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Efficient removal of Al(Ⅲ)and P507 from high concentration MgCl_(2)solution based on in-situ reaction strategy
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作者 Qiang WANG Meng WANG +3 位作者 Zong-yu FENG Yong-qi ZHANG Xiao-wei HUANG Xiang-xin XUE 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第9期3042-3053,共12页
For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high conce... For a highly efficient recycling of a wastewater containing a high concentration of MgCl_(2),Al(Ⅲ)and P507 were scheduled to be removed in advance.In this study,the in-situ removal of Al(Ⅲ)and P507 from a high concentration MgCl_(2)solution at different pH values and Al/P molar ratios was investigated.The results showed that P507 formed organic complexes of Al_(x)(OH)_y^(Z+)-P507 at pH of 2.0-4.0.At pH of 4.0-5.0,Al(Ⅲ)precipitated and transferred into Al(OH)_(3)with a flocculent amorphous morphology.Active sites on the Al(OH)_(3)surface enhanced the removal efficiency of P507.At pH of 6.0-6.5,Al(Ⅲ)and Mg(Ⅱ)formed layered crystalline Al(OH)_(3)and MgAl_(2)(OH)_(8with)small pore channels and fewer active sites,resulting in a reduced removal efficiency of P507.When the Al/P molar ratio exceeded 13 and the pH was between 4.0 and 5.0,the removal rates of both Al(Ⅲ)and P507 were higher than98%,while the concentration loss of Mg(Ⅱ)was only 0.2%-0.9%. 展开更多
关键词 in-situ removal AL(III) p507 MgCl_(2)solution pH Al/p molar ratio
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Electro-assisted photocatalytic reduction of CO_(2) in ambient air using Ag/TNTAs at the gas-solid interface
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作者 Feng Yue Zhaoya Fan +7 位作者 Cong Li Yang Meng Shuo Zhang Mengke Shi Minghua Wang Mario Berrettoni Jun Li Hongzhong Zhang 《Materials Reports(Energy)》 EI 2024年第2期71-82,共12页
The direct conversion of atmospheric CO_(2) into fuel via photocatalysis exhibits significant practical application value in advancing the carbon cycle.In this study,we established an electro-assisted photocatalytic s... The direct conversion of atmospheric CO_(2) into fuel via photocatalysis exhibits significant practical application value in advancing the carbon cycle.In this study,we established an electro-assisted photocatalytic system with dual compartments and interfaces,and coated Ag nanoparticles on the titanium nanotube arrays(TNTAs)by polydopamine modification.In the absence of sacrificial agent and alkali absorption liquid conditions,the stable,efficient and highly selective conversion of CO_(2) to CO at the gas-solid interface in ambient air was realized by photoelectric synergy.Specifically,with the assistance of potential,the CO formation rates reached 194.9μmol h^(−1) m^(−2) and 103.9μmol h^(−1) m^(−2) under ultraviolet and visible light irradiation,respectively;the corresponding CO_(2) conversion rates in ambient air were 30%and 16%,respectively.The excellent catalytic effect is mainly attributed to the formation of P–N heterojunction during the catalytic process and the surface plasmon resonance effect.Additionally,the introduction of solid agar electrolytes effectively inhibits the hydrogen evolution reaction and improves the electron utilization rate.This system promotes the development of photocatalytic technology for practical applications and provides new insights and support for the carbon cycle. 展开更多
关键词 Electro-assisted photocatalytic Gas-solid interface Ambient air pn heterojunction practical applications
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Study on the optimal incident proton energy of ^(7)Li(p,n)^(7)Be neutron source for boron neutron capture therapy
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作者 Yi-Nan Zhu Zuo-Kang Lin +3 位作者 Hai-Yan Yu Ye Dai Zhi-Min Dai Xiao-Han Yu 《Nuclear Science and Techniques》 SCIE EI CAS CSCD 2024年第3期170-180,共11页
Boron neutron capture therapy(BNCT)is recognized as a precise binary targeted radiotherapy technique that effectively eliminates tumors through the^(10)B(n,α)^(7)Li nuclear reaction.Among various neutron sources,acce... Boron neutron capture therapy(BNCT)is recognized as a precise binary targeted radiotherapy technique that effectively eliminates tumors through the^(10)B(n,α)^(7)Li nuclear reaction.Among various neutron sources,accelerator-based sources have emerged as particularly promising for BNCT applications.The^(7)Li(p,n)^(7)Be reaction is highly regarded as a potential neutron source for BNCT,owing to its low threshold energy for the reaction,significant neutron yield,appropriate average neutron energy,and additional benefits.This study utilized Monte Carlo simulations to model the physical interactions within a lithium target subjected to proton bombardment,including neutron moderation by an MgF_(2)moderator and subsequent BNCT dose analysis using a Snyder head phantom.The study focused on calculating the yields of epithermal neutrons for various incident proton energies,finding an optimal energy at 2.7 MeV.Furthermore,the Snyder head phantom was employed in dose simulations to validate the effectiveness of this specific incident energy when utilizing a^(7)Li(p,n)^(7)Be neutron source for BNCT purposes. 展开更多
