Nearfield acoustic holography(NAH)is a powerful tool for realizing source identification and sound field reconstruction.The wave superposition(WS)-based NAH is appropriate for the spatially extended sources and does n...Nearfield acoustic holography(NAH)is a powerful tool for realizing source identification and sound field reconstruction.The wave superposition(WS)-based NAH is appropriate for the spatially extended sources and does not require the complex numerical integrals.Equivalent source method(ESM),as a classical WS approach,is widely used due to its simplicity and efficiency.In the ESM,a virtual source surface is introduced,on which the virtual point sources are taken as the assumed sources,and an optimal retreat distance needs to be considered.A newly proposed WS-based approach,the element radiation superposition method(ERSM),uses piston surface source as the assumed source with no need to choose a virtual source surface.To satisfy the application conditions of piston pressure formula,the sizes of pistons are assumed to be as small as possible,which results in a large number of pistons and sampling points.In this paper,transfer matrix modes(TMMs),which are composed of the singular vectors of the vibro-acoustic transfer matrix,are used as the sparse basis of piston normal velocities.Then,the compressive ERSM based on TMMs is proposed.Compared with the conventional ERSM,the proposed method maintains a good pressure reconstruction when the number of sampling points and pistons are both reduced.Besides,the proposed method is compared with the compressive ESM in a mathematical sense.Both simulations and experiments for a rectangular plate demonstrate the advantage of the proposed method over the existing methods.展开更多
MOF-based materials have been widely explored in electrochemical CO_(2)reduction reactions for the production of valuable chemicals.Understanding the reconstruction of those catalysts under working conditions is cruci...MOF-based materials have been widely explored in electrochemical CO_(2)reduction reactions for the production of valuable chemicals.Understanding the reconstruction of those catalysts under working conditions is crucial for the identification of active sites and clarification of reaction mechanism.Herein,a series of six N coordinated Sn-based metal-organic frameworks(Sn-N6-MOFs)are newly developed for electrochemical CO_(2)reduction(CO_(2)RR).2%Sn-N6-MOF achieves the optimal catalytic performance with a formate Faradaic efficiency of~85%and a current density of 23 mA·cm^(-2) at-1.23 V vs.RHE.In-situ Raman results combined with ex-situ ^(119)Sn Mössbauer measurements reveal the structural reconstruction of Sn-N6-MOFs during CO_(2)RR,generating tin nanoclusters as the real active sites for CO_(2)electroreduction to HCOOH.展开更多
Background: Current techniques in partial auricular reconstruction can utilize an autologous or alloplastic framework covered by a variety of soft tissue envelopes. Objective: Is to evaluate the benefit of using polyp...Background: Current techniques in partial auricular reconstruction can utilize an autologous or alloplastic framework covered by a variety of soft tissue envelopes. Objective: Is to evaluate the benefit of using polypropylene mesh to reconstruct helix framework in partial auricular defects covered with local postauricular skin flap. Method: Eleven patients with partial auricular defect were treated by using polypropylene mesh helix framework which is covered with post auricular flap in a two stage repair;clinical results of the procedure were evaluated. Results: This technique achieved satisfactory results in 9 (81.8%) cases. Early Post operative complications: Hematoma formation in one case, mild infection in two cases, edema in two cases, and Partial overlying skin breakdown in one case with failure of technique. Late Post operative complications: Hypertrophic scar in one case, narrow retroauricular sulcus in one case, hair bearing skin over the auricle in one case. Conclusion: It is a simple technique, with satisfactory clinical results, easily done, even under local anesthesia, with no donor site morbidity of autogenous cartilage harvesting, not costly as other alloplastic substitutes, large series and longer follow up period are needed for better evaluation of this technique.展开更多
Along with China’s opening-up to the world and speedy social economic development, the economic strength will not serve as the only attribute of evaluating an enterprise. In this paper, by analyzing from the perspect...Along with China’s opening-up to the world and speedy social economic development, the economic strength will not serve as the only attribute of evaluating an enterprise. In this paper, by analyzing from the perspective of the management accounting framework under corporate social responsibility, the theoretical bases for enterprises to manage corporate image were discussed from two aspects economic strength and social responsibility.展开更多
