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A multi-sensor-based distributed real-time measurement system for glacier deformation
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作者 DONG Han-chuan LIU Shuang +4 位作者 PANG Li-li TAO Zhi-gang FANG Li-de ZHANG Zhong-hua LI Xiao-ting 《Journal of Mountain Science》 SCIE CSCD 2023年第10期2913-2927,共15页
Glacier disasters occur frequently in alpine regions around the world,but the current conventional geological disaster measurement technology cannot be directly used for glacier disaster measurement.Hence,in this stud... Glacier disasters occur frequently in alpine regions around the world,but the current conventional geological disaster measurement technology cannot be directly used for glacier disaster measurement.Hence,in this study,a distributed multi-sensor measurement system for glacier deformation was established by integrating piezoelectric sensing,coded sensing,attitude sensing technology and wireless communication technology.The traditional Modbus protocol was optimized to solve the problem of data identification confusion of different acquisition nodes.Through indoor wireless transmission,adaptive performance analysis,error measurement experiment and landslide simulation experiment,the performance of the measurement system was analyzed and evaluated.Using unmanned aerial vehicle technology,the reliability and effectiveness of the measurement system were verified on the site of Galongla glacier in southeastern Tibet,China.The results show that the mean absolute percentage errors were only 1.13%and 2.09%for the displacement and temperature,respectively.The distributed glacier deformation real-time measurement system provides a new means for the assessment of the development process of glacier disasters and disaster prevention and mitigation. 展开更多
关键词 Glacier disasters Distributed deformation measurement MULTI-SENSOR real-time LoRa Data adaptive.
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Real-time measurement of high rotational projectile axial acceleration based on 2-axis acceleration sensor
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作者 郭泽荣 吴日恒 李世义 《Journal of Beijing Institute of Technology》 EI CAS 2011年第4期451-455,共5页
The real-time measurement principle of high rotational projectile's angular velocity based on 2-axis acceleration sensor and the axial acceleration measurement error caused by the installation error are discussed.The... The real-time measurement principle of high rotational projectile's angular velocity based on 2-axis acceleration sensor and the axial acceleration measurement error caused by the installation error are discussed.The 2-axis acceleration sensor is applied to measure the high rotational projectile's angular velocity and the measurement value of axial acceleration,the axial acceleration of the high rotational projectile equals the measurement value of axial acceleration subtracting the centrifugal acceleration component,so that the high-accuracy real-time measurement of axial acceleration is realized.The memory test has confirmed the strike tally of the theoretical analysis and the test result.The measurement technique can satisfy the high-accuracy measurement of the high rotational projectile axial acceleration in the self-determination course correction fuze projectile. 展开更多
关键词 course correction fuze high rotational projectile angular velocity axial acceleration real-time signal process
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Micro-failure process and failure mechanism of brittle rock under uniaxial compression using continuous real-time wave velocity measurement 被引量:3
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作者 WU Zhi-jun WANG Zhi-yang +2 位作者 FAN Li-feng WENG Lei LIU Quan-sheng 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第2期556-571,共16页
In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indi... In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indicate that the evolutions of wave velocities became progressively anisotropic under uniaxial loading due to the direction-dependent development of micro-damage.A wave velocity model considering the inner anisotropic crack evolution is proposed to accurately describe the variations of wave velocities during uniaxial compression testing.Based on which,the effective elastic parameters are inferred by a transverse isotropic constitutive model,and the evolutions of the crack density are inversed using a self-consistent damage model.It is found that the propagation of axial cracks dominates the failure process of brittle rock under uniaxial loading and oblique shear cracks develop with the appearance of macrocrack. 展开更多
关键词 elastic wave velocity brittle rock failure uniaxial compression test continuous real-time measurement anisotropic damage evolution theory and modelling
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Real-time measurement of atmospheric parameters for the 127-element adaptive optics system of 1.8-m telescope 被引量:1
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作者 母杰 郑文佳 +1 位作者 李梅 饶长辉 《Chinese Optics Letters》 SCIE EI CAS CSCD 2012年第12期1-4,共4页