关键词 Boron neutron capture therapy ^(7)Li(p n)7Be neutron source Incident proton energy Monte Carlo simulation
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Effects of drought on non-structural carbohydrates and C,N,and P stoichiometric characteristics of Pinus yunnanensis seedlings
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作者 Zhijuan Zhao Lina Wang +7 位作者 Yuanxi Liu Jianli Sun Jiandong Xiao Qiong Dong Lianfang Li Wanjie Zhang Chao Wang Junwen Wu 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第1期90-102,共13页
To study non-structural carbohydrate character-istics and nutrient utilization strategies of Pinus yunnanen-sis under continuous drought conditions,2-year-old seed-lings were planted in pots with appropriate water,lig... To study non-structural carbohydrate character-istics and nutrient utilization strategies of Pinus yunnanen-sis under continuous drought conditions,2-year-old seed-lings were planted in pots with appropriate water,light and moderate and severe drought treatments[(80±5),(65±5),(50±5),and(35±5)%of field water-holding capacity].Non-structural carbohydrates,carbon(C),nitrogen(N),and phosphorus(P)concentrations were measured in each plant component.The results show that:(1)With increasing drought,non-structural carbohydrates gradually increased in leaves,stems,and coarse roots,while gradually decreased in fine roots;(2)C concentrations of all were relatively stable under different stress levels.Phosphorous utilization of each component increased under light and moderate drought conditions,while N and P utilization efficiency of each plant component decreased under severe drought.Growth was mainly restricted by N,first decreasing and then increasing with increased drought;(3)There was a correlation between the levels of non-structural carbohydrates and C,N,and P in each component.Changes in N concentration affected the interconversion between soluble sugar and starch,which play a regulatory role in the fluctuation of the concentration of non-structural carbohydrates;and,(4)Plasticity analysis showed that P.yunnanensis seedlings responded to drought mainly by altering starch concentration,the ratio of soluble sugar to starch in leaves and stems,and further by alter-ing N and P utilization efficiencies.Overall,these results suggest that the physiological activities of all organs of P.yunnanensis seedlings are restricted under drought and that trade-offs exist between different physiological indicators and organs.Our findings are helpful in understanding non-structural carbohydrate and nutrient adaptation mechanisms under drought in P.yunnanensis seedlings. 展开更多
关键词 pinus yunnanensis seedlings DROUGHT non-structural carbohydrates C n p stoichiometric characteristics
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Effects of tree size and organ age on variations in carbon,nitrogen,and phosphorus stoichiometry in Pinus koraiensis
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作者 Yanjun Wang Guangze Jin Zhili Liu 《Journal of Forestry Research》 SCIE EI CAS CSCD 2024年第3期155-165,共11页
Carbon(C),nitrogen(N),and phosphorus(P)are of fundamental importance for growth and nutrient dynamics within plant organs and deserve more attention at regional to global scales.However,our knowledge of how these nutr... Carbon(C),nitrogen(N),and phosphorus(P)are of fundamental importance for growth and nutrient dynamics within plant organs and deserve more attention at regional to global scales.However,our knowledge of how these nutrients vary with tree size,organ age,or root order at the individual level remains limited.We determined C,N,and P contents and their stoichiometric ratios(i.e.,nutrient traits)in needles,branches,and fine roots at different organ ages(0-3-year-old needles and branches)and root orders(1st-4th order roots)from 64 Pinus koraiensis of varying size(Diameter at breast height ranged from 0.3 to 100 cm)in northeast China.Soil factors were also measured.The results show that nutrient traits were regulated by tree size,organ age,or root order rather than soil factors.At a whole-plant level,nutrient traits decreased in needles and fine roots but increased in branches with tree size.At the organ level,age or root order had a negative effect on C,N,and P and a positive effect on stoichiometric ratios.Our results demonstrate that nutrient variations are closely related to organ-specific functions and ecophysiological processes at an individual level.It is suggested that the nutrient acquisition strategy by younger trees and organ fractions with higher nutrient content is for survival.Conversely,nutrient storage strategy in older trees and organ fractions are mainly for steady growth.Our results clarified the nutrient utilization strategies during tree and organ ontogeny and suggest that tree size and organ age or root order should be simultaneously considered to understand the complexities of nutrient variations. 展开更多
