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基于Realizable k-ε湍流模型的氨气泄漏数值模拟研究 被引量:19
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作者 孙恩吉 李红果 王敏 《中国安全生产科学技术》 CAS CSCD 北大核心 2017年第2期114-118,共5页
针对液氨泄漏事故,为了分析不同泄漏点、不同排风条件下氨气的运移规律,以便合理设置应急处置装备、采取有效措施,基于Realizable k-ε的氨气泄漏有限元数值模拟分析方法,计算了液氨泄漏质量,模拟分析了增加排风口、不同液氨泄漏口及不... 针对液氨泄漏事故,为了分析不同泄漏点、不同排风条件下氨气的运移规律,以便合理设置应急处置装备、采取有效措施,基于Realizable k-ε的氨气泄漏有限元数值模拟分析方法,计算了液氨泄漏质量,模拟分析了增加排风口、不同液氨泄漏口及不同液氨泄漏量的氨气扩散规律及浓度变化情况。模拟结果表明:对流排风口位置对于泄漏氨气浓度影响较大,泄漏口位置对泄漏氨气扩散影响不显著;氨气泄漏量的增加使得泄漏口垂直方向氨气浓度显著增加。 展开更多
关键词 realizable k-ε 湍流模型 氨气 泄漏 数值模拟
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应用Realizable k-ε湍流模型的振荡水翼绕流数值模拟研究(英文) 被引量:7
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作者 刘臻 史宏达 刘芸 《哈尔滨工程大学学报》 EI CAS CSCD 北大核心 2008年第6期628-634,共7页
采用计算流体力学软件Fluent提供的Realizable k-ε湍流模型计算了振荡水翼的绕流问题,利用有限体积法求解雷诺平均N-S方程,空间离散应用二阶迎风格式,速度—压力耦合格式为SIMPLEC格式;为了验证该数值格式及湍流模型,计算了文献中的算... 采用计算流体力学软件Fluent提供的Realizable k-ε湍流模型计算了振荡水翼的绕流问题,利用有限体积法求解雷诺平均N-S方程,空间离散应用二阶迎风格式,速度—压力耦合格式为SIMPLEC格式;为了验证该数值格式及湍流模型,计算了文献中的算例并做了对比;考察了不同参数对振荡水翼周围流场及受力特征的影响,研究表明在一定水翼攻角条件下,水翼振幅及振荡频率均对振荡水翼的涡结构产生发展及其受力特征具有明显的影响. 展开更多
关键词 振荡水翼 数值模拟 FLUENT realizable k-ε湍流模型
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障碍物对火焰结构影响的Realizable k-ε模型数值模拟 被引量:1
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作者 徐进生 李登科 +1 位作者 胡军然 刘杰 《工业安全与环保》 北大核心 2014年第4期40-42,共3页
在管道内设置长方体障碍物,对火焰翻越障碍物的情形进行数值模拟研究,分析火焰褶皱现象。基于可实现k-ε模型(Realizable k-εmodel)和EDC(涡流耗散概念模型),建立湍流加速火焰现象的数值模型,实现管道火焰流场的可视化,研究障碍物对火... 在管道内设置长方体障碍物,对火焰翻越障碍物的情形进行数值模拟研究,分析火焰褶皱现象。基于可实现k-ε模型(Realizable k-εmodel)和EDC(涡流耗散概念模型),建立湍流加速火焰现象的数值模型,实现管道火焰流场的可视化,研究障碍物对火焰结构、火焰流场的加速过程,分析了导致火焰发生褶皱的机理,得出火焰在翻越障碍物后会形成两个相反方向的涡流。 展开更多
关键词 火焰结构 障碍物 数值模拟 涡流 可实现k-ε模型
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基于24Model-D-ISM的地铁站火灾疏散影响因素研究
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作者 孙世梅 张家严 《中国安全科学学报》 CAS CSCD 北大核心 2024年第4期153-159,共7页
为预防地铁站火灾事故,深入了解地铁站火灾人员疏散影响因素间的内在联系与层次结构,基于第6版“2-4”模型(24Model)分析63起地铁站火灾疏散事故,充分考虑各个因素之间的交互作用,提取19个影响地铁站人员疏散的关键因素,建立地铁站火灾... 为预防地铁站火灾事故,深入了解地铁站火灾人员疏散影响因素间的内在联系与层次结构,基于第6版“2-4”模型(24Model)分析63起地铁站火灾疏散事故,充分考虑各个因素之间的交互作用,提取19个影响地铁站人员疏散的关键因素,建立地铁站火灾人员疏散影响因素指标体系;采用算子客观赋权法(C-OWA)改进决策试验与评价实验法(DEMATEL),确定地铁站火灾人员疏散的重要影响因素;在此基础上,采用解释结构模型(ISM)分析各个因素间的层次结构及相互作用路径,构建地铁站火灾人员疏散影响因素的多级递阶结构模型。研究结果表明:疏散引导、恐慌从众行为、人员拥挤为地铁站火灾人员疏散的关键影响因素;地铁站火灾人员疏散受表层因素、中间层因素、深层因素共同作用的影响,其中,疏散教育与培训、设施维护与检查、疏散预案等因素是根源影响因素,重视根源影响因素的改善有利于从本质上预防和控制事故的发生。 展开更多
关键词 “2-4”模型(24model) 决策试验与评价实验法(DEMATEL) 解释结构模型(ISM) 地铁站 火灾疏散 影响因素
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修正Realizable k-ε模型在高压淹没水射流中的应用 被引量:12
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作者 余健翔 刘剑 +2 位作者 王观石 罗嗣海 汪杰 《科学技术与工程》 北大核心 2021年第12期5024-5030,共7页
淹没水射流在工程中具有广泛的应用,空化是高压淹没水射流的基本特征。现有的空化模型仍不完善,对各种工况普适性较差,数值模拟仍存在较大误差。为了提高数值模拟对淹没水射流的预测能力,采用Realizable k-ε模型模拟淹没水射流,使用修... 淹没水射流在工程中具有广泛的应用,空化是高压淹没水射流的基本特征。现有的空化模型仍不完善,对各种工况普适性较差,数值模拟仍存在较大误差。为了提高数值模拟对淹没水射流的预测能力,采用Realizable k-ε模型模拟淹没水射流,使用修正的模型常数并结合滞止压力实验验证,研究5~40 MPa射流压力下的修正模型常数。结果表明,对模型常数进行修正可有效地提高模型对0~70倍直径射程范围内淹没水射流轴心压力的预测能力,使误差降低至10%以内,可见使用修正常数的Realizable k-ε模型模拟高压淹没水射流是一种简便且准确的方法。 展开更多
关键词 淹没水射流 数值模拟 修正模型 realizable k-ε模型
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静水条件下倾斜射流的Realizable k-ε和RNG k-ε数值模拟研究 被引量:2
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作者 王卓 《人民珠江》 2017年第5期53-57,共5页
进行了静水条件下倾斜射流的实验与数值模拟,分析了不同工况下倾斜射流的运动轨迹、顶点高度、横截面宽度及浓度分布情况与规律。重点验证了Realizable k-ε和RNG k-ε两个湍流模型在该问题模拟中的适用性,结果证明这两个模型都可以较... 进行了静水条件下倾斜射流的实验与数值模拟,分析了不同工况下倾斜射流的运动轨迹、顶点高度、横截面宽度及浓度分布情况与规律。重点验证了Realizable k-ε和RNG k-ε两个湍流模型在该问题模拟中的适用性,结果证明这两个模型都可以较准确地计算出静水条件下倾斜射流的运动与稀释情况,但前者相对后者更为精确。 展开更多
关键词 静水条件 倾斜射流 realizable k-ε模型 RNG k-ε模型
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Realization of the Infinite-Dimensional 3-Algebras in the Calogero-Moser Model
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作者 杨燕新 姚少魁 +1 位作者 张春红 赵伟忠 《Chinese Physics Letters》 SCIE CAS CSCD 2015年第4期5-8,共4页
