Early Neoarchean Magmatic and Paleoproterozoic Metamorphic Events in the Northern North China Craton:SHRIMP Zircon Dating and Hf Isotopes of Archean Rocks from the Miyun Area,Beijing

The Miyun area of Beijing is located in the northern part of the North China Craton （NCC） and includes a variety of Archean granitoids and metamorphic rocks. Magmatic domains in zircon from a tonalite reveal Early Neoarchean （2752±7 Ma） ages show a small range in εHf（t） from 3.1 to 7.4 and tDM1（Hf） from 2742 to 2823 Ma, similar to their U-Pb ages, indicating derivation from a depleted mantle source only a short time prior to crystallization. SHRIMP zircon ages of granite, gneiss, amphibolite and hornblendite in the Miyun area reveal restricted emplacement ages from 2594 to 2496 Ma. They also record metamorphic events at ca. 2.50 Ga, 2.44 Ga and 1.82 Ga, showing a similar evolutionary history to the widely distributed Late Neoarchean rocks in the NCC. Positive eHf（t） values of 1.5 to 5.9, with model ages younger than 3.0 Ga for magmatic zircon domains from these Late Neoarchean intrusive rocks indicate that they are predominantly derived from juvenile crustal sources and suggest that significant crustal growth occurred in the northern NCC during the Neoarchean. Late Paleoproterozoic metamorphism developed widely in the NCC, not only in the Trans-North China Orogen, but also in areas of Eastern and Western Blocks, which suggest that the late Paleoproterozoic was the assembly of different micro-continents, which resulted in the final consolidation to form the NCC, and related to the development of the Paleo-Mesoproterozoic Columbia or Nuna supercontinent.

An Important Spreading Event of the Neo-Tethys Ocean during the Late Jurassic and Early Cretaceous: Evidence from Zircon U-Pb SHRIMP Dating on Diabase in Nagarze, Southern Tibet

Widely distributed in Gyangzê-Chigu area, southern Tibet, NW- and nearly E-W-trending diabase（gabbro）-gabbro diorite dykes are regarded as the product of the large-scale spreading of the late Neo-Tethys Ocean. In order to constrain the emplacement age of these dykes, zircons of two samples from diabases in Nagarzê were dated by using the U-Pb SHRIMP method. Two nearly the same weighted mean ^206pb/^23SU ages were obtained in this paper, which are 134.9±1.8 Ma （MSWD=0.65） and 135.5 ± 2.1 Ma （MSWD=1.40）, respectively. They not only represent the crystallization age of the diabase, but also documented an important spreading event of the Neo-Tethys Ocean during the late Jurassic and early Cretaceous. This dating result is of great significance to reconstruct the temporal framework of the late Neo-Tethys Ocean in the Qinghai-Tibet Plateau.

Zircon SHRIMP U-Pb dating for island arc volcanic rock of Fangniugou area in Yitong region of Jilin Province

Polymetallic iron ore sulphate deposits of marine volcanic rock have been developed in the Fangniugou area,Jilin Province,China,but the division of volcanic ore-bearing strata has not been specifically elucidated and there is disagreement about the division.The sampling and SHRIMP U-Pb zircon dating of volcanic rock for Daheishan in the Fangniugou area and the northeast slope of the Duanjiadian were described.The volcanic rock formation period and recorded the volcanic events in the Daheishan mountains were systematically researched.Two samples of high-precision U-Pb zircon dating were used to represent the volcanic rock fomation period of the Late Silurian.The measured data reflect that multiple volcanic activities occurred during the Middle Silurian,Early Silurian,Middle Ordovician and Silurian,and Late Ordovician,probably matching volcanic events in the Songnan Basin identified from zircon dating.At the same time,it is confirmed that a controversial "conglomerate of Daheishan" did in fact develop in the Late Silurian,and those sections of both the Dazigou and Xinlitun-Taoshan with graptolite had been reversed.

Formation Age of the Sujiagou Komatiites in Western Shandong: Further Constraints from SHRIMP U-Pb Zircon Dating on Granitic Dykes

Komatiites are presented as direct evidence for higher mantle temperatures during the Archean. In the North China Craton, komatiites with spinifex structure have been identified only at one locality, i.e. the Sujiagou area, western Shandong. They were considered as formed during the early Neoarchean mainly based on their association with supracrustal rocks considered to be that age. This study carried out SHRIMP U-Pb zircon dating on metamorphosed trondhjemitic and monzogranitic dykes intruding the Sujiagou komatiites, and they have magmatic zircon ages of 2592 ± 12 Ma and 2586 ± 13 Ma respectively. This provides direct evidence that the komatiites formed during the early Neoarchean.

