Static compressive properties and damage constitutive model of rubber cement mortar with dry-and wet-curing conditions

To investigate the static compressive properties and mechanical damage evolution of rubber cement-based materials(RCBMs) with dry-and wet-curing conditions, uniaxial compression and cyclic loading-unloading tests were carried out on rubber cement mortar(RCM). The mechanical properties of the uniaxial compression specimens cured at 95%(wet-curing) and 50%(dry-curing) relative humidities and cyclic loading-unloading specimens cured at wet-curing were analyzed. Under uniaxial compression, the peak stress loss ratio is higher for dry-curing than for wet-curing. The peak strain decreases with the increase of rubber content, and the peak strain increases with the decrease of curing humidity. Under cyclic loading-unloading, the variation trends of residual strain differences of the normal cement mortar and RCM at each cyclic level with the number of cycles are basically the same, but the failure modes are different. The analysis of the internal mesostructure by a scanning electron microscope(SEM) shows that initial damage is further enhanced by reducing curing humidity and adding rubber aggregate. The damage constitutive model based on strain equivalence principle and statistical theories was used to describe the uniaxial compression characteristics of RCM, and the law of mechanical damage evolution was predicted.

Effect of Rubber Particles on Cement Stabilized Gravel System

The primary objective of this paper was to study the mechanical properties and durability of the cement stabilized gravel by different compact method. The influence of rubber particle content on mechanical properties of samples was studied by compaction tests and freezing thawing recycle tests. Pore structure and fractal characteristic of mixture were analyzed quantitatively using mercury intrusion porosimetry （MIP）. X-ray diffraction （XRD） was adopted to identify the composition phases. The morphology analysis in micro scale and elemental analysis of samples were carried out by scanning electron microscope （SEM）. The optimum compressive strengths of rubber cement stabilized gravel （RCSG） with static compaction method and with vibratory compaction method were obtained by controlling compaction degree and vibration time, respectively. From the compaction tests, the vibratory compaction method is preferred compared with the static compaction method as better compressive strength can be improved by about 340%-360%. Besides, test results also reveal that compressive strength of samples with vibratory compaction method or static compaction method will decrease with the rubber particle bulk content increasing. The freezing thawing recycle tests indicate that freezing thawing resistance has been improved （frozen stability coefficient K has been increased from 0.89 to 0.97） by the addition of rubber particles. MIP tests show that the mean pore diameter and porosity of mixture have been increased from 70 to 250 nm and 9% to 24% respectively, with the rubber particles content increasing. Component analysis shows that the calcium silicate hydrate （CSH） is the predominant hydrate product with or without the addition of rubber particles.

Hybrid Modified Rubber Powder and Its Application in Cement Mortar

This research focused on using the waste rubber powder as a kind of regenerate resources to improve the mechanical properties of cement mortar.The two kinds of hybrid modified rubber powder TRP and ATRP were prepared by sol-gel method and then used in cement mortar.The structures and properties of them were studied.It is shown that the nano Si-O-Si network is generated in TRP and ATRP networks and the hydrophilic group is grafted on the surface of ATRP.The mechanical properties of rubber-treated mortar（RTM） were tested and the microstructures of them were also studied.Compared to the mortars with unmodified rubber powders（RP）,NaOH treated rubber powder（SRP） and coupling agent treated rubber powder（CRP）,the RTM with ATRP has the highest compressive strength and flexural strength.The stress-strain curves shown that the peak of stress of RTM with ATRP is increased and indicated the higher compression deformation and toughness.It is found that the interfacial adhesion between the ATRP and cement mortar is increased distinctly by SEM,which results in enhanced ductility and mechanical properties of RTM with ATRP.

Performance of the Cement Matrix Composite Material With Rubber Powder

The effect of the deferent rubber content substituted for fine aggregate on the mortar performance was studied.The effects of the rubber coated with the coating materials on the mortar compressive strength,bending strength and impact work were discussed.The optimum rubber powder content and the suitable coating material were found.Through the electrical probe test-BEI,SEI and calcium ion distribution,and the slight crack and the interface between the rubber and cement matrix are analyzed.The results show that the rubber powder coated with the surface treatment materials A,B and C has the capability of absorbing a large amount of energy under the compressive and flexural load and the slight cracks of R-C were controlled and restrained.