Many people may be interested in Paleontology since the subject allows for large amounts of imagination and freedom in the creation of scenes. Dinosaurs draw the biggest interest because of their diversity in peculiar...Many people may be interested in Paleontology since the subject allows for large amounts of imagination and freedom in the creation of scenes. Dinosaurs draw the biggest interest because of their diversity in peculiar forms and often unusually large size of many species. There are people like artists who help the field paleontologists to describe, interpret and reconstruct fossils, and others that create drawings, restorations, sculptures and, most recently, computer animations for science, art and joy. To this end, a successful professional should have specific knowledge that will allow them to produce high-quality work. The current paper aims at: 1) providing knowledge on various topics of Paleontology, in order to understand the time scale of life on earth, its evolution and diversity;2) generating appreciation for the evolution of climatic conditions, continental plates and movement and the Mesozoic environment in which dinosaurs evolved;3) offering an understanding of scientific nomenclature used in Paleontology, and interpretation of drawings and meanings;4) helping one to realize how scientists extract information from bones, tracks, eggs, embryos and other remains;5) examining the physiology of dinosaurs, their metabolism, behaviors, growth rates estimated lifetime and diet;and 6) leading to the understanding of the relations between different dinosaur species and how Paleontologists complete missing parts from uncomplete skeletons. Examining the evolution of life, we observe that life began about 3.8 billion years ago in the deep sea. The first simple animals such as worms and jellyfish appeared in the oceans around 600 mya. The crust of the earth continuously moves to produce changes in the land masses and changes in the climatic conditions that affect the evolution of life. The life of the earth is divided into geological eras. At the end of each geological era, a major event of extinction occurred, which every time obliterated important groups of life. Dinosauria was one of the most successful clades of animals that lived on terrestrial ecosystems for over 160 million years, but was extinct at one of the major extinction events 66 mya. The remains of animals allow scientists and artists to recreate their forms usually in great detail and extract a lot of information about their lives. The paper describes in detail how and where to find information and explains how to interpret them in order to understand the meanings. The paper presents all the above in a simplified way giving the required knowledge without using difficult scientific terms and provides the essential knowledge to the interested person to appreciate the science of Paleontology.展开更多
Dinosaurs due to their diverse species and peculiar forms have drawn the interest of both artists and scientists. One way to unlock the unknown life of dinosaurs is to reconstruct dinosaurs through drawings, computer ...Dinosaurs due to their diverse species and peculiar forms have drawn the interest of both artists and scientists. One way to unlock the unknown life of dinosaurs is to reconstruct dinosaurs through drawings, computer animations or sculptures. Following the Introduction on “Dinosaur Reconstruction” by the present authors, where important Paleontological knowledge was presented, the next step is to examine some specific information along with necessary details for dinosaur reconstruction. The first and basic step to be taken for a reconstruction is the posture of the animal;this is the theme of the current paper. Dinosaurs would move either bipedally or quadrupedally depending on their kind and body construction. Based on the available literature, various issues in relation to the posture of an animal at different instances are examined. These are: postures of bipedal dinosaurs during walking, observation of living bipedal animals, postures of quadruped dinosaurs during walking, feeding styles, and dinosaur tails. Theropods had a locomotor behavior like modern birds, with the step width increasing when the animals decreased speed. The general posture and movement of quadrupeds and especially sauropods, remains a subject of great and much controversy. Some scientists believe that sauropod necks were generally held in a neutral or undeflected state during most of the time, while others believe that sauropod necks behaved like all present-day amniote with the mid-cervical region held nearly vertical. Also, there are indications that dinosaurs usually held their tails above ground. For all dinosaurs, the long tail was acting as a counterbalance to the head and body. As a validating example, the case of Amargasaurus is investigated with the help of a model, where the various positions of the animal are examined. A certain posture was chosen for a full-size steel and concrete reconstruction based on the features of the animal.展开更多