We investigate realization of the infinite-dimensional 3-algebras in the classical Calogero-Moser model. In terms of the Lax matrix of the Calogero Moser model and the Nambu 3-brackets in which the variables are the c... We investigate realization of the infinite-dimensional 3-algebras in the classical Calogero-Moser model. In terms of the Lax matrix of the Calogero Moser model and the Nambu 3-brackets in which the variables are the coordinates qi, and canonically conjugate momenta pi and the coupling parameter β are an extra auxiliary phase-space parameter, we present the realization of the Virasoro-Witt, w∞ and SDi f f (T2) 3-algebras, respectively. 展开更多
关键词 realization of the Infinite-Dimensional 3-Algebras in the Calogero-Moser model
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Minimal Realization of Linear Graph Models for Multi-physics Systems
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作者 Clarence W.DE SILVA 《Instrumentation》 2019年第4期72-84,共13页
An engineering system may consist of several different types of components,belonging to such physical"domains"as mechanical,electrical,fluid,and thermal.It is termed a multi-domain(or multi-physics)system.Th... An engineering system may consist of several different types of components,belonging to such physical"domains"as mechanical,electrical,fluid,and thermal.It is termed a multi-domain(or multi-physics)system.The present paper concerns the use of linear graphs(LGs)to generate a minimal model for a multi-physics system.A state-space model has to be a minimal realization.Specifically,the number of state variables in the model should be the minimum number that can completely represent the dynamic state of the system.This choice is not straightforward.Initially,state variables are assigned to all the energy-storage elements of the system.However,some of the energy storage elements may not be independent,and then some of the chosen state variables will be redundant.An approach is presented in the paper,with illustrative examples in the mixed fluid-mechanical domains,to illustrate a way to recognize dependent energy storage elements and thereby obtain a minimal state-space model.System analysis in the frequency domain is known to be more convenient than in the time domain,mainly because the relevant operations are algebraic rather than differential.For achieving this objective,the state space model has to be converted into a transfer function.The direct way is to first convert the state-space model into the input-output differential equation,and then substitute the time derivative by the Laplace variable.This approach is shown in the paper.The same result can be obtained through the transfer function linear graph(TF LG)of the system.In a multi-physics system,first the physical domains have to be converted into an equivalent single domain(preferably,the output domain of the system),when using the method of TFLG.This procedure is illustrated as well,in the present paper. 展开更多
关键词 Multi-physics modelling Mechatronic Systems Linear Graphs Dependent Energy Storage Elements Redundant State Variables Minimal State-space realization Domain Conversion Equivalent models Frequency-domain model
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基于Realizable湍流模型的弯管流动模拟分析 被引量:9
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作者 纪宏超 李耀刚 《机械工程与自动化》 2013年第4期46-47,共2页
以工程实际中广泛应用的管道为基础,针对管道输送中弯管的薄弱环节,基于Fluent可实现湍流模型,分别采用定常与非定常模拟的方法,建立油水两相流流场的数学模型,研究弯管油水两相流动的速度、压力、流线部分的特性。研究结果表明定常与... 以工程实际中广泛应用的管道为基础,针对管道输送中弯管的薄弱环节,基于Fluent可实现湍流模型,分别采用定常与非定常模拟的方法,建立油水两相流流场的数学模型,研究弯管油水两相流动的速度、压力、流线部分的特性。研究结果表明定常与非定常数值模拟弯管两项流动都具有较好的模拟效果。 展开更多
关键词 弯管 模拟分析 湍流模型 realizable
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Parameter Extraction for 2-π Equivalent Circuit Model of RF CMOS Spiral Inductors 被引量:1
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作者 高巍 余志平 《Journal of Semiconductors》 EI CAS CSCD 北大核心 2006年第4期667-673,共7页
A novel parameter extraction method with rational functions is presented for the 2-πequivalent circuit model of RF CMOS spiral inductors. The final S-parameters simulated by the circuit model closely match experiment... A novel parameter extraction method with rational functions is presented for the 2-πequivalent circuit model of RF CMOS spiral inductors. The final S-parameters simulated by the circuit model closely match experimental data. The extraction strategy is straightforward and can be easily implemented as a CAD tool to model spiral inductors. The resulting circuit models will be very useful for RF circuit designers. 展开更多
