Activity and Selectivity in CO Hydrogenation with Silica-supported Ru-Co Bimetallic Cluster-derived Catalysts

The catalytic performance of bimetallic Ru-Co catalysts prepared from a series of H3Ru3Co(CO)12. RuCo2(CO)11 and HRuCo3(CO)12 in CO hydrogenation was investigated, and it was found that the Ru-Co bimetallic carbonyl cluster-derived catalysts showed a high activity for products, particularly higher oxygenates, compared with the catalysts prepared from impregnation or co-impregnation of monometallic clusters such as [HRu3(CO)11] and Co4(CO)12. The selectivity for oxygenates in CO hydrogenation highly increased with the molar ratio of Co/Ru in the Ru-Co bimetallic cluster to CO/H2 in feed gas. Raising reaction temperature led to an intensive increase of CO conversion and a considerable decrease of selectivity for oxygenates. In situ FT-IR studies revealed that the band at 1584 cm-1 on Ru-Co bimetallic cluster-derived catalysts at 453 K under syngas (CO/H2 = 0. 5) has a good linear relationship to rates of oxygenate formation, which is likely associated with an intermediate to produce oxygenates in CO hydrogenation.

Graphene-loaded nickel−vanadium bimetal oxides as hydrogen pumps to boost solid-state hydrogen storage kinetic performance of magnesium hydride

To modify the thermodynamics and kinetic performance of magnesium hydride(MgH_(2))for solid-state hydrogen storage,Ni_(3)V_(2)O_(8)-rGO(rGO represents reduced graphene oxide)and Ni_(3)V_(2)O_(8)nanocomposites were prepared by hydrothermal and subsequent heat treatment.The beginning hydrogen desorption temperature of 7 wt.%Ni_(3)V_(2)O_(8)-rGO modified MgH_(2)was reduced to 208℃,while the additive-free MgH_(2)and 7 wt.%Ni_(3)V_(2)O_(8)doped MgH_(2)appeared to discharge hydrogen at 340 and 226℃,respectively.A charging capacity of about 4.7 wt.%H_(2)for MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO was achieved at 125℃ in 10 min,while the dehydrogenated MgH_(2)took 60 min to absorb only 4.6 wt.%H_(2)at 215℃.The microstructure analysis confirmed that the in-situ generated Mg_(2)Ni/Mg_(2)N_(i)H_(4) and metallic V contributed significantly to the enhanced performance of MgH_(2).In addition,the presence of rGO in the MgH_(2)+7 wt.%Ni_(3)V_(2)O_(8)-rGO composite reduced particle aggregation tendency of Mg/MgH_(2),leading to improving the cyclic stability of MgH_(2)during 20 cycles.

Combined effects of ultrasonic vibration and FeCoNiCrCu coating on interfacial microstructure and mechanical properties of Al/Mg bimetal by compound casting

In this work,a new treatment method combining ultrasonic vibration with FeCoNiCrCu high entropy alloy(HEA)coating was used to prepared Al/Mg bimetal through the lost foam compound casting.The effects of composite treatment involving ultrasonic vibration and HEA coating on interfacial microstructure and mechanical properties of Al/Mg bimetal were studied.Results demonstrate that the interface thickness of the Al/Mg bimetal with composite treatment significantly decreases to only 26.99%of the thickness observed in the untreated Al/Mg bimetal.The HEA coating hinders the diffusion between Al and Mg,resulting the significant reduction in Al/Mg intermetallic compounds in the interface.The Al/Mg bimetal interface with composite treatment is composed of Al_(3)Mg_(2)and Mg_(2)Si/AlxFeCoNiCrCu+FeCoNiCrCu/δ-Mg+Al_(12)Mg_(17)eutectic structures.The interface resulting from the composite treatment has a lower hardness than that without treatment.The acoustic cavitation and acoustic streaming effects generated by ultrasonic vibration promote the diffusion of Al elements within the HEA coating,resulting in a significant improvement in the metallurgical bonding quality on the Mg side.The fracture position shifts from the Mg side of the Al/Mg bimetal only with HEA coating to the Al side with composite treatment.The shear strength of the Al/Mg bimetal increases from 32.16 MPa without treatment to 63.44 MPa with ultrasonic vibration and HEA coating,increasing by 97.26%.

