Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties a...Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.展开更多
Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characterist...Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.展开更多
Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chem...Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chemical composition . The residual carbon content of the fused magnesia-chrome material made in reducing atmosphere is very high, if this material is used in the MgO-Al203-Cr2O3 ramming mix , it would cause spalling of the furnace lining during drying-out.展开更多
Magnesia-alumina-chrome ramming mixes with same chemical compositions were prepared by using different raw materials such as fused magnesia-chrome synthetic materials and sintered one, wasted bricks and magnesia-alumi...Magnesia-alumina-chrome ramming mixes with same chemical compositions were prepared by using different raw materials such as fused magnesia-chrome synthetic materials and sintered one, wasted bricks and magnesia-alumina spinels. Their physical properties were tested and microstructures were analyzed. The results show that the ramming mixes made of different raw materials bring about different microstructures and properties although the mixes have the same chemical composition, binder content and aggregate size composition.展开更多
Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as b...Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.展开更多
文摘Silicon fines, boron acid solid powders and microfine SiO 2 as sintering agents were incorporated into Al 2O 3-SiC-C ramming mix in order to investigated their effects on the microstructure, mechanical properties and sintering behavior of the ramming mix. Results show that all the three agents could improved both densification and mehanical properties markedly, compared to that of non-agent specimens and the effect of the composite of boron acid solid powders and microfine SiO 2 is the best. The oxidation resistance increased with the addition of agents, which is supported by densification. Microstructures showed that agent powders could fill pores or produce liquid phases at high temperature, therefore, improve the sintering of the ramming mix.
文摘Fused materials from ZrO2 stabilized by CaO or MgO, or the combined additive consisting of CaO and MgO are made. With using chemical, petrographic, X-ray phase and electron microscopic researches the main characteristics of these materials are determined. It is shown that, the materials of all compositions have low water absorption; they are characterized by equal struc-ture. The materials stabilized by the combined additive consisting of CaO and MgO are presented by generally the cubic phase and a small amount of tetragonal and monoclinic ZrO2 phases. Depending on CaO： MgO ratio in the materials the tetragonal ZrO2 phase settles down in a cubic matrix in the form of separate grains, and sites of net like structure in the form of a ＂woven＂ interlacing （2.9% of CaO and 2. 6% of MgO ）. An influence of the above mentioned fused stabilized ZrO2 materials and quantity of monoclinic zirconia, on the forming of zirconia mix on a phosphate bond and properties of＂ .fired samples is studied. The samples from mix based on ZrO2 stabilized by the combined additive consisting of 2.9% CaO and 2.6% MgO with 20% of monoclinic Zr02 are characterized by the highest properties： after .firing at 1 580 ~C open porosity of 14. 3% - 14. 8%, apparent density of 4. 67 -4. 69 g · cm^-5, cold crushing strength of 62 - 68 MPa, thermal shock resistance （ 1 300℃←→air） of 15 thermal cycles, linear growth of 0. 2%. The manufacturing technology of powders mix-ture for ramming mix based on the new fused material .from ZrO2 stabilized by the combined additive is developed and its production is mastered. From this mixture the large-size, shaped products on the phosphate bond are made at one carbon black production plant, which are installed in the combustion chamber of the carbon black production reactor.
文摘Mg0-Al2O3-Cr2O3 ramming mixes made of different raw materials have different mineral structure and different physical properties though with the identical particle size distribution, the same amount of binder and chemical composition . The residual carbon content of the fused magnesia-chrome material made in reducing atmosphere is very high, if this material is used in the MgO-Al203-Cr2O3 ramming mix , it would cause spalling of the furnace lining during drying-out.
文摘Magnesia-alumina-chrome ramming mixes with same chemical compositions were prepared by using different raw materials such as fused magnesia-chrome synthetic materials and sintered one, wasted bricks and magnesia-alumina spinels. Their physical properties were tested and microstructures were analyzed. The results show that the ramming mixes made of different raw materials bring about different microstructures and properties although the mixes have the same chemical composition, binder content and aggregate size composition.
文摘Aluminium powders were introduced to Al2O3-SiC-C dry ramming mixes in order to improve sintering properties and oxidation resistance according to their service conditions and installation methods. Properties such as bulk density, porosity, modulus of rupture, crushing strength and hot modulus of rupture as a function of aluminium addition were investigated in the present work. The microstructure and thermodynamics for the heat treated specimens were also analyzed. The results show that as aluminium addition increasing, the bulk density of the specimen treated at 220℃ tends to decrease and the apparent porosity increases, the strength of the specimens treated at 1100℃ and 1450℃ increases markedly, the bulk density tends to increase, apparent porosity and linear shrinkage decrease. The HMOR at 1400℃ is enhanced from 1.0 MPa to 3.5 MPa with 3% aluminium. Aluminium is served as sintering agent and anti-oxidant and it will react with CO and CO2 forming Al2O3 , which is helpful to enhance the strength, densify the structure and improve the overall properties.