Objective To report utility of Medpor frameworks in auricular reconstruction and management of frameworks protrusion. Methods Retrorespectively analysis of clinical information in 31 patients who underwent auricular r...Objective To report utility of Medpor frameworks in auricular reconstruction and management of frameworks protrusion. Methods Retrorespectively analysis of clinical information in 31 patients who underwent auricular reconstruction from April 2000 to October 2002. Results All 31 reconstructed auricles were in good condition at two weeks postoperatively. Framework protrusion occurred later in 11 patients. The framework was retained in 8 of these cases after secondary repair, but had to be removed in 3 patients. In 27 patients, the reconstructed auricle was rated as esthetically succesful. Conclusion Medpor framework protrusion is likely to occur when skin tension is high with minimal soft tissue coverage over the framework and can result from impact by strong external force. Despite the concern of protrusion, Medpor frameworks can be used in place of autologous cartilaginous graft in auricular reconstruction.展开更多
In this work,nickel foam supported CeO_(2)-modified CoBDC(BDC stands for terephthalic acid linker)metal-organic frameworks(NF/CoBDC@CeO_(2)) are prepared by hydrothermal and subsequent impregnation methods,which can b...In this work,nickel foam supported CeO_(2)-modified CoBDC(BDC stands for terephthalic acid linker)metal-organic frameworks(NF/CoBDC@CeO_(2)) are prepared by hydrothermal and subsequent impregnation methods,which can be further transformed to NF/CoOOH@CeO_(2) by reconstruction during the electrocatalytic test.The obtained NF/CoOOH@CeO_(2) exhibits excellent performance in electrocatalytic oxidation of 5-hydroxymethylfurfural(HMF) because the introduction of CeO_(2) can optimize the electronic structure of the heterointerface and accelerate the accumulation of ^(*)OH.It requires only a potential of 1.290 V_(RHE) to provide a current density of 50 mA cm^(-2) in 1.0 M KOH+50 mM HMF,which is 222 mV lower than that required in 1,0 M KOH(1.512 V_(RHE)).In addition,density-functional theory calculation results demonstrate that CeO_(2) biases the electrons to the CoOOH side at the heterointerface and promotes the adsorption of ^(*)OH and ^(*)HMF on the catalyst surface,which lower the reaction energy barrier and facilitate the electrocata lytic oxidation process.展开更多
Deep learning is capable of greatly promoting the progress of super-resolution imaging technology in terms of imaging and reconstruction speed,imaging resolution,and imagingflux.This paper proposes a deep neural netwo...Deep learning is capable of greatly promoting the progress of super-resolution imaging technology in terms of imaging and reconstruction speed,imaging resolution,and imagingflux.This paper proposes a deep neural network based on a generative adversarial network(GAN).The generator employs a U-Net-based network,which integrates Dense Net for the downsampling component.The proposed method has excellent properties,for example,the network model is trained with several different datasets of biological structures;the trained model can improve the imaging resolution of different microscopy imaging modalities such as confocal imaging and wide-field imaging;and the model demonstrates a generalized ability to improve the resolution of different biological structures even out of the datasets.In addition,experimental results showed that the method improved the resolution of caveolin-coated pits(CCPs)structures from 264 nm to 138 nm,a 1.91-fold increase,and nearly doubled the resolution of DNA molecules imaged while being transported through microfluidic channels.展开更多