Preparation, interfacial regulation and strengthening of Mg/Al bimetal fabricated by compound casting: A review

Mg/Al bimetal combines the advantages of both aluminum and magnesium and has broad application prospects in automotive, aerospace,weapons, digital products and so on. The compound casting has the characteristics of low cost, easy to achieve metallurgical combination and suitable for the preparation of complex bimetallic parts. However, bimetallic joint strength is low due to differences of physical properties between Al and Mg, oxide film on metallic surface and interfacial Al-Mg IMCs, which is closely related to the interfacial microstructure and properties. Therefore, how to control the interface of the bimetal to achieve performance enhancement is the focus and difficulty in this field. At present, there are mainly the following strengthening methods. First, the “zincate galvanizing” and “electrolytic polishing+anodic oxidation” technology were exert on the surface of Al alloy to remove and break the oxide film, which improved the wettability between Al and Mg. Second, the undesirable Al-Mg IMCs were reduce or elimination by adding the interlayers(Zn, Ni and Ni-Cu). Thirdly, the evolution process of interfacial microstructure was changed and fine strengthening phases were formed by adding Si element to Al alloy or rare earth element to Mg alloy. Fourthly, mechanical vibration and ultrasonic vibration were applied in the process of the filling and solidification to refine and homogenize the interfacial structure. Finally, some other methods, including secondary rolling, thermal modification, heat treatment and constructing exterior 3D morphology, also can be used to regulate the interfacial microstructure and compositions. The above strengthening methods can be used alone or in combination to achieve bimetallic strengthening. Finally, the future development direction of the Mg/Al bimetal is prospected, which provides some new ideas for the development and application of the Mg/Al bimetal.

Effect of HEA/Al composite interlayer on microstructure and mechanical property of Ti/Mg bimetal composite by solid-liquid compound casting

In this study,HEA/AI composite interlayer was used to fabricate Ti/Mg bimetal composites by solidliquid compound casting process.The Al layer was prepared on the surface of TC4 alloy by hot dipping,and the FeCoNiCr HEA layer was prepared by magnetron sputtering onto the Al layer.The influence of the HEA layer thickness and pouring temperature on interface evolution was investigated based on SEM observation and thermodynamic analysis.Results indicate that the sluggish diffusion effect of HEA can effectively inhibit the interfacial diffusion between Al and Mg,which is conducive to the formation of solid solution,especially when the thickness of HEA is 800 nm.With the increase of casting temperature from 720 ℃ to 730 ℃,740℃,and 750 ℃,α-Al(Mg),α-Al(Mg)+Al3Mg2,Al3Mg2+Al12Mg17,and Al12Mg17+δ-Mg are formed at the interface of Ti/Mg bimetal,respectively.When the thickness of the HEA layer is 800 nm and the pouring temperature is 720 ℃,the bonding strength of the Ti/Mg bimetal can reach the maximum of 93.6 MPa.

Effects of mechanical vibration on filling and solidification behavior, microstructure and performance of Al/Mg bimetal by lost foam compound casting

Al/Mg bimetal was prepared by lost foam solid-liquid compound casting,and the effects of mechanical vibration on the filling and solidification behavior,microstructure and performance of the bimetal were investigated.Results show that the mechanical vibration has a remarkable influence on the filling and solidification processes.It is found that after mechanical vibration,the filling rate increases and the filling rate at different times is more uniform than that without vibration.In addition,the mechanical vibration also increases the wettability between liquid AZ91D and A356 inlays.The mechanical vibration reduces the horizontal and vertical temperature gradient of the casting and makes the temperature distribution of the whole casting more uniform.Compared to the Al/Mg bimetal without vibration,the shear strength is improved by 39.76%after the mechanical vibration is applied,due to the decrease of the inclusions and Al_(12)Mg_(17) dendrites,and the refinement and uniform distribution of the Mg_(2)Si particles in the interface of the Al/Mg bimetal.

Effect of melt-to-solid volume ratio and preheating temperature on Mg/Al bimetals interface by centrifugal casting

Compound casting is an efficient method for bonding dissimilar metals,in which a dramatic reaction can occur between the melt and solid.The centrifugal casting process,a type of compound casting,was applied to cast Al/Mg dissimilar bimetals.Magnesium melt was poured at 700 °C,with melt-to-solid volume ratios(Vm/Vs) of 1.5 and 3,into a preheated hollow aluminum cylinder.The preheating temperatures of the solid part were 320,400,and 450 °C,and the constant rotational speed was 1,600 rpm.The cast parts were kept inside the casting machine until reaching the cooling temperature of 150 °C.The result showed that an increase in preheating temperature from 320 to 450 °C led to an enhanced reaction layer thickness.In addition,an increase in the Vm/Vs from 1.5 to 3 resulted in raising the interface thickness from 1.2 to 1.8 mm.Moreover,the interface was not continuously formed when a Vm/Vs of 3 was selected.In this case,the force of contraction overcame the resultant acting force on the interface.An interface formed at the volume ratio of 1.5 was examined using scanning electron microscopy(SEM) equipped with energy-dispersive X-ray spectroscopy(EDS),and the results demonstrated the formation of Al_(3)Mg_(2),Al_(12)Mg_(17) and(δ+Al_(12)Mg_(17)) eutectic structures in the interface.