Experimental Study of Rubberized Asphalt Emulsion Modified Portland cement concrete

The poor fatigue properties and high rigidity of cement asphalt emulsion treated mis(CETM) have for a long time been problems restricting its further development making it impossible for C-ETMto be used as surface layer materials. In this paper, a new kind of cement asphalt emulsion composite-rubberized asphalt emulsion modified Portland cement concrete (RACC) was proposed, which was formed by dispersing rubberized aSPhalt emulsion coated coarse aggregates into cement mortar matrix. In order to evaluate systematically the performance of RACC, laboratory tests with nearly one thousand SPecimen were conducted for resilient modulus, fatigue properties, ultimate ban and length,abrasion, temperature contraction, and dry shrinkage. The experimental results show that the problems existed in C-ETM have to a great extends been solved by RACc. To verify the field performance and inquire into paving technology, teSt road appearsatlsfactory it is concluded that when thed ape surface laycr of semi-rigid base course, RACC is more for surface layer material than both Portland cement concrete(PCC) and asphalt concrete(AC)

Study on Modification of Waste Rubber Powder in Cement-Based Composites Mixed with Waste Rubber Powder

In view of the disadvantage that the mechanical properties of cement-based composites can be significantly reduced by incorporating waste rubber powder in situ, the surface modification methods of the original rubber powder by coupling agent KH560, sodium hydroxide, polyvinyl alcohol (PVA), methyl hydroxyethyl cellulose ether (MHEC) and tetraethyl orthosilicate (TEOS) as precursors were adopted respectively. The modification of waste rubber powder was studied by Change rate of mortar strength of cement-based composite mortar mixed with waste rubber powder. The results show that the hybrid modification method using tetraethyl orthosilicate as precursor has better ef-fect. When 5 phr ethyl orthosilicate is added, the compressive strength and flexural strength of cement-based composite mortar can be increased by 31.7% and 28%. Scanning electron microscopy (SEM) results show that the surface of waste rubber powder with good modification effect has many pro-trusions and flake-like porous structures which are beneficial to its bonding with cement-based materials.

胶粉纤维改性水泥稳定碎石抗裂性能研究

针对水泥稳定碎石基层易开裂问题,在混合料中掺入适量胶粉及聚乙烯醇(PVA)纤维,开展强度、抗压回弹模量、干缩性能和扫描电镜试验(SEM);分别掺入橡胶粉、改性胶粉、PVA纤维、不同水泥剂量的胶粉纤维,对比其对混合料抗裂性能的影响。发现掺入材料对水泥稳定碎石混合料性能具有明显影响。掺入胶粉、改性胶粉后会降低混合料强度和抗压回弹模量,提升抗干缩性能;掺入纤维能增强混合料强度、模量和抗干缩性能;加入不同水泥剂量的胶粉纤维对混合料强度、抗压回弹模量提升效果明显,但降低了抗干缩性能;宏观力学指标试验和SEM试验结果显示出改性胶粉纤维与水泥基具有良好的黏结性,可以提升水泥稳定碎石混合料的抗裂能力。

废弃橡胶粉对水泥稳定碎石抗疲劳性能的影响

为了消除水泥稳定碎石基层因疲劳损伤产生的裂缝,采用三分点加载方法系统研究了不同废弃橡胶粉掺量下水泥稳定碎石的疲劳性能,运用三点弯曲梁法表征了掺加废弃橡胶粉的水泥稳定碎石抗疲劳机理.结果表明:掺加10、20 kg/m^(3)废弃橡胶粉的水泥稳定碎石疲劳寿命优于基准组水泥稳定碎石;当废弃橡胶粉掺量为10、20 kg/m^(3)时水泥稳定碎石的起裂韧度是基准组的1.49、2.58倍,失稳韧度是基准组的1.30、2.21倍,断裂能也较大,抗疲劳性能显著;当废弃橡胶粉掺量为30 kg/m^(3)时,水泥稳定碎石的抗疲劳性能并没有提高,这可能与废弃橡胶粉掺量过大导致弯拉强度降低有关.