Structure-from-Motion(SfM)techniques have been widely used for 3D geometry reconstruction from multi-view images.Nevertheless,the efficiency and quality of the reconstructed geometry depends on multiple factors,i.e.,t...Structure-from-Motion(SfM)techniques have been widely used for 3D geometry reconstruction from multi-view images.Nevertheless,the efficiency and quality of the reconstructed geometry depends on multiple factors,i.e.,the base-height ratio,intersection angle,overlap,and ground control points,etc.,which are rarely quantified in real-world applications.To answer this question,in this paper,we take a data-driven approach by analyzing hundreds of terrestrial stereo image configurations through a typical SfM algorithm.Two main meta-parameters with respect to base-height ratio and intersection angle are analyzed.Following the results,we propose a Skeletal Camera Network(SCN)and embed it into the SfM to lead to a novel SfM scheme called SCN-SfM,which limits tie-point matching to the remaining connected image pairs in SCN.The proposed method was applied in three terrestrial datasets.Experimental results have demonstrated the effectiveness of the proposed SCN-SfM to achieve 3D geometry with higher accuracy and fast time efficiency compared to the typical SfM method,whereas the completeness of the geometry is comparable.展开更多
3D reconstruction based on single view aims to reconstruct the entire 3D shape of an object from one perspective.When existing methods reconstruct the mesh surface of complex objects,the surface details are difficult ...3D reconstruction based on single view aims to reconstruct the entire 3D shape of an object from one perspective.When existing methods reconstruct the mesh surface of complex objects,the surface details are difficult to predict and the reconstruction visual effect is poor because the mesh representation is not easily integrated into the deep learning framework;the 3D topology is easily limited by predefined templates and inflexible,and unnecessary mesh self-intersections and connections will be generated when reconstructing complex topology,thus destroying the surface details;the training of the reconstruction network is limited by the large amount of information attached to the mesh vertices,and the training time of the reconstructed network is too long.In this paper,we propose a method for fast mesh reconstruction from single view based on Graph Convolutional Network(GCN)and topology modification.We use GCN to ensure the generation of high-quality mesh surfaces and use topology modification to improve the flexibility of the topology.Meanwhile,a feature fusion method is proposed to make full use of the features of each stage of the image hierarchically.We use 3D open dataset ShapeNet to train our network and add a new weight parameter to speed up the training process.Extensive experiments demonstrate that our method can not only reconstruct object meshes on complex topological surfaces,but also has better qualitative and quantitative results.展开更多
Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scal...Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scale implementation of CO_(2)RR is severely hindered by the lack of high‐performance CO_(2)RR electrocatalysts.Heterogeneous molecular catalysts and metal‐organic framework with well‐defined structure and high tunability of the metal centers and ligands show great promise for CO_(2)RR in terms of both fundamental understanding and practical application.Here,structural and interfacial engineering of these well‐defined metal‐organic ensembles is summarized.This review starts from the fundamental electrochemistry of CO_(2)RR and its evaluation criteria,and then moves to the heterogeneous molecular catalysts and metal‐organic framework with emphasis on the engineering of metal centers and ligands,their interaction with supports,as well as in situ reconstruction of metal‐organic ensembles.Summary and outlook are present in the end,with the hope to inspire and provoke more genuine thinking on the design and fabrication of efficient CO_(2)RR electrocatalysts.展开更多
Most oxygen evolution reaction(OER)electrocatalysts show poor stability under industrial alkaline conditions(20–30 wt.%KOH).Therefore,it is essential to develop stable,efficient,and low-cost OER catalysts for industr...Most oxygen evolution reaction(OER)electrocatalysts show poor stability under industrial alkaline conditions(20–30 wt.%KOH).Therefore,it is essential to develop stable,efficient,and low-cost OER catalysts for industrial water electrolysis.Herein,we present a straightforward approach for the complete electrochemical reconstruction of Ni-BDC,a Ni-based metal-organic framework,for OER.This method involves the continuous release of Fe^(3+)from Fe foam counter electrode in a high-concentration(6.0 M,25 wt.%)KOH solution.The continuously Fe^(3+)releasing not only realizes in situ Fe^(3+)doping,but also introduces abundant defects in the obtained catalyst during cyclic voltammetry activation,thereby accelerating the electrochemical reconstruction.The reconstructed OER catalyst(Fe-doped nickel hydroxide/oxyhydroxide nanosheets supported on Ni foam,Fe-NiO_(x)(OH)y/NF)manifests a low overpotential of 217 mV at 10 mA cm^(-2)and 263 m V at 100 m A cm^(-2)in 1.0 M KOH.Noteworthy,the Fe-NiO_(x)(OH)_(y)/NF also demonstrates high stability in 30 wt.%KOH.This strategy of regulating the electrochemical reconstruction process sheds light on the construction of stable and efficient OER catalysts for industrial water electrolysis.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.61701133)。