Selective hydrogenation of glucose to sorbitol with tannic acid-based porous carbon sphere supported Ni-Ru bimetallic catalysts

Ni-Ru bimetallic porous carbon sphere(Ni-Ru@PCS) catalysts were synthesized via formaldehyde-assisted, metal-coordinated crosslinking sol-gel chemistry, in which biomass-derived tannic acid and F127 surfactant were used as carbon precursor and soft template, respectively, and Ni2+and Ru3+were used as cross-linkers. In the developed method, Ni-Ru particles became uniformly dispersed in the carbon skeleton due to strong coordination bonds between metal ions(Ni2+and Ru^(3+)) and tannic acid molecules and bimetal interactions. The as-synthesized Ni-Ru10:1@PCS catalyst with a loading Ni:Ru mole ratio of 10:1 was applied for the selective hydrogenation of glucose to sorbitol, and provided 99% glucose conversion with a sorbitol selectivity of 100% at 140℃ in 150 min reaction time and exhibited good stability and recyclability in which sorbitol yield remained at 98% after 4 cycles with little or no metal agglomeration. The catalyst was applied to glucose solutions as high as 20 wt% with 97% sorbitol yields being obtained at 140℃ in 20 h. The developed bimetallic porous carbon sphere catalysts take advantage of sustainably-derived materials in their structure and are applicable to related biomass conversion reactions.

Effect of immersion Ni plating on interface microstructure and mechanical properties of Al/Cu bimetal

A nickel-based coating was deposited on the pure Al substrate by immersion plating,and the Al/Cu bimetals were prepared by diffusion bonding in the temperature range of 450-550 ℃.The interce microstructure and fracture surface of Al/Cu joints were studied by scanning electron microscopy（SEM） and X-ray diffraction（XRD）.The mechanical properties of the Al/Cu bimetals were measured by tensile shear and microhardness tests.The results show that the Ni interiayer can effectively eliminate the formation of Al-Cu intermetallic compounds.The Al/Ni interface consists of the Al3Ni and Al3Ni2 phases,while it is Ni-Cu solid solution at the Ni/Cu interce.The tensile shear strength of the joints is improved by the addition of Ni interiayer.The joint with Ni interiayer annealed at 500 ℃ exhibits a maximum value of tensile shear strength of 34.7 MPa.

Effect of homogenization annealing on microstructure, composition and mechanical properties of 7050/6009 bimetal slab

Homogenization annealing of the 7050/6009 bimetal slab prepared by direct-chill casting was investigated and its effects on microstructural evolution, composition distribution and mechanical properties in the interfacial region of the bimetal were studied. The results show that the optimized homogenization annealing process was 460℃for 24 h. After homogenization annealing, the Zn-rich phases and Al15（FeMn）3Si2phases were precipitated at the interface of the bimetal. The diffusion layer thickness of homogenized bimetal increased by 30 μm from 440 to480℃for 24 h, while it increased by 280 μm from 12 to 36 h at 460℃. The Vickers hardnessesat 6009 alloy side and interface of the bimetal decreased after homogenized annealing and grain coarsening was considered asthedominating softening mechanism.The hardness variation at 7050 alloy side was complicated due to the combined action of solution strengthening, dispersion strengthening and dissolution of reinforced phases.

Microstructure and properties of Al/Cu bimetal in liquid-solid compound casting process

A Ni-P coating was deposited on Cu substrate by electroless plating and the Al/Cu bimetal was produced by solid？liquid compound casting technology. The microstructure, mechanical properties and conductivity of Al/Cu joints with different process parameters （bonding temperature and preheating time） were investigated. The results showed that intermetallics formed at the interface and the thickness and variety increased with the increase of bonding temperature and preheating time. The Ni？P interlayer functioned as a diffusion barrier and protective film which effectively reduced the formation of intermetallics. The shear strength and conductivity of Al/Cu bimetal were reduced by increasing the thickness of intermetallics. In particular, the detrimental effect of Al2Cu phase was more obvious compared with the others. The sample preheated at 780 ℃ for 150 s exhibited the maximum shear strength and conductivity of 49.8 MPa and 5.29×10^5 S/cm, respectively.