丁苯胶粉固井水泥浆的研究

本文对市售丁苯胶粉(SB)理化性能分析,并对其用于固井水泥浆进行探讨。红外光谱分析表明其是以高岭土为隔离剂的羧基丁苯胶粉,其水溶液粒度分布呈现纳米级颗粒并表明其具有良好可再分析特性;在水泥浆中单独使用丁苯胶粉存在破乳现象,若添加以十二烷基二甲胺羟丙基磺基甜菜碱LHSB与壬基酚聚醚TX-15组合物(质量比4∶1)为稳定剂时,可消除破乳现象,90℃和140℃稠化曲线均正常;水泥浆中引入丁苯胶粉,水泥浆略有增稠,失水和SPN值均变小,说明胶粉起到辅助降失水和提高水泥浆抗窜性能;胶粉影响水泥石24 h早期强度,但对于6 d后水泥石起到降模量和增加泊松比的作用,水泥石弹韧性得到了改善。

搅拌工艺对高掺量丁苯乳液改性硫铝酸盐水泥性能的影响

研究了搅拌速度与搅拌时间对高掺量丁苯乳液改性硫铝酸盐水泥砂浆的匀质性、含气量、流变性能、早期强度等宏观性能的影响,采用TGA、BET等微观手段研究了硬化砂浆的水化程度和孔隙特征。结果表明:延长搅拌时间、提高搅拌速率均可改善砂浆的匀质性和力学强度。但以176 r/min搅拌时,延长搅拌时间会提高新拌砂浆含气量,增大硬化砂浆“凝胶孔”含量,抑制水泥前1 h的水化。以108 r/min搅拌时,延长搅拌时间则促进水泥前1 h的水化。延长搅拌时间和提升搅拌速率阻碍砂浆絮凝,破坏水泥颗粒桥接,显著降低结构构筑速率。延长搅拌时间,砂浆屈服应力和塑性黏度降低。优化搅拌工艺,有助于为充填层修补砂浆的搅拌规范制定提供重要参数。

顶驱型机械旋转水泥头的研制

为配合旋转尾管固井,水泥头不仅要具备旋转功能,而且要承受拉伸及扭转载荷,使其结构发生了根本变化。威德福、贝克休斯、斯伦贝谢、哈里伯顿等国外公司均研制了成熟的顶驱型旋转水泥头产品,国内中海油服与宝石机械联合进行了顶驱型机械旋转水泥头的国产化研制。文中介绍了国产顶驱型机械旋转水泥头的结构、工作原理和关键技术。现场应用情况表明,该产品主要技术指标及性能均满足设计要求,技术先进,工作性能稳定,满足了现场使用需求。该顶驱型机械旋转水泥头的研制为当前深水固井作业提供了装备保障。

橡胶水泥土动剪模量和阻尼比共振柱试验研究

橡胶水泥土作为一种经济环保的耐腐蚀轻质填筑材料,在沿海港口工程及灯塔等基础建设中具有广泛的应用前景。基于共振柱试验,对不同橡胶掺量、水泥掺量和围压下橡胶水泥土动力特性展开研究,重点探究各影响因素对其动剪模量和阻尼比的影响规律。结果表明:固结压力下橡胶水泥土的累计轴向应变随着橡胶掺量和围压的增大而增大,随水泥掺量增大而减小;橡胶水泥土动剪模量曲线衰减程度随橡胶掺量的增加和水泥掺量的减小而减弱,非线性特征减弱,而受围压影响则较小;最大动剪模量随着橡胶掺量的增大而减小,随水泥掺量和围压的增大而增大。当橡胶掺量较低或水泥掺量较高时,其掺量改变对最大动剪模量影响最大;橡胶的掺入减缓了动剪模量衰减幅度,并且在较低围压下促使其更早地发生衰减。而水泥掺量的减小和围压的增大则会推迟衰减,衰减幅度也相对更大;阻尼比随动剪应变的增加而单调递增,增大橡胶掺量和减小围压会使其阻尼比增大,当水泥掺量小于15%时,阻尼比随水泥掺量增加而增大,而当水泥掺量大于15%时,阻尼比反而随之降低。

