This study was aimed to investigate the effects of hydrothermal aging, propene and SO<sub>2</sub> poisoning on the ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) performance of both...This study was aimed to investigate the effects of hydrothermal aging, propene and SO<sub>2</sub> poisoning on the ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) performance of both Cu-SAPO-34 and Cu-ZSM-5. The catalytic activities of fresh, aged and poisoned samples were tested in ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) of NO<sub>x</sub> conditions. The XRD, TG and N<sub>2</sub>-desorption results showed that the structures of the Cu-SAPO-34 and Cu-ZSM-5 remained intact after 750˚C hydrothermally aged, SO<sub>2</sub> and propene poisoned. After hydrothermal aging at 750˚C for 12 h, the NO reduction performance of Cu-ZSM-5 was significantly reduced at lower temperatures, while that of Cu-SAPO-34 was less affected. Moreover, Cu-SAPO-34 catalyst showed high NO conversion with SO<sub>2</sub> or propene compared to Cu-ZSM-5. However, Cu-ZSM-5 showed a larger drop in catalytic activity with SO<sub>2</sub> or propene compared to Cu-SAPO-34 catalyst. The H<sub>2</sub>-TPR results showed that Cu<sup>2 </sup> ions could be reduced to Cu<sup> </sup> and Cu<sup>0</sup> for Cu-ZSM-5, while no significant transformation of copper species was observed for Cu-SAPO-34. Meanwhile, the UV-vis DRS results showed that CuO species were formed in Cu-ZSM-5, while little changes were observed for the Cu-SAPO-34. Cu-SAPO-34 showed high sulfur and hydrocarbon poison resistance compared to Cu-ZSM-5. In summary, Cu-SAPO-34 with small-pore zeolite showed higher hydrothermal stability and better hydrocarbon and sulfur poison resistant than Cu-ZSM-5 with medium-pore.展开更多
采用BDL粉尘比电阻测定仪、巴柯粒度分析仪和COULTERTM SA 3100TM比表面积分析仪对某燃用准格尔煤电厂飞灰的比电阻、粒度及比表面积进行了分析,研究了烟气中SO3对微细颗粒物导电性能和团聚性能的影响.结果表明:在锅炉额定工况下当烟气...采用BDL粉尘比电阻测定仪、巴柯粒度分析仪和COULTERTM SA 3100TM比表面积分析仪对某燃用准格尔煤电厂飞灰的比电阻、粒度及比表面积进行了分析,研究了烟气中SO3对微细颗粒物导电性能和团聚性能的影响.结果表明:在锅炉额定工况下当烟气中SO3的质量浓度增加约34.3 mg/m3时,飞灰比电阻降低约2个数量级,同时飞灰表面张力减小,黏附力增大,使得微细颗粒团聚为大颗粒,平均粒径增大,比表面积减小,从而使电除尘器效率明显提高.展开更多
文摘This study was aimed to investigate the effects of hydrothermal aging, propene and SO<sub>2</sub> poisoning on the ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) performance of both Cu-SAPO-34 and Cu-ZSM-5. The catalytic activities of fresh, aged and poisoned samples were tested in ammonia-selective catalytic reduction (NH<sub>3</sub>-SCR) of NO<sub>x</sub> conditions. The XRD, TG and N<sub>2</sub>-desorption results showed that the structures of the Cu-SAPO-34 and Cu-ZSM-5 remained intact after 750˚C hydrothermally aged, SO<sub>2</sub> and propene poisoned. After hydrothermal aging at 750˚C for 12 h, the NO reduction performance of Cu-ZSM-5 was significantly reduced at lower temperatures, while that of Cu-SAPO-34 was less affected. Moreover, Cu-SAPO-34 catalyst showed high NO conversion with SO<sub>2</sub> or propene compared to Cu-ZSM-5. However, Cu-ZSM-5 showed a larger drop in catalytic activity with SO<sub>2</sub> or propene compared to Cu-SAPO-34 catalyst. The H<sub>2</sub>-TPR results showed that Cu<sup>2 </sup> ions could be reduced to Cu<sup> </sup> and Cu<sup>0</sup> for Cu-ZSM-5, while no significant transformation of copper species was observed for Cu-SAPO-34. Meanwhile, the UV-vis DRS results showed that CuO species were formed in Cu-ZSM-5, while little changes were observed for the Cu-SAPO-34. Cu-SAPO-34 showed high sulfur and hydrocarbon poison resistance compared to Cu-ZSM-5. In summary, Cu-SAPO-34 with small-pore zeolite showed higher hydrothermal stability and better hydrocarbon and sulfur poison resistant than Cu-ZSM-5 with medium-pore.
基金国家科技支撑计划课题(2012BAA02B02)北京市优秀人才培养资助项目(20140000204400001)+1 种基金National Science and Technology Program of China(2012BAA09B02)Excellent Talents Training Funded Project of Beijing(20140000204400001)
文摘采用BDL粉尘比电阻测定仪、巴柯粒度分析仪和COULTERTM SA 3100TM比表面积分析仪对某燃用准格尔煤电厂飞灰的比电阻、粒度及比表面积进行了分析,研究了烟气中SO3对微细颗粒物导电性能和团聚性能的影响.结果表明:在锅炉额定工况下当烟气中SO3的质量浓度增加约34.3 mg/m3时,飞灰比电阻降低约2个数量级,同时飞灰表面张力减小,黏附力增大,使得微细颗粒团聚为大颗粒,平均粒径增大,比表面积减小,从而使电除尘器效率明显提高.
