A numerical model for proton exchange membrane (PEM) fuel cell is developed, which can simulate such basic transport phenomena as gas-liquid two-phase flow in a working fuel cell. Boundary conditions for both the conv...A numerical model for proton exchange membrane (PEM) fuel cell is developed, which can simulate such basic transport phenomena as gas-liquid two-phase flow in a working fuel cell. Boundary conditions for both the conventional and the interdigitated modes of flow are presented on a three-dimensional basis. Numerical techniques for this model are discussed in detail. Validation shows good agreement between simulating results and experimental data. Furthermore, internal transport phenomena are discussed and compared for PEM fuel cells with conventional and interdigitated flows. It is found that the dead-ended structure of an interdigitated flow does increase the oxygen mass fraction and decrease the liquid water saturation in the gas diffusion layer as compared to the conventional mode of flow. However, the cathode humidification is important for an interdigitated flow to acquire better performance than a conventional flow fuel cell.展开更多
A three-dimensional, non-isothermal, two-phase model for a PEM water electrolysis cell(PEMEC) is established in this study.An effective connection between two-phase transport and performance in the PEMECs is built thr...A three-dimensional, non-isothermal, two-phase model for a PEM water electrolysis cell(PEMEC) is established in this study.An effective connection between two-phase transport and performance in the PEMECs is built through coupling the liquid water saturation and temperature in the charge conservation equation. The distributions of liquid water and temperature with different operating(voltage, temperature, inlet velocity) and physical(contact angle, and porosity of anode gas diffusion layer) parameters are examined and discussed in detail. The results show that the water and temperature distributions, which are affected by the operating and physical parameters, have a combined effect on the cell performance. The effects of various parameters on the PEMEC are of interaction and restricted mutually. As the voltage increases, the priority factor caused by the change of inlet water velocity changes from the liquid water saturation increase to the temperature drop in the anode catalyst layer. While the priority influence factor caused by the contact angle and porosity of anode gas diffusion layer is the liquid water saturation. Decreasing the contact angle or/and increasing the porosity can improve the PEMEC performance especially at the high voltage. The results can provide a better understanding of the effect of heat and mass transfer and the foundation for optimization design.展开更多
基金Supported by "985" Funds, Shanghai Jiaotong University, China.
文摘A numerical model for proton exchange membrane (PEM) fuel cell is developed, which can simulate such basic transport phenomena as gas-liquid two-phase flow in a working fuel cell. Boundary conditions for both the conventional and the interdigitated modes of flow are presented on a three-dimensional basis. Numerical techniques for this model are discussed in detail. Validation shows good agreement between simulating results and experimental data. Furthermore, internal transport phenomena are discussed and compared for PEM fuel cells with conventional and interdigitated flows. It is found that the dead-ended structure of an interdigitated flow does increase the oxygen mass fraction and decrease the liquid water saturation in the gas diffusion layer as compared to the conventional mode of flow. However, the cathode humidification is important for an interdigitated flow to acquire better performance than a conventional flow fuel cell.
基金supported by the National Natural Science Foundation of China (Grant Nos. 51876061 and 51821004)the Fundamental Research Funds for the Central Universities (Grant No. 2018ZD04)。
文摘A three-dimensional, non-isothermal, two-phase model for a PEM water electrolysis cell(PEMEC) is established in this study.An effective connection between two-phase transport and performance in the PEMECs is built through coupling the liquid water saturation and temperature in the charge conservation equation. The distributions of liquid water and temperature with different operating(voltage, temperature, inlet velocity) and physical(contact angle, and porosity of anode gas diffusion layer) parameters are examined and discussed in detail. The results show that the water and temperature distributions, which are affected by the operating and physical parameters, have a combined effect on the cell performance. The effects of various parameters on the PEMEC are of interaction and restricted mutually. As the voltage increases, the priority factor caused by the change of inlet water velocity changes from the liquid water saturation increase to the temperature drop in the anode catalyst layer. While the priority influence factor caused by the contact angle and porosity of anode gas diffusion layer is the liquid water saturation. Decreasing the contact angle or/and increasing the porosity can improve the PEMEC performance especially at the high voltage. The results can provide a better understanding of the effect of heat and mass transfer and the foundation for optimization design.