A real-time method for measuring atmospheric parameters based on co-processor field-programmable gate array (FPGA) and main processor digital signal processing (DSP) is proposed for ground-based telescopes with ad... A real-time method for measuring atmospheric parameters based on co-processor field-programmable gate array (FPGA) and main processor digital signal processing (DSP) is proposed for ground-based telescopes with adaptive optics (AO) systems. Coherence length, outer scale, average wind speed, and coherence time are estimated according to closed-loop data on the residual slopes and the corrected voltages of AO systems. This letter introduces the principle and architecture design of the proposed method, which is successfully applied in the 127-element AO system of the 1.8-m telescope of Yunnan Astronomical Observatory. The method enables real-time atmospheric observations with the same object and path of the AO system. This method is also applicable to extended objects. 展开更多
关键词 real time real-time measurement of atmospheric parameters for the 127-element adaptive optics system of 1.8-m telescope AO
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Correlation between the rock mass properties and maximum horizontal stress:A case study of overcoring stress measurements
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作者 Peng Li Meifeng Cai +2 位作者 Shengjun Miao Yuan Li Yu Wang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS 2025年第1期39-48,共10页
Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress magnitude.To investigate the correlation between the rock mass properties and maximum horizontal stre... Understanding the mechanical properties of the lithologies is crucial to accurately determine the horizontal stress magnitude.To investigate the correlation between the rock mass properties and maximum horizontal stress,the three-dimensional(3D)stress tensors at 89 measuring points determined using an improved overcoring technique in nine mines in China were adopted,a newly defined characteristic parameter C_(ERP)was proposed as an indicator for evaluating the structural properties of rock masses,and a fuzzy relation matrix was established using the information distribution method.The results indicate that both the vertical stress and horizontal stress exhibit a good linear growth relationship with depth.There is no remarkable correlation between the elastic modulus,Poisson's ratio and depth,and the distribution of data points is scattered and messy.Moreover,there is no obvious relationship between the rock quality designation(RQD)and depth.The maximum horizontal stress σ_(H) is a function of rock properties,showing a certain linear relationship with the C_(ERP)at the same depth.In addition,the overall change trend of σ_(H) determined by the established fuzzy identification method is to increase with the increase of C_(ERP).The fuzzy identification method also demonstrates a relatively detailed local relationship betweenσ_H and C_(ERP),and the predicted curve rises in a fluctuating way,which is in accord well with the measured stress data. 展开更多
关键词 overcoring stress measurements elastic modulus Poisson's ratio rock quality designation maximum horizontal stress fuzzy identification
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Real-time reliability evaluation based on damaged measurement degradation data 被引量:16
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作者 王小林 蒋平 +1 位作者 郭波 程志君 《Journal of Central South University》 SCIE EI CAS 2012年第11期3162-3169,共8页
A method was proposed to evaluate the real-time reliability for a single product based on damaged measurement degradation data.Most researches on degradation analysis often assumed that the measurement process did not... A method was proposed to evaluate the real-time reliability for a single product based on damaged measurement degradation data.Most researches on degradation analysis often assumed that the measurement process did not have any impact on the product's performance.However,in some cases,the measurement process may exert extra stress on products being measured.To obtain trustful results in such a situation,a new degradation model was derived.Then,by fusing the prior information of product and its own on-line degradation data,the real-time reliability was evaluated on the basis of Bayesian formula.To make the proposed method more practical,a procedure based on expectation maximization (EM) algorithm was presented to estimate the unknown parameters.Finally,the performance of the proposed method was illustrated by a simulation study.The results show that ignoring the influence of the damaged measurement process can lead to biased evaluation results,if the damaged measurement process is involved. 展开更多
关键词 degradation analysis damaged measurement real-time reliability expectation maximization algorithm
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The real-time measurement of welding temperature field and closed-loop control of isotherm width 被引量:2
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作者 张华 潘际銮 廖宝剑 《Science China(Technological Sciences)》 SCIE EI CAS 1999年第2期129-135,共7页
The real-time measurement of welding temperature field by colorimetric method is described, and with the data acquired from it closed-loop control system of the parameters of temperature field is developed and tested.... The real-time measurement of welding temperature field by colorimetric method is described, and with the data acquired from it closed-loop control system of the parameters of temperature field is developed and tested. Experimental results prove that it has high measurement speed (time of a field within 0.5 s) and good dynamic response quality. Weld penetration can be controlled satifactorily under unstable welding condition. 展开更多
关键词 welding temperature field thermal CYCLE real-time measurement CLOSED-LOOP control of penetration.