关键词 2-π compact model parameters extraction RF CMOS spiral inductors
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A hybrid Lagrangian-Eulerian numerical model for sea-ice dynamics 被引量:3
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作者 JI Shunying LI Hai +2 位作者 SHEN Hung Tao WANG Ruixue YUE Qianjin 《Acta Oceanologica Sinica》 SCIE CAS CSCD 2007年第5期12-24,共13页
A hybrid Lagrangian - Eulerian (HLE) method is developed for sea ice dynamics, which combines the high computational efficiency of finite difference method (FDM) with the high numerical accuracy of smoothed partic... A hybrid Lagrangian - Eulerian (HLE) method is developed for sea ice dynamics, which combines the high computational efficiency of finite difference method (FDM) with the high numerical accuracy of smoothed particle hydrodynamics (SPH). In this HLE model, the sea ice cover is represented by a group of Lagrangian ice particles with their own thicknesses and concentrations. These ice variables are interpolated to the Eularian gird nodes using the Gaussian interpolation function. The FDM is used to determine the ice velocities at Eulerian grid nodes, and the velocities of Lagrangian ice particles are interpolated from these grid velocities with the Gaussian function also. The thicknesses and concentrations of ice particles are determined based on their new locations. With the HLE numerical model, the ice ridging process in a rectangular basin is simulated, and the simulated results are validated with the analytical solution. This method is also applied to the simulation of sea ice dynamics in a vortex wind field. At last, this HLE model is applied to the Bohai Sea, and the simulated concentration, thickness and velocity match the satellite images and the field observed data well. 展开更多
关键词 hybrid Lagrangian - Eulerian model sea-ice dynamics numerical model
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基于标准和Realizable k~ε湍流模型的阶梯式溢洪道流的数值模拟 被引量:21
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作者 闫晓惠 陈新 李华煜 《水利科技与经济》 2015年第10期29-31,共3页
采用Realizable k~ε湍流模型并结合VOF自由面追踪技术对阶梯式溢洪道流进行了数值模拟。计算所得水力特性与文献中的实验观察结论基本一致,验证了该模拟方法在分析阶梯式溢洪道流中的有效性。分析了3个不同阶梯处的竖直表面压强分布情... 采用Realizable k~ε湍流模型并结合VOF自由面追踪技术对阶梯式溢洪道流进行了数值模拟。计算所得水力特性与文献中的实验观察结论基本一致,验证了该模拟方法在分析阶梯式溢洪道流中的有效性。分析了3个不同阶梯处的竖直表面压强分布情况,对标准和Realizable k~ε这两种湍流模型的预测结果进行了比较,结果表明Realizable k~ε湍流模型在该问题的分析中优于标准k~ε湍流模型。 展开更多
关键词 realizable k~ε 湍流模型 阶梯式溢洪道 数值模拟
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Analysis of axial strain in one-dimensional loading by different models 被引量:2
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作者 G.Aryanpour M.Farzaneh 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第5期745-753,共9页
Different phenomenological equations based on plasticity, primary creep (as a viscoplastic mechanism), secondary creep (as another viscoplastic mechanism) and different combinations of these equations are presente... Different phenomenological equations based on plasticity, primary creep (as a viscoplastic mechanism), secondary creep (as another viscoplastic mechanism) and different combinations of these equations are presented and used to describe the material inelastic deformation in uniaxial test. Agreement of the models with experimental results and with the theoretical concepts and physical realities is the criterion of choosing the most appropriate formulation for uniaxial test. A model is thus proposed in which plastic deformation, primary creep and secondary creep contribute to the inelastic deformation. However, it is believed that the hardening parameter is composed of plastic and primary creep parts. Accordingly, the axial plastic strain in a uniaxial test may no longer be considered as the hardening parameter. Therefore, a proportionality concept is proposed to calculate the plastic contribution of deformation. 展开更多
关键词 modelling Uniaxial test Plastic - Creep Strain hardening - Proportionality
