Structure and Infrared Radiation Property of Co_(1-x)ZnxFe_2O_4 Ferrites by XAFS Analysis

Co1-xZnxFe2O4 ferrites were prepared by solid state reaction. The microstructure and performance were studied by X-ray diffraction, X-ray absorption fine-structure analysis and IRE-2 infrared radiant test. It is found that infrared radiance show a nonlinear change with x, exhibiting the infrared radiance of this material improved and the average radiance in the 8-14 μm waveband reached 0.91. The Co^3＋ and Zn^2＋ ions are found to occupy both tetrahedral and octahedral sites, and correspondingly, the fraction of Fe^3＋ ions in B-site decreases nonlinearly in ferrites. The lattice parameters are found to concern with Zn^2＋, and the activation energy deduces from crystal strain and crystal vibrate increases with content Zn^2＋. The redistribution of the Co^3＋ and Zn^2＋ ions between tetrahedral and octahedral sites is related to the providing a selective tetrahedral and octahedral sites infrared radiance of Co1-xZnxFe2O4 ceramics with increasing x.

RELATIONSHIP BETWEEN INFRARED RADIATION AND CRYSTAL STRUCTURE IN Fe-Mn-Co-Cu-O SPINELS

Ni^3＋ and Cr^3＋ doped Fe-Mn-Co-Cu-O spinels have been prepared by solid phase sintering. The valence states and distribution of transition ions in the spinel crystals are inferred by the consideration of thermodynamic principle and crystalline field theory. The mierostructure and performance of those are studied by X-ray diffraction （XRD）, Fourier transform infrared （FT-IR）, and IRE-2 infrared radiant instrument. Ni3＋ and Cr3＋ occupy the vacancies or substitute the other ions in the spinel structures and form diverse spinel structures, which exhibit infrared integral emissivities of 0.93 in the whole band, and 0. 94 in the band within 14-25μm too. The content of Fe2O3 and MnO2 in the spinel crystals changes, maybe it induces infrared radiativity of spinels differently.

Structure and Infrared Radiation Properties of Substituted Cordierites

Zn^2＋ - or Ti^4＋ -substituted cordierites with the nominal compositions of Mg1 .6 Zn0.4 Al4 Si5 O18 and Mg1.8 Ti0.2 Al4.4 Si4.6 O18 respectively, were prepared by a conventional solid state reaction method. The structure of the substituted eordierites was characterized by X- ray diffraction （ XRD ）, infrared （ 1R ） spectroscopy and 29 Si magic angle spinning （ MAS ） nuclear magnetic resonance （ NMR ）. The infoared radiation properties were investigated in the bands within 2.5-25μm. Compared with the na-substituted cordierite composition （ Mg2 Al4 Si5 O18 ）, Zn^2＋ - or Ti^4＋ -substituted cordierites show superior infrared properties. XRD and IR results confirm the formation of hexagonal a-eordierite as the main eo＇stal phase for the substituted cordierites. 29 Si MAS NMR result indicates that Zn^2＋ or Ti^4＋ Substitutions for partial Mg^2＋ of a-eordierite promoted the ordering of the distribution oral and Si atoms in T1 （ tetrahedra connecting six-raembered rings together with [ MgO6] octahedra ） and T2 （ tetraheda forming six-reentered rings） tetrahedral sites. This resulted in a lattice deformation and increased the anharmonicity of polarization vibration, which is responsible for the improvement of infrared radiation properties of the substituted eordierites.

Influence of Microwave Radiation on Properties and Structure of Fe_2O_3/SO_4^(2-) Solid Superacid Catalyst

The microwave radiation method was introduced to prepare the Fe_2O_3/SO solid superacid.Its structure and properties were investigated by means of X-ray diffraction and infrared spectrum analyses as well as measurement of magnetic susceptibility and rate of esterification. The structure of the superacids prepared in microwave field can be crystalline or non-crystalline, the latter has not been reported yet in literatures. Comparing with the traditional superacid, the non-crystalline Fe2O3/SO superacid prepared in microwave field has the highest magnetic susceptibility and catalytic activity. The di-coordination of Fe2O3 and SO and the S=O bi-bond were reinforced by microwave radiation, which is favorable for increasing the acid intensity of the Fe2O3/SO catalyst

X-Ray Radiation Sensing Properties of ZnS Thin Film:A Study on the Effect of Annealing

Chemically synthesized ZnS thin film is found to be a good x-ray radiation sensor. We report the effect of annealing on the x-ray radiation detection sensitivity of a ZnS thin film synthesized by a chemical bath deposition technique. The chemically synthesized ZnS films are annealed at 333, 363 and 393K for 1 h. Structural analyses show that the lattice defects in the films decrease with annealing. Further, the band gap is also found to decrease from 3.38 to 3.21 eV after annealing at 393K. Current-voltage characteristics of the films are studied under dark and x-ray irradiation conditions. Due to the decrease of lattice defects and band gap, the conductivity under dark conditions is found to increase from 2.06 × 10^-6 to 1.69 × 10^-5 S/em, while that under x-ray irradiation increases from 4.13 × 10^-5 to 5.28 ×10^-5 S/cm. On the other hand, the x-ray radiation detection sensitivity of the films is found to decrease with annealing. This decrease of detection sensitivity is attributed to the decrease of the band gap as well as some structural and surface morphological changes occurring after annealing.