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Development of in-situ Marine Sediment Geo-Acoustic Measurement System with Real-Time and Multi Frequencies (the Second Generation) 被引量:7
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作者 陶春辉 邓显明 +6 位作者 李红星 周建平 金肖兵 傅顺声 Wlkens R. H 顾春华 何拥华 《China Ocean Engineering》 SCIE EI 2009年第4期769-778,共10页
Compared with the laboratory acoustic measurement of sediment samples, the in-situ acoustic measurement in marine sediment is considered more accurate and rehable, because it covers all of the surrounding environment ... Compared with the laboratory acoustic measurement of sediment samples, the in-situ acoustic measurement in marine sediment is considered more accurate and rehable, because it covers all of the surrounding environment factors and avoids the disturbance during the course of sampling and transporting of sediment samples. A new multi-frequency in-situ geoacoustic measurement system (MFIS^AMS) has been developed. The system can provide acoustic vdocity (compressional wave) and attenuation profiles of the uppermost 4 - 8 m sediment in the seafloor. It consists of 8 channels with 12 frequencies (multi-frequencies) and 0.5 - 2 MHz sampling rates. The data collected can be transmiuted in real-time. Associated with inclinometer and altimeter, it can provide the data for depth emendation. Acoustic velocity and attenuation data have been obtained from two in-situ experiments conducted in the Hangzhou Bay. 展开更多
关键词 marine sediment in-situ acoustic measurement acoustic velocity and attenuation
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Influence of variables on the system of real-time measurement of temperature field with ICCD as sensor 被引量:2
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作者 张华 潘际銮 +1 位作者 廖宝剑 虞俊 《Science China(Technological Sciences)》 SCIE EI CAS 1999年第1期21-27,共7页
The influence of all variables, such as materials of a measured object, condition of its surface, distance, and shut off time in the measurement of temperature field by colorimetric method with ICCD as sensor, is anal... The influence of all variables, such as materials of a measured object, condition of its surface, distance, and shut off time in the measurement of temperature field by colorimetric method with ICCD as sensor, is analyzed theoretically and studied by experiments. The obtained results prove the feasibility and reliability of the developed method. 展开更多
关键词 COMPUTER IMAGE two-color temperature measurement ICCD.
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Real-time forward modeling and inversion of logging-while-drilling electromagnetic measurements in horizontal wells 被引量:2
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作者 WANG Lei LIU Yingming +2 位作者 WANG Caizhi FAN Yiren WU Zhenguan 《Petroleum Exploration and Development》 CSCD 2021年第1期159-168,共10页
Based on the pseudo-analytical equation of electromagnetic log for layered formation,an optimal boundary match method is proposed to adaptively truncate the encountered formation structures.An efficient integral metho... Based on the pseudo-analytical equation of electromagnetic log for layered formation,an optimal boundary match method is proposed to adaptively truncate the encountered formation structures.An efficient integral method is put forward to significantly accelerate the convergence of Sommerfeld integral.By asymptotically approximating and subtracting the first reflection/transmission waves from the scattered field,the new Sommerfeld integral method has addressed difficulties encountered by the traditional digital filtering method,such as low computational precision and limited operating range,and realized the acceleration of the computation speed of logging-while-drilling electromagnetic measurements(LWD EM).By making use of the priori information from the offset/pilot wells and interactively adjusting the formation model,the optimum initial guesses of the inversion model is determined in order to predict the nearby formation boundaries.The gradient optimization algorithm is developed and an interactive inversion system for the LWD EM data from the horizontal wells is established.The inverted results of field data demonstrated that the real-time interactive inversion method is capable of providing the accurate boundaries of layers around the wellbore from the LWD EM,and it will benefit the wellbore trajectory optimization and reservoir interpretation. 展开更多
关键词 logging-while-drilling electromagnetic measurement horizontal well real-time forward modeling interactive inversion bed boundary
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Real-Time Black Carbon Emissions from Light-Duty Passenger Vehicles Using a Portable Emissions Measurement System 被引量:1
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作者 Xuan Zheng Liqiang He +4 位作者 Xiaoyi He Shaojun Zhang Yihuan Cao Jiming Hao Ye Wu 《Engineering》 SCIE EI CAS 2022年第9期73-81,共9页
Black carbon(BC)is considered the second largest anthropogenic climate forcer,but the radiative effects of BC are highly correlated with its combustion sources.On-road vehicles are an important source of anthropogenic... Black carbon(BC)is considered the second largest anthropogenic climate forcer,but the radiative effects of BC are highly correlated with its combustion sources.On-road vehicles are an important source of anthropogenic BC.However,there are major uncertainties in the estimates of the BC emissions from on-road light-duty passenger vehicles(LDPVs),and results obtained with the portable emissions measurement system(PEMS)method are particularly lacking.We developed a PEMS platform and evaluated the on-road BC emissions from ten in-use LDPVs.We demonstrated that the BC emission factors(EFs)of gasoline direction injection(GDI)engine vehicles range from 1.10 to 1.56 mg.km^(-1),which are higher than the EFs of port fuel injection(PFI)engine vehicles(0.10–0.17 mg.km^(-1))by a factor of 11.The BC emissions during the cold-start phase contributed 2%–33%to the total emissions.A strong correlation(R^(2)=0.70)was observed between the relative BC EFs and average vehicle speed,indicating that traffic congestion alleviation could effectively mitigate BC emissions.Moreover,BC and particle number(PN)emissions were linearly correlated(R^(2)=0.90),and compared to PFI engine vehicles,the instantaneous PN-to-BC emission rates of GDI engine vehicles were less sensitive to vehicle specific power-to-velocity(VSPV)increase in all speed ranges. 展开更多