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Analytical models for the penetration of semi-infinite targets by rigid,deformable and erosive long rods 被引量:15
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作者 He-Ming Wen Bin Lan 《Acta Mechanica Sinica》 SCIE EI CAS CSCD 2010年第4期573-583,共11页
A theoretical study is presented herein on the pen- etration of a semi-infinite target by a spherical-headed long rod for Yp 〉 S, where Yp is the penetrator strength and S is the static target resistance. For Yp 〉 S... A theoretical study is presented herein on the pen- etration of a semi-infinite target by a spherical-headed long rod for Yp 〉 S, where Yp is the penetrator strength and S is the static target resistance. For Yp 〉 S, depending upon initial impact velocity, there exist three types of penetration, namely, penetration by a rigid long rod, penetration by a deforming non-erosive long rod and penetration by an erosive long rod. If the impact velocity of the penetrator is higher than the hydrodynamic velocity (VH), it will penetrate the target in an erosive mode; if the impact velocity lies between the hydrodynamic velocity (VH) and the rigid body velocity (VR), it will penetrate the target in a deformable mode; if the impact velocity is less than the rigid body velocity (VR), it will penetrate the target in a rigid mode. The critical conditions for the transition among these three penetration modes are proposed. It is demonstrated that the present model predictions correlate well with the experimental observations in terms of depth of penetration (DOP) and the critical transition conditions. 展开更多
关键词 Long rod Semi-infinite target - Penetration Alekseevskii-Tate model Rigid body velocity - Hydrodynamic velocity
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Periodic Packing Mode for Trickle-Bed Reactors: Experiments and Modeling 被引量:2
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作者 刘国柱 米镇涛 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2004年第3期372-378,共7页
A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determini... A periodic packing mode of trickle-bed reactor (TBR) for the gas limited reaction was proposed. Hy-drogenation of 2-ethylanthraquinone over Pd/Al2O3 in a laboratory-scale TBR was taken as a test reaction for determining whether the periodic packing mode is advantageous. The effects of operating conditions and packing type on TBR performance were experimentally examined to demonstrate the cause-effect relationships. A mathe-matic model of TBR considering axial dispersion and fractional wetting was developed to quantitatively illuminate the reason of performance enhancement. 展开更多
关键词 trickle-bed reactor periodic packing mode modelING HYDROGENATION 2- ethylanthraquinone
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Numerical analysis of the failure process of soil-rock mixtures through computed tomography and PFC3D models 被引量:19
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作者 Yang Ju Huafei Sun +2 位作者 Mingxu Xing Xiaofei Wang Jiangtao Zheng 《International Journal of Coal Science & Technology》 EI 2018年第2期126-141,共16页
Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurat... Soil-rock mixture (SRM) is a unique type of geomaterial characterized by a heterogeneous composition and a complicated structure. It is intractable for the continuum-based soil and rock mechanics theories to accurately characterize and predict the SRM's mechanical properties. This study reports a novel numerical method incorporating microfocus computed tomography and PFC3D codes to probe the deformation and failure processes of SRM. The three-dimensional (3D) PFC models that represent the SRM's complex structures were built. By simulating the entire failure process in PFC3D, the SRM's strength, elastic modulus and crack growth were obtained. The influence of rock ratios on the SRM's strength, deformation and failure processes, as well as its internal mesoscale mechanism, were analyzed. By comparing simulation results with experimental data, it was verified that the 3D PFC models were in good agreement with SRM's real structure and the SRM's compression process, deformation and failure patterns; its intrinsic mesomechanism can be effectively analyzed based on such 3D PFC models. 展开更多