关键词 Tree size Organ age(or root order) Carbon(C) nitrogen(n) phosphorus(p) pinus koraiensis
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Investigation on Breakdown Characteristics of Various Surface Terminal Structures for GaN-Based Vertical P-i-N Diodes
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作者 Song Shi Guanyu Wang +5 位作者 Yingcong Xiang Chuan Guo Xing Wang Yinlin Pu Huilan Li Zhixian Li 《Journal of Applied Mathematics and Physics》 2024年第2期554-568,共15页
GaN-based vertical P-i-N diode with mesa edge terminal structure due to electric field crowding effect, the breakdown voltage of the device is significantly reduced. This work investigates three terminal structures, i... GaN-based vertical P-i-N diode with mesa edge terminal structure due to electric field crowding effect, the breakdown voltage of the device is significantly reduced. This work investigates three terminal structures, including deeply etched, bevel, and stepped-mesas terminal structures, to suppress electric field crowding effects at the device and junction edges. Deeply-etched mesa terminal yields a breakdown voltage of 1205 V, i.e., 89% of the ideal voltage. The bevel-mesa terminal achieves about 89% of the ideal breakdown voltage, while the step-mesa terminal is less effective in mitigating electric field crowding, at about 32% of the ideal voltage. This work can provide an important reference for the design of high-power, high-voltage GaN-based P-i-N power devices, finding a terminal protection structure suitable for GaNPiN diodes to further enhance the breakdown performance of the device and to unleash the full potential of GaN semiconductor materials. 展开更多
关键词 Gan p-I-n Mesa Edge Terminal Electric Field Crowding
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Effects of COD to Phosphorus Ratios on the Metabolism of PAOs in Enhanced Biological Phosphorus Removal with Different Carbon Sources 被引量:2
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作者 Tao Jiang Junguo He +1 位作者 Xiaonan Yang Jianzheng Li 《Journal of Harbin Institute of Technology(New Series)》 EI CAS 2015年第4期87-91,共5页
To elucidate the phosphorus removal and metabolism under various COD / P ratio,a sludge highly enriched in PAOs was used to investigate the impacts of COD / P in batch tests under different carbon supply conditions. A... To elucidate the phosphorus removal and metabolism under various COD / P ratio,a sludge highly enriched in PAOs was used to investigate the impacts of COD / P in batch tests under different carbon supply conditions. Acetate,propionate and a mixture of acetate and propionate at a ratio of 3 ∶ 1( COD basis) was used as carbon sources with the COD / P of 20,15,10 and 5. 0 g COD /gP,respectively. The minimum COD / P ratios for complete P removal were found to be 8. 24 g COD /gP for acetate,11. 40 g COD /gP for propionate and9. 10 g COD /gP for the 3 ∶ 1 mixture of acetate and propionate. Converted to a mass basis,all three cases had a very similar ratio of 7. 7 g VFA /gP,which represented a useful guide for operation of EBPR plants to identify possible shortages in VFAs. The trend in PHV accumulation during the anaerobic period along with the decrease of COD / P ratios suggested that,PAOs may use the TCA pathway for anaerobic VFA uptake to maintain the required NADH production with reduced glycogen degradation. During the aerobic phase,the glycogen pool was reduced but remained enough compared to the requirement for anaerobic VFA uptake,and the synthesis and degradation of glycogen was not the inhibition factor of PAOs. 展开更多
关键词 enhanced biological phosphorus removal COD / p ratio ACETATE GLYCOGEn
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Comparison of foliar nutrient concentrations between natural and artificial forests of Pinus sylvestris var. mongolica on sandy land, China 被引量:7
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作者 ZHU Jiao-jun TAN Hui +1 位作者 KANG Hong-zhang XU Mei-ling 《Journal of Forestry Research》 SCIE CAS CSCD 2006年第3期177-184,共8页