文摘Nearfield acoustic holography(NAH)is a powerful tool for realizing source identification and sound field reconstruction.The wave superposition(WS)-based NAH is appropriate for the spatially extended sources and does not require the complex numerical integrals.Equivalent source method(ESM),as a classical WS approach,is widely used due to its simplicity and efficiency.In the ESM,a virtual source surface is introduced,on which the virtual point sources are taken as the assumed sources,and an optimal retreat distance needs to be considered.A newly proposed WS-based approach,the element radiation superposition method(ERSM),uses piston surface source as the assumed source with no need to choose a virtual source surface.To satisfy the application conditions of piston pressure formula,the sizes of pistons are assumed to be as small as possible,which results in a large number of pistons and sampling points.In this paper,transfer matrix modes(TMMs),which are composed of the singular vectors of the vibro-acoustic transfer matrix,are used as the sparse basis of piston normal velocities.Then,the compressive ERSM based on TMMs is proposed.Compared with the conventional ERSM,the proposed method maintains a good pressure reconstruction when the number of sampling points and pistons are both reduced.Besides,the proposed method is compared with the compressive ESM in a mathematical sense.Both simulations and experiments for a rectangular plate demonstrate the advantage of the proposed method over the existing methods.
基金financially supported by the National Key Research and Development Program of China(No.2021YFA1500502)the National Natural Science Foundation of China(22102176)+1 种基金CAS Project for Young Scientists in Basic Research(YSBR-022)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB36030200)。
文摘MOF-based materials have been widely explored in electrochemical CO_(2)reduction reactions for the production of valuable chemicals.Understanding the reconstruction of those catalysts under working conditions is crucial for the identification of active sites and clarification of reaction mechanism.Herein,a series of six N coordinated Sn-based metal-organic frameworks(Sn-N6-MOFs)are newly developed for electrochemical CO_(2)reduction(CO_(2)RR).2%Sn-N6-MOF achieves the optimal catalytic performance with a formate Faradaic efficiency of~85%and a current density of 23 mA·cm^(-2) at-1.23 V vs.RHE.In-situ Raman results combined with ex-situ ^(119)Sn Mössbauer measurements reveal the structural reconstruction of Sn-N6-MOFs during CO_(2)RR,generating tin nanoclusters as the real active sites for CO_(2)electroreduction to HCOOH.
文摘Background: Current techniques in partial auricular reconstruction can utilize an autologous or alloplastic framework covered by a variety of soft tissue envelopes. Objective: Is to evaluate the benefit of using polypropylene mesh to reconstruct helix framework in partial auricular defects covered with local postauricular skin flap. Method: Eleven patients with partial auricular defect were treated by using polypropylene mesh helix framework which is covered with post auricular flap in a two stage repair;clinical results of the procedure were evaluated. Results: This technique achieved satisfactory results in 9 (81.8%) cases. Early Post operative complications: Hematoma formation in one case, mild infection in two cases, edema in two cases, and Partial overlying skin breakdown in one case with failure of technique. Late Post operative complications: Hypertrophic scar in one case, narrow retroauricular sulcus in one case, hair bearing skin over the auricle in one case. Conclusion: It is a simple technique, with satisfactory clinical results, easily done, even under local anesthesia, with no donor site morbidity of autogenous cartilage harvesting, not costly as other alloplastic substitutes, large series and longer follow up period are needed for better evaluation of this technique.
文摘Along with China’s opening-up to the world and speedy social economic development, the economic strength will not serve as the only attribute of evaluating an enterprise. In this paper, by analyzing from the perspective of the management accounting framework under corporate social responsibility, the theoretical bases for enterprises to manage corporate image were discussed from two aspects economic strength and social responsibility.