Pt-Re/rGO bimetallic catalyst for highly selective hydrogenation of cinnamaldehyde to cinnamylalcohol

In the present work, a series of Pt-based catalysts, alloyed with a second metal, i.e., Re, Sn, Er, La, and Y, and supported on activated carbon, ordered mesoporous carbon, N-doped mesoporous carbon or reduced graphene oxide(rGO), have been developed for selective hydrogenation of cinnamaldehyde to cinnamylalcohol. Re and rGO were proved to be the most favorable metal dopant and catalyst support, respectively. Pt_(50) Re_(50)/rGO showed the highest cinnamylalcohol selectivity of 89% with 94% conversion of cinnamaldehyde at the reaction conditions of 120 °C, 2.0 MPaH_2 and 4 h.

Characteristics evolution of 6009/7050 bimetal slab prepared by direct-chill casting process

6009/7050 alloy bimetal slab was prepared by a direct-chill (DC) casting process. Homogenizing annealing, hot rolling and T6 treatment were successively performed and their effects on microstructure and properties of the slab were studied. The results reveal that the average diffusion layer thickness of as-cast slab, determined by interdiffusion of elements Zn, Cu, Mg and Si, was about 400 μm. Excellent metallurgical bonding was achieved because all tensile samples fractured on the softer 6009 alloy side after homogenizing annealing. After homogenizing annealing plus rolling, the average diffusion layer thickness decreased to 100 μm, while the network structure of 7050 alloy side transformed to dispersive nubby structure. Furthermore, subsequent T6 treatment resulted in diffusion layer thickness up to 200 μm and an obvious increase of the Vickers hardness for both 7050 and 6009 sides. The layered structure of the as-cast 6009/7050 bimetal is retained after hot rolling and T6 treatment.

Combustion characteristic and aging behavior of bimetal thermite powders

Nanothermites have been employed as fuel additives in energetic formulations due to their higher energy density over CHNO energetics. Nevertheless, sintering and degradation of nanoparticles significantly limit the practical use of nanothermites. In this work, combustion characteristic and aging behavior of aluminum/iron oxide(Al/Fe2O3) nanothermite mixtures were investigated in the presence of micron-scale nickel aimed to produce bimetal thermite powders. The results showed that the alumina content in the combustion residue increased from 88.3% for Al/Fe2O3 nanothermite to 96.5% for the nanothermite mixture containing 20 wt% nickel. Finer particle sizes of combustion residue were obtained for the nanothermite mixtures containing nickel, indicative of the reduced agglomeration. Both results suggested a more complete combustion in the bimetal thermite powders. Aging behavior of the nanothermite mixture was also assessed by measuring the heat of combustion of the mixture before and after aging process. The reduction in heat of combustion of nanothermite mixtures containing nickel was less severe as compared to a significant decrease for the nanothermite mixture without nickel, indicating better aging resistance of the bimetal thermite powders.

Fabrication of plain carbon steel/high chromium white cast iron bimetal by a liquid–solid composite casting process

High-chromium white cast iron （HCWCI） is one of the most widely used engineering materials in the mining and cement industries. However, in some components, such as the pulverizer plates of ash mills, the poor machinability of HCWCI creates difficulties. The bimetal casting technique is a suitable method for improving the machinability of HCWCI by joining an easily machined layer of plain carbon steel （PCS） to its hard part. In this study, the possibility of PCS/HCWCI bimetal casting was investigated using sand casting. The investigation was conducted by optical and electron microscopy and non-destructive, impact toughness, and tensile tests. The hardness and chemical composition profiles on both sides of the interface were plotted in this study. The results indicated that a conventional and low-cost casting technique could be a reliable method for producing PCSYdCWCI bimetal. The interfacial microstructure comprised two distinct lay- ers： a very fine, partially spheroidized pearlite layer and a coarse full pearlite layer. Moreover, characterization of the microstructure revealed that the interface was free of defects.