In order to examine the causes of degradation of Pinus sylvestris var. mongolica plantations on sandy land, the foliar concentrations of N, P, K and C were analyzed and compared between the field grown P. sylvestris v... In order to examine the causes of degradation of Pinus sylvestris var. mongolica plantations on sandy land, the foliar concentrations of N, P, K and C were analyzed and compared between the field grown P. sylvestris var. mongolica trees from two provenances (natural forests and plantations). The results indicated that natural tree needles had lower N, P and C concentrations, and higher K concentrations than those of plantation tree needles. For plantation tree needles, ratios of N: P, P. K and N: K increased with tree age before 45 years old; but they were not clear for the natural tree needles. Compared with the conclusions reported on Pinus spp., we found that the foliar N and P concentrations were in the optimal range for both natural and plantation tree needles. This result suggested that N or P might not be the absolute limit factors in plant nutrient for P sylvestris var. mongolica on sandy land. However, foliar K concentrations in both natural and plantation tree needles were much lower than those reported on Pinus spp. (〉4.80 g kg-1).The N: P ratio of natural needles was in the adequate ranges, but N: P ratio of plantation needles was out of the adequate ranges. These results indicated that there was a better balanced nutrition status in the natural forest than in the plantations. If only considering the foliar nutrient concentrations of P sylvestris var. mongolica from different provenances, it might be concluded that the degradation phenomenon of P. sylvestris var. mongolica plantations was not induced by nutrition deficiency of absolute nutrients of N and P, but might be induced by other mineral nutrients or by the effectiveness of N and P nutrients. The unbalanced nutrition status and relatively quick decomposition of needles in the plantations might also contribute to the degradation. 展开更多
关键词 Degradation phenomenon Forest ecosystem on sandy land n p ratio natural Mongolian pine pinus sylvestris var. mongolica plantation Mongolian pine
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The Electrophysiology of Semantic Processing in Individuals with Autism Spectrum Disorder:A Meta-Analysis
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作者 Danfeng Yuan Xiangyun Yang +1 位作者 Lijuan Yang Zhanjiang Li 《International Journal of Mental Health Promotion》 2023年第10期1067-1079,共13页
Language difficulties vary widely among people with autism spectrum disorder(ASD).However,the semantic processing of autistic person and its underlying electrophysiological mechanism are still unclear.This meta-analys... Language difficulties vary widely among people with autism spectrum disorder(ASD).However,the semantic processing of autistic person and its underlying electrophysiological mechanism are still unclear.This meta-analysis aimed to explore the disturbance of semantic processing in patients with ASD.PubMed,Web of Science,and Embase were searched for eventrelated potential(ERP)studies on semantic processing in autistic people published in English before September 01,2022.Pooled estimates were calculated by fixed-effects or random-effects models according to the heterogeneity using Comprehensive Meta-Analysis 2.0.The potential moderators were explored by meta-regression and subgroup analysis.This meta-analysis has been registered at the Prospero International Prospective Register of Systematic Reviews(no.CRD 42021265852).A total of 14 articles and 18 studies,including 254 autistic people and 262 neurodevelopmental people were included in this meta-analysis.Compared to the comparison group,autistic people showed an overall reduced N400 amplitude(Hedges’g=0.350,p<0.001)in response to linguistic stimuli instead of non-linguistic stimuli.The N400 amplitude was affected by verbal intelligence and gender.The reduced overall N400 amplitude in autistic people under linguistic stimuli suggests a linguistic-specific deficit in semantic processing in individuals of autism.The decrease of N400 amplitude might be a promising indication of the pool language capacity of autism. 展开更多
关键词 Autism spectrum disorder n400 p600 SEMAnTIC event-related potential META-AnALYSIS
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CuO/CeO_(2) p−n异质结光催化降解亚甲基蓝的性能及机理
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作者 陈欢欢 罗绍华 +3 位作者 雷雪飞 滕飞 纪献兵 李晓东 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2024年第6期1951-1964,共14页
采用简单微波回流法和均相沉淀技术合成CuO/CeO_(2) p−n异质结复合材料,并对其光催化降解亚甲基蓝溶液的性能进行研究。CuO/CeO_(2)异质结复合材料的降解效率明显强于CeO_(2)。结果表明,以Cu/Ce摩尔比为1/3制备的复合材料(1/3 Cu/Ce)的... 采用简单微波回流法和均相沉淀技术合成CuO/CeO_(2) p−n异质结复合材料,并对其光催化降解亚甲基蓝溶液的性能进行研究。CuO/CeO_(2)异质结复合材料的降解效率明显强于CeO_(2)。结果表明,以Cu/Ce摩尔比为1/3制备的复合材料(1/3 Cu/Ce)的光催化活性最高,在180 min内降解效率达到96.2%。CuO和CeO_(2)之间形成的p−n异质结促进了光生载流子的分离和传输,从而提高了其光催化活性。计算了CuO/CeO_(2)异质结的能带位置偏移,其价带偏移(∆EVBO)为1.58 eV,导带偏移(∆ECBO)为−0.48 eV。计算结果进一步证明CuO与CeO_(2)之间形成了p−n异质结。 展开更多
关键词 CUO CeO_(2) pn异质结 光催化机理 亚甲基蓝
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Atmospheric nitrogen deposition affects forest plant and soil system carbon:nitrogen:phosphorus stoichiometric flexibility:A meta-analysis