废弃橡胶改性水泥基材料研究进展

橡胶颗粒具有良好的吸能变形能力,将橡胶颗粒掺入水泥基中可以有效提高材料的韧性,同时能够增强水泥基的抗冻性、抗开裂、抗冲击等性能。但由于橡胶颗粒是一种憎水物质,导致橡胶与水泥浆液的界面粘结力较弱,水泥基材料的强度有所下降,因此对橡胶水泥基材料进行化学与物理改性研究。结果表明,改性橡胶通过两种方式来增强水泥基材料的性能:其一,改性剂通过溶解橡胶颗粒表面的杂质和在其表面形成一层薄膜来提高橡胶的亲水性;其二,改性剂与水化产物发生反应,形成有效的化学交联,使橡胶颗粒与水泥浆液形成紧密连接。同时研究发现,橡胶颗粒与纤维聚合物对水泥基材料的增强增韧有协同作用。

橡胶水泥复合土抗压及抗剪强度特性研究

为了探索橡胶水泥复合土的路用可行性,本文研究了不同橡胶掺量下橡胶水泥复合土的抗压及抗剪强度特性。结果表明:橡胶颗粒的加入对橡胶水泥复合土抗压强度的发展有不利影响,随着橡胶掺量的增加,复合土的抗压强度逐渐降低,但橡胶颗粒的加入缓解了复合土的脆性破坏特征;橡胶颗粒的加入对橡胶水泥复合土抗剪强度的发展有积极影响,随着橡胶掺量的增加,复合土的抗剪强度先增大后降低,当橡胶掺量为10%时,复合土的抗剪强度达到峰值,其粘聚力也达到最大值;当橡胶掺量为5%时,复合土的内摩擦角达到最大值。

橡胶粉改性聚乙烯纤维增强水泥基复合材料的静力和抗冲击性能

为研究橡胶粉改性聚乙烯纤维增强水泥基复合材料(PE-ECC)的物理力学性能,对掺入不同粒径橡胶粉的PE-ECC进行静力和抗冲击性能试验。通过分析橡胶粉PE-ECC的弹性模量、泊松比、立方体抗压强度、轴心抗压强度、劈裂抗拉强度和轴心抗拉强度,探讨不同橡胶粉粒径对PEECC基本力学性能的影响;利用分离式霍普金森压力杆进行橡胶粉PE-ECC的抗冲击性能试验,基于不同应变率下的动态应力-应变曲线,分析应变率对橡胶粉PE-ECC动态增长因子(DIF)、动态压缩强度和动态峰值应变的影响。结果表明:随着橡胶粉的加入,PE-ECC的各项物理力学性能均有一定程度下降;橡胶粉粒径为0.20~0.90 mm时,体积掺量为10%、橡胶粉粒径为0.30 mm的PE-ECC各项力学性能降幅最小,其立方体抗压强度、轴心抗压强度、弹性模量和动态抗压强度相对无橡胶粉PE-ECC分别减小了8.9%、15.6%、10.8%和23.4%;与无橡胶粉PE-ECC类似,橡胶粉PE-ECC的受拉应变硬化特征明显,掺入不同粒径(0.20~0.90 mm)橡胶粉的PE-ECC极限拉应变均稳定在4.6%左右。此外,橡胶粉粒径对PE-ECC动态峰值应变影响很小,随着冲击应变率的提高,橡胶粉PE-ECC的动态增长因子DIF和动态压缩强度呈逐渐增大趋势。

