The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop rel...The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop reliable monitoring and control strategies. This paper described one approach based on generation function technique with the following two steps. First, a new mechanism for propylene polymerization was proposed by considering the effects of the reactive impurities in the material on the propylene polymerization. Second, a series of equations of population balance for the propylene polymerization in loop reactors were established based on the proposed mechanism. Accordingly, the equations were transformed into the mathematic matrix through the generation function technique to investigate the effects of the reactive impurities on the propylene polymerization. Significant effects of the reactive impurities were analyzed through computational simulation. The results show that the concentration of active centre on catalysts and the polymerization conversion both decrease with the increase of the initial concentration of any reactive impurity; hydrogen concentration decreases with the increase of the initial concentration of ethylene or butylenes, whereas, it increases with the increase of the initial concentration of propadiene; the simulated weight average molecular weight and the molecular weight distribution index of polymer resins both increase with the increase of the initial concentration of ethylene or butylenes. They decrease with the increase of the initial concentration of propadiene.展开更多
基金This work was financially supported by the National Natural Science Foundation of China (No. 20406016)Fujian Petrochemical Company of SINOPEC (No. MS/FJ-08-JS-15-2005-01)
文摘The estimation of the amount of reactive impurities in a loop reactor is of strategic importance to the propylene polymerization industry. It is essential to investigate the level of impurities in order to develop reliable monitoring and control strategies. This paper described one approach based on generation function technique with the following two steps. First, a new mechanism for propylene polymerization was proposed by considering the effects of the reactive impurities in the material on the propylene polymerization. Second, a series of equations of population balance for the propylene polymerization in loop reactors were established based on the proposed mechanism. Accordingly, the equations were transformed into the mathematic matrix through the generation function technique to investigate the effects of the reactive impurities on the propylene polymerization. Significant effects of the reactive impurities were analyzed through computational simulation. The results show that the concentration of active centre on catalysts and the polymerization conversion both decrease with the increase of the initial concentration of any reactive impurity; hydrogen concentration decreases with the increase of the initial concentration of ethylene or butylenes, whereas, it increases with the increase of the initial concentration of propadiene; the simulated weight average molecular weight and the molecular weight distribution index of polymer resins both increase with the increase of the initial concentration of ethylene or butylenes. They decrease with the increase of the initial concentration of propadiene.
