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Mechanistic Insights into the Fluorescence Quenching of Rhodamine 6G by Graphene Oxide
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作者 Lu Chen Lei Zhang +1 位作者 Shen-longJiang Qun Zhang 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2018年第2期165-170,245,共7页
The fluorescence quenching of Rhodamine 6G (R6G) by graphene oxide (GO) was interrogated by R6G fluorescence measurements using a set of controlled GO samples with varied C/O ratios as the quencher. The carbonyl g... The fluorescence quenching of Rhodamine 6G (R6G) by graphene oxide (GO) was interrogated by R6G fluorescence measurements using a set of controlled GO samples with varied C/O ratios as the quencher. The carbonyl groups on the GO nanosheet turned to play a dominant role in quenching the R6G fluorescence. The quenching in the static regime can be described by the "sphere of action" model. The significant absorption of the R6G fluorescence by the ground-state complex formed between R6G and GO was identified to be responsible for the static quenching mechanisms in quenching. This work offers the R6G/GO system. insights into the fluorescence 展开更多
关键词 Graphene oxide rhodarnine 6g Fluorescence Carbonyl group Static quench-ing Sphere of action Ground-state complex
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