Current Status and Prospect of Infrared Radiation Ceramics for Energy-saving Applications in High Temperature Furnaces

Nowadays,it is a great challenge to reduce energy consumption and exhaust emission for human activities,in particular,high temperature industries.Among many efforts made to realize energy savings for high temperature furnaces and kilns,the use of high emissivity materials is considered to be an effective route to increase their thermal efficiency by enhancing heat transfer.Most materials with high refractoriness and superior chemical stability have weak infrared absorption and radiation properties;however,their emissivity in infrared regions（1 —25 μm） could be effectively increased by ion doping.This is attributed to three main mechanisms：1） distortion of the crystal lattice;2） increase of free carrier absorption; 3） formation of impurity energy level.In this paper,the development and advancement of various material systems with high emissivity including non-oxides and oxide based ceramics were reviewed.It is also suggested that the establishment of evaluation models or instruments for energy savings would be beneficial to design and application of high emissivity materials in various high-temperature environment.Furthermore,more efforts should be made on durability of high emissivity materials at high service temperatures and on the standardization of testing methods for emissivity.

Effects of thermal transport properties on temperature distribution within silicon wafer

A combined conduction and radiation heat transfer model was used to simulate the heat transfer within wafer and investigate the effect of thermal transport properties on temperature non-uniformity within wafer surface. It is found that the increased conductivities in both doped and undoped regions help reduce the temperature difference across the wafer surface. However, the doped layer conductivity has little effect on the overall temperature distribution and difference. The temperature level and difference on the top surface drop suddenly when absorption coefficient changes from 104 to 103 m-1. When the absorption coefficient is less or equal to 103 m-1, the temperature level and difference do not change much. The emissivity has the dominant effect on the top surface temperature level and difference. Higher surface emissivity can easily increase the temperature level of the wafer surface. After using the improved property data, the overall temperature level reduces by about 200 K from the basis case. The results will help improve the current understanding of the energy transport in the rapid thermal processing and the wafer temperature monitor and control level.

Total Heat Exchange Factor Based on Non-Gray Radiation Properties of Gas in Reheating Furnace

Modified mathematical models based on imaginary plane zone method in reheating furnace were developed in which non-gray radiation properties of gas were considered,and the Newton＇s method and the finite difference method were adopted. Effects of productivity,fuel consumption,fuel-air ratio,calorific value of fuel and inserting depth of thermocouple on total heat exchange factor along the length of reheating furnace were investigated. The results show that total heat exchange factor increases with productivity or inserting depth of thermocouple,and it decreases when fuel consumption,fuel-air ratio or calorific value of fuel increases. The results are valuable for dynamical compensation of total heat exchange factor for online control mathematical models in reheating furnace.

A Method for Measuring Thermal Radiation Properties of Semi-Transparent Films

This paper presents a method(F method)for determining the optical constants and the thicknesses of semi- transparent thin films.It has the following distinctive features:high precision;rapid determination of the measured quantities;wide range of convergence of solutions;capable of judging whether or not the results are reasonable.In order to meet the needs of application and engineering design,a family of curves designated Fig.n-F was prepared.Using it n,k,d of the films can be conveniently and accurately determined.From the optical constants and the thicknesses of the films determined by the F method,all important thermal radiation properties of the semi-transparent films needed in application can be obtained.

Design and analysis of bidirectional deployable parabolic cylindrical antenna

A bidirectional deployable parabolic cylindrical reflector for an L-band synthetic aperture radar is presented in this study, in which a self-deployed antenna with low weight was designed. The antenna consists of four curved surfaces formed from thin sheets of composite materials connected by hinges along the edges, and the reflective surface is provided by the front surface. The edge profiles of connecting lines were obtained through geometric analysis. A scaled model, including design and manufac- ture, was demonstrated to validate the process from the folded state to the fully deployed state. The non-contact synchronous vision measuring method was used to test the basic frequency of the scaled model, and the test results gave the verification of the analyses. Compared with the existing unidirectional deployable antenna, this new type of bidirectional deployable antenna can be applied to larger-size antennas and has better performance because the glass-woven tape connections were substituted with more reliable hinges. Static, modal, harmonic response, and transient response analyses of the full-sized reflector structure were mod- eled with the commercial finite element （FE） package ABAQUS. The modeling techniques were developed to predict the struc- tural dynamic behavior of the reflector and the results showed that the first natural frequency was 0.865 Hz, and the reflector structure had good stiffness in three directions. This proposed structure has very high stiffness-to-mass ratio because of its hollow solid construction. A preliminary simulation of radiation properties of the parabolic cylindrical antenna, fed by an off-set linear feed horn array, was conducted to obtain the radiation pattern of the feed and the reflector.

EXPERIMENTAL STUDY ON EFFECTS OF HUMIDITY AND CHEMICAL COMPOSITION UPON IMAGINARY PART OF REFRACTIVE INDEX OF AEROSOL PARTICLES

Experimental study is made of the relationship between the imaginary part of refractive index (IRI) of atmospheric aerosol particles and relative humidity,and between IRI and chemical element through the assay of chemical constituents of the particles.Evidence suggests that atmospheric humidity and aerosols' chemical ingredients have great effects on the IRI's and they should thus be considered in the research of the radiation properties of the particles in the atmosphere.