Zircon SHRIMP U-Pb Ages,Geochemistry and Nd-Hf Isotopes of~1.0 Ga A-Type Felsic Rocks in the Southwestern Yangtze Block,South China:Petrogenesis and Tectonic Implications

The petrogenesis and tectonic affinity of Late Mesoproterozoic igneous rocks in the Yangtze Block are important to understand its tectonic evolution within the context of the Rodinia supercontinent’s reconstruction.Here,we report the SHRIMP zircon U-Pb ages,geochemistry,and Nd-Hf isotopic data for dacite from the Zegu Formation of the Dengxiangying Group in southwestern Yangtze Block.The crystallization age of the Zegu dacite is 1037 Ma.These rocks have relatively high Ga,Zr,Hf,and HREE contents,as well as high(10000×Ga)/Al(2.7-2.9)and FeOt/MgO(3.8-10.5)ratios,showing a geochemical affinity of A-type granitoids.Moreover,they are characterized by negativeεNd(t)(-3.6 to-7.5)and zirconεHf(t)values(-0.3 to-14.4),indicating that they likely generated via partial melting of an ancient continental crust source.The tectonic discriminant diagrams showed that the Zegu dacites have high Y and Nb contents(plotted in the‘within-plate’magmatic rocks field).In conclusion,the geochemistry and isotopic data indicated that the 1037 Ma felsic volcanic rock in the Dengxiangying Group generated during an intra-plate rift basin along a passive margin.Our work thus argues against a Grenvillian orogen’s existence in the Yangtze Block.In view of the subsequent Neoproterozoic subduction-related magmatism in the region,we suggest that the Yangtze Block might have been along the periphery of the Rodinia.

Zircon SHRIMP U-Pb dating of granites from Dulan and the chronological framework of the North Qaidam UHP belt, NW China

Zircon SHRIMP dating of granites from Dulan,east segment of North Qaidam UHP belt shows that they are 406.6±3.5 Ma for Yematan-E,407.3±4.3 and 397±6 Ma for Balijiehatan-W,404.5±4.0 and 397.0±3.7 Ma for Shuiwenzhan-N,380.5±5.0 Ma for Shuiwenzhan-S,382.5±3.6 and 372.5±2.8 Ma for Chachagongma.These granites from Dulan represent the products of the third and fourth periods of Paleozoic magmatism in North Qaidam.Geochemically,the granitoids with metalumious to weak peratuminous are quartz diorite,granodiorite,and granite in composition and mainly belong to calc-alkaline series,a few samples to calc or alkali-calc series.The third period of granites is a rock association of granodiorite+granite,with initial 87Sr/86Sr ratios from 0.7082 to 0.7110 and T2DM model ages from 1.41–1.90 Ga;and the fourth period of granites is a rock association of quartz diorite+granodiorite+granite,with initial 87Sr/86Sr ratios from 0.7072 to 0.7091 and T2DM model ages from 1.07–1.38 Ga.Therefore,the third period of granites has higher initial 87Sr/86Sr ratios and T2DM model ages.On the contrary,the fourth period of granites has Nd(t)values from 0.6 to-3.0,higher than that of the third granite with Nd(t)values-3.2 to-9.3.Thus,the data comparison indicates that the third granites may derive from Paleo-proterzoic continental crust with mantle material whereas the fourth granites may derive from the Meso-proterzoic basalt crust with continental material.Combined with regional geology,we thought that the third granites were formed relative to plate exhumation and the fourth granites to delamination of the lithospheric mantle.

Mineralization Styles and Genesis of the Yinkeng Au-Ag-Pb-Zn-Cu-Mn Polymetallic Orefield, Southern Jiangxi Province, SE China: Evidence from Geology, Fluid Inclusions, Isotopes and Chronology