关键词 Black carbon Light-duty gasoline vehicles Portable emissions measurement system real-time emissions
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Research on the Real-Time Phase Jump Process Method for Plasma Electron Density Measurement in HL-2A Tokamak 被引量:2
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作者 丁宝钢 陈超 +3 位作者 王闻迪 吴彤宇 周艳 阴泽杰 《Plasma Science and Technology》 SCIE EI CAS CSCD 2015年第10期837-841,共5页
In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference sig... In the real-time plasma electron density measurement using far infrared (FIR) laser interferometry, the plasma electron density can be calculated by measuring the real time phase difference between the reference signal and the probe signal. A novel Real-time Phase Jump Process (RPJP) method is applied to the HL-2A tokamak. With this method, the phase difference 1 precision is up to 1/3600 fringe (1 fringe is equal to a phase shift of 2π), and the dynamic measure- ment range is extensible 65536 fringes. The time resolution of the phase difference is 80 ns, while the feedback delay is 180 its. 展开更多
关键词 RPJP FPGA FRINGE real-time electron density
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Data network traffic analysis and optimization strategy of real-time power grid dynamic monitoring system for wide-frequency measurements 被引量:4
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作者 Jinsong Li Hao Liu +2 位作者 Wenzhuo Li Tianshu Bi Mingyang Zhao 《Global Energy Interconnection》 EI CAS CSCD 2022年第2期131-142,共12页
The application and development of a wide-area measurement system(WAMS)has enabled many applications and led to several requirements based on dynamic measurement data.Such data are transmitted as big data information ... The application and development of a wide-area measurement system(WAMS)has enabled many applications and led to several requirements based on dynamic measurement data.Such data are transmitted as big data information flow.To ensure effective transmission of wide-frequency electrical information by the communication protocol of a WAMS,this study performs real-time traffic monitoring and analysis of the data network of a power information system,and establishes corresponding network optimization strategies to solve existing transmission problems.This study utilizes the traffic analysis results obtained using the current real-time dynamic monitoring system to design an optimization strategy,covering the optimization in three progressive levels:the underlying communication protocol,source data,and transmission process.Optimization of the system structure and scheduling optimization of data information are validated to be feasible and practical via tests. 展开更多
关键词 Power system Data network Wide-frequency information real-time system Traffic analysis Optimization strategy
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A non-contact real-time measurement of lamp dimension based on machine vision 被引量:5
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作者 宋丽梅 王朋强 +4 位作者 常玉兰 李晓捷 习江涛 郭庆华 李秉男 《Optoelectronics Letters》 EI 2015年第2期145-148,共4页
In order to realize the online measurement of lamp dimension,the bulb image dimension measurement based on vision(BIDMV)is proposed.The image of lamp is obtained by camera.After image processing,such as Otsu algorithm... In order to realize the online measurement of lamp dimension,the bulb image dimension measurement based on vision(BIDMV)is proposed.The image of lamp is obtained by camera.After image processing,such as Otsu algorithm,median filter,ellipse fitting and envelope rectangle fitting,the dimension of lamp can be calculated.Based on this method,a non-contact real-time measurement system of the lamp’s dimension is developed.The precision of the proposed method is 0.07 mm,and it can satisfy the tolerance of the National Standard GB15766.1-2008.The experiment results show that the proposed method has a faster measuring speed and a higher precision compared with other measurement methods. 展开更多
关键词 Image processing Median filters Time measurement
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Real-time measurement of temperature field with ICCD as sensor (II)──Principle and method for optimum design of wavelength 被引量:1
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作者 张华 潘际銮 廖宝剑 《Science China(Technological Sciences)》 SCIE EI CAS 1998年第5期496-501,共6页
The colorimetric method for real-time measurement of temperature field using ICCD as sensor was developed. In order to ensure the accuracy and sensitivity, the relationship between the ratio response of two-color imag... The colorimetric method for real-time measurement of temperature field using ICCD as sensor was developed. In order to ensure the accuracy and sensitivity, the relationship between the ratio response of two-color images and radiant property of body, transmission property of filter, spectral response of ICCD is discussed. The analysis is based on computer calculation of the established mathematical model. On the basis of the analysis, optimum wavelengths are obtained for a given sensor system. Experimental work was carried out to check the correctness of the theoretical results. The method is useful for general purpose of study and design of the developed system. 展开更多
关键词 two-color measurING TEMPERATURE TEMPERATURE FIELD ICCD image processing.