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作者 Xiyan Jiang Xiaojing Wang +7 位作者 Yaqi Qiao Yi Cao Yan Jiao An Yang Mengzhou Liu Lei Ma Mengya Song Shenglei Fu 《Forest Ecosystems》 SCIE CSCD 2024年第3期307-317,共11页
Background:Nitrogen(N)deposition affects forest stoichiometric flexibility through changing soil nutrient availability to influence plant uptake.However,the effect of N deposition on the flexibility of carbon(C),N,and... Background:Nitrogen(N)deposition affects forest stoichiometric flexibility through changing soil nutrient availability to influence plant uptake.However,the effect of N deposition on the flexibility of carbon(C),N,and phosphorus(P)in forest plant-soil-microbe systems remains unclear.Methods:We conducted a meta-analysis based on 751 pairs of observations to evaluate the responses of plant,soil and microbial biomass C,N and P nutrients and stoichiometry to N addition in different N intensity(050,50–100,>100 kg·ha^(-1)·year^(-1)of N),duration(0–5,>5 year),method(understory,canopy),and matter(ammonium N,nitrate N,organic N,mixed N).Results:N addition significantly increased plant N:P(leaf:14.98%,root:13.29%),plant C:P(leaf:6.8%,root:25.44%),soil N:P(13.94%),soil C:P(10.86%),microbial biomass N:P(23.58%),microbial biomass C:P(12.62%),but reduced plant C:N(leaf:6.49%,root:9.02%).Furthermore,plant C:N:P stoichiometry changed significantly under short-term N inputs,while soil and microorganisms changed drastically under high N addition.Canopy N addition primarily affected plant C:N:P stoichiometry through altering plant N content,while understory N inputs altered more by influencing soil C and P content.Organic N significantly influenced plant and soil C:N and C:P,while ammonia N changed plant N:P.Plant C:P and soil C:N were strongly correlated with mean annual precipitation(MAT),and the C:N:P stoichiometric flexibility in soil and plant under N addition connected with soil depth.Besides,N addition decoupled the correlations between soil microorganisms and the plant.Conclusions:N addition significantly increased the C:P and N:P in soil,plant,and microbial biomass,reducing plant C:N,and aggravated forest P limitations.Significantly,these impacts were contingent on climate types,soil layers,and N input forms.The findings enhance our comprehension of the plant-soil system nutrient cycling mechanisms in forest ecosystems and plant strategy responses to N deposition. 展开更多
关键词 C:n:p stoichiometry META-AnALYSIS Forest ecosystem nitrogen addition form nutrient cycles
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Diverse functions of GmNLA1 members in controlling phosphorus homeostasis highlight coordinate response of soybean to nitrogen and phosphorus availability
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作者 Ming Zhou Yaxue Li +3 位作者 Xing Lu Panmin He Cuiyue Liang Jiang Tian 《The Crop Journal》 SCIE CSCD 2023年第4期1251-1260,共10页
Nitrogen(N) and phosphorus(P) are two essential mineral nutrients for plant growth,which are required in relative high amount in plants.Plants have evolved a series of strategies for coordinately acquiring and utilizi... Nitrogen(N) and phosphorus(P) are two essential mineral nutrients for plant growth,which are required in relative high amount in plants.Plants have evolved a series of strategies for coordinately acquiring and utilizing N and P.However,physiological and molecular mechanisms underlying of N and P interactions remain largely unclear in soybean(Glycine max).In this study,interactions of N and P were demonstrated in soybean as reflected by significant increases of phosphate(Pi) concentration in both leaves and roots by N deficiency under Pi sufficient conditions.A total of four nitrogen limitation adaptation(NLA),encoding RING-type E3 ubiquitin ligase were subsequently identified in soybean genome.Among them,transcription of Gm NLA1-1 and Gm NLA1-3 was decreased in soybean by N starvation under Pi sufficient conditions,not for Gm NLA1-2.Suppression of all three Gm NLA1 members was able to increase Pi concentration regardless of the P and N availability in the growth medium,but decrease fresh weight under normal conditions in soybean hairy roots.However,comparted to changes in control lines at two N levels,N deficiency only resulted in a relatively higher increase of Pi concentration in Gm NLA1-1 or Gm NLA1-3 suppression lines,strongly indicating that Gm NLA1-1 and Gm NLA1-3 might regulate P homeostasis in soybean response to N starvation.Taken together,our result suggest that redundant and diverse functions present in Gm NLA1 members for soybean coordinate responses to P and N availability,which mediate P homeostasis. 展开更多
关键词 GmnLA1 n availability p deficiency p homeostasis SOYBEAn
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Influence of the wastewater composition on denitrification and biological P-removal in the S-DN-P process: (c) Dissolved and undissolved substrates
