A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties wer...A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties were highly investigated through ~1H-NMR,UV and PL spectroscopy.The quenching behavior was also investigated,and the results demonstrate that incomplete quenching exists,which is consistent with the cationic poly(p-phenylene vinylene) related copolymer containing bulky phenylene substitutents,prob...展开更多
基金supported by the National Natural Science Foundation of China(Nos.20774043,20874048)the Fok Ying-Tong Education Foundation(No.111051)+1 种基金the Natural Science Foundation of Jiangsu Province of China(No.BK2008453)the Scientific Research Foundation of Nanjing University of Posts and Telecommunications (NUPT)(Nos.NY207035 and NY207011)
文摘A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties were highly investigated through ~1H-NMR,UV and PL spectroscopy.The quenching behavior was also investigated,and the results demonstrate that incomplete quenching exists,which is consistent with the cationic poly(p-phenylene vinylene) related copolymer containing bulky phenylene substitutents,prob...