Characterization of carbon fibers recovered through mechanochemical-enhanced recycling of waste carbon fiber reinforced plastics

In this study,we present the characterization of the carbon fibers recovered from the mechanochemical-enhanced recycling of carbon fiber reinforced fibers.The objectives of the study were to investigate the effect of our modified recycling method on the interfacial properties of recovered fibers.The reinforced plastics were recycled;the recycling efficiency was determined and the recovered fibers were sized using 1 wt%and 3 wt%concentration of(3-aminopropyl)triethoxysilane.We characterized the morphologies utilizing the electron spectroscopy for chemical analysis(ESCA),atomic force microscopy(AFM),FTIR-attenuated total reflection(ATR)spectroscopy and scanning electron microscopy(SEM).Although the surface of the fibers had no cracks,there was evidence of contaminations which affected the interfacial properties and the quality of the fibers.Results showed that the trends in the recovered and virgin fibers were similar with an increase in sizing concentration.The results highlighted the perspectives of increasing the quality of recovered fibers after the recycling process.

Development and Properties of Glass Fiber Reinforced Plastics Geogrid

Glass fiber reinforced plastics geogrid has a wide application in the field of soil reinforcement because of its high strength, good toughness, and resistance to environmental stress, creep resistance and strong stability. In order to get high-powered glass fiber reinforced plastics geogrid and its mechanical characteristics, the properties and physical mechanical index of geogrid have been got through the study of its raw material, production process and important quality index. The analysis and study have been made to the geogrid＇s mechanical properties with loading speed, three-axial compression, temperature tensile test and FLAC3D numerical simulation, thus obtain the mechanical parameters of its displacement time curve, breaking strength and elongation at break. Some conclusions can be drawn as follows： （a） Using glass fiber materials, knurling and coated projection process, the f^acture strength and corrosion resistance of geogrid are greatly improved and the interlocking bite capability of soil is enhanced. （b） The fracture strength of geogrid is related to temperature and loading rate. When the surrounding rock pressure is fixed, the strength and anti-deformation ability of reinforced soil are significantly enhanced with increasing reinforced layers. （c） The pullout test shows the positive correlation between geogrid displacement and action time. （d） As a new reinforced material, the glass fiber reinforced plastics geogrid is not mature enough in theoretical research and practical experience, so it has become an urgent problem both in theoretical study and practical innovation.

Critical Thrust Force Forecasting for Drilling Exit Delamination of Carbon Fibre Reinforced Plastics

Exit delamination is excessive drilling thrust force.Therefore,it is necessary to investigate the critical thrust force which cause exit delamination when carbon fibre reinforced plastics(CRFP)is drilled.According to the linear elastic fracture mechanics,the mechanics of composite material and the classical thin plate bending theory,a common theoretical model of the critical drilling thrust force for CFRP plates is established.Compared with the experimental data of previous studies,the results show that the theoretical values agree well with the experimental values.This model can be used to forecast the critical thrust force for the drilling-induced delamination of CFRP.

Square concrete columns strengthened with carbon fiber reinforced plastics sheets at low temperatures

Twenty-one square concrete columns were constructed and tested. The testing results indicate that bonded carbon fiber reinforced plastics(CFRP) sheets can be used to increase the strength and improve the serviceability of damaged concrete columns at low temperatures. The failure of the specimens,in most cases,takes place within the middle half of the columns. And the failure of strengthened columns is sudden and explosive. The CFRP sheets increase both the axial load capacity and the ultimate concrete compressive strain of the columns. The ultimate loads of strengthened columns at-10,0 and 10 ℃ increase averagely by 9.09%,6.63% and 17.83%,respectively,as compared with those of the control specimens. The axial compressive strength of strengthened columns is related to the curing temperatures. The improvement of axial compressive strength decreases with reducing temperature,and when the temperature drops to a certain value,the improvement increases with falling temperature.

Behaviour of Multiscale Progressive Damage for Different Matrix Glass Fiber Reinforced Plastics Bars

The damage formation and evolution of glass fiber reinforced plastics( GFRP) bar on mechanical properties were mainly evaluated by theoretical analysis and numerical calculations which lack of test basis of damage process. The two different matrices of unsaturated polyester and vinylester GFRP bars were selected to carry out a series of macro-mesoscopic physical and mechanical tests to analyze the tensile progressive damage process on a multiscale. The formation of apparent crack,the bonding of internal components as well as the strain change were all reflected damage evolution of GFRP bar,and a certain correlation existed between them. Wherein the matrix has an obvious impact on the damage of bar,the component stress transfer effect of vinylester bar is better than unsaturated polyester from crack propagation observation and scanning electron microscopy( SEM). The cyclic loading tests quantitatively reflect the difference of damage accumulation between different matrix bars,and the failure load of bars decreases nearly 10%.

