Fe2O3, TiO2, CuO and ZnO powders were mixed according to the formula of （1-x）TiO2 xCuO-Fe2O3 or （1-x）TiO2 xZnO-Fe2O3 （x=0, 0.2 0.4, 0.6, 0.8, 1）, and well ball-milled with H2O for 3 h to ensure homogeneity of th...Fe2O3, TiO2, CuO and ZnO powders were mixed according to the formula of （1-x）TiO2 xCuO-Fe2O3 or （1-x）TiO2 xZnO-Fe2O3 （x=0, 0.2 0.4, 0.6, 0.8, 1）, and well ball-milled with H2O for 3 h to ensure homogeneity of the powdered solids, then fired at 1200℃ for 4 h. The fired samples were reduced at 500℃ with hydrogen gas. The reduced samples were subjected to recalcination at 500℃ in CO2 atmosphere. Both of fired, reduced and calcined samples were characterized by X-ray diffraction, vibrating sample magnetometry, reflected light microscopy and scanning electron microscopy. Different phases were formed after firing of Cu^＋2 or Zn^2＋ substituted Fe2TiO5. Magnetization （Bs） of the formed phases after firing are very low corresponding to diluted magnetic semiconductors （DMS） and increases with increasing the substituted cations （Cu^＋2 or Zn^2＋）. The reduction of the fired samples enhanced the Bs values whereas the reducibility increases with increasing the Cu^＋2 or Zn^2＋ content. Samples show different tendency toward CO2 decomposition which is very important for environmental minimization for CO2.展开更多
文摘Fe2O3, TiO2, CuO and ZnO powders were mixed according to the formula of （1-x）TiO2 xCuO-Fe2O3 or （1-x）TiO2 xZnO-Fe2O3 （x=0, 0.2 0.4, 0.6, 0.8, 1）, and well ball-milled with H2O for 3 h to ensure homogeneity of the powdered solids, then fired at 1200℃ for 4 h. The fired samples were reduced at 500℃ with hydrogen gas. The reduced samples were subjected to recalcination at 500℃ in CO2 atmosphere. Both of fired, reduced and calcined samples were characterized by X-ray diffraction, vibrating sample magnetometry, reflected light microscopy and scanning electron microscopy. Different phases were formed after firing of Cu^＋2 or Zn^2＋ substituted Fe2TiO5. Magnetization （Bs） of the formed phases after firing are very low corresponding to diluted magnetic semiconductors （DMS） and increases with increasing the substituted cations （Cu^＋2 or Zn^2＋）. The reduction of the fired samples enhanced the Bs values whereas the reducibility increases with increasing the Cu^＋2 or Zn^2＋ content. Samples show different tendency toward CO2 decomposition which is very important for environmental minimization for CO2.