Direct Synthesis of Dimethyl Carbonate from CO_2 and CH_3OH Using 0.4nm Molecular Sieve Supported Cu-Ni Bimetal Catalyst

The 0.4 nm molecular sieve supported Cu-Ni bimetal catalysts for direct synthesis of dimethyl carbonate (DMC) from CO 2 and CH 3 OH were prepared and investigated. The synthesized catalysts were fully characterized by BET, XRD (X-ray diffraction), TPR (temperature programmed reduction), IR (infra-red adsorption), NH 3-TPD (temperature programmed desorption) and CO 2-TPD (temperature programmed desorption) techniques. The results showed that the surface area of catalysts decreased with increasing metal content, and the metals as well as Cu-Ni alloy co-existed on the reduced catalyst surface. There existed interaction between metal and carrier, and moreover, metal particles affected obviously the acidity and basicity of carrier. The large amount of basic sites facilitated the activation of methanol to methoxyl species and their subsequent reaction with activated carbon dioxide. The catalysts were evaluated in a continuous tubular fixed-bed micro-gaseous reactor and the catalyst with bimetal loading of 20% (by mass) had best catalytic activities. Under the conditions of 393 K, 1.1 MPa, 5 h and gas space velocity of 510 h 1 , the selectivity and yield of DMC were higher than 86.0 % and 5.0 %, respectively.

Study on liquid-liquid bimetal composite casting hammers

Crusher hammers for the mineral processing industry must meet the demands of both high wear resistance at the hammer head and high impact toughness at the hammer handle. The crusher hammers made of Hadfield steel have typical y low service life of less than 40 hours. To solve the problem, a kind of bimetal crusher hammers made of high chromium cast iron （HCCI） and low al oy steel （LAS） has been successful y developed by using liquid-liquid composite casting. The microstructure and composite interface bonding was analyzed using optical microscope, SEM, EDX and XRD. Micrographs indicate that the composite interface is metal urgical y bonded with a zigzag shape across the boundary and without unbound region or void. After heat treatment, the composite hammers have shown excellent properties. The hardness of HCCI is at least 63 HRC and its αk is greater than 3.5 J？cm-2; the hardness of LAS is greater than 35 HRC and its αk is no less than 80 J？cm-2. Diffusion of elements takes place at the interface and forms a transition region. The micro hardness increases from LAS to the interface and then to HCCI. Wear comparison was made separately between the bimetal composite hammer and a Hadfield steel hammer in two quarries of Jilin province and Liaoning province. The results showed that the liquid-liquid bimetal composite hammers did not have the fal ing off of hammer head or impact fracture phenomenon, and their service life was 3.75 times as long as that of the Hadfield steel hammers.

INTERFACE DEFORMATION CHARACTERISTICS OF BIMETAL FORMING

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High Cr white cast iron/carbon steel bimetal liner by lost foam casting with liquid-liquid composite process

Liners in wet ball mill for mineral processing industry must bear abrasive wear and corrosive wear, and consequently, the service life of the liner made from traditional materials, such as Hadfield steel and alloyed steels, is typically less than ten months. Bimetal liner, made from high Cr white cast iron and carbon steel, has been successfully developed by using liquid-liquid composite lost foam casting process. The microstructure and interface of the composite were analyzed using optical microscope, SEM, EDX and XRD. Micrographs indicate that the boundary of bimetal combination regions is staggered like dogtooth, two liquid metals are not mixed, and the interface presents excellent metallurgical bonding state. After heat treatment, the composite liner specimens have shown excellent properties, including hardness 〉 61 HRC, fracture toughness ak 〉16.5 J.cm2 and bending strength 〉1,600 MPa. Wear comparison was made between the bimetal composite liner and alloyed steel liner in an industrial hematite ball mill of WISCO, and the results of eight-month test in wet grinding environment have proved that the service life of the bimetal composite liner is three times as long as that of the alloyed steel liner.

Analysis and FEM simulation of extrusion process of bimetal tubes through rotating conical dies

Bimetal tube extrusion process through rotating conical dies was studied analytically and numerically. A kinematically admissible velocity field was developed to evaluate the internal power and the power dissipated on frictional and velocity discontinuity surfaces. By balancing the moment applied by the rotary die with the moments caused by the circumferential frictions in the container and on the mandrel, the twisting length of the material in the container was determined. By equating the total power with the required external power, the extrusion pressure was determined by optimizing with respect to the slippage parameter between the die and the outer material. It is shown that the extrusion pressure is decreased by about 20% by the die rotation. The bimetal tube extrusion process through rotating die was also simulated using the finite element code, ABAQUS. Analytical results were compared with the results given by the finite element method. These comparisons show a good agreement.