Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri n...Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri ng while ignoring R clustering in practice, so it has some limitation especially when the number of sample and index is very large. Furthermore, because of igno ring the association between the different indexes, the clustering result is not good & true. In this paper, we present the model and the algorithm of two-level hierarchi cal clustering which integrates Q clustering with R clustering. Moreover, becaus e two-level hierarchical clustering is based on the respective clustering resul t of each class, the classification of the indexes directly effects on the a ccuracy of the final clustering result, how to appropriately classify the inde xes is the chief and difficult problem we must handle in advance. Although some literatures also have referred to the issue of the classificati on of the indexes, but the articles classify the indexes only according to their superficial signification, which is unscientific. The reasons are as follow s: First, the superficial signification of some indexes usually takes on different meanings and it is easy to be misapprehended by different person. Furthermore, t his classification method seldom make use of history data, the classification re sult is not so objective. Second, for some indexes, its superficial signification didn’t show any mean ings, so simply from the superficial signification, we can’t classify them to c ertain classes. Third, this classification method need the users have higher level knowledge of this field, otherwise it is difficult for the users to understand the signifi cation of some indexes, which sometimes is not available. So in this paper, to this question, we first use R clustering method to cluste ring indexes, dividing p dimension indexes into q classes, then adopt two-level clustering method to get the final result. Obviously, the classification result is more objective and accurate. Moreover, after the first step, we can get the relation of the different indexes and their interaction. We can also know under a certain class indexes, which samples can be clustering to a class. (These semi finished results sometimes are very useful.) The experiments also indicates the effective and accurate of the algorithms. And, the result of R clustering ca n be easily used for the later practice.展开更多
This paper presents the synthetic and structure studies of molybdenum（tungsten）-copper-sulphur-dialkyldithiocarbamate cluster compounds.The reactions of（M=Mo,W;n=0,2）,CuCl,and R<sub>2</sub>dtc￣-（R<...This paper presents the synthetic and structure studies of molybdenum（tungsten）-copper-sulphur-dialkyldithiocarbamate cluster compounds.The reactions of（M=Mo,W;n=0,2）,CuCl,and R<sub>2</sub>dtc￣-（R<sub>2</sub>=Me<sub>2</sub>,Et<sub>2</sub>,C<sub>4</sub>H<sub>8</sub>,C<sub>5</sub>H<sub>1</sub>0） yield a series of tetra-,hexa-,and heptanuclear cluster compounds.Their spectroscopic properties and the synthetic reaction mechanism are discussed.展开更多
文摘Hierarchical clustering analysis based on statistic s is one of the most important mining algorithms, but the traditionary hierarchica l clustering method is based on global comparing, which only takes in Q clusteri ng while ignoring R clustering in practice, so it has some limitation especially when the number of sample and index is very large. Furthermore, because of igno ring the association between the different indexes, the clustering result is not good & true. In this paper, we present the model and the algorithm of two-level hierarchi cal clustering which integrates Q clustering with R clustering. Moreover, becaus e two-level hierarchical clustering is based on the respective clustering resul t of each class, the classification of the indexes directly effects on the a ccuracy of the final clustering result, how to appropriately classify the inde xes is the chief and difficult problem we must handle in advance. Although some literatures also have referred to the issue of the classificati on of the indexes, but the articles classify the indexes only according to their superficial signification, which is unscientific. The reasons are as follow s: First, the superficial signification of some indexes usually takes on different meanings and it is easy to be misapprehended by different person. Furthermore, t his classification method seldom make use of history data, the classification re sult is not so objective. Second, for some indexes, its superficial signification didn’t show any mean ings, so simply from the superficial signification, we can’t classify them to c ertain classes. Third, this classification method need the users have higher level knowledge of this field, otherwise it is difficult for the users to understand the signifi cation of some indexes, which sometimes is not available. So in this paper, to this question, we first use R clustering method to cluste ring indexes, dividing p dimension indexes into q classes, then adopt two-level clustering method to get the final result. Obviously, the classification result is more objective and accurate. Moreover, after the first step, we can get the relation of the different indexes and their interaction. We can also know under a certain class indexes, which samples can be clustering to a class. (These semi finished results sometimes are very useful.) The experiments also indicates the effective and accurate of the algorithms. And, the result of R clustering ca n be easily used for the later practice.
文摘This paper presents the synthetic and structure studies of molybdenum（tungsten）-copper-sulphur-dialkyldithiocarbamate cluster compounds.The reactions of（M=Mo,W;n=0,2）,CuCl,and R<sub>2</sub>dtc￣-（R<sub>2</sub>=Me<sub>2</sub>,Et<sub>2</sub>,C<sub>4</sub>H<sub>8</sub>,C<sub>5</sub>H<sub>1</sub>0） yield a series of tetra-,hexa-,and heptanuclear cluster compounds.Their spectroscopic properties and the synthetic reaction mechanism are discussed.