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作者 Hee-Jeong Choi Chul-Ho Choi +1 位作者 Seung-Mok Lee Diwakar Tiwari 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2009年第8期1074-1079,共6页
The denitdfication and P-removal in the sorption-denitrification-P-removal (S-DN-P) process were carded out under various wastewater compositions. It is noted that P-removal largely depends on the wastewater composi... The denitdfication and P-removal in the sorption-denitrification-P-removal (S-DN-P) process were carded out under various wastewater compositions. It is noted that P-removal largely depends on the wastewater composition as well to the quantity of the substrates present in wastewater fraction. Three different wastewater fractions are obtained as: raw wastewater, dissolved wastewater (obtained with filtration using 0.45 μm filter), and undissolved wastewater (i.e., infiltrate obtained by above filtration). The ratio of P-release/CODtotal-consumption clearly inferred that undissolved wastewater possess very low value i.e., 0.0008 followed by raw wastewater 0.008 and dissolved wastewater 0.03. When this ratio was nearby 0.01, enhanced P-removal was observed. Moreover, the ratio of P-uptake to NO3^--N decomposition for raw wastewater was two times for dissolved wastewater. Interestingly, it was observed that the P-removal and denitrification depend not only on the dissolved substrates but also the undissolved substrates present in the wastewater. The result of the P-removal obtained with this S-DN-P process did not show a big difference of 36%, 34% and 30%, respectively, for raw, dissolved and undissolved wastewater. 展开更多
关键词 DEnITRIFICATIOn pOLYHYDROXYBUTYRATE sequencing batch biofilm reactor sorption denitrification p-removals
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Microbial synthesis of N, P co-doped carbon supported PtCu catalysts for oxygen reduction reaction
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作者 Shaohui Zhang Suying Liu +6 位作者 Jingwen Huang Haikun Zhou Xuanzhi Liu Pengfei Tan Haoyun Chen Yili Liang Jun Pan 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2023年第9期486-495,共10页
Developing highly efficient and stable platinum-based electrocatalyst for oxygen reduction reaction(ORR) is critical to expediting commercialization of fuel cells.Herein,several PtCu alloy nanocatalysts supported on N... Developing highly efficient and stable platinum-based electrocatalyst for oxygen reduction reaction(ORR) is critical to expediting commercialization of fuel cells.Herein,several PtCu alloy nanocatalysts supported on N,P co-doped carbon(PtCu/NPC) were prepared by microbial-sorption and carbonization-reduction.Among them,PtCu/NPC-700 ℃ exhibits excellent catalytic performance for ORR with a mass activity of 0.895 A mg_(pt)^(-1)(@0.9 V) which is 8.29 folds of commercial Pt/C.Additionally,the ECSA and MA of PtCu/NPC-700℃ only decrease by 14.2% and 18.7% respectively,while Pt/C decreases by 35.2% and 52.8% after 10,000 cycles of ADT test.Moreover,the PtCu/NPC-700℃ catalyst emanates a maximum power density of 715 mW cm^(-2) and only 11.1% loss of maximum power density after 10,000 ADTs in single-cell test,indicating PtCu/NPC-700℃ also manifests higher activity and durability in actual single-cell operation than Pt/C.This research provides an easy and novel strategy for developing highly active and durable Pt-based alloy catalyst. 展开更多
关键词 Microbial synthesis n p co-doping ptCu catalyst Oxygen reduction reaction
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Construction of multi-walled carbon nanotubes/ZnSnO_(3)heterostructures for enhanced acetone sensing performance
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作者 杜丽勇 孙鹤鸣 《Chinese Physics B》 SCIE EI CAS CSCD 2023年第5期371-377,共7页
Carbon nanotubes(CNTs)have attracted many researcher's attention in gas sensing field because of their excellent physical and chemical properties.Herein,multi-walled carbon nanotubes(MWCNTs)/ZnSnO_(3)heterostructu... Carbon nanotubes(CNTs)have attracted many researcher's attention in gas sensing field because of their excellent physical and chemical properties.Herein,multi-walled carbon nanotubes(MWCNTs)/ZnSnO_(3)heterostructures have been obtained by a simple hydrothermal method without additional annealing process.The structural and composition information are characterized by x-ray diffraction(XRD),field-emission scanning electron microscopy(FESEM),transmission electron microscopy(TEM)and x-ray photoelectron spectroscopy(XPS).The acetone sensing properties of pure MWCNTs,ZnSnO_(3)and MWCNTs/ZnSnO_(3)heterostructures are systematically investigated,respectively.The results show that MWCNTs/ZnSnO_(3)heterostructures have better sensing properties compared with pure MWCNTs and ZnSnO_(3)sample.Specifically,MWCNTs/ZnSnO_(3)heterostructures exhibit not only high responses of 24.1 and rapid response/recovery speed of 1 s/9 s to 100 ppm acetone,but also relatively good repeatability and long-term stability.The enhanced sensing performance is analyzed in detail.In addition,this work provides the experimental and theory basis for synthesis of high-performance MWCNT-based chemical sensors. 展开更多