关键词 Soil-rock mixture (SRM) - PFC3D model Three-dimensional structure Microfocus computed tomography (μCT) Failure mechanism Crack growth
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Roll System and Stock's Multi-parameter Coupling Dynamic Modeling Based on the Shape Control of Steel Strip 被引量:3
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作者 Yang ZHANG Yan PENG +1 位作者 Jianliang SUN Yong ZANG 《Chinese Journal of Mechanical Engineering》 SCIE EI CAS CSCD 2017年第3期614-624,共11页
The existence of rolling deformation area in the rolling mill system is the main characteristic which dis- tinguishes the other machinery. In order to analyze the dynamic property of roll system's flexural deformatio... The existence of rolling deformation area in the rolling mill system is the main characteristic which dis- tinguishes the other machinery. In order to analyze the dynamic property of roll system's flexural deformation, it is necessary to consider the transverse periodic movement of stock in the rolling deformation area which is caused by the flexural deformation movement of roll system simul- taneously. Therefore, the displacement field of roll system and flow of metal in the deformation area is described by kinematic analysis in the dynamic system. Through intro- ducing the lateral displacement function of metal in the deformation area, the dynamic variation of per unit width rolling force can be determined at the same time. Then the coupling law caused by the co-effect of rigid movement and flexural deformation of the system structural elements is determined. Furthermore, a multi-parameter coupling dynamic model of the roll system and stock is established by the principle of virtual work. More explicitly, the cou- pled motion modal analysis was made for the roll system. Meanwhile, the analytical solutions for the flexural defor- mation movement's mode shape functions of rolls are discussed. In addition, the dynamic characteristic of the lateral flow of metal in the rolling deformation area has been analyzed at the same time. The establishment ofdynamic lateral displacement function of metal in the deformation area makes the foundation for analyzing the coupling law between roll system and rolling deformation area, and provides a theoretical basis for the realization of the dynamic shape control of steel strip. 展开更多
关键词 Roll system Rolling deformation area Coupling dynamic model Mode shape function - Lateraldisplacement function
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Investment in deepwater oil and gas exploration projects:a multi-factor analysis with a real options model 被引量:5
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作者 Xin-Hua Qiu Zhen Wang Qing Xue 《Petroleum Science》 SCIE CAS CSCD 2015年第3期525-533,共9页
Deepwater oil and gas projects embody high risks from geology and engineering aspects, which exert substantial influence on project valuation. But the uncer- tainties may be converted to additional value to the projec... Deepwater oil and gas projects embody high risks from geology and engineering aspects, which exert substantial influence on project valuation. But the uncer- tainties may be converted to additional value to the projects in the case of flexible management. Given the flexibility of project management, this paper extends the classical real options model to a multi-factor model which contains oil price, geology, and engineering uncertainties. It then gives an application example of the new model to evaluate deepwater oil and gas projects with a numerical analytical method. Compared with other methods and models, this multi-factor real options model contains more project information. It reflects the potential value deriving not only from oil price variation but also from geology and engi- neering uncertainties, which provides more accurate and reliable valuation information for decision makers. 展开更多
