the lake,and the method has been proved accurate in the application.

The technology and practice of water saving at Baosteel

With the development of the production scale and the increasing of the process technologies and facilities,product quality and the requirement of water supply continuously put forward new requirements to water treatment technology.The practice of the water saving technology should ensure the safe of water using and the innovation of technique data.Especially the stabilization of water quality should also meet the production at full capacity,reduce equipment failure rate and maintain the sustainable development under the condition of the minimal resource consumption.This article describes the practice of Baosteel saving technology,water-saving ideas from the system to start,according to Baosteel raw water intake requirements and process water and drainage characteristics,water and salt water tidal according to changes in the Yangtze River and the Yangtze River upstream and downstream trends in water discharge on water quality factors,established the electrical conductivity,chloride ion indicators for the control of the Yangtze River water,the implementation of 'avoid salt build light' water at the same time,combined with the actual situation of water pollution in the Yangtze River,the use of force coefficient correlation theory,the implementation of 'avoid taking clear pollution' to ensure the quality of raw water intake. System and cascade utilization of water,process water,based on whole plant water balance testing, analysis,technical parameters of the system and processes the user running the pressure balance pipe network,and implemented a stabilization system to adjust water pressure,reducing the water supply network systemwater loss;application of electrochemical principles,the implementation of the protection of underground pipes Baosteel,implemented a water use,steps to use,the operating mode of water supply in series to increase water reuse,reduce wastewater discharge system. Water quality stability and water-saving in the process;carry out water quality stability technology in the different complicated processes of the steel industry;apply the environmental protection and water quality, sterilization,non-phosphorus and low phosphorus technologies which are suitable for high concentration of circulating water.By these technologies,we achieved the water-saving in the process in different seasons and solved the technical problems affecting production such as equipment corrosion,scaling and the formation of the water quality proprietary technology under the conditions of high heat load production as well. The use of water ecological conservation and biological treatment technology:the implementation of the reservoir to the ecological technology is characterized by food chain and wetland environmental technology characterized by plants chain.Reservoir ecological management techniques in the use of natural conditions, wind direction,temperature,light and fish biomass in the reservoir water level regulation of balance and combination of organic,control and resolve the reservoirs in spring and summer algae problems and water quality changes rot of the 'fresh' operating problems.The artificial wetland technology develops a new way for metallurgical plants' wastewater treatment.All the measures by the implementation of water to create the conditions for the system to achieve the water target of constant innovation,reaching the advanced level of iron and steel enterprises.

Optimization of Shanghai marine environment monitoring sites by integrating spatial correlation and stratified heterogeneity

The water quality grades of phosphate（PO4-P） and dissolved inorganic nitrogen（DIN） are integrated by spatial partitioning to fit the global and local semi-variograms of these nutrients. Leave-one-out cross validation is used to determine the statistical inference method. To minimize absolute average errors and error mean squares,stratified Kriging（SK） interpolation is applied to DIN and ordinary Kriging（OK） interpolation is applied to PO4-P.Ten percent of the sites is adjusted by considering their impact on the change in deviations in DIN and PO4-P interpolation and the resultant effect on areas with different water quality grades. Thus, seven redundant historical sites are removed. Seven historical sites are distributed in areas with water quality poorer than Grade IV at the north and south branches of the Changjiang（Yangtze River） Estuary and at the coastal region north of the Hangzhou Bay. Numerous sites are installed in these regions. The contents of various elements in the waters are not remarkably changed, and the waters are mixed well. Seven sites that have been optimized and removed are set to water with quality Grades III and IV. Optimization and adjustment of unrestricted areas show that the optimized and adjusted sites are mainly distributed in regions where the water quality grade undergoes transition.Therefore, key sites for adjustment and optimization are located at the boundaries of areas with different water quality grades and seawater.

A comparison of the water management systems in France and China

This paper compares legal systems for water management in France and China, with a focus on integrated water resources management and regarding in particular the formulation of policies and their implemen- tation. The research shows that China has committed itself to the efficient management of water resources through the development of various policy tools during the current period. This commitment, however, has often been interrupted and distorted by politics, resulting in the neglect of socioeconomic and environmental priorities. France has developed a legislative framework and practical instruments to apply integrated water resources manage- ment at the river basin level since the 1960s. This experience and the current implementation of the European Water Framework Directive brings elements that can contribute to Chinese society meeting its water challenges.

基于萤火虫算法的BP神经网络的水质评价

Assessment of water quality by firefly algorithm based on BP neural network model(FA-BP model)is built.In this model,the evaluation index function is constructed by BP Artificial Neural Network Algorithm(BP model),and Firefly Algorithm(FA model)is introduced to optimize weight values and thresholds to find the optimal solution.Fuzzy Comprehensive Evaluation method,Grey Incidence Analysis Algorithm and FA-BP model will be applied to evaluate the water quality of the five main rivers in Lianyungang City including Longwei,Yudai,Dapu,Paidan,and Dongyan River.The results show that the Fuzzy Comprehensive Evaluation method is difficult to use for slight pollution rivers with several slightly over standard indexes.It will be easy to ignore the impact of extreme indexes by Grey Incidence Analysis Algorithm.FA-BP model solves the shortcomings of the two methods.The evaluation results provide an important reference for the formulation of reasonable measures.It is a relatively comprehensive evaluation method and has a good application prospect in water quality evaluation.

A review of environmental characteristics and effects of low-molecular weight organic acids in the surface ecosystem

Low molecular weight organic acids （LMWOAs） are prevalent on the earth＇s surface. They are vital intermediate products during metabolic pathways of organic matter and participate in the tricarboxylic acid cycle during life activities. Photochemical reactions are pivotal for LMWOAs＇ origination and play a large role in determining their diversity and their ultimate fate. Within the long time that organic matter is preserved in sediments, it can be decomposed and converted to release organic and inorganic pollutants as well as C, N, and P nutrients, which are of potential ecological risk in causing secondary pollution to lake water. The sediment pool is a comprehensive and complex compartment closely associated with overlying water by various biochemical processes, during which LMWOAs play critical roles to transport and transform elements. This article elucidates geochemical behaviors of LMWOAs in the surface environment in details, taking natural water, soil, and aerosol as examples, focusing on reviewing research developments on sources and characteristics, migration and mineralization of LMWOAs and relevant environmental effects. Simultaneously, this review article depicts the categories and contents of LMWOAs or their contribution to DOC in environmental media, and evaluates their importance during organic matter early diagenesis. Through concluding and discussing the conversion mechanisms and influencing factors, the next research orientations on LMWOAs in lake ecosystems are determined, mainly concerning relationships with hydrochemical parameters and microorganisms, and interactions with pollutants. This will enrich the knowledge on organic matter degradation and related environmental effects, and help reconstruct a theoretical framework for organic compound succession and influencing factors, providing basic data for lake eutrophication and ecological risk assessment, conducive to better control over water pollution and proper management of water quality.