文摘Many people may be interested in Paleontology since the subject allows for large amounts of imagination and freedom in the creation of scenes. Dinosaurs draw the biggest interest because of their diversity in peculiar forms and often unusually large size of many species. There are people like artists who help the field paleontologists to describe, interpret and reconstruct fossils, and others that create drawings, restorations, sculptures and, most recently, computer animations for science, art and joy. To this end, a successful professional should have specific knowledge that will allow them to produce high-quality work. The current paper aims at: 1) providing knowledge on various topics of Paleontology, in order to understand the time scale of life on earth, its evolution and diversity;2) generating appreciation for the evolution of climatic conditions, continental plates and movement and the Mesozoic environment in which dinosaurs evolved;3) offering an understanding of scientific nomenclature used in Paleontology, and interpretation of drawings and meanings;4) helping one to realize how scientists extract information from bones, tracks, eggs, embryos and other remains;5) examining the physiology of dinosaurs, their metabolism, behaviors, growth rates estimated lifetime and diet;and 6) leading to the understanding of the relations between different dinosaur species and how Paleontologists complete missing parts from uncomplete skeletons. Examining the evolution of life, we observe that life began about 3.8 billion years ago in the deep sea. The first simple animals such as worms and jellyfish appeared in the oceans around 600 mya. The crust of the earth continuously moves to produce changes in the land masses and changes in the climatic conditions that affect the evolution of life. The life of the earth is divided into geological eras. At the end of each geological era, a major event of extinction occurred, which every time obliterated important groups of life. Dinosauria was one of the most successful clades of animals that lived on terrestrial ecosystems for over 160 million years, but was extinct at one of the major extinction events 66 mya. The remains of animals allow scientists and artists to recreate their forms usually in great detail and extract a lot of information about their lives. The paper describes in detail how and where to find information and explains how to interpret them in order to understand the meanings. The paper presents all the above in a simplified way giving the required knowledge without using difficult scientific terms and provides the essential knowledge to the interested person to appreciate the science of Paleontology.
文摘Dinosaurs due to their diverse species and peculiar forms have drawn the interest of both artists and scientists. One way to unlock the unknown life of dinosaurs is to reconstruct dinosaurs through drawings, computer animations or sculptures. Following the Introduction on “Dinosaur Reconstruction” by the present authors, where important Paleontological knowledge was presented, the next step is to examine some specific information along with necessary details for dinosaur reconstruction. The first and basic step to be taken for a reconstruction is the posture of the animal;this is the theme of the current paper. Dinosaurs would move either bipedally or quadrupedally depending on their kind and body construction. Based on the available literature, various issues in relation to the posture of an animal at different instances are examined. These are: postures of bipedal dinosaurs during walking, observation of living bipedal animals, postures of quadruped dinosaurs during walking, feeding styles, and dinosaur tails. Theropods had a locomotor behavior like modern birds, with the step width increasing when the animals decreased speed. The general posture and movement of quadrupeds and especially sauropods, remains a subject of great and much controversy. Some scientists believe that sauropod necks were generally held in a neutral or undeflected state during most of the time, while others believe that sauropod necks behaved like all present-day amniote with the mid-cervical region held nearly vertical. Also, there are indications that dinosaurs usually held their tails above ground. For all dinosaurs, the long tail was acting as a counterbalance to the head and body. As a validating example, the case of Amargasaurus is investigated with the help of a model, where the various positions of the animal are examined. A certain posture was chosen for a full-size steel and concrete reconstruction based on the features of the animal.
文摘Objective To report utility of Medpor frameworks in auricular reconstruction and management of frameworks protrusion. Methods Retrorespectively analysis of clinical information in 31 patients who underwent auricular reconstruction from April 2000 to October 2002. Results All 31 reconstructed auricles were in good condition at two weeks postoperatively. Framework protrusion occurred later in 11 patients. The framework was retained in 8 of these cases after secondary repair, but had to be removed in 3 patients. In 27 patients, the reconstructed auricle was rated as esthetically succesful. Conclusion Medpor framework protrusion is likely to occur when skin tension is high with minimal soft tissue coverage over the framework and can result from impact by strong external force. Despite the concern of protrusion, Medpor frameworks can be used in place of autologous cartilaginous graft in auricular reconstruction.