关键词 Investment decision - Real options Multi-factor model Option pricing - Deepwater oil and gas
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Modelling of Quasi 3-D Groundwater Flow and Studying of Equivalent Drainage Boundary in Beihai Peninsula,Guangxi 被引量:2
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作者 Chen Chongxi Lin Min Li GuominChina University of Geosciences , Wuhan 430074Jiang Jianmin Ye Shanshi Wu NaidongGeology Bureau of Guangxi Autonomous Region , Naming 530023 《Journal of Earth Science》 SCIE CAS CSCD 1992年第1期109-119,共11页
This paper describes a quasi 3-D finite element model of the groundwater flow in two -aquifer system which is constructed from a sequence of aquifer flow equations coupled by leakage terms representing flow through th... This paper describes a quasi 3-D finite element model of the groundwater flow in two -aquifer system which is constructed from a sequence of aquifer flow equations coupled by leakage terms representing flow through the aquitard . It is applied to evaluate the maximum rate of groundwater resources exploited from the coastal aquifer without seawater intrusion . The main task in this model is to determine the drainage boundary of the aquifer extending under the sea . The information of the boundary can be obtained from the fluctuations of the groundwater level caused by sea-tide fluctuations . A new idea, Equivalent Drainage Boundary (EDB), is proposed and the corresponding methods , determining the EDB, are developed with tidal fluctuations data observed in boreholes . The quasi 3-D model and the methods determining EDB have been applied to the aquifer system of Beihai peninsula , Guangxi Autonomous Region of China for calculating the available groundwater resources . 展开更多
关键词 quad 3 - D model coastal aquifer Equivalent Drainage Boundary available groundwater resources Beihai peninsula .
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Kinetic Modeling the Formation of Low-mature Gases and Analysis of the Possibility to Be Accumulated 被引量:2
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作者 SHUAI Yanhua WANG Hui ZHANG Shuichang SU Aiguo 《Acta Geologica Sinica(English Edition)》 SCIE CAS CSCD 2008年第3期537-542,共6页
At present, shallow gases have received much attention due to low cost in exploration and production. Low-mature gases, as one significant origin to shallow gas, turns to be an important research topic. The present un... At present, shallow gases have received much attention due to low cost in exploration and production. Low-mature gases, as one significant origin to shallow gas, turns to be an important research topic. The present understanding of low-mature gases is confined within some geological cases, and few laboratory studies have been reported. Therefore, the potential and characters of low- mature gases are not clear up to now. Here, two premature samples (one coal and the other shale) were pyrolyzed in a gold confined system. The gaseous components including hydrocarbon gases and non-hydrocarbon gases were analyzed. Based on kinetic modeling, the formation of low-mature gases was modeled. The results showed that during low mature stage, about 178 mL/gTOC gas was generated from the shale and 100 mL/gTOC from the coal. Two third to three fourth of the generated gases are non-hydrocarbon gases such as H2S and CO2. The total yields of C1-5 for the two samples are almost the same, 30-40 mL/gTOC, but individual gaseous hydrocarbon is different. The shale has much lower C1 but higher C2-5, whereas the coal has higher C1 but lower C2-5. Hydrocarbon gases formed during low-mature stage are very wet. The stable carbon isotope ratios of methane range from -40‰ to -50‰ (PDB), in good consistence with empiric criterion for low-mature gases summed up by the previous researchers. The generation characters suggest that the low-mature gases could be accumulated to form an economic gas reservoir, but most of them occur only as associated gases. 展开更多
关键词 low-mature gases kinetic modeling carbon isotope ratio of methane potential of C1-5
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