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Field instrumentation for real-time measurement of soil-water characteristic curve 被引量:1
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作者 Abdul Halim Hamdany Yuanjie Shen +3 位作者 Alfrendo Satyanaga Harianto Rahardjo Tsen-Tieng Daryl Lee Xuefeng Nong 《International Soil and Water Conservation Research》 SCIE CSCD 2022年第4期586-596,共11页
Suction measurement has a vital role in unsaturated soil analysis.However,measuring soil suction remains a challenging task due to a number of issues such as the limited range of suction measurement,cavitation,or long... Suction measurement has a vital role in unsaturated soil analysis.However,measuring soil suction remains a challenging task due to a number of issues such as the limited range of suction measurement,cavitation,or long equilibrium time.It is even more challenging when the suction measurement is to be carried on the field.Hence,the development of a new suction measurement device which is able to measure high suction range for a long duration without tedious maintenance and yet portable enough for site measurement is required.In this study,a new sensor which is referred to as NTU Osmotic Tensiometer was developed along with the method to correct for decay and temperature.The NTU osmotic tensiometer is based on polymer swelling capacity in order to measure in-situ soil suction in real time for a very long duration.It requires minimum maintenance as the polymer-based sensor is not affected by the cavitation phenomenon.However,correction for decay and temperature is of paramount importance and therefore explained in this paper.Verification of the NTU osmotic tensiometer was carried out by comparing the field measurement results from the NTU osmotic tensiometer and the small tip tensiometer.The performance of the NTU osmotic tensiometer was found to be comparable with that of the small tip tensiometer,but the NTU osmotic tensiometer is able to measure more than 100 kPa soil suction.Therefore,it is possible to obtain the field soil-water characteristic curve by combining the measured in-situ soil suction from the NTU osmotic tensiometer with the measured in-situ water content from the moisture sensor as illustrated in the paper. 展开更多
关键词 Suction measurement TENSIOMETER Moisture sensor SWCC Field measurement
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The Real-Time,High Precision Phase Difference Measurement of Electron Density in HL-2A Tokamak 被引量:1
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作者 丁宝钢 吴彤宇 +2 位作者 李世平 周艳 阴泽杰 《Plasma Science and Technology》 SCIE EI CAS CSCD 2015年第9期797-801,共5页
This paper introduces a real-time high precision measurement of phase difference based on Field Programmable Gate Array(FPGA) technology,which has been successfully applied to laser grating interference measurement ... This paper introduces a real-time high precision measurement of phase difference based on Field Programmable Gate Array(FPGA) technology,which has been successfully applied to laser grating interference measurement and real-time feedback of plasma electron density in HL-2A tokamak.It can track the changes of electron density while setting the starting point of the density curve to zero.In a laboratory test,the measuring accuracy of phase difference is less than 0.1°,the time resolution is 80 ns,and the feedback delay is 180 μs. 展开更多
关键词 phase difference HL-2A FPGA real-time high precision
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Real-Time Liquid Evaporation Rate Measurement Based on a Microchip Laser Feedback Interferometer 被引量:1
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作者 TAN Yi-Dong ZHANG Song +2 位作者 REN Zhou ZHANG Yong-Qin ZHANG Shu-Lian 《Chinese Physics Letters》 SCIE CAS CSCD 2013年第12期46-48,共3页
We present a novel scheme to realize the direct real-time measurement of liquid evaporation rate and nanometer order liquid level monitoring.It is based on the phase measurement technology of Nd:YAG microchip laser fr... We present a novel scheme to realize the direct real-time measurement of liquid evaporation rate and nanometer order liquid level monitoring.It is based on the phase measurement technology of Nd:YAG microchip laser frequency-shifted feedback,which not only has a high resolution and precision but also ultrahigh sensitivity.The evaporation rates of four different transparent liquids and hot water are measured.Experimental results indicate the ease and convenience of measuring and present promising application prospects in non-cooperative target measurement. 展开更多
