Plasma Jet Imaging by CCD Technology in Rapid Mold Manufacturing

Plasma spraying is an important enabling technology i n near-net-shaped process as well as many high-performance coating applicatio ns. Recently, it is being applied to rapid mould manufacturing to reduce develop ment time and manufacturing cost. In this process, inputted powders are heated a nd accelerated by plasma jet, and impinge on master pattern or prototype to form ing a thick coating. Mould will be fabricated after backed-up with consolidated material and other post-treatments. Amongst numerous factors that affect the l ife and properties of mould made by this novel method, quality of coating is the most important one. However, the complex nature of the spray process results in a large number of processing parameters that must be controlled in order to obt ain optimum coatings. Traditional "trial and error" method is too time and cost consuming for the optimal processing parameters. Maybe modeling and diagnostics of process is the best way to ravel out the problems. It has been proved that pl asma-gas flowrate, power level and spray distance are the most critical variabl es. So flow visualization and diagnostics for plasma jet quality has become an i mportant task to obtain a repeatable and reliable plasma processing technology. Using enthalpy probe diagnostics, spectrometry and optical measurement, we can o btain the distribution of temperature field of plasma jet. These results can hel p us to design gun configuration and optimize processing parameters for high dep osition efficiency and good qualities of rapid mould manufacturing. Nevertheless , it is still very difficult to realize real-time diagnoses because of restrict of diagnosis condition and drawback of measurement approach. In our researches, a real-time data collection and image processing system for plasma jet with high temperature, velocity and compressed energy has been realiz ed by CCD sensor. In this paper, we firstly focus our attention on collection pr inciple and methods, and an effective method for collecting data in high tempera ture area is presented. Then a system of real-time data collection by CCD camer a is developed. Finally, fake color image processing is given to analyze the law of temperature field distribution under different conditions. The results are i mportant to realize the visualization of plasma spraying, and especially to furt her study on closed-loop feedback control of forming quality for plasma rapid m anufacturing process.

Preparation Technology of Solvent-free Polyurethane:A Mini-Review

Solvent-free polyurethanes are synthesized under certain conditions via a rapid reaction between liquid prepolymers.During this process the molecular weight of the polymer is rapidly increased to produce polymeric materials containing a carbamate-based structure at a very fast rate.The organic solvents are completely avoided in the solvent-free polyurethane synthesis process,thus avoiding all the problems associated with the use of organic solvents.Solvent-free polyurethane synthetic leather is extruded directly without adding solvents in the production and processing process,which has the advantages of low VOC emission and environmentally friendly.This review brings together theoretical and experimental research on the application and synthesis and preparation of solvent-free polyurethanes to generate an understanding of the theory and synthesis and preparation techniques associated with solvent-free polyurethanes.The review includes(i)the application and development direction of solvent-free polyurethane,(ii)an overview of the technology of solvent-free polyurethane synthetic leather preparation,(iii)a study of the modification and synthesis of solvent-free polyurethane prepolymers,(iv)a summary of the technology of rapid foam forming of solvent-free polyurethane and its influencing factors,(v)a review of the technology of solvent-free polyurethane synthetic leather preparation.In addition to the review,a corresponding overview of the theoretical and experimental advances in solvent-free delayed foaming technology in recent years and a summary of the technology and experience in the preparation of solvent-free polyurethanes are also presented.