High-temperature effect on continuous glass fiber reinforced polypropylene multilayer composite and corrugated sandwich panels

The high-temperature mechanical behaviors of Multi-Layer Composite Panels(MCP)and Corrugated Sandwich Panels(CSP)of Continuous Glass Fiber-Reinforced Polypropylene(CGFRPP)are critical for their application in aerospace fields,which have been rarely mentioned in previous studies.High-temperature quasi-static tensile and compression tests on CGFRPP MCP are conducted first.The results showed that the tensile and compression strength,stiffness,and tensile modulus of MCP decreased with increasing temperature.The Gibson model was found to be more suitable for predicting the high-temperature mechanical performance of MCP after comparing the calculated results of different theoretical models with experimental data.Secondly,hightemperature planar compression tests were conducted on the CGFRPP CSP,revealing that the main failure modes were corrugated core buckling and delamination between the face panel and core material,with delamination being intensified at higher temperatures.Therefore,we proposed a strength theoretical model that considers structural buckling failure and interface delamination failure,and introduced the influence factor to evaluate the effect of interface delamination on structural strength.

Effects of fiber orientation on tool wear evolution and wear mechanism when cutting carbon fiber reinforced plastics

The aim of the present paper is to reveal the influence of different fiber orientations on the tool wear evolution and wear mechanism. Side-milling experiments with large-diameter milling tools are conducted. A finite element(FE) cutting model of carbon fiber reinforced plastics(CFRP)is established to get insight into the cutting stress status at different wear stages. The results show that different fiber orientations bring about distinct differences in the extent, profile and mechanism of tool wear. Severer wear occurs when cutting 45° and 90° plies, followed by 0°, correspondingly,the least wear is obtained when θ = 135°(θ represents the orientation of fibers). Moreover, the worn profiles of cutting tools when θ = 0° and 45° are waterfall edge, while round edge occurs whenθ = 135° and a combined shape of waterfall and round edge is obtained when θ = 90°. The wear mechanisms under different fiber orientations are strongly dependent on the cutting stress distributions. The evolution of tool wear profile is basically consistent with the stress distribution on the tool surface at different wear stages, and the extent of tool wear is determined by the magnitude of stress on the tool surface. Besides, the worn edges produce an actual negative clearance angle,which decreases the actual cutting thickness and leads to compressing and bending failure of fibers beneath the cutting region as well as low surface qualities.

Fabrication and Drilling Tests of Chemical Vapor Deposition Diamond Coated Drills in Machining Carbon Fiber Reinforced Plastics

Chemical vapor deposition (CVD) diamond coated drills are fabricated by depositing diamond films on Co-cemented tungsten carbide (WC-Co) drills. The characteristics of as-deposited diamond coatings are investigated by scanning electron microscope (SEM) and Raman spectra. To evaluate the cutting performance of diamond coated drills, comparative drilling tests are conducted using diamond coated and uncoated WC-Co drills, with carbon fiber reinforced plastics (CFRPs) as the workpiece on a high-speed computer numerical control (CNC) machine. Thrust force and tool wear are measured during the drilling process. The results show that diamond coated drill exhibits better cutting performance, compared with the uncoated drill. The value of flank wear is about 70 μm after machining 90 holes, about a half of that of the WC-Co drill with 145 μm after drilling only 30 holes. The wear rate of WC-Co drill is higher than that of diamond coated drill before diamond films peeling off. The diamond coated drill achieves more predictable hole quality. The improved cutting performance of the diamond coated drill is due to the high hardness, wear resistance and low coefficient of friction.

Impact Responses of the Carbon Fiber Fabric Reinforced Composites

To study the response characteristics of the carbon fiber fabric reinforced composites under impact loading, one dimensional strain impact test, multi gauge technique and Lagrange analysis method are used. The decaying rule of the stress σ , strain ε , strain rate ε · and density ρ with time and space is obtained. By the theory of dynamics, the impact response characteristics of the material is analyzed and discussed.

Entrance and Exit Defects During Coarse Pitch Orbital Drilling of Carbon Fiber Reinforced Plastic Plates

Formation of entrance and exit defects in coarse pitch orbital drilling(CPOD)of carbon fiber reinforced plastic(CFRP)plates was investigated.Deep observation on entrance and exit morphology shows tear and burr are typical defects.Meanwhile,tear is more obvious than burr,and more entrance tears emerge than exit tears.As one of the major causes of entrance and exit defects in CPOD,cutting forces were substaintially studied by contrast experiments.Then,the effect of cutting parameters on entrance and exit tear was qualitatively analyzed through a single factor test.Experiment results indicate that the variation of rotation speed has little influence on entrance and exit tear.Increasing tangential feed per tooth can enlarge entrance tear,but bring little effect on exit tear.By increasing axial feed pitch,the hole entrance and exit show severe tear.When revolution radius grows bigger and bigger,entrance and exit tear firstly decreases,and then increases.Finally,the models of tear and delamination during CPOD of CFRP were established,the formation mechanisms of entrance and exit defects were revealed,and the control strategies were accordingly put forward.