关键词 measurement MICROCHIP TRANSPARENT
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Development of sensor system for real-time measurement of droplet deposition of agricultural sprayers 被引量:1
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作者 Longlong Li Ruirui Zhang +7 位作者 Liping Chen Tongchuan Yi Gang Xu Daxuan Xue Qing Tang Linhuan Zhang Andrew John Hewitt Yining An 《International Journal of Agricultural and Biological Engineering》 SCIE EI CAS 2021年第5期19-26,共8页
During the chemical application process,droplet deposition on a target is an important reference indicator for evaluating the spraying technique and its performance.In order to quickly obtain deposition results in the... During the chemical application process,droplet deposition on a target is an important reference indicator for evaluating the spraying technique and its performance.In order to quickly obtain deposition results in the field,this study proposed a novel system based on surface humidity sensors.The basic principle is to convert the measured physical quantity change into a capacitance change,thereby realizing the physical quantity to electrical signal conversion.An Android application for mobile terminal and the corresponding coordinator were developed,which allowed operators to control multiple sensors simultaneously through the Bluetooth.The soluble tracer detected by spectrophotometer was used to calibrate the system.The obtained results indicated a good correlation between deposition volume and voltage increment output from the newly developed system(R2 of the six nozzles with Dv0.5 ranging from 107.28μm to 396.20μm were 0.8674-0.9729),and a power regression model based on the least squares technique(R2=0.8022)was developed.In the field test,the system exhibited an optimal performance in predicting the deposition volume.Compared with the conventional method of measuring tracer concentration,the deviation was less than 10%.In addition,the system exhibited good fitting curve of the deposition distribution with droplet number results measured by the water sensitive paper method. 展开更多
关键词 deposition measurement agricultural sprayer droplets intelligent sensor
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Protonated acetone ion chemical ionization time-of-flight mass spectrometry for real-time measurement of atmospheric ammonia 被引量:2
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作者 Fengshuo Dong Hang Li +2 位作者 Bing Liu Ruidong Liu Keyong Hou 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第4期66-74,共9页
Ammonia(NH_(3))is ubiquitous in the atmosphere,it can affect the formation of secondary aerosols and particulate matter,and cause soil eutrophication through sedimentation.Currently,the use of radioactive primary reag... Ammonia(NH_(3))is ubiquitous in the atmosphere,it can affect the formation of secondary aerosols and particulate matter,and cause soil eutrophication through sedimentation.Currently,the use of radioactive primary reagent ion source and the humidity interference on the sensitivity and stability are the two major issues faced by chemical ionization mass spectrometer(CIMS)in the analysis of atmospheric ammonia.In this work,a vacuum ultraviolet(VUV)Kr lamp was used to replace the radioactive source,and acetone was ionized under atmospheric pressure to obtain protonated acetone reagent ions to ionize ammonia.The ionization source is designed as a separated three-zone structure,and even 90 vol.%high-humidity samples can still be directly analyzed with a sensitivity of sub-ppbv.A signal normalization processing method was designed,and with this new method,the quantitative relative standard deviation(RSD)of the instrument was decreased from 17.5%to9.1%,and the coefficient of determination was increased from 0.8340 to 0.9856.The humidity correction parameters of the instrument were calculated from different humidity,and the ammonia concentrations obtained under different humidity were converted to its concentration under zero humidity condition with these correction parameters.The analytical time for a single sample is only 60 sec,and the limit of detection(LOD)was 8.59 pptv(signalto-noise ratio S/N=3).The ambient measurement made in Qingdao,China,in January 2021 with this newly designed CIMS,showed that the concentration of ammonia ranged from 1 to 130 ppbv. 展开更多
关键词 Ammonia(NH_(3)) Chemical ionization mass spectrometer(CIMS) Vacuum ultraviolet(VUV)lamp Single photon ionization real-time analysis
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