The organic nanoparticles of a blue-light-emitting molecule,1,3-diphenyl-5-(9-anthryl)-2-pyrazoline,were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morpholo...The organic nanoparticles of a blue-light-emitting molecule,1,3-diphenyl-5-(9-anthryl)-2-pyrazoline,were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morphologies,spherical,doughnut-shaped and cubic,could be observed on the silicon substrate for the nanoparticles by the volume-controlled addition of acetonitrile. The evolution of particle morphology as a function of acetonitrile addition was attributed to the variation of the growth habits of the particles in the different environment. The nanoparticles exhibit the novel photoluminescence spectra as compared to those of monomer and the bulk crystals.展开更多
Organic nanocrystals of 1,3,5-triphenyl-2-pyrazoline (TPP) with a series of sizes were synthesized by reprecipitation method. The luminescence quantum efficiency of TPP nanocrystals increases from 24.2% for the nanocr...Organic nanocrystals of 1,3,5-triphenyl-2-pyrazoline (TPP) with a series of sizes were synthesized by reprecipitation method. The luminescence quantum efficiency of TPP nanocrystals increases from 24.2% for the nanocrystals with an average size of 300 nm to 34.6% for those with an average size of 20 nm. Surface capping by polyvinyl pyrrolidone (PVP) will improve the quantum efficiency of TPP nanocrystals. The size-dependence and capping-induced variation of the luminescence quantum efficiency was elucidated in viewpoint of aggregation quenching and the equilibrium between the TPP monomers and the aggregates in TPP nanocrystals.展开更多
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina ,ChineseAcademyofSciencesandtheNationalResearchFundforFundamentalKeyProjectsNo 973 (No .G19990 3 3 0 )
文摘The organic nanoparticles of a blue-light-emitting molecule,1,3-diphenyl-5-(9-anthryl)-2-pyrazoline,were prepared by reprecipitation method using acetonitrile as the solvent for the molecular precursor. Three morphologies,spherical,doughnut-shaped and cubic,could be observed on the silicon substrate for the nanoparticles by the volume-controlled addition of acetonitrile. The evolution of particle morphology as a function of acetonitrile addition was attributed to the variation of the growth habits of the particles in the different environment. The nanoparticles exhibit the novel photoluminescence spectra as compared to those of monomer and the bulk crystals.
基金ProjectsupportedbytheNationalNaturalScienceFoundationofChina ,ChineseAcademyofSciencesandtheMajorStateBasicResearchDevelopmentProgram (No .G19990 330 )
文摘Organic nanocrystals of 1,3,5-triphenyl-2-pyrazoline (TPP) with a series of sizes were synthesized by reprecipitation method. The luminescence quantum efficiency of TPP nanocrystals increases from 24.2% for the nanocrystals with an average size of 300 nm to 34.6% for those with an average size of 20 nm. Surface capping by polyvinyl pyrrolidone (PVP) will improve the quantum efficiency of TPP nanocrystals. The size-dependence and capping-induced variation of the luminescence quantum efficiency was elucidated in viewpoint of aggregation quenching and the equilibrium between the TPP monomers and the aggregates in TPP nanocrystals.
