Synthesis, characterization and application of a dispersant based on rosin for coal-water slurry

A rosin derivative and maleopimaric acid diethanolamide(MAD), was synthesized, characterized by FTIR and1 H NMR, and applied as dispersant for the coal-water slurry(CWS) prepared from Chinese Shenfu coal. The CWS application performance investigation shows that the MAD dispersant has better abilities in reducing CWS viscosity and stabilizing the slurry than a commercial dispersant—sulfonated naphthalene-formaldehyde condensate(SNF). The physicochemical property investigation of the two tested dispersants shows that the adsorption amount of the MAD at coal-water interface is much larger than that of SNF, and the MAD has better wetting property than the SNF on the coal surface. It indicated that the excellent capabilities of MAD are related to the adsorption mode of standing upright on the coal surface. Based on the above, the mechanism of dispersion and stabilization of the CWS prepared from MAD dispersant is presented.

Synthesis of multifunctional monomers from rosin for the properties enhancement of soybean-oil based thermosets

Two kinds of rosin derivatives, （2-hydroxy-3-（methacryloyloxy）propyl 7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,4b,5,6,10,10a- decahydrophenanthrene-1-carboxylate） （HMPIDDC） and （（（7-isopropyl-1,4a-dimethyl-1,2,3,4,4a,9,10,10a-octahydrophenan- thren-1-yl）methyl）azanediyl）bis（2-hydroxypropane-3,1-diyl）bis（2-methylacrylate） （IDOMAHM） were synthesized under mild and easy to implement conditions. The two derivatives were employed as the rigid monomers to copolymerize with acrylated epoxidized soybean oil （AESO）, as so to improve the performance of the cured resins. The chemical structures of HMPIDDC and IDOMAHM were confirmed by nuclear magnetic resonance （NMR） and Fourier Transform Infrared （FT-IR） before copolymerization. The curing behaviors of pristine AESO, AESO/HMPIDDC blend, and AESO/IDOMAHM blend were monitored by differential scanning calorimetry （DSC）. Moreover, the thermal and mechanical properties of the cured resins were evaluated by universal mechanical testing, dynamic mechanical analysis （DMA） and thermogravimetric analysis （TGA）. The results demonstrated that after the introduction of HMPIDDC and IDOMAHM, the glass transition temperature and mechanical properties of the copolymerized resin were significantly increased. In one word, HMPIDDC and IDOMAHM showed dramatic potential to be used as bio-based compounds to improve the properties of soybean-oil based thermosets.