The structure, electrostatic properties, and Raman spectra of aflatoxin B1 （AFB1） and AFB1-Ag complex are studied by density functional theory with B3LYP/6- 311G（d,p）/Lan12dz basis set. The results show that the s...The structure, electrostatic properties, and Raman spectra of aflatoxin B1 （AFB1） and AFB1-Ag complex are studied by density functional theory with B3LYP/6- 311G（d,p）/Lan12dz basis set. The results show that the surface-enhanced Raman scattering （SERS） and pre-resonance Raman spectra of AFB1-Ag complex strongly depend on the adsorption site and the excitation wavelength found to enhance 102-103 order compared to of the incident light. The SERS factors are normal Raman spectrum of AFB1 molecule due to the larger static polarizabilities of the AFB1-Ag complex, which directly results in the stronger chemical enhancement in SERS spectra. The pre-resonance Raman spectra of AFB1-Ag complex are explored at 266, 482, 785, and 1064 nm incident light wavelength, in which the enhancement factors are about 10^2-10^4, mainly caused by the charge-transfer excitation resonance. The vibrational modes are analyzed to explain the relationship between the vibrational direction and the enhanced Raman intensities.展开更多
We present an experimental study on low-threshold broadband spectrum generation mainly due to the amplirfication of the cascaded stimulated Raman scattering （SRS） effect in a four-stage fiber master oscillator power...We present an experimental study on low-threshold broadband spectrum generation mainly due to the amplirfication of the cascaded stimulated Raman scattering （SRS） effect in a four-stage fiber master oscillator power amplifier system. The cascaded SRS is achieved by using a long passive fiber pumped by a pulsed fiber laser cen： tered at wavelength 1064 nm. The amplified spontaneous emission during the amplification process is efficiently suppressed by cutting the length of the passive fiber and by using a double-clad ytterbium-doped fiber amplifier. The generated broadband spectrum spans from 960nm to 1700nm with maximum average output 13.6 W and average spectral power density approximately 17. 7 mW/nm.展开更多
基金ACKNOWLEDGMENTS This work was supported by the National Natural Science Foundation of China （No.11174237）, the National Basic Rcsearch Program of China （No.2013CB328904）, and the Application Basic program of Sichuan Province （No.2013JY0035）.
文摘The structure, electrostatic properties, and Raman spectra of aflatoxin B1 （AFB1） and AFB1-Ag complex are studied by density functional theory with B3LYP/6- 311G（d,p）/Lan12dz basis set. The results show that the surface-enhanced Raman scattering （SERS） and pre-resonance Raman spectra of AFB1-Ag complex strongly depend on the adsorption site and the excitation wavelength found to enhance 102-103 order compared to of the incident light. The SERS factors are normal Raman spectrum of AFB1 molecule due to the larger static polarizabilities of the AFB1-Ag complex, which directly results in the stronger chemical enhancement in SERS spectra. The pre-resonance Raman spectra of AFB1-Ag complex are explored at 266, 482, 785, and 1064 nm incident light wavelength, in which the enhancement factors are about 10^2-10^4, mainly caused by the charge-transfer excitation resonance. The vibrational modes are analyzed to explain the relationship between the vibrational direction and the enhanced Raman intensities.
基金Supported by the National Natural Science Foundation of China under Grant No 11404404the Outstanding Youth Fund Project of Hunan Provincethe Fund of Innovation of National University of Defense Technology under Grant No B120701
文摘We present an experimental study on low-threshold broadband spectrum generation mainly due to the amplirfication of the cascaded stimulated Raman scattering （SRS） effect in a four-stage fiber master oscillator power amplifier system. The cascaded SRS is achieved by using a long passive fiber pumped by a pulsed fiber laser cen： tered at wavelength 1064 nm. The amplified spontaneous emission during the amplification process is efficiently suppressed by cutting the length of the passive fiber and by using a double-clad ytterbium-doped fiber amplifier. The generated broadband spectrum spans from 960nm to 1700nm with maximum average output 13.6 W and average spectral power density approximately 17. 7 mW/nm.