The Yinkeng orefield in Yudu County,Jiangxi Province,SE China,is a zone of concentrated Au-Ag-Pb-Zn-Cu-Mn polymetallic ores.Based on summing up basic geology and ore geology of the orefieid,the polymetallic deposits in the orefield have been divided into seven major substyles according to their occurring positions and control factors.The ore-forming fluid inclusion styles in the orefield include those of two-phase fluid,liquid CO2-bearing three-phase and daughter mineral-bearing multi-phase.The homogenization temperatures range from 382° to 122℃,falling into five clusters of 370° to 390°,300° to 360°,230° to 300°,210° to 290° and 120° to 200°,and the clusters of 300° to 360°,230° to 300° and 120° to 200° are three major mineralization stages,with fluid salinity peaks from 4.14% to 7.31%,2.07% to 7.31% and 0.53% to 3.90%,respectively.The ore-forming fluids are mainly type of NaCl-H2O with medium to high density （0.74-1.02 g/cm3）,or CO2-bearing NaCl-H2O with medium to low density （0.18-0.79 g/cm3）.The fluid salinity and density both show a decline tendency with decreasing temperature.According to the measurement and calculation of Hand O-isotopic compositions in the quartz of the quartz-sulfide veins,δDV-SMOW of the ore-forming fluid is from-84‰ to-54‰,and δ18OV-SMOW of that is from 6.75‰ to 9.21‰,indicating a magmatic fluid.The δ34SV-CDT of sulfides in the ores fall into two groups,one is from-4.4‰ to 2.2‰ with average of-1.42‰,and the other from 18.8‰ to 21.6‰ with average of 19.8‰.The S-isotopic data shows one peak at-4.4‰ to 2.2‰ （meaning-1.42‰） suggesting a simple magmatic sulfur source.The ore Pbisotopic ratios are 206pb/204pb from 17.817 to 17.983,207pb/204pb from 15.470 to 15.620 and 208pb/204pb from 38.072 to 38.481,indicating characteristics of mantle-derived lead.The data show that the major ore deposits in the orefield have a magmatic-hydrothermal genesis and that the SHRIMP zircon age of the granodiorite porphyry,closely related to the mineralization,is 151.2±4.2 Ma （MSWD =1.3）,which can represent the formation ages of the ores and intrusion rocks.The study aids understanding of the ore-forming processes of the major metallic ore deposits in the orefield.

Diagenetic and Mineralization Age of the Hehuaping Tin-polymetallic Orefield,Hunan Province

The Hehuaping tin deposit is a large deposit found in recent years during geological surveys. The discovered tin deposit includes not only rock-alteration type deposits in fault zones, but also deposits developed in interstratified rupture zones between Devonian carbonate rocks （Qiziqiao Formation） and sandstone （Tiaomajian Formation）. The finding of tin deposits of the latter type has greatly enriched tin-mineralization types in the famous Nanling polymetallic metallogenetic region and may provide us with a new potential orientation for prospecting of tin deposits in the region. It is commonly believed that the forming of the tin deposits in the Nanling region should be related to the Yanshanian instead of Indosinian granitic magmatism. Systematical zircon U-Pb SHRIMP dating in this paper shows that tin mineralizations have endured at least two stages. The early stage should be related to the intrusion of the main body of the Wangxianling granite, which was emplaced during the Indosinian period with a diagenetic and minerafized age of 224.0±1.9 Ma （MSWD=0.54）, and the late stage should be related to the intrusion of Yanshaulan granitic porphyry that took place after 142±3 Ma （MSWD=0.5）.

Zircon U-Pb Age,Geochemical Data:Constraints on the Origin and Tectonic Evolution of the Metamafic Rocks from Longmuco-Shuanghu-Lancang Suture Zone,Tibet

Bulk-rock major and trace elements and zircon U-Pb data are reported for Permian metamafic rocks from Guoganjianan, in the western part of Longmuco-Shuanghu-Lancang suture zone. These results offer new insights into mantle source characteristics and geodynamic setting of Permian ophiolitic fragments. U-Pb isotopic dating using SHRIMP II method reveals that the metamafic rocks were formed at 274.7± 3.9 and 279.8± 3.6 Ma. The metamafic rocks mostly show N-MORB-typed rare earth element patterns and are enrichment in large-ion lithophile elements, indicating that they are probably derived from partial melting of a depleted mantle in a back-arc basin. Our new data, together with recent studied results on Paleozoic ophiolitic fragments suggest the Paleo-Tethys Ocean in Central Qiangtang opened at Cambrian and widened between Ordovician and Devonian. Northward subduction started in the Late Devonian–Early Carboniferous and a back-arc basin developed during Permian.

