In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The...In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The acceleration ability of electrons of SiO2 and ZnS was compared through the variation of emission intensity based on ZnS：Er phosphor during the reverse of polarity of sinusoidal voltage. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result not only demonstrates that parts of primary electron comes from electrode, but electrons in conduction band of SiO2 can be heated to higher energy than that of ZnS.展开更多
The molecular model of Trifluoromethylthiosulphenyl Chloride, CF 3 SSCl, was presented. Ab initio method was used to calculate the structure and Raman and Infrared spectra. The results show that CF 3 ...The molecular model of Trifluoromethylthiosulphenyl Chloride, CF 3 SSCl, was presented. Ab initio method was used to calculate the structure and Raman and Infrared spectra. The results show that CF 3 SSCl possess stereoscopic structure of C 1 symmetry with a torsional angle of 94.2°. The potential energy distribution and isotope replacement methods were applied to determine the vibrational assignment. The vibrational frequencies and corresponding modes of the molecule were obtained. The calculated vibrational frequencies are in good agreement with experiments.展开更多
A novel solid state cathodoluminescence(SSCL) device(the device has a structure of ITO/SiO2/Alq3/SiO2/Al) is fabricated using organic materials as the fluorescent film sandwiched between two SiO2 layers.When alternati...A novel solid state cathodoluminescence(SSCL) device(the device has a structure of ITO/SiO2/Alq3/SiO2/Al) is fabricated using organic materials as the fluorescent film sandwiched between two SiO2 layers.When alternating current(AC) voltage is applied to this device,uniform emissions are observed.When the voltage is 50 V,a longer wavelength emission(522 nm) is obtained,but the shorter wavelength emission(465 nm) is dominant when the voltage is 76 V.The origins of these emissions are discussed.The interface formed between SiO2 and tris-(8-hydroquinoline) aluminum(Alq3) of SSCL device was investigated by using X-ray photoelectron spectroscopy(XPS).Analyses of the XPS spectra reveal a deep diffusion of the indium into the interface.On the other hand,the interaction between indium and Alq3 occurs at the interface and results in the formation of a carbon-oxygen-metal(In or Al) complex in the contact region.This effect causes a luminescence quenching in the SSCL device.展开更多
文摘In layered optimization scheme and solid state cathodoluminescence, silicon oxide plays a very important role in obtaining high energy hot electrons to excite luminescent centers or organic luminescent ma terials. The acceleration ability of electrons of SiO2 and ZnS was compared through the variation of emission intensity based on ZnS：Er phosphor during the reverse of polarity of sinusoidal voltage. The ratio of maximum emission intensity under positive and negative half period is 2.18. This result not only demonstrates that parts of primary electron comes from electrode, but electrons in conduction band of SiO2 can be heated to higher energy than that of ZnS.
文摘The molecular model of Trifluoromethylthiosulphenyl Chloride, CF 3 SSCl, was presented. Ab initio method was used to calculate the structure and Raman and Infrared spectra. The results show that CF 3 SSCl possess stereoscopic structure of C 1 symmetry with a torsional angle of 94.2°. The potential energy distribution and isotope replacement methods were applied to determine the vibrational assignment. The vibrational frequencies and corresponding modes of the molecule were obtained. The calculated vibrational frequencies are in good agreement with experiments.
基金supported by the National Natural Science Foundation of China (Grant No. 60806047)the Natural Science Foundation Project of CQ CSTC (Grant No. 2009BB2237)+1 种基金the Science and Technology of Chongqing Municipal Education Commission (Grant No. KJ080816)the Natural Science Foundation of Chongqing Normal University (Grant Nos. 07XLB015 and 08XLS12)
文摘A novel solid state cathodoluminescence(SSCL) device(the device has a structure of ITO/SiO2/Alq3/SiO2/Al) is fabricated using organic materials as the fluorescent film sandwiched between two SiO2 layers.When alternating current(AC) voltage is applied to this device,uniform emissions are observed.When the voltage is 50 V,a longer wavelength emission(522 nm) is obtained,but the shorter wavelength emission(465 nm) is dominant when the voltage is 76 V.The origins of these emissions are discussed.The interface formed between SiO2 and tris-(8-hydroquinoline) aluminum(Alq3) of SSCL device was investigated by using X-ray photoelectron spectroscopy(XPS).Analyses of the XPS spectra reveal a deep diffusion of the indium into the interface.On the other hand,the interaction between indium and Alq3 occurs at the interface and results in the formation of a carbon-oxygen-metal(In or Al) complex in the contact region.This effect causes a luminescence quenching in the SSCL device.
