Bipolar Blue Light-emitting Polyfluorenes Containing Dibenzothiophene-S,S-dioxide/Carbazole Units

Bipolar blue light-emitting polyfluorenes（PFSO-Cz） containing electron-deficient dibenzothiophene-S,S- dioxide（SO） and electron-rich carbazole（Cz） unit were synthesized. All the polymers show a high thermal stability with the decomposition temperatures over 400 ℃ and higher photoluminescence quantum yields. The highest occupied molecular orbital energy levels（EHMH＇s） slightly enhance and the lowest unoccupied molecular orbital energy levels（ELuMo＇S） gently depress with the increase of Cz content in the polymers. PL spectra of the polymers display remarkable red shift and broadening with the increase of solvent polarities, indicating significant intramolecular charge transfer（ICT） effect in the polymers. Electroluminescence（EL） spectra of the polymers exhibit a broadening tendency with increasing the content of Cz unit in the polymers. The superior device performances were obtained with the maximum lumhlous efficiency（LEmax） of 5.2 cd/A, the maximum external quantum efficiency（EQEmax） of 4.8% and the Internationale de I＇Eclairage（CIE）（x,y） coordinates of （0.16, 0.17） for PFSO15-Cz10 based on the single-layer device of ITO/PEDOT：PSS/EL/CsF/A1. The results indicate that the efficient bipolar blue light-emitting polyfluorenes are also constructed by Suzuki copolymerization using the monomers in common use.

Blue light-emitting polyfluorenes containing dibenzothiophene-S,S-dioxide unit in alkyl side chain

Blue light-emitting polyfluorenes containing dibenzothiophene-S,S-dioxide(SO) unit in alkyl side chain(PF-FSOs and PF-CzSOs) were synthesized. All the polymers show high thermal stability with the decomposition temperatures over400 °C. The highest occupied molecular orbital(HOMO) and the lowest unoccupied molecular orbital(LUMO) energy levels of the copolymer slightly decrease with the increase of SO content in side chain. PL spectra of the polymers show slightly red shift and broadening with the increase of solvent polarities, indicating unremarkable intramolecular charge transfer(ICT) effect in the polymers containing SO unit in alkyl side chain. EL spectra of the polymers are almost unchanged in the current densities from 100 to 400 mA cm.2, indicating the superb EL stability of the resulted polymers. The EL spectra of the copolymers exhibit obvious blue-shift and narrowing with the CIE of(0.18, 0.11) for PF-FSO10 and(0.17, 0.11) for PF-CzSO10, respectively,compared with PF-SO10 containing SO unit in main chain with the CIE of(0.16, 0.17) and PFO with the CIE of(0.18, 0.18).The superior device performances were obtained with the luminous efficiency(LEmax) of 1.17 and 0.68 cd A.1 for PF-FSO15 and PF-CzSO20, respectively, compared with the LEmax of 0.37 cd A.1 for PFO. The results indicate that linking SO unit to alkyl side chain of the polyfluorene is a promising strategy for efficient blue light-emitting polymers.

EFFICIENT WHITE EMITTING COPOLYMERS BASED ON BIPOLAR FLUORENE-co-DIBENZOTHIOPHENE-S,S-DIOXIDE-co-CARBAZOLE BACKBONE

Efficient white light emitting polymers were synthesized based on poly（9,9-dioctylfluorene-co-dibenzothiophene- S,S-dioxide） as blue emitter and a bisphenylamine functionalized 2,1,3-benzothiadiazole （DPABT） as red emitter. It was found that the incorporation of hole-transporting carbazole moiety into polymer main chain could effectively reduce the hole injection barriers, which can lead to distinctly improved charge balance in the emissive layer. Additionally, the hole- transporting carbazole units may form efficient bipolar host with electron-transporting dibenzothiophene-S,S-dioxide units. The white light emitting diodes based on single polymer PFSOCzDPABT showed the maximum luminous efficiency of 3.3 cd/A with the maximum luminance of 10282 cd/m2, and the luminous efficiency showed only 24% roll off at current density of 400 mA/cm2. These Commission Internationale d＇Enclairage （CIE） coordinates of the devices changed slightly with the driving voltages increasing from 8 V to 12 V, and were very close to National Television System Committee （NTSC） standard white light emission of （0.33, 0.33）. The results indicated that the incorporating bipolar host and low band gap DPABT unit was a promising way to achieve efficient single white light emitting copolymers.