Experimental study on slender reinforced concrete columns wrapped with CFRP

By axial compression tests on 6 reinforced concrete slender columns wrapped with carbon fiber-reinforced plastic (CFRP),with slenderness ratio(SR) from 4.5 to 17.5,the results show that when SR increases the retrofitting effect declines. In the case of same SR,the stability coefficient (SC) for the reinforced concrete(RC) columns with CFRP is much less than that without CFRP. There is 20% increase of stable bearing capacity to the former as compared with the latter when the SR in less than 17.5. The study summarized the simplified formula for SC,which provides a reference for engineering designers.

Quasi-plane-hypothesis of strain coordination for RC beams seismically strengthened with externally-bonded or near-surface mounted fiber reinforced plastic

The application of fiber reinforced plastic（FRP）,including carbon FRP and glass FRP,for structural repair and strengthening has grown due to their numerous advantages over conventional materials such as externally bonded reinforcement（EBR） and near-surface mounted（NSM） strengthening techniques.This paper summarizes the results from 21 reinforced concrete beams strengthened with different methods,including externally-bonded and near-surface mounted FRP,to study the strain coordination of the FRP and steel rebar of the RC beam.Since there is relative slipping between the RC beam and the FRP,the strain of the FRP and steel rebar of the RC beam satisfy the quasi-plane-hypothesis;that is,the strain of the longitudinal fiber that parallels the neutral axis of the plated beam within the scope of the effective height（h 0） of the cross section is in direct proportion to the distance from the fiber to the neutral axis.The strain of the FRP and steel rebar satisfies the equation：ε FRP =βε steel,and the value of β is equal to 1.1-1.3 according to the test results.

Double linear strain distribution assumption of RC beam strengthened with external-bonded or near-surface mounted fiber reinforced plastic

Rehabilitation of existing structures with fiber reinforced plastic(FRP)has been growing in popularity because they offer superior performance in terms of resistance to corrosion and high specific stiffness.The strain coordination results of 34 reinforced concrete beams(four groups)strengthened with different methods were presented including external-bonded or near-surface mounted glass or carbon FRP or helical rib bar in order to study the strain coordination of the strengthening materials and steel rebar of RC beam.Because there is relative slipping between concrete and strengthening materials(SM),the strain of SM and steel rebar of RC beam satisfies the double linear strain distribution assumption,that is,the strain of longitudinal fiber parallel to the neutral axis of plated beam within the scope of effective height(h0)of the cross section is in direct proportion to the distance from the fiber to the neutral axis.The strain of SM and steel rebar satisfies the equation εGCH=βεsteel,where the value of β is equal to 1.1-1.3 according to the test results.

Strain coordination of quasi-plane-hypothesis for reinforced concrete beam strengthened by epoxy-bonded glass fiber reinforced plastic plate

The testing of thirteen reinforeed concrete （RC） beams strengthened by epoxy-bonded glass fiber reinforced plastic plate （GFRP） shows that the RC beam and the GFRP plate with epoxy bonding on it can work fairly well in coordination to eaeh other. But there is relative slipping between RC beam and GFRP plate. And the strain of GFRP and steel rebar of RC beam satisfies the quasi-plane-hypothesis, that is, the strain of longitudinal fiher that parallels to the neutral axis of plated beam within the scope of effective height （ h0 ） of the cross section is in direct proportion to the distance from the fiber to the neutral axis. The strain of GFRP and steel rebar satisfies the equation： εGFRP=Kεsteel.

Feasibility study of wave-motion milling of carbon fiber reinforced plastic holes

Carbon fiber reinforced plastic(CFRP)has been applied in aeronautics,aerospace,automotive and medical industries due to its superior mechanical properties.However,due to its difficult-to-cut characteristic,various damages in twist drilling and chip removal clog in core drilling could happen,inevitably reducing hole quality and hole-manufacturing efficiency.This paper proposes the wave-motion milling(WMM)method for CFRP hole-manufacturing to improve hole quality.This paper presents a motion path model based on the kinematics of the WMM method.The wave-motion cutting mode in WMM was analyzed first.Then,comparison experiments on WMM and conventional helical milling(CHM)of CFRP were carried out under dry conditions.The results showed that the hole surface quality of the CFRP significantly improved with a decrease of 18.1%–36%of Ra value in WMM compared to CHM.WMM exerted a significantly weaker thrust force than that of CHM with a reduction of 12.0%–24.9%and 3%–7.7%for different axial feed per tooth and tangential feed per tooth,respectively.Meanwhile,the hole exit damages significantly decreased in WMM.The average tear length at the hole exit in WMM was reduced by 3.5%–29.5%and 35.5%–44.7%at different axial feed per tooth and tangential feed per tooth,respectively.Moreover,WMM significantly alleviated tool wear.The experimental results suggest that WMM is an effective and promising strategy for CFRP hole-manufacturing.