废旧橡胶粉对水泥稳定碎石基层力学及干缩性能的影响

为研究废旧橡胶粉对水泥稳定碎石基层混合料力学及干缩性能的影响,将不同粒径和掺量的橡胶粉以等质量等粒径的方式替换集料,通过考察劈裂强度、弯拉强度、抗压回弹模量和干缩试验研究了不同粒径和掺量的橡胶粉对水泥稳定碎石基层混合料力学及干缩性能的影响。结果表明,掺入橡胶粉降低了水泥稳定碎石基层混合料的劈裂强度、弯拉强度和抗压回弹模量,抑制了水泥稳定碎石的干燥收缩,且橡胶粉的粒径和掺量越大性能变化幅度越大。相较于不掺橡胶粉,掺入40目质量分数0.50%的橡胶粉时,水泥稳定碎石混合料90 d的劈裂强度、弯拉强度和抗压回弹模量分别降低了32.8%、51.0%和26.3%,累计干缩应变和干缩系数分别降低了27.4%和25.5%。

水泥及胶粉掺量对砂浆拉伸黏结强度的影响

为提高砂浆拉伸黏结强度,研究了不同水泥及胶粉掺量对砂浆拉伸黏结强度的影响。结果表明:当水泥掺量较低时,增加胶粉掺量能在一定程度上提高砂浆的拉伸黏结强度;当胶粉掺量较小时,增加水泥掺量能显著提高砂浆的拉伸黏结强度;当水泥掺量与胶粉掺量均较大时,同时增大水泥与胶粉掺量会降低砂浆的拉伸黏结强度。

水泥橡胶沥青混凝料与公路面层粘接性能研究

为了研究水泥橡胶沥青混凝土公路路面层间粘接性能,在原材料中掺入6.0%的水泥,借助车轮碾压制备试件。分析车轮轮胎接地压力,采用三维有限元模型展示路面结构,考虑不同行车方向和弹性弹簧部分粘弹性,构建剪切模量和拉拔模量方程。在低温-10、常温20、高温40℃状态下,测试复合试件直接剪切、拉拔力学性能,并分析不同温度区间层间粘接程度变化规律。结果表明,所研究方法剪切强度和拉拔强度与实际研究过程中的数值一致,粘接强度仅在40℃下与实际值存在最大为0.05 N/mm^(2)的误差。

道路桥梁修复材料强度与组成材料关系研究

为了研究橡胶颗粒、硫铝酸盐水泥(SAC)和普通硅酸盐水泥(OPC)对修复材料力学性能的影响,以水泥掺量和橡胶掺量作为变量,对修复材料的流动度、抗压强度、抗折强度、强度增长百分比和折压比等参数进行了分析。试验结果表明:掺入OPC增加了新型修复材料的初始流动度、20min流动度,而掺入橡胶降低了新型修复材料的初始流动度、20min流动度。随着OPC和橡胶掺量的增加,新型修复材料的抗压强度和抗折强度均呈现降低的趋势,但韧性有所提高。

再生橡胶砂浆的力学性能研究

本文旨在添加聚乙酸乙烯酯对再生橡胶砂浆进行改性,解决其在工程实际中容易出现开裂和粘附性能较差等缺陷,从而拓宽再生橡胶砂浆在房屋工程中的应用,进一步缓解废旧轮胎橡胶对生态环境造成的危害。通过一系列的力学实验,研究再生橡胶掺量和聚乙酸乙烯酯掺量对再生橡胶砂浆的流动度、抗折强度、抗压强度和干燥收缩量的影响。结果表明,随着再生橡胶颗粒掺量增加,水泥砂浆的流动度和抗折强度、抗压强度明显降低,降低幅度分别约为37.3%、65.1%和81.4%,试件体积干燥收缩变大,增幅约为61.8%。当再生橡胶掺量一定,随着聚乙酸乙烯酯掺量增多,水泥砂浆流动度和体积收缩量分别增大了31.3%和22.8%,而抗折、抗压强度分别降低了33.1%和45.5%。本文的结论将对再生橡胶砂浆在房屋工程中的应用提供有益的参考价值。