基金National Key Research and Development Program of China (2021YFB3500700)National Natural Science Foundation of China (51802015)Fundamental Research Funds for the Central Universities (FRF-EYIT-23-07)。
文摘In this work,nickel foam supported CeO_(2)-modified CoBDC(BDC stands for terephthalic acid linker)metal-organic frameworks(NF/CoBDC@CeO_(2)) are prepared by hydrothermal and subsequent impregnation methods,which can be further transformed to NF/CoOOH@CeO_(2) by reconstruction during the electrocatalytic test.The obtained NF/CoOOH@CeO_(2) exhibits excellent performance in electrocatalytic oxidation of 5-hydroxymethylfurfural(HMF) because the introduction of CeO_(2) can optimize the electronic structure of the heterointerface and accelerate the accumulation of ^(*)OH.It requires only a potential of 1.290 V_(RHE) to provide a current density of 50 mA cm^(-2) in 1.0 M KOH+50 mM HMF,which is 222 mV lower than that required in 1,0 M KOH(1.512 V_(RHE)).In addition,density-functional theory calculation results demonstrate that CeO_(2) biases the electrons to the CoOOH side at the heterointerface and promotes the adsorption of ^(*)OH and ^(*)HMF on the catalyst surface,which lower the reaction energy barrier and facilitate the electrocata lytic oxidation process.
基金Subjects funded by the National Natural Science Foundation of China(Nos.62275216 and 61775181)the Natural Science Basic Research Programme of Shaanxi Province-Major Basic Research Special Project(Nos.S2018-ZC-TD-0061 and TZ0393)the Special Project for the Development of National Key Scientific Instruments and Equipment No.(51927804).
文摘Deep learning is capable of greatly promoting the progress of super-resolution imaging technology in terms of imaging and reconstruction speed,imaging resolution,and imagingflux.This paper proposes a deep neural network based on a generative adversarial network(GAN).The generator employs a U-Net-based network,which integrates Dense Net for the downsampling component.The proposed method has excellent properties,for example,the network model is trained with several different datasets of biological structures;the trained model can improve the imaging resolution of different microscopy imaging modalities such as confocal imaging and wide-field imaging;and the model demonstrates a generalized ability to improve the resolution of different biological structures even out of the datasets.In addition,experimental results showed that the method improved the resolution of caveolin-coated pits(CCPs)structures from 264 nm to 138 nm,a 1.91-fold increase,and nearly doubled the resolution of DNA molecules imaged while being transported through microfluidic channels.
基金National Natural Science Foundation of China(No.41701534)Open Fund of State Key Laboratory of Coal Resources and Safe Mining(No.SKLCRSM19KFA01)+1 种基金Ecological and Smart Mine Joint Foundation of Hebei Province(No.E2020402086)State Key Laboratory ofGeohazard Prevention and Geoenvironment Protection(No.SKLGP2019K015)
文摘Structure-from-Motion(SfM)techniques have been widely used for 3D geometry reconstruction from multi-view images.Nevertheless,the efficiency and quality of the reconstructed geometry depends on multiple factors,i.e.,the base-height ratio,intersection angle,overlap,and ground control points,etc.,which are rarely quantified in real-world applications.To answer this question,in this paper,we take a data-driven approach by analyzing hundreds of terrestrial stereo image configurations through a typical SfM algorithm.Two main meta-parameters with respect to base-height ratio and intersection angle are analyzed.Following the results,we propose a Skeletal Camera Network(SCN)and embed it into the SfM to lead to a novel SfM scheme called SCN-SfM,which limits tie-point matching to the remaining connected image pairs in SCN.The proposed method was applied in three terrestrial datasets.Experimental results have demonstrated the effectiveness of the proposed SCN-SfM to achieve 3D geometry with higher accuracy and fast time efficiency compared to the typical SfM method,whereas the completeness of the geometry is comparable.