Numerical Determination of Shear Strength of Steel Reinforced Concrete Column Strengthened by CFRP Sheets

The earthquake resistant property of reinforced concrete members depends on the interaction between reinforcing bars and surrounding concrete through bond to a large degree. In this paper a general system aimed at dealing with the failure analysis of reinforced concrete columns strengthened with carbon fiber reinforced plastic (CFRP) sheets including bond slip of the anchored reinforcing bars at the foot of the columns is presented. It is based on the yield design theory with a mixed modeling of the structure, according to which the concrete material is treated as a classical two dimensional continuum, whereas the longitudinal reinforcing bars are regarded as one dimensional rods including bond slip at the foot of the columns. In shear reinforced zones both the shear CFRP sheets and transverse reinforcing bars are incorporated in the analysis through a homogenization procedure and they are only in tension. The approach is then implemented numerically by means of the finite element formulation. The numerical procedure produces accurate estimates for the loading carrying capacity of the shear members taken as an illustrative application by correlation with the experimental results, so the proposed approach is valid.

Shear capacity of reinforced concrete columns strengthened with CFRP sheet

This paper discusses the results of tests on the shear capacity of reinforced concrete columns strengthened with carbon fiber reinforced plastic (CFRP) sheet. The shear transfer mechanism of the specimens reinforced with CFRP sheet was studied. The factors affecting the shear capacity of reinforced concrete columns strengthened with CFRP sheet were analyzed. Several sug-gestions such as the number of layers, width and tensile strength of the CFRP sheet are proposed for this new strengthening technique. Finally, a simple and practical design method is presented in the paper. The calculated results of the suggested method are shown to be in good agreement with the test results. The suggested design method can be used in evaluating the shear capacity of reinforced concrete columns strengthened with CFRP sheet.

EXTRUSION DIE CAE OF THE STEEL REINFORCED PLASTIC PIPE

The steel reinforced plastic pipe is a new kind of pressure pipe. It is made up with steelwires and plastic. Because reinforced skeleton of the steel wire increase the complexityof plastic flow during the extrusion phase, the traditional design criteria of extrusiondie is not suitable. The study on extrusion die of the kind of pipe is very importantstep in produce development. Using finite element (FE) method in this paper, theflow rule of molten plastic inside the die has been predicted and a groap of optimalstructural parameters was obtained. These results are helpful for reducing the designcycle and improve the quality of the final product.

Dynamic Characteristics Analysis of Multilayer Fiber Reinforced Plastic Shaft

In order to study the dynamic characteristics of multilayer fiber reinforced plastic(MFRP)shaft,the coupling model of three-dimensional equivalent bending stiffness theory and transfer matrix method is established,and the influence of thickness-radius ratio,length-radius ratio,layer angles,layer proportion,and stacked approaches on MFRP shaft dynamic characteristics is investigated.The result shows that the proposed coupling model has high accuracy in MFRP shaft dynamic performance prediction.The proportion of small-angle layers is the decisive factor of MFRP shaft natural frequency.With the increase of thickness-radius ratio and length-radius ratio,the natural frequency of MFRP shaft decreases.The natural frequency of MFRP shaft with the angle layers combination of±45°and±90°is smaller compared with the metal shaft no matter in simple/free boundary condition or simple/simple supported boundary condition.

Flexural Behavior of FRP-Reinforced Concrete Composite Member

Concrete Filled FRP （Reinforced Polymeric Plastic） Tubes （CFFT） and Reinforced Concrete Filled FRP Tubes （RCFFT） are known to have the capability to enhance structural performance in terms of structural stability, ductility, as well as chemical resistance when compared with conventional concrete members. In this study, the authors evaluate the structural performance of the CFFT and the RCFFT through flexural tests for the purpose of applying the members as flexural ones. Moreover, the compressive behavior of the CFFT and the RCFFT members was investigated to examine their confinement effects. Based on the experimental and analytical results of the compressive behavior of the members, equations for estimating the ultimate compressive strengths of the CFFT and the RCFFT were proposed. In addition, the degree of improvement on the flexural performance of the RCFFT member strengthened by the FRP was analyzed from the flexural tests.