Petrological, geochemical and chronological constraints for the tectonic setting of the Dongco ophiolite in Tibet

The Dongco ophiolite occurred in the middle-western segment of the Bangong-Nujiang suture zone. The thickness of the ophiolite suite is more than 5 km, which is composed, from bottom to top, of the mantle peridotite, mafic-ultramafic cumulates, basic sills (dykes) and basic lava and tectoni- cally emplaced in Jurassic strata (Mugagongru Group). The Dongco cumulates consist of dunite- troctolite-olivine-gabbro, being a part of DTG series of mafic-ultramafic cumulates. The basic lavas are characterized by being rich in alkali (Na2O+ K2O), TiO2, P2O5 and a LREE-rich type pattern dip- ping right with [La/Yb]=6.94―16.6 as well as a trace elements spider-diagram with normal anomaly of Th, Nb, Ta, Hf. Therefore, the Dongco basic lavas belong to ocean-island basalt (OIB) and dis- tinctly differ from mid-ocean ridge basalt (MORB) and island-arc basalt (IAB) formed in the plate convergence margin. The basic lavas have higher 87Sr/86Sr (0.704363―0.705007), lower 143Nd/144Nd (0.512708―0.512887) and εNd(t ) from +2.7―+5.8, indicating that they derive from a two-components mixing mantle source of depleted mantle (DM) and enriched mantle (EMI). From above it is ready to see that the Dongco ophiolite forms in oceanic island (OIB) where the mantle source is replaced by a large amount of enriched material, therefore it distinctly differs from these ophiolites formed in island-arc and mid-oecan ridge. Newly obtained SHRIMP U-Pb dating for zircon of the cumulate troctolite is 132 ± 3 Ma and whole-rock dating of ^(39)Ar/^(40)Ar for the basalt is 173.4 ± 2.7 Ma and 140.9 ± 2.8 Ma, indicating that the Dongco ophiolite formed at Early Cretaceous and the middle-western segment of the Bangong-Nujiang oceanic basin was still in the developing and evolving period at Early Cretaceous.

Progress and Controversy in the Study of HP-UHP Metamorphic Terranes in the West and Middle Central China Orogen

During the past ten years, various types of HP-UHP metamorphic rocks have been discovered in the South Altyn Tagh, the North Qaidam and the North Qinling （秦岭） in the West and Middle Central China orogen. The UHP rocks, as lentoid bodies in regional gneisses, include eclogite （garnet-bearing pyroxenite）, garnet peridotite and various pelitic or felsic gneisses. There are many records of minerals and microstructures of exsolution indicate the UHP metamorphism, such as coesite （or its pseudomorph）, diamond, exsolution of clinopyroxene/amphibole/＋rutile or rutile＋quartz＋apatite in garnet, exsolution of quartz in omphacite and exsolution of kyanite＋spinel in precursor stishovite.The discovery of microstructure evidence for the presence of precursor stishovite in typical Alrich gneiss from the South Altyn Tagh reveals continental subduction and exhumation to and from a depth of more than 350 km. It is the petrological record of the deepest subduction and exhumation of continental rock in the world. The in situ zircon U-Pb dating using LA-ICP- MS or SHRIMP methods shows that the metamorphic ages of the HP-UHP rocks in the South Altyn Tagh, the North Qaidam and the North Qinling are 475-509, 420--457, and 485-514 Ma, respectively. The metamorphic ages of HP-UHP rocks in the North Qaidam are 20-80 Ma younger than those in the South Altyn Tagh and the North Qinling, and the metamorphic ages do not systematically increase or decrease from the South Altyn Tagh through the North Qaidam to the North Qinling. The absence of time transgressive variety of the metamorphism in the three regions does not support the hypothesis that the HP-UHP rocks in these re. gions form the same HP-UHP metamorphic zone. And the HP-UHP rocks in these regions can not be simply correlated to the collision between the North China plate and the South China plate. At present, the study of the HP-UHP rocks in the West and Middle Central China orogen faces several key issues or challenges, such as： （1） the continental subduction to the mantle depth of stishovite stability field （〉9 GPa） is occasional or universal; （2） the mechanism of exhumation for the continental rocks subducted to the depth of stishovite stability field （〉300 km）; （3） the tectonic setting and geodynamical mechanism of producing the HP-UHP metamorphic zones in the South Altyn Tagh, the North Qaidam and the North Qinling. Further studies aiming at these problems will make important progress not only in metamorphlsm of the HP-UHP rocks in the West and Middle Central China orogen, but also in continen. tal deep subduction and exhumation in solid earth science. It will also contribute to the establishment of the theory of continental deep subduction.