基金This work was supported,in part,by the Natural Science Foundation of Jiangsu Province under Grant Numbers BK20201136,BK20191401in part,by the National Nature Science Foundation of China under Grant Numbers 61502240,61502096,61304205,61773219in part,by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)fund.
文摘3D reconstruction based on single view aims to reconstruct the entire 3D shape of an object from one perspective.When existing methods reconstruct the mesh surface of complex objects,the surface details are difficult to predict and the reconstruction visual effect is poor because the mesh representation is not easily integrated into the deep learning framework;the 3D topology is easily limited by predefined templates and inflexible,and unnecessary mesh self-intersections and connections will be generated when reconstructing complex topology,thus destroying the surface details;the training of the reconstruction network is limited by the large amount of information attached to the mesh vertices,and the training time of the reconstructed network is too long.In this paper,we propose a method for fast mesh reconstruction from single view based on Graph Convolutional Network(GCN)and topology modification.We use GCN to ensure the generation of high-quality mesh surfaces and use topology modification to improve the flexibility of the topology.Meanwhile,a feature fusion method is proposed to make full use of the features of each stage of the image hierarchically.We use 3D open dataset ShapeNet to train our network and add a new weight parameter to speed up the training process.Extensive experiments demonstrate that our method can not only reconstruct object meshes on complex topological surfaces,but also has better qualitative and quantitative results.
文摘Electrochemical carbon dioxide reduction(CO_(2)RR)has been generally regarded as green technologies that can convert renewable energy such as sunlight and wind into fuels and valuable chemicals.However,the large‐scale implementation of CO_(2)RR is severely hindered by the lack of high‐performance CO_(2)RR electrocatalysts.Heterogeneous molecular catalysts and metal‐organic framework with well‐defined structure and high tunability of the metal centers and ligands show great promise for CO_(2)RR in terms of both fundamental understanding and practical application.Here,structural and interfacial engineering of these well‐defined metal‐organic ensembles is summarized.This review starts from the fundamental electrochemistry of CO_(2)RR and its evaluation criteria,and then moves to the heterogeneous molecular catalysts and metal‐organic framework with emphasis on the engineering of metal centers and ligands,their interaction with supports,as well as in situ reconstruction of metal‐organic ensembles.Summary and outlook are present in the end,with the hope to inspire and provoke more genuine thinking on the design and fabrication of efficient CO_(2)RR electrocatalysts.
基金supported by the China Postdoctoral Science Foundation(2022T150502)the National Energy-Saving and Low-Carbon Materials Production and Application Demonstration Platform Program(TC220H06N)。
文摘Most oxygen evolution reaction(OER)electrocatalysts show poor stability under industrial alkaline conditions(20–30 wt.%KOH).Therefore,it is essential to develop stable,efficient,and low-cost OER catalysts for industrial water electrolysis.Herein,we present a straightforward approach for the complete electrochemical reconstruction of Ni-BDC,a Ni-based metal-organic framework,for OER.This method involves the continuous release of Fe^(3+)from Fe foam counter electrode in a high-concentration(6.0 M,25 wt.%)KOH solution.The continuously Fe^(3+)releasing not only realizes in situ Fe^(3+)doping,but also introduces abundant defects in the obtained catalyst during cyclic voltammetry activation,thereby accelerating the electrochemical reconstruction.The reconstructed OER catalyst(Fe-doped nickel hydroxide/oxyhydroxide nanosheets supported on Ni foam,Fe-NiO_(x)(OH)y/NF)manifests a low overpotential of 217 mV at 10 mA cm^(-2)and 263 m V at 100 m A cm^(-2)in 1.0 M KOH.Noteworthy,the Fe-NiO_(x)(OH)_(y)/NF also demonstrates high stability in 30 wt.%KOH.This strategy of regulating the electrochemical reconstruction process sheds light on the construction of stable and efficient OER catalysts for industrial water electrolysis.