关键词 carbon nanotube ZnSnO_(3) pn heterostructures ACETOnE
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Spatial Distribution of Soil Total Nutrients of Farmland in Liaoning Province 被引量:14
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作者 吕国红 张玉书 +2 位作者 陈鹏狮 纪瑞鹏 焦晓光 《Agricultural Science & Technology》 CAS 2010年第1期154-158,共5页
[Objective]The aim was to reveal the spatial distribution characteristics of total nutrients in soil and provide a theoretical basis for farmland management and improvement of crop yield. [Method]GIS technique was use... [Objective]The aim was to reveal the spatial distribution characteristics of total nutrients in soil and provide a theoretical basis for farmland management and improvement of crop yield. [Method]GIS technique was used to analyze the spatial distribution characteristics of total C,total N,total P and total K for different soil layers in Liaoning Province. [Result]The results showed that the content of total C,total N,total P decrease from east to west,but the content of total K was high in north district of Liaoning Province. The content of total C,total N,total P and total K was higher in soil surface (0-20 cm) than the lower (20-40 cm). Total K varied less with soil depth,and its mean content was respectively 17.64 g/kg and 17.08 g/kg for soil surface and soil lower layer. [Conclusion]The results of the distribution of soil total nutrients in different soil layers supplied a theory basis for farmland management. 展开更多
关键词 Total C Total n Total p Total K Spatial distribution
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Fuzzy Foldness of P-Ideals in BCI-Algebras
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作者 Mahasin A. Ahmed 《Journal of Applied Mathematics and Physics》 2020年第10期2129-2141,共13页
This paper aims to introduce new notions of (fuzzy) n-fold P-ideals and (fuzzy) n-fold weak P-ideals in BCI-algebras, and investigate several properties of the foldness theory of P-ideals in BCI-algebras. Finally, we ... This paper aims to introduce new notions of (fuzzy) n-fold P-ideals and (fuzzy) n-fold weak P-ideals in BCI-algebras, and investigate several properties of the foldness theory of P-ideals in BCI-algebras. Finally, we construct a computer-program for studying the foldness theory of P-ideals in BCI-algebras. 展开更多
关键词 BCK/BCI Algebras p-Ideals of BCI-Algebras Fuzzy p-Ideal of BCI-Algebra Fuzzypoint (Fuzzy) n-Fold p-Ideals (Fuzzy) n-Fold Weak p-Ideals
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Fertilization Affects Biomass Production of Suaeda salsa and Soil Organic Carbon Pool in East Coastal Region of China 被引量:5
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作者 MENG Qing-feng YANG Jing-song +2 位作者 YAO Rong-jiang LIU Guang-ming YU Shi-peng 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2013年第9期1659-1672,共14页
Land use practice significantly affects soil properties. Soil is a major sink for atmospheric carbon, and soil organic carbon (SOC) is considered as an essential indicator of soil quality. The objective of this stud... Land use practice significantly affects soil properties. Soil is a major sink for atmospheric carbon, and soil organic carbon (SOC) is considered as an essential indicator of soil quality. The objective of this study was to assess the effects of N and P applied to Suaeda salsa on biomass production, SOC concentration, labile organic carbon (LOC) concentration, SOC pool and carbon management index (CMI) as well as the effect of the land use practice on soil quality of coastal tidal lands in east coastal region of China. The study provided relevant references for coastal exploitation, tidal land management and related study in other countries and regions. The field experiment was laid out in a randomized complete block design, consisting of four N-fertilization rates (0 (NO), 60 (N1), 120 (N2) and 180 kg ha-1 (N3)), three P-fertilization rates (0 (P0), 70 (P1) and 105 kg ha-~ (P2)) and bare land without vegetation. N and P applied to S. salsa on coastal tidal lands significantly affected biomass production (above-ground biomass and roots), bulk density (Pb), available N and P, SOC, LOC, SOC pool and CMI. Using statistical analysis, significantly interactions in N and P were observed for biomass production and the dominant factor for S. salsa production was N in continuous 2-yr experiments. There were no significant interactions between N and P for SOC concentration, LOC concentration and SOC pool. However, significant