The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） tec...The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM（50.8±0.3 cm^-1） at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.展开更多
Implementation of laser-plasma-based acceleration stages in user-oriented facilities requires the definition and deployment of appropriate diagnostic methodologies to monitor and control the acceleration process.An ov...Implementation of laser-plasma-based acceleration stages in user-oriented facilities requires the definition and deployment of appropriate diagnostic methodologies to monitor and control the acceleration process.An overview is given here of optical diagnostics for density measurement in laser-plasma acceleration stages,with emphasis on wellestablished and easily implemented approaches.Diagnostics for both neutral gas and free-electron number density are considered,highlighting real-time measurement capabilities.Optical interferometry,in its various configurations,from standard two-arm to more advanced common-path designs,is discussed,along with spectroscopic techniques such as Stark broadening and Raman scattering.A critical analysis of the diagnostics presented is given concerning their implementation in laser-plasma acceleration stages for the production of high-quality GeV electron bunches.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.21673211 and 21203047)the Foundation of Heilongjiang Bayi Agricultural University,China(Grant No.XZR2014-16)the Science Challenging Program of China(Grant No.JCKY2016212A501)
文摘The structural deformation of NO2 group induced by an intense femtosecond laser field of liquid nitromethane（NM）molecule is detected by time-and frequency-resolved coherent anti-Stokes Raman spectroscopy（CARS） technique with the intense pump laser. Here, we present the mechanism of molecular alignment and deformation. The CARS spectra and its FFT spectra of liquid NM show that the NO2 torsional mode couples with the CN symmetric stretching mode and that the NO2 group undergoes ultrafast structural deformation with a relaxation time of 195 fs. The frequency of the NO2 torsional mode in liquid NM（50.8±0.3 cm^-1） at room temperature is found. Our results prove the structural deformation of two groups in liquid NM molecule occur simultaneously in the intense laser field.
基金support from the European Unions Horizon 2020 research and innovation program under Grant Agreement No.653782-EuPRAXIAthe MIUR-funded Italian research Network ELI-Italy
文摘Implementation of laser-plasma-based acceleration stages in user-oriented facilities requires the definition and deployment of appropriate diagnostic methodologies to monitor and control the acceleration process.An overview is given here of optical diagnostics for density measurement in laser-plasma acceleration stages,with emphasis on wellestablished and easily implemented approaches.Diagnostics for both neutral gas and free-electron number density are considered,highlighting real-time measurement capabilities.Optical interferometry,in its various configurations,from standard two-arm to more advanced common-path designs,is discussed,along with spectroscopic techniques such as Stark broadening and Raman scattering.A critical analysis of the diagnostics presented is given concerning their implementation in laser-plasma acceleration stages for the production of high-quality GeV electron bunches.