interaction was obtained for CMI at the 0-20 cm depth and N played a dominant role in the variation of CMI. There were significant improvements for soil measured attributes and parameters, which suggested that increasing the rates of N and P significantly decreased Pb at the 0-20 cm depth and increased available N and P, SOC, LOC, SOC pool as well as CMI at both the 0-20 and 20-40 cm depth, respectively. By correlation analysis, there were significantly positive correlations between biomass (above- ground biomass and roots) and SOC as well as LOC in 2010 and 2011 across all soil depth, respectively. The treatment with N at 180 kg ha-~ and P at 105 kg ha-1 was superior to the other treatments. The results from the 2-yr continuous experiments indicated that, in short-term, there were a few accumulation of SOC and LOC concentrations by means of N and P application to S. salsa, whereas in the long run, S. salsa with N and P application was recommended for coastal tidal lands because of its great potential of carbon sequestration, improvements of soil nutrition status and promotion of soil quality. 展开更多
关键词 Suaeda salsa production coastal tidal lands n and p application soil organic carbon labile organic carbon carbon management index
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Generation and transformation of ROS on g-C_3N_4 for efficient photocatalytic NO removal:A combined in situ DRIFTS and DFT investigation 被引量:4
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作者 Jieyuan Li Ping Yan +5 位作者 Kanglu Li Wanglai Cen Xiaowei Yu Shandong Yuan Yinghao Chu Zhengming Wang 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2018年第10期1695-1703,共9页
Understanding the performance of reactive oxygen species(ROS)in photocatalysis is pivotal for advancing their application in environmental remediation.However,techniques for investigating the generation and transforma... Understanding the performance of reactive oxygen species(ROS)in photocatalysis is pivotal for advancing their application in environmental remediation.However,techniques for investigating the generation and transformation mechanism of ROS have been largely overlooked.In this study,considering g‐C3N4 to be a model photocatalyst,we have focused on the ROS generation and transformation for efficient photocatalytic NO removal.It was found that the key to improving the photocatalysis performance was to enhance the ROS transformation from·O2^-to·OH,elevating the production of·OH.The ROS directly participate in the photocatalytic NO removal and tailor the rate‐determining step,which is required to overcome the high activation energy of the intermediate conversion.Using a closely combined experimental and theoretical method,this work provides a new protocol to investigate the ROS behavior on g‐C3N4 for effective NO removal and clarifies the reaction mechanism at the atomic level,which enriches the understanding of ROS in photocatalytic environmental remediation. 展开更多
关键词 pHOTOCATALYSIS Reactive oxygen species g‐C3n4 nO removal Reaction mechanism
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Nonlinear Properties of an Inhomogeneous Diode Structure in a Strong Microwave Field
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作者 Sanobar Reymbaeva Gulmurza Abdurakhmanov Aleksandra Orel 《World Journal of Condensed Matter Physics》 CAS 2023年第1期1-13,共13页
Results of experimental investigation of detection (rectification) of high power X-band microwave signal in diodes of various design (semiconductor p-n-junction, point-contact, Schottky, Metal-Isolator-Metal—MIM) are... Results of experimental investigation of detection (rectification) of high power X-band microwave signal in diodes of various design (semiconductor p-n-junction, point-contact, Schottky, Metal-Isolator-Metal—MIM) are reported. The maximum of the detected direct voltage V vs. power P of microwave signal and subsequent polarity reversal, previously found in MIM diodes in the optical and microwave bands, have found to be characteristic of all investigated diodes as well. After the reversal of polarity, this dependence comes linear, and the sign of the voltage corresponds to thermoEMF. In some diodes, the hysteresis on V(P) was observed. All 5 types of V(P) of MIM diodes (have made from different pairs of metals), reported earlier, were reproduced on same p-n-junction diode by variable external DC bias. These results joined with abnormal frequency cutoff forced to suggest that there is an unknown mechanism for direct flow of charge carriers (and for generate direct current) in the high-frequency electrical field, which differs from the conventional rectification. 展开更多
关键词 Quadratic Detection p-n-Junction point Contact Schottky Barrier High-power Microwave Signal polarity Reversal ThermoEMF